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One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature

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Chinese Chemical Letters 2024年第11期35卷 486-491页

作者： Tao Tang Chen Li Sipu Li Zhong Qiu Tianqi Yang Beirong Ye Shaojun Shi Chunyang Wu Feng Cao Xinhui Xia Minghua Chen Xinqi Liang Xinping He Xin Liu Yongqi Zhang Institute of Fundamental and Frontier Science University of Electronic Science and Technology of ChinaChengdu 611731China Department of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China College of Materials Science&Engineering Zhejiang University of TechnologyHangzhou 310014China School of Chemistry and Materials Engineering Changshu Institute of TechnologyChangshu 215500China State Key Laboratory of Electronic Thin Film and Integrated Devices University of Electronic Science and Technology of ChinaChengdu 611731China Department of Engineering Technology Huzhou CollegeHuzhou 313000China Key Laboratory of Engineering Dielectric and Applications(Ministry of Education) School of Electrical and Electronic EngineeringHarbin University of Science and TechnologyHarbin 150080China State Key Laboratory of Photocatalysis on Energy and Environment Fuzhou UniversityFuzhou 350116China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China

Highly active transition metal nitrides are desirable for electrocatalytic reactions,but their long-term stability is still unsatisfactory and thus limiting commercial ***,for the first time,we report a unique and universal room-temperature urea plasma method for controllable synthesis of N-doped carbon coated metal(Fe,Co,Ni,etc.)nitrides arrays *** preformed metal oxides arrays can be successfully converted into metal nitrides arrays with preserved nanostructures and a thin layer of N-doped carbon(N-C)via one-step urea ***,as a representative case,N-C@CoN nanowire arrays are illustrated and corresponding formation mechanism by plasma is ***,the designed N-C@Co N catalysts deliver excellent electrocatalytic activity and long-term stability both in oxygen evolution reaction(OER)and urea oxidation reaction(UOR).For OER,a low overpotential(264 mV at 10 mA/cm^(2))and high stability(>50 h at 20 mA/cm^(2))are *** UOR,a current density of100 m A/cm^(2) is achieved at only 1.39 V and maintain over 100 *** calculations reveal that the synergetic coupling effect of CoN and N-C can significantly facilitate the charge-transfer process,optimize adsorbed intermediates binding strength and further greatly decrease the energy *** strategy provides a novel method for fabrication of N-C@metal nitrides as highly active and stable catalysts.

关键词： Urea plasma Metal nitrides Carbon shell Oxygen evolution reaction Urea oxidation reaction

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Defects and morphology engineering for constructing V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S nanotube heterojunction arrays toward efficient bifunctional electrocatalyst for overall water splitting

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Journal of Energy Chemistry 2024年第7期94卷 29-40页

作者： Wenyuan Sun Alan Meng Lei Wang Guicun Li Jinfeng Cui Yongkai Sun Zhenjiang Li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Key Laboratory of Optic-electric Sensing and Analytical Chemistryfor Life Science MOE College of Chemistry and Molecular EngineeringQingdao Universityof Science and TechnologyQingdao 266042ShandongChina College of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Qingdao Huanghai University Qingdao 266000ShandongChina College of Electromechanical Engineering Qingdao University of Science and TechnologyQingdao 266061ShandongChina

The development of highly active,stable and inexpensive electrocatalysts for hydrogen production by defects and morphology engineering remains a great ***,S vacancies-rich Ni_(3)S_(2)@Cu_(2)S nan-otube heterojunction arrays were in-situ grown on copper foam(V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF)for efficient electrocatalytic overall water *** the merits of nanotube arrays and efficient electronic mod-ulation drived by the OD vacancy defect and 2D heterojunction defect,the resultant V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF electrocatalyst exhibits excellent electrocatalytic activity with a low overpotential of 47 mV for the hydrogen evolution reaction(HER)at 10 mA cm^(-2) current density,and 263 mV for the oxygen evolution reaction(OER)at 50 mA cm^(-2) current density,as well as a cell voltage of 1.48 V at 10 mA cm^(-2).Moreover,the nanotube heterojunction arrays endows V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF with outstanding stability in long-term catalytic processes,as confirmed by the continuous chronopotentiom-etry tests at current densities of 10 mA cm^(-2) for 100 h.

