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Dual-function photoelectrode of TiO_(2)nanotube array/CdZnS/ZnS heterojunction for efficient photoelectrochemical cathodic protection and anti-biofouling

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Journal of Materials science & technology 2024年第22期189卷 25-36页

作者： Feng Qian Jing Tian Chongqing Guo Li Liu Shiqiang Chen Jiarun Li Ning Wang Lei Wang School of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042China Institute of Marine Science and Technology Shandong UniversityQingdao 266237China Key Laboratory of Marine Environmental Corrosion and Bio-fouling Institute of OceanologyChinese Academy of SciencesQingdao 266071China College of Chemical Engineering Qingdao University of Science and TechnologyQingdao 266042China

The low photoelectric conversion efficiency of photoelectrode is an important factor that limits the application in photoelectrochemical cathodic protection(PECCP)field for marine anti-corrosion of metallic *** this work,a photoelectrode of TiO_(2)/CdZnS/ZnS triple-phase heterojunction was fabricated by loading the narrow-band CdZnS associated with the broad-band ZnS via hydrothermal and continuous ion layer adsorption methods,*** composite of CdZnS enhances the photoelectric conversion ability of TiO_(2),while the ZnS composite can prevent the CdZnS from photo-corrosion and suppress the spillover of the photogenerated *** three-phase heterostructure effectively improves the PECCP performance on 316 L stainless steel(SS)under simulated solar irradiation,especially in 3.5 wt%NaCl solution without the sacrificial *** addition,the prepared TiO_(2)/CdZnS/ZnS photoelectrode also performs anti-biofouling effect evidenced by the high removal efficiency of Pseudomonas aeruginosa(***),which can be attributed to the oxidizability of photogenerated *** TiO_(2)/CdZnS/ZnS triple-phase heterojunction with desirable performance is a promising semiconductor material for the applications of PECCP and anti-biofouling.

关键词： Photoelectrochemical cathodic protection Anti-corrosion TiO_(2)/CdZnS/ZnS Anti-biofouling P.aeruginosa

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An effective strategy of constructing multi-metallic oxides of ZnO/ CoNiO_(2)/CoO/C microflowers for improved supercapacitive performance

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Chinese Journal of Chemical engineering 2024年第3期67卷 1-8页

作者： Wei Guo Yan Zhang Xiaxin Lei Shuang Wang College of Physics Taiyuan University of TechnologyJinzhong 030600China College of Environmental Science and Engineering Taiyuan University of TechnologyJinzhong 030600China Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization Taiyuan University of TechnologyTaiyuan 030024China

In this work,a new ZnO/CoNiO_(2)/CoO/C metal oxides composite is prepared by cost-effective hydrothermal method coupled with annealing process under N_(2) ***,the oxidation-defect annealing environment is conducive to both morphology and component of the composite,which flower-like ZnO/CoNiO_(2)/CoO/C is *** from good chemical stability of ZnO,high energy capacity of CoNiO_(2) and CoO and good conductivity of C,the as-prepared sample shows promising electrochemical behavior,including the specific capacity of 1435 C·g^(-1) at 1 A·g^(-1),capacity retention of 87.3%at 20 A·g^(-1),and cycling stability of 90.5%for 3000 cycles at 5 A·g^(-1),***,the prepared ZnO/CoNiO_(2)/CoO/C/NF//AC aqueous hybrid supercapacitors device delivers the best specific energy of 55.9 W·h·kg^(-1) at 850 W·kg^(-1).The results reflect that the as-prepared ZnO/CoNiO_(2)/CoO/C microflowers are considered as high performance electrode materials for supercapacitor,and the strategy mentioned in this paper is benefit to prepare mixed metal oxides composite for energy conversion and storage.

关键词： Composites Electrochemistry Hydrothermal Transition metal oxides Structural control Supercapacitors

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Advanced modeling of the absorption enhancement of black carbon particles in chamber experiments by considering the morphology and coating thickness

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Frontiers of environmental science & engineering 2024年第9期18卷 129-142页

作者： Xiaodong Wei Jianlin Hu Chao Liu Xiaodong Xie Junjie Yin Song Guo Min Hu Jianfei Peng Huijun Wang Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters Key Laboratory of Meteorological Disaster(Ministry of Education)Nanjing University of Information Science and TechnologyNanjing 210044China Nansen−Zhu International Research Centre Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China East China Air Traffic Management Bureau CAAC Shanghai 200335China State Key Joint Laboratory of Environmental Simulation and Pollution Control International Joint Laboratory for Regional Pollution Control(IJRC)(Ministry of Education)College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Tianjin Key Laboratory of Urban Transport Emission Research&State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control College of Environmental Science and EngineeringNankai UniversityTianjin 300071China

