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Boosting Alcohol Oxidation Electrocatalysis with Multifactorial Engineered Pd1/Pt Single-Atom Alloy-BiOx Adatoms Surface

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Nano-Micro Letters 2025年第7期17卷 404-417页

作者： Yujia Liao Wen Chen Yutian Ding Lei Xie Qi Yang Qilong Wu Xianglong Liu Jinliang Zhu Renfei Feng Xian-Zhu Fu Shuiping Luo Jing-Li Luo Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service SafetyCollege of Materials Science and EngineeringShenzhen University Department of Chemistry City University of Hong Kong School of Resources Environment and MaterialsMOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsGuangxi University Department of Chemistry Southern University of Science and Technology (SUSTech) Canadian Light Source Inc.

engineering nanomaterials at single-atomic sites could enable unprecedented catalytic properties for broad applications, yet it remains challenging to do so on the surface of multimetallic nanocrystals. Herein, we present the multifactorial engineering（size, shape, phase, and composition） of the fully ordered Pt Bi nanoplates at atomic level, achieving a unique catalyst surface where the face-centered cubic（fcc） Pt edges are modified by the isolated Pd atoms and Bi Ox adatoms. This Pd1/Pt-Bi Ox electrocatalyst exhibits an ultrahigh mass activity of 16.01 A mgPt+Pd-1toward ethanol oxidation in alkaline electrolyte and enables a direct ethanol fuel cell of peak power density of 56.7 mW cm-2. The surrounding Bi Ox adatoms are critical for mitigating CO-poisoning on the Pt surface, and the Pd1/Pt single-atom alloy further facilitates the electrooxidation of CH3CH2OH. This work offers new insights into the rational design and construction of sophisticated catalyst surface at single-atomic sites for highly efficient electrocatalysis.

关键词： Alcohol oxidation Electrocatalysis Fuel cell Intermetallic Single-atom alloy

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2D phosphides heterostructures on titanium microfiltration membrane for enhanced ampere-level current density overall seawater splitting

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Nano Research 2025年第1期18卷 249-259页

作者： Wenjing Dai Xin Wang Yulong Ma Sisi He Ming Chen Zhaohui Yin Shuheng Tian Maolin Wang Shixiang Yu Hang Zhang Yuanzhe Wang Hong Wang Jianxin Li Faming Gao Bowen Cheng Yun Wang Zhen Yin Ding Ma Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization College of Chemical Engineering and Materials ScienceTianjin University of Science and TechnologyTianjin 300457China State Key Laboratory of Biobased Fiber Manufacturing Technology Tianjin University of Science and TechnologyTianjin 300457China Haian Institute of High-Tech Research Nanjing UniversityHaian 226600China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China State Key Laboratory of Separation Membranes and Membrane Processes Separation Membrane Science and Technology International Joint Research CentreTiangong UniversityTianjin 300387China Centre for Catalysis and Clean Energy School of Environment and ScienceGold Coast CampusGriffith UniversitySouthportQueensland 4222Australia

The advancement of direct seawater electrolysis is a significant step towards sustainable hydrogen production,addressing the critical need for renewable energy sources and efficient resource ***,direct seawater electrolysis has to face several challenges posed by the corrosiveness of highly concentrated chloride and the competitive chlorine evolution reaction(ClER).To overcome these issues,we designed a novel NiP_(2)@CoP electrocatalyst on a porous titanium microfiltration(Ti MF)*** obtained bifunctional NiP_(2)@CoP catalyst outperforms the Pt/C and IrO_(2),as evidenced by its low overpotentials of 192 and 425 mV at a current density of 500 mA·cm^(-2) for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in alkaline seawater(1 M KOH+0.5 M NaCl),***,only 231 and 569 mV overpotentials are required at the current density of 1500 mA·cm^(-2) towards HER and OER in alkaline seawater,*** importantly,no ClER was observed,demonstrating its excellent selectivity to *** selection of porous Ti MF membrane as an electrode substrate further enhances the performance by providing a robust structure that promotes the fast generation and release of gas *** promising outcomes obtained with NiP_(2)@CoP catalysts on Ti MF support,therefore,pave the way for the commercial viability of direct seawater electrolysis technologies at industrial-level current densities.