关键词： Nanotubearrays Heterojunction Vacancy Bifunctional electrocatalyst Overall water splitting

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Polysulfide modified PtCu intermetallic nanocatalyst with enrichment realizes efficient electrooxidation ethanol to CO_(2)

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Nano Research 2024年第4期17卷 2320-2327页

作者： Shuanglong Zhou Zheng Lv Liang Zhao Dan Zhang Zuocao Wang Yu Dai Bin Li Olga Starostenko Jianping Lai Lei Wang Key Laboratory of Eco-chemical Engineering Ministry of EducationTaishan scholar advantage and characteristic discipline team of Eco-chemical process and technologyLaboratory of Inorganic Synthesis and Applied ChemistryCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China College of Foreign Languages Qingdao City UniversityQingdao 266106China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine Kyiv 02160Ukraine Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

The main problem faced by ethanol oxidation reaction(EOR)includes low activity,poor selectivity,and *** the study,we found that polysulfide modified on the surface of PtCu intermetallic(IM)/C can simultaneously enrich hydroxyl and ethanol,which could effectively improve the catalytic activity,CO_(2) selectivity,and durability of *** mass activity and the specific activity of the product in 1 M KOH electrolyte reached 17.83 A·mgPt^(-1) and 24.67 mA·cm^(-2).The CO_(2) selectivity of polysulfide modified product achieved 93.5%,which was 30 folds higher than Pt/*** addition,the catalyst showed high catalytic *** mechanism study demonstrates that the surface modified polysulfide could significantly boost the enrichment effect of ethanol and hydroxyl species,accelerating C–C bond cleavage and CO oxidation.

关键词： Pt CO_(2) selectivity enrichment effect ethanol oxidation reaction(EOR) electrocatalyst

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Unraveling environmental influences on the spatial and temporal dynamics of cyanobacterial blooms in Lake Erhai during its early stage of eutrophication

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地球空间信息科学学报（英文版） 2024年第6期27卷中插14,1989-2007页

作者： Shangbo Yang Jianzhong Lu Xiaoling Chen Xuejiao Hou Zushuai Wei Jinru Wu State Key Laboratory of Information Engineering in Surveying Mappingand Remote SensingWuhan UniversityWuhanChina School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhenChina State Key Laboratory of Information Engineering in Surveying Mappingand Remote SensingWuhan UniversityWuhanChina School of Geospatial Engineering and Science Sun Yat-Sen UniversityGuangzhouChina South China Institute of Environmental Sciences Ministry of Ecology and EnvironmentGuangzhouChina

Lake Erhai,a lake in the early stage of eutrophication,has been threatened by algal blooms(particularly the overproliferation of blue-green algae),which can have an impact on drinking water safety and the lake's *** the governing factors of cyanobacterial blooms is critical for taking timely and effective action during this key eutrophication-transition ***,long-term records of cyanobacterial bloom and its key dominating factors remain *** is,therefore,essential to understand the bloom dynamics and the driving forces before any control strategies can be *** investigated the cyanobacterial phycocyanin concentration variability based on satellite observations from 2003 to 2019,by using the empirical orthogonal function *** observed a decrease in the coverage of the dominant mode of variability in phycocyanin magnitudes compared to the period 2003 to 2011,with variations primarily occurring in the northern *** largest variability was identified to be predominant in July,and an apparent timing shift in variability was observed in December 2016 and *** 95％quantile regression model indicated a distinct upper boundary response in cyanobacteria proliferation to the joint Total Nitrogen(TN)and Total Phosphorus(TP)concentrations,which occurred in summer from 2003 to *** apparent response of cyanobacterial bloom to TP was observed during the winters from 2016 to ***,water level and TN:TP ratio played a central role in summer from 2003 to 2011,while from 2016 to 2019,TN:TP ratio was found to dominate in the summer *** winter,air temperature turned out to be a significant modulating factor compared to water *** results suggest that implementing a phosphorus reduction strategy,while controlling TN:TP ratio and suitable water level manipulation,should be considered to ensure the sustainability of Lake Erhai,especially under a consistent global warming scenario.