Measurements studies have shown that the absorption of radiation by black carbon(BC)increases as the particles ***,there are significant discrepancies between the measured and modeled absorption enhancement(E_(abs)),largely due to the simplifications used in modeling the mixing states and shape *** took advantage of chamber experiments on BC aging and developed an efficient method to resolve the particle shape based on the relationship between the coating fraction(ΔD_(ve)/D_(ve),0)and fractal dimension(D_(f)),which can also reflect the variations of D_(f)during the whole BC aging *** with externally and partly mixed states(0≤ΔD_(ve)/D_(ve),0≤0.5)can be considered to be uniformly distributed with the D_(f)values of 1.8–2.1,whereas the Df values are constrained in the range 2.2–2.8 for fully mixed states(ΔD_(ve)/D_(ve),0>0.5).The morphological parameters(i.e.,the effective density and the dynamic shape factor)were compared with the measured values to verify the simulated *** simulated mean deviations of morphological parameters were smaller than 8%for the method resolving the particle *** applying a realistic shape and refractive index,the mass absorption cross for fully mixed states can be improved by 11%compared with a simplified core–shell *** on our understanding of the influence of D_(f)andΔD_(ve)/D_(ve),0 on E_(abs),we propose a two-stage calibration equation to correct the E_(abs)values estimated by the core–shell model,which reduces the simulation error in the Mie calculation by 6%–14%.

关键词： Black carbon Mixing states Fractal dimension Dynamic shape factor Absorption enhancement

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Early Triassic Legoupil Formation in Schmidt Peninsula,Antarctic Peninsula:Provenance and Depositional Settings

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Journal of Earth science 2024年第2期35卷 317-331页

作者： Chao Zhang Ying-Chun Cui Chen-Guang Liu Fang-Hua Cui Lu-Yuan Wang Wei-Qiang Zhang School of Resources and Environmental Engineering Shandong University of TechnologyZibo255049China MNR Key Laboratory for Polar Science Polar Research Institute of ChinaShanghai201209China Key Laboratory of Marine Sedimentology and Environmental Geology First Institute of OceanographyState Oceanic AdministrationQingdao266061China Laboratory for Marine Geology Qingdao National Laboratory for Marine Science and TechnologyQingdao266061China Key Laboratory of Mineral Resources Evaluation in Northeast Asia Ministry of Land and ResourcesChangchun130061China

Geochemical compositions can be used to determine the tectonic setting of sedimentary basins,while where the link of source to sink is no longer preserved,detrital zircon age patterns can aid in resolving the original basin *** metasedimentary Legoupil Formation,located at Cape Legoupil and the Schmidt Peninsula,could give a hint for the tectonic evolution of Antarctic *** this contribution,we constrain the sedimentary provenance of the Legoupil Formation through geochemistry and detrital zircon U-Pb *** petrography and geochemical features indicate that the provenance of the Legoupil Formation could be felsic *** zircon grains record a steady supply of Permian and Ordovician material into the Legoupil *** youngest concordant zircon ages of 262 Ma suggest that the depositional time of Legoupil Formation is no older than Late *** detrital zircon age spectrum of Legoupil Formation suggests that the Legoupil Formation sediments should be derived from regional sources endemic to western Gondwana prior to its *** with the previous studies,geochemistry and detrital zircons reflect an active continental margin tectonic setting and the detrital zircon spectra of Legoupil Formation are similar to the ones deposited in forearc tectonic setting.

关键词： Schmidt Peninsula Legoupil Formation Trinity Peninsula Group detrital zircons Antarctic Peninsula geochemistry

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Underwater acoustic metamaterials

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National science Review 2023年第6期10卷 258-280页

作者： Erqian Dong Peizheng Cao Jinhu Zhang Sai Zhang Nicholas X.Fang Yu Zhang Key Laboratory of Underwater Acoustic Communication and Marine Information Technology of the Ministry of Education College of Ocean and Earth Sciences Xiamen University State Key Laboratory of Marine Environmental Science Xiamen University School of Physics and Electronic Engineering Jiangsu University Department of Mechanical Engineering Massachusetts Institute of Technology