关键词： direct seawater electrolysis porous titanium microfiltration membrane phosphides heterostructures NiP_(2)@CoP electrocatalyst excellent selectivity to oxygen evolution reaction(OER)

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Construction of novel g-C_(3)N_(4)/β-FeOOH Z-Scheme heterostructure photocatalyst modified with carbon quantum dots for efficient degradation of RhB

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Journal of Materials science & technology 2024年第14期181卷 11-19页

作者： Juhua Luo Xing Liu Jieliang Gu Wenjie Zhao Minming Gu Yu Xie School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China Jiangsu Provincial Key Laboratory of Eco-Environmental Materials Yancheng Institute of TechnologyYancheng 224051China College of Environment and Chemical Engineering Nanchang Hangkong UniversityNanchang 330063China

The degradation of organic pollutants using semiconductor photocatalysts is a new ecological approach,but the currently available photocatalysts are not very ***,in order to obtain efficient visible-light photocatalysts,g-C_(3)N_(4)/β-FeOOH-modified carbon quantum dots(CDs)composite photocat-alysts with Z-Scheme charge transfer mechanism were successfully *** phase composition and morphology of the composite were characterized by X-ray diffraction(XRD),scanning electron mi-croscopy(SEM),transmission electron microscopy(TEM),Fourier transform infrared spectrophotometry(FT-IR),and X-ray photoelectron spectroscopy(XPS)*** to the upconversion effect of the CDs,the optical response range of the composite was effectively widened,and the optical utilization rate was *** Z-Scheme heterostructure not only improves the light trapping ability,significantly inhibits charge-carrier complexation,and realizes the spatial separation of redox sites,but also ensures that the photocatalyst maintains a suitable valence-conductivity band position and maintains the strong redox *** addition,CDs have the unique characteristics of electronic storage and transfer,which effectively enhance the quantum separation efficiency of the *** photocatalytic efficiency was measured by degrading rhodamine B(RhB)under visible *** degradation performance was the best when the weight ratio of CDs was 6%,and the RhB solution degradation rate reached 100%in 60 *** unique structure and reliable mechanism provide a way for the development of advanced photocat-alyst.

关键词： Photocatalyst Degradation Visible light g-C_(3)N_(4) Carbon quantum dots

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Bibliometric analysis and scientific trends on perfluorinated and polyfluoroalkyl substances (PFASs) as an emerging pollutant

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Water-Energy Nexus 2024年第1期7卷 187-199页

作者： Guo, Hongan Xing, Meiyan Sun, Xiaojie Liu, Tao Key Laboratory of Yangtze Water Environment for Ministry of Education College of Environmental Science and Engineering Tongji University Shanghai200092 China Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology Guilin University of Technology Guilin541004 China

The persistence, bioaccumulation, and toxicity of perfluorinated and polyfluoroalkyl substances (PFASs), along with their concentrations in the environment and humans, have attracted global attention. However, so far, there have been seldom reports providing a systematical review in the entire field of PFASs research. Therefore, this study summarizes 14,112 relevant publications (2005–2022) and conducts bibliometric analysis using Vosviewer and CiteSpace. The findings offer insights into global PFASs research trends, assisting scientists in establishing their research directions. Unlike traditional literature reviews, this article presents a new method for data collection and analysis that achieves quantitative visualization of the information from the past 18 years in the field of PFASs. Results show a significant increase in global PFASs publications, with China leading in publication output and the US in international collaborations. Author Kurunthachalam Kanna has the highest publication records. Document co-citation clustering and key line analysis identifies four major research areas and landmarks, while betweenness centrality analysis reveals developmental processes. Citation burst analysis finds that PFASs toxicity and monitoring have been hot areas, suggesting the need for greater attention towards the types and levels of PFASs in various environmental media and the removal processes of PFASs responsible for pollution, which may emerge as future research hotspots. © 2024

关键词： Toxicity

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Crystallographic orientation dependence on nanoscale friction behavior of energetic β-HMX crystal

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Friction 2023年第12期11卷 2264-2277页

作者： Ying YIN Hongtao LI Zhihong CAO Binghong LI Qingshan LI Hongtu HE Jiaxin YU Institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621999China Key Laboratory of Testing Technology for Manufacturing Process in Ministry of Education State Key Laboratory of Environment-friendly Energy MaterialsSouthwest University of Science and TechnologyMianyang 621010China