关键词： Cyanobacterial phycocyanin concentration spatio-temporal variability nutrient reduction remote sensing

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Catalytic recycling of plastics into value-added products

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Nano Research 2024年第11期17卷 9428-9445页

作者： Tianyu Wei Pengcheng Zhou Wenxian Liu Xijun Liu Tairong Kuang Functional Polymers and Advanced Materials (FPAM) Lab Zhejiang Key Laboratory of Plastic Modification and Processing Technology College of Materials Science and Engineering Zhejiang University of Technology Hangzhou 310014 China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Nonferrous Metals and Featured Materials MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials School of Resources Environment and Materials Guangxi University Nanning 530004 China

The overuse and ineffective management of plastics have led to significant environmental pollution. Catalytic upcycling into value-added chemicals has emerged as a promising solution. This review provides a comprehensive overview of recent advances in catalytic upcycling, focusing on the cleavage of chemical bonds such as carbon-carbon (C-C), carbon-oxygen (C-O), and carbon-hydrogen (C-H) in plastics. It systematically discusses plastics conversion via electrocatalysis, thermal catalysis, and photocatalysis. Additionally, it explores the conversion of plastics into value-added chemicals and functional polymers. The review also addresses the challenges in this field and aims to offer insights for developing sustainable and effective plastics upcycling technologies.

关键词： plastics recycling catalysis chemical recycling value-added chemicals functional polymers

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Pyrometallurgical recycling of spent lithium-ion batteries from conventional roasting to synergistic pyrolysis with organic wastes

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Journal of Energy Chemistry 2023年第10期85卷 547-561,I0014页

作者： Chao Pan Yafei Shen China Energy Science and Technology Research Institute Co.Ltd. Nanjing 210023JiangsuChina Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC) Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044JiangsuChina

The synergistic pyrolysis has been increasingly used for recycling spent lithium-ion batteries(LIBs)and organic wastes(hydrogen and carbon sources),which are in-situ transformed into various reducing agents such as H_(2),CO,and char via carbothermal and/or gas thermal *** with the conventional roasting methods,this“killing two birds with one stone”strategy can not only reduce the cost and energy consumption,but also realize the valorization of organic *** paper concluded the research progress in synergistic pyrolysis recycling of spent LIBs and organic *** the one hand,valued metals such as Li,Co,Ni,and Mn can be recovered through the pyrolysis of the cathode materials with inherent organic materials(e.g.,separator,electrolyte)or graphite *** the pyrolysis process,the organic materials are decomposed into char and gases(e.g.,CO,H_(2),and CH_(4))as reducing agents,while the cathode material is decomposed and then converted into Li_(2)CO_(3) and low-valent transition metals or their oxides via in-situ thermal *** formed Li_(2)CO_(3) can be easily recovered by the water leaching process,while the formed transition metals or their oxides(e.g.,Co,CoO,Ni,MnO,etc.)can be recovered by the reductant-free acid leaching or magnetic separation *** the other hand,organic wastes(e.g.,biomass,plastics,etc.)as abundant hydrogen and carbon sources can be converted into gas(e.g.,H_(2),CO,etc.)and char via *** cathode materials are decomposed and subsequently reduced by the pyrolysis gas and *** addition,the pyrolysis oil and gas can be upgraded by catalytic reforming with the active metals derived from cathode ***,great challenges are proposed to promote this promising technology in the industrial applications.