Acoustic metamaterials have been widely investigated over the past few decades and have realized acoustic parameters that are not achievable using conventional *** demonstrating that locally resonant acoustic metamaterials are capable of acting as subwavelength unit cells,researchers have evaluated the possibility of breaking the classical limitations of the material mass density and bulk *** with theoretical analysis,additive manufacturing and engineering applications,acoustic metamaterials have demonstrated extraordinary capabilities,including negative refraction,cloaking,beam formation and super-resolution *** to the complexity of impedance boundaries and mode transitions,there are still challenges in freely manipulating acoustic propagation in an underwater *** review summarizes the developments in underwater acoustic metamaterials over the past 20 years,which include underwater acoustic invisibility cloaking,underwater beam formation,underwater metasurfaces and phase engineering,underwater topological acoustics and underwater acoustic metamaterial *** the evolution of underwater metamaterials and the timeline of scientific advances,underwater acoustic metamaterials have demonstrated exciting applications in underwater resource development,target recognition,imaging,noise reduction,navigation and communication.

关键词： underwater acoustic metamaterials invisibility cloaking beam formation topological acoustics metasurfaces absorbers

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Photo-enhanced uranium recovery from spent fuel reprocessing wastewater via S-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3) heterojunctions

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SusMat 2024年第2期4卷 41-50页

作者： Qi Meng Linzhen Wu Xiaoyong Yang Ying Xiong Fanpeng Kong Tao Duan State Key Laboratory of Environment-friendly Energy Materials NuclearWaste and Environmental Safety Key Laboratory of DefenseSouthwest University of Science and TechnologyMianyangSichuanChina MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage Harbin Institute of TechnologyHarbinHeilongjiangChina Department of Materials Science and Engineering KTH Royal Institute of TechnologyStockholmSweden

Re-extracting environmentally transportable hexavalent uranium from wastew-ater produced by spent fuel reprocessing using the photocatalytic technology is a crucial strategy to avoid uranium pollution and recover nuclear fuel strategic ***,we have designed S-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3)heterojunction photocatalysts based on the built-in electric field and the energy band bend-ing theory,and have further revealed the immobilization process of hexavalent uranium conversion into relatively insoluble tetravalent uranium in terms of thermodynamics and *** to the results,the hexavalent uranium removal and recovery ratios in wastewater are as high as 93.38%and 83.58%,***,C_(3)N_(5)/Fe_(2)O_(3)heterojunctions also exhibit satisfactory cat-alytic activity and selectivity even in the presence of excessive impurity cations(including Na^(+),K^(+),Ca^(^(2+)),Mg^(2+),Sr^(2+),and Eu^(3+))or various organics(such as xylene,tributylphosphate,pyridine,tannic acid,citric acid,and oxalic acid).It is believed that this work can provide a potential opportunity for S-scheme heterojunction photocatalysts to re-enrich uranium from spent fuel wastewater.

关键词： nuclear wastewater S-scheme heterostructure uranium recovery

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Graphene reinforced nanoarchitectonics of 3D interconnected magnetic-dielectric frameworks for high-efficient and anti-corrosive microwave absorbers

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Journal of Materials science & technology 2024年第1期168卷 194-207页

作者： Chenchen Liu Xiaofang Feng Shuning Liu Guo Lin Zhongxiang Bai Lingling Wang Ke Zhu Xiulan Li Xiaobo Liu School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu611731China Sichuan Province Engineering Technology Research Center of Novel CN Polymeric Materials Chengdu611731China School of Chemical Engineering Northwest UniversityXi’an710069China Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology School of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou510275China

The combination of high efficiency and environmental stability is vital to promote the commercial appli-cations of microwave absorption(MA)materials,yet remains challenging in the absence of facile ***,we put forward a graphene-reinforced construct approach for one-pot synthesis of 3D intercon-nected magnetic-dielectric frameworks via pre-functionalization and subsequent *** in-teractions among discrete precursors are capable of manipulating the confined growth and interfacial *** enhancements in MA properties are triggered in a straightforward manner us-ing ultralow feeding fractions of graphene oxide *** minimum reflection loss is up to-60.1 dB(99.9999%wave absorption)and the effective absorption bandwidth reaches 5.9 GHz(almost covering the Ku band).Remarkably,based on the optimization by ultralow concentrations of graphene,the as-prepared nanoarchitecture simultaneously integrates strong absorption,broad bandwidth,and low matching *** embedded graphene nanosheets serve as high-speed electron transmission channels and hollow resonance cavities,facilitating multimode attenuations and impedance-matching ***-while,the graphene-reinforced framework suppresses the corrosion of magnetic components,whose cor-rosion rate reduces by an order of *** study provides a simple procedure to boost magnetic-dielectric absorbers for comprehensive MA performances and enhanced corrosion resistance.