Tribology behaviors of energetic crystals play critical roles in the friction-induced hotspot in highenergy explosive,however,the binder and energetic crystals are not distinguished properly in previous *** this study,for the first time,the nanoscale friction ofβ-octahydro-1,3,5,7-tetranitro1,3,5,7-tetrazocine(β-HMX)crystal is studied with nanoscratch tests under the ramping load *** results show that the nanoscale friction and wear ofβ-HMX crystal,as a typical energetic material,is highly depended on the applied *** friction coefficient ofβ-HMX crystal is initially high when no discernible wear is observed,and then it decreases to a stable value which varies from~0.2 to~0.7,depending on the applied load,scratch direction,and crystal ***β-HMX(011)surfaces show weakly friction and wear anisotropy behavior;in contrast,theβ-HMX(110)surfaces show strongly friction and wear anisotropy behavior where the friction coefficient,critical load for the elastic–plastic deformation transition and plastic–cracking deformation transition,and deformation index at higher normal load are highly depended on the scratch *** analyses indicate the slip system and direction ofβ-HMX surfaces play key roles in determining the nanoscale friction and wear ofβ-HMX *** obtained results can provide deeper insight into the friction and wear of energetic crystal materials.

关键词： β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine(β-HMX) nanoscratch friction wear plastic deformation

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Water-soluble organic matter with various polarities in PM_(2.5) over Xi'an,China:Abundance,functional groups,and light absorption

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Particuology 2024年第1期84卷 281-289页

作者： Xueting Yang Shasha Huang Dan Li Hongmei Xu Yaling Zeng Liu Yang Diwei Wang Ningning Zhang Junji Cao Zhenxing Shen Department of Environmental Science and Engineering Xi'an Jiaotong UniversityXi'an710049China School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhen518055China State Key Laboratory of Loess and Quaternary Geology Institute of Earth EnvironmentChinese Academy of SciencesXi'an710049China

Humic-like substances(HULIS)are a major component of brown carbon and consequently play a major role in climate *** this study,70 PM_(2.5) samples were collected from Xi'an in winter 2019 and summer *** HULIS(HULIS-n),acidic HULIS(HULIS-a),and high-polarity water-soluble organic compounds(HP-WSOC)were analyzed to determine their carbon concentrations and measure their ultraviolet-visible absorption and infrared *** the three components,HULIS-n had the highest carbon content in both winter(3.29±1.45μg m^(-3))and in summer(1.38±1.10μg m^(-3)).The semi-quantitative results for the functional groups revealed that HP-WSOC was rich in carboxylic acids and had high aromaticity in winter,whereas HULIS-n was rich in carboxylic acids in ***,HULJS-a was richer in nitrate esters and saturated aliphatic hydrocarbons in summer than in *** results for specific ultraviolet absorbance(SUVA)and E_(250)/E_(365) revealed that HULIS had higher molecular weight and aromaticity in winter than in ***-n dominated in the total light absorption of HULIS+HP-WSOC in both winter(73.08%)and summer(48.57%).Overall,the results on the carbon content,optical properties,and functional groups of WSOCs with differing polarity can improve un-derstanding of environmental and climatic effects.

关键词： Humic-like substances(HULIS) Aromaticity Fourier-transform infrared(FTIR) spectroscopy Light absorbance

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The iron-based biochar activating chlorite(ClO_(2)^(−))driven by mechanochemical ultrasonic:piecewise kinetics,biomimetic catalytic-mechanism,and novel advanced redox process

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Frontiers of environmental science & engineering 2025年第2期19卷 151-168页

作者： Qihui Xu Qianhui Yang Yuming Xie Lin Hu Zhenghao Fei Hong You School of Chemical and Environmental Engineering Yancheng Teachers UniversityYancheng 224007China State Key Laboratory of Urban Water Resources and Environment Harbin Institute of TechnologyHarbin 150090China School of Marine Science and Technology Harbin Institute of Technology at WeihaiWeihai 264209China