关键词： Synergistic pyrolysis Spent LIBs Biomass Recycling Reduction roasting

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Assessment of nitrous oxide emission from mariculture of marine fish and crustaceans in China,2003–2022

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Acta Oceanologica Sinica 2024年第12期43卷 58-65页

作者： Guizhu Liang Yuqing Wang Tao Zhang Zhiqiang Liu Ziru Yin Jiaru Li Yufeng Zhang Ying Liu College of Marine Technology and Environment Dalian Ocean UniversityDalian 116023China Key Laboratory of Environment Controlled Aquaculture Ministry of EducationDalian 116023China State Environmental Protection Key Laboratory of Coastal Ecosystem Dalian 116023China College of Biosystems Engineering and Food Science Zhejiang UniversityHangzhou 310058China

Aquaculture,as the fastest-growing food production sector in the world,is becoming an increasingly nonnegligible source of greenhouse gas *** this,there has been limited research on nitrous oxide(N_(2)O)emission from marine aquaculture in China,where more marine aquaculture occurs than anywhere else,*** estimated N_(2)O emissions(E)from marine mariculture of 10 fish and 6 crustacean species in China from 2003 to 2022 using production data from the China Fishery Statistical Yearbook(2004–2023),and data for feed conversion rates and types from the *** 2003,marine aquaculture production,the annual N_(2)O emissions(E_(A)),and the annual N_(2)O emissions per unit of aquaculture area(EI_(A))trend *** E_(A)of fish culture was lower than that of crustaceans,but the EI_(A)of fish culture was generally *** bass(0.308 Tg/a,in terms of N)and white shrimp(0.945 Tg/a,in terms of N)had the highest average E_(A)among fish and crustacean cultures,*** highest average E_(A)from fish and crustacean were both Guangdong Province(fish:0.248 Tg,crustacean:0.547 Tg),and the highest sea area were both the South China Sea(fish:0.316 Tg,crustacean:1.082 Tg);the highest average EI_(A)for fish and crustacean were Tianjin City[35.40 t/(hm^(2)·a)]and Guangxi Zhuang Autonomous Region[19.83 t/(hm^(2)·a)],respectively,and the highest sea areas were both the South China Sea(fish:0.316 Tg,crustacean:1.082 Tg).These analyses provide baseline data for a greenhouse gas emissions inventory for China,based on an interpretation of them,we provide recommendations for reducing N_(2)O emissions in marine fish and crustacean culture.

关键词： marine aquaculture fish crustacean nitrous oxide emission

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Constructing seasonal records of Ross Ice Shelf elevation changes using ICESat altimetry data

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Geodesy and Geodynamics 2025年第3期16卷 331-340页

作者： Lexian Yuan Shengkai Zhang Feng Xiao Xiao Li Tingguo Lu Hui Luo Fei Li Chinese Antarctic Center of Surveying and Mapping Wuhan University School of Electrical Engineering Naval University of Engineering Key Laboratory of Polar Environment Monitoring and Public Governance (Wuhan University) Ministry of Education State Key Laboratory of Geodesy and Earth's Dynamics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences Institute of Environmental Engineering ETH Zurich Department of Earth and Space Sciences Southern University of Science and Technology

Ice shelves are important passageways for ice sheets flowing into the ocean. Through iceberg calving and basal melting, ice shelves exert considerable influence on the mass balance of the Antarctic Ice Sheet and glacier stability. The Ross Ice Shelf(RIS), the largest body of floating ice on Earth, plays an essential role in any changes in the mass balance of the Antarctic Ice Sheet. The long-term elevation change trend of RIS has been calculated with multiple satellite altimetry in previous studies. However, the seasonal variations were less revealed. Based on crossover analysis and indirect observation adjustments, this study proposed a new method for constructing seasonal records for surface elevation changes in the RIS using ICESat laser altimetry data from 2003 to 2009. The results showed that surface elevation changes exhibited seasonal variations with fluctuations over 20 cm, and the seasonal change characteristics were closely related to the temperature. Interannual variations in RIS surface elevation decreased from 2003 to2009 at a rate of 2 cm/yr. From March 2003 to April 2007, the surface elevation decreased at 3.7 cm/yr;however, after April 2007, the surface elevation increased at 5.5 cm/yr. The more recent stages of surface elevation growth have been influenced by reductions in the summer basal melt, which is related to the decreases in ocean heat content.