关键词： 3D Magnetic-dielectric framework Graphene nanosheet Microwave absorption Anti-corrosion

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A novel hollow flower shaped Cu9S8 antibacterial agent for removing sulfonamide in water environment: effects of composite with magnetic biochar, differential adsorption, and mechanism study

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environmental science and Pollution Research 2024年第54期31卷 62810-62824页

作者： Li, Rui-Peng Hu, Zheng-Rong Wang, Xing Chen, Jun Liu, Qing-Qing Zhao, Ying Zhao, Zhong-Bao Lu, Xu-Lin Zhang, Zhi-Wei Chemical Engineering College Hebei Normal University of Science and Technology Qinhuangdao066600 China Hebei University of Environmental Engineering Hebei Key Laboratory of Agroecological Safety Qinhuangdao066100 China

In this study, hollow nanoflower spherical Cu9S8 and Cu9S8/Fe3O4@BC with adsorption and antibacterial properties was prepared by coprecipitation and solvothermal method, respectively. The adsorption results showed that the Cu9S8 exhibited excellent adsorption performance on sulfonamide antibiotics (SAs), especially for sulfamethoxazole (SMZ). The optimal addition amount of Cu9S8 is 0.2 g, which results in a maximum adsorption capacity of 33.4 mg/g for SMZ within 120 min. The fitting results of adsorption and desorption kinetics and thermodynamics, as well as the conditions such as pH value and ionic strength were compared. It was found that different interactions led to the differential adsorption of SAs by Cu9S8. The desorption experiment further elucidated its adsorption mechanism. The large desorption capacity indicates that SAs on Cu9S8 can be further recovered and treated. The auto-deposition characteristics of Cu9S8 and the hysteresis loop of Cu9S8/Fe3O4@BC were studied to effectively recover Cu9S8 from aquatic environments. Additionally, more than 99% of Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) were exterminated by Cu9S8 and Cu9S8/Fe3O4@BC within 20 min. The above results suggested that the hollow nanoflower spherical Cu9S8 and Cu9S8/Fe3O4@BC composite materials can provide a new strategy for solving pollution problems and waste treatment. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Escherichia coli

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Hydrogel-based catalysts for hydrogen generation by the hydrolysis of B–H compounds under external physical fields

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Journal of Energy Chemistry 2023年第11期86卷 518-535,I0011页

作者： Chunling Qin Wenliu Wu Hassanien Gomaa Shuai Wu Cuihua An Qibo Deng Ning Hu Key Laboratory of Hebei Province on Scale-span Intelligent Equipment Technology School of Mechanical Engineeringand School of Materials Science and EngineeringHebei University of TechnologyTianjin 300401China State Key Laboratory of Reliability and Intelligence Electrical Equipment Hebei University of TechnologyTianjin 300130China Advanced Equipment Research Institute Co. Ltd.Of HEBUTTianjin 300401China

Hydrogen is a popular clean high-energy-density ***,its utilization is limited by the challenges toward low-cost hydrogen production and safe hydrogen ***,these issues can be addressed using promising hydrogen storage materials such as B–H *** stored in B–H compounds can be released by hydrolysis at room temperature,which requires catalysts to increase the rate of the ***,several effective approaches have been developed for hydrogen generation by catalyzing the hydrolysis of B–H *** review summarizes the existing research on the use of nanoparticles loaded on hydrogels as catalysts for the hydrolysis of B–H ***,the factors affecting the hydrolysis rate,such as temperature,p H,reactant concentration,and type of nano particles,were ***,the preparation methods(in situ reduction,one-pot method,template adsorption,etc.)for the hydrogel catalysts and the types of loaded catalysts were ***,the hydrogel catalysts that can respond to magnetic fields,ultrasound fields,optical fields,and other physical fields are ***,the issues and future developments of hydrogel-based catalysts are *** review can inspire deeper investigations and provide guidance for the study of hydrogel catalysts in the field of hydrogen production via hydrolysis.

关键词： Hydrogel Nanoparticlec atalyst B-H compounds Hydrolysis reaction External physical field

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Ozonation of aromatic monomer