Chlorite(ClO_(2)^(−)or COI)is used to establish the advanced reduction and oxidation process(AROP).The iron/biochar-based particles(iron-based hydrothermal carbon with hinge-like structure,FebHCs,20 mg/L)can be utilized to activate COI(2 mmol/L)to present selective oxidation in removing triphenylmethane derivatives(15 min,90%).The protonation(H+at~102μmol/L level)played a huge role(k-2nd=0.136c-H+−0.014(R^(2)-adj=0.986),and rapp=−0.0876/c-H++1.017(R^(2)-adj=0.996))to boost the generation of the active species(e.g.,high-valent iron oxidizing species(HVI=O)and chlorine dioxide(ClO_(2))).The protonation-coupled electron transfer promoted Fe-substances in Feb/HCs activating COI(the calculated kobs ranging from 0.066−0.285 min^(−1)).The form of ClO_(2) mainly attributed to proton-coupled electron transfer(1e/1H+).The HVI=O was generated from the electron transfer within the coordination ***,carbon particles in FebHCs serve as the bridge for electron *** above roles contribute to the fracture and formation of coordination-induced bonds between Lx-FeII/III and ClO_(2)^(−)at phase interface to form *** ultrasonic(US)cavitation enhanced the mass transfer of active species in bulk solution,and the HVI=O and ClO_(2) attack unsaturated central carbon atoms of triphenylmethane derivatives to initiate selective ***,the scale-up experiment with continuous flow(k values of approximately 0.2 min^(−1),COD removal efficiency of approximately 80%)and the reactor with COMSOL simulation have also proved the applicability of the *** study offers a novel AROP and new insights into correspondingly heterogeneous interface activation mechanisms.

关键词： Chlorite Iron-based biochar Ultrasonic Chlorine dioxide High-valent iron oxidizing species

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A potential threat from biodegradable microplastics: mechanism of cadmium adsorption and desorption in the simulated gastrointestinal environment

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Frontiers of environmental science & engineering 2024年第2期18卷 63-75页

作者： Timing Jiang Xiang Wu Shushan Yuan Changfei Lai Shijie Bian Wenbo Yu Sha Liang Jingping Hu Liang Huang Huabo Duan Yafei Shi Jiakuan Yang School of Environmental Science&Engineering Huazhong University of Science and TechnologyWuhan 430074China School of Resources and Environmental Science Hubei UniversityWuhan 430062China Hubei Provincial Engineering Laboratory for Solid Waste Treatment Disposal and Recycling Wuhan 430074China School of Civil Engineering Architecture and EnvironmentHubei University of TechnologyWuhan 430068China State Key Laboratory of Coal Combustion Huazhong University of Science and TechnologyWuhan 430074China

It has been demonstrated that microplastics (MPs) can accumulate heavy metals from the environment and transfer them into organisms via the food chain. However, adsorption and desorption capacities for biodegradable MPs relative to those for conventional MPs remain poorly understood. In this study, cadmium (Cd(II)) adsorption and desorption characteristics of polylactic acid (PLA), a typical biodegradable MP, were investigated. Two conventional MPs, i.e., polypropylene (PP) and polyamide (PA) were used for comparison. The maximum Cd(II) adsorption capacities of the MPs studied in the adsorption experiments decreased in the order PA (0.96 ± 0.07 mg/g) > PLA (0.64 ± 0.04 mg/g) > PP (0.22 ± 0.03 mg/g). The Pseudo-second-order kinetic model and Freundlich isothermal model described the Cd(II) adsorption behaviors of PLA MPs well. X-ray photoelectron spectroscopy and two-dimensional Fourier transform infrared correlation spectroscopy analysis indicated that oxygen functional groups were the major and preferential binding sites of PLA MPs, which contributed to their high Cd(II) adsorption capacities. Simulated gastric and intestinal fluids both significantly enhanced the desorption capacities of the examined MPs. Notably, degradation of the PLA MPs during in vitro human digestion made the Cd(II) on the PLA MPs more bioaccessible (19% in the gastric phase and 62% in the intestinal phase) than Cd(II) on the PP and PA MPs. These results indicate the remarkable capacities of biodegradable MPs to accumulate Cd(II) and transfer it to the digestive system and show that biodegradable MPs might pose more severe threats to human health than conventional nonbiodegradable MPs.

关键词： Biodegradable microplastics Cadmium Adsorption and desorption Gastrointestinal environment Two-dimensional correlation spectroscopy Bioaccessibility

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Tuning interfacial charge transfer for efficient visible-light-driven photodegradation and simultaneous H_(2)evolution

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Journal of Materials science & technology 2024年第1期168卷 35-49页

作者： Zhiyang Li Yaogang Chen Yinghe Zhang Wei Ai Qian Lei Tingjun Yao Dan Zhong Wenjie Liu Wenbiao Jin Lei Yang State Key Laboratory of Urban Water Resource and Environment Shenzhen Key Laboratory of Organic Pollution Prevention and ControlSchool of Civil and Environmental EngineeringHarbin Institute of Technology ShenzhenShenzhen 518055China Key Laboratory of Northwest Water Resources Environment and EcologyMinistry of EducationSchool of Environmental and Municipal EngineeringXi’an University of Architecture and TechnologyXi’an 710055China CNAS Accredited Test Center Guangdong Engineering Technology Research Center of Air PurificationHealthlead Co.Ltd.Shenzhen 518055China School of Science Harbin Institute of Technology ShenzhenShenzhen 518055China