关键词： Ross Ice Shelf Elevation change ICESat Seasonal variations Antarctic

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Indoor air particles in research vessel from Shanghai to Antarctic: Characteristics, influencing factors, and potential controlling pathway

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Journal of environmental sciences 2023年第4期126卷 784-793页

作者： Xudong Wu Fange Yue Jiancheng Wang Xiawei Yu Hongwei Liu Weihua Gu Mingming Han Juan Li Zhouqing Xie Anhui Key Laboratory of Polar Environment and Global Change Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Department of Anesthesiology the First Affiliated Hospital of University of Science and Technology of ChinaHefei 230001China Center for Excellence in Urban Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China

Despite millions of seafarers and passengers staying on ships each year, few studies have been conducted on the indoor air quality inside ship hulls. In this study, we investigated the levels and size distribution of indoor particulate matter during two cruises of the research vessel “Xuelong” from Shanghai to Antarctica. The results showed that the particle size less than 2.5 μm(PM_(2.5)), and particle size less than 10 μm(PM_(10)) concentrations in different rooms of the ship widely varied. We observed high particulate matter(PM) levels in some of the rooms. The mass concentration distribution was dominated by 1–4 μm particles, which may have been caused by the hygroscopic growth of fine particles. The dominant factors influencing PM concentrations were indoor temperature, relative humidity, and human activity. We quantified contributions of these factors to the levels of indoor particles using a generalized additive model. In clean rooms, the levels of indoor particles were controlled by temperature and relative humidity, whereas in polluted rooms, the levels of indoor particles were mainly influenced by temperature and human activity, which implied that controlling temperature and human activity would efficiently reduce the levels of indoor particles.

关键词： Indoor air Ship Influencing factor Generalized additive model(GAM) Quantification Controlling pathway

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Exploring formation mechanism and source attribution of ozone during the 2019 Wuhan Military World Games:Implications for ozone control strategies

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Journal of environmental sciences 2024年第2期136卷 400-411页

作者： Lei Zhang Lili Wang Runyu Wang Nan Chen Yuan Yang Ke Li Jie Sun Dan Yao Yuesi Wang Minghui Tao Yang Sun Institute of Atmospheric Physics Chinese Academy of SciencesBeijing 100029China University of the Chinese Academy of Sciences Beijing 100049China Hubei Ecological Environment Monitoring Center Station Wuhan 430072China Guizhou Research and Designing Institute of Environmental Sciences Guizhou Academy of Environmental Science and DesignGuiyang 550081China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China School of Environment Key Laboratory for Yellow River and Huai River Water Environment and Pollution ControlMinistry of EducationHenan Normal UniversityXinxiang 453007China Key Laboratory of Regional Ecology and Environmental Change School of Geography and Information EngineeringChina University of GeosciencesWuhan 430074China

A series of emission reduction measures were conducted in Wuhan,Central China,to ensure good air quality during the 7th Military World Games(MWG)in October *** better understand the implications for ozone(O_(3))pollution control strategies,we applied integrated analysis approaches based on the de-weathered statistical model,parameterization methods,chemical box model,and positive matrix factorization *** the MWG,concentrations of O_(3),NO_x,and volatile organic compound(VOCs),OFP(O_(3)formation potential),L_(OH)(OH radical loss rate)were 83μg/m^(3),43μg/m^(3),26 ppbv,188μg/m^(3),and 3.9 s^(-1),respectively,which were 26%,18%,3%,15%,and 13%lower than pre-MWG values and 6%,39%,30%,33%,and 50%lower than post-MWG values,*** removing meteorological influence,O_(3)and its precursors during the MWG decreased largely compared with post-MWG values,and only O_(3),NO_(2),and oxygenated VOCs(OVOCs)declined compared with pre-MWG values,which revealed the emission reduction measures during the MWG played an important role for O_(3)*** six VOCs sources,the mass contributions of biomass burning and solvents usage during the MWG decreased largely compared with pre-MWG values.O_(3)production was sensitive to VOCs and the key species were aromatics,OVOCs,and alkenes,which originated mainly from solvents usage,biomass burning,industrial-related combustion,and vehicle *** O_(3)concentration during the strict control was mainly caused by OVOCs reduction due to biomass burning ***,the O_(3)abatement strategies of Wuhan should be focused on the mitigation of high-reactivity VOCs.

关键词： VOCs Ozone Wuhan Military World Games Source apportionment Relative incremental reactivity Random forest

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