The edge-graphitized carbon nitride(C_(3)N_(4)-C g)was prepared by secondary pyrolysis to construct ZnO/C_(3)N_(4)-C g(ZCN)type-Ⅱheterojunction photocatalyst via a facile sonication dispersion method,which achieved∼7.04-fold and∼18.3-fold enhanced visible-light-driven photocatalytic performance for refrac-tory micropollutant removal and simultaneous hydrogen(H_(2))evolution respectively compared to con-ventional ZnO/g-C_(3)N_(4)Step-scheme *** apparent quantum efficiency of the ZCN_(0.4)het-erojunction reaches 0.92%(λ=420 nm).Such excellent performance stems from that the edge-graphene moieties stitched onto the interface of heterojunction extend light absorption to the full visible spec-trum,meanwhile,the built-in electric field generated during Fermi level alignment accompanying fa-vorable band-bending structure provides an effective pathway for the rapid migration of photoinduced electrons via the edge graphene channel to improve interfacial charge separation ***,the midgap states introduced in ZCN heterojunction could temporarily retain photoexcited electrons to effectively inhibit the in situ carrier recombination for improved photocatalytic H_(2)***,ZCN/peroxymonosulfate system exhibited excellent anti-interference performance against complex water bodies under visible illumination due to the synergistic effect between the co-existing anions and organic ***,the eco-friendly nature of the ZCN/peroxymonosulfate system showed no biotoxicity of reaction filtrate on cell proliferation after treatment,which avoided secondary ***-ering the outstanding performance in photocatalysis,the ZCN system exhibits broad potential for practical applications in water pollution control and green energy production.

关键词： ZnO C_(3)N_(4)-C g Heterojunction Photodegradation Hydrogen evolution

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Investigating the effect of volatility on the hygroscopicities of acetate nanoparticle aerosols by surface plasmon resonance microscopy

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Journal of environmental sciences 2024年第4期138卷 167-178页

作者： Bo Yang Zhibo Xie Jianguo Liu Huaqiao Gui Jiaoshi Zhang Xiuli Wei Zetao Fan Douguo Zhang Key Laboratory of Environmental Optics and Technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China CAS Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Advanced Laser Technology Laboratory of Anhui Province Department of Optics and Optical EngineeringUniversity of Science and Technology of ChinaHefei 230026China

Under high relative humidity(RH)conditions,the release of volatile components(such as acetate)has a significant impact on the aerosol *** this work,one surface plasmon resonance microscopy(SPRM)measurement system was introduced to determine the hygroscopic growth factors(GFs)of three acetate aerosols separately or mixed with glucose at different *** Ca(CH_(3)COO)_(2) or Mg(CH_(3)COO)_(2) aerosols,the hygroscopic growth trend of each time was lower than that of the previous time in three cyclic humidification from 70% RH to 90% RH,which may be due to the volatility of acetic acid leading to the formation of insoluble hydroxide(Ca(OH)_(2) or Mg(OH)_(2))under high RH *** the third calculated GF(using the Zdanovskii-Stokes-Robinson method)for Ca(CH_(3)COO)_(2) or Mg(CH_(3)COO)_(2) in bicomponent aerosols with 1:1 mass ratio were 3.20% or 5.33% lower than that of the first calculated GF at 90% *** calculated results also showed that the hygroscopicity change of bicomponent aerosol was negatively correlated with glucose content,especially when the mass ratio of Mg(CH_(3)COO)_(2) to glucose was 1:2,the GF at 90% RH only decreased by4.67% after three cyclic *** coupled plasma atomic emission spectrum(ICP-AES)based measurements also indicated that the changes of Mg^(2+)concentration in bicomponent was lower than that of the *** results of this study reveal thatduring the efflorescence transitions of atmospheric nanoparticles,the organic acids diffusion rate may be inhibited by the coating effect of neutral organic components,and the particles aging cycle will be prolonged.

关键词： Hygroscopic growth Volatility Acetate aerosols Nanoparticle aerosol Surface plasmon resonance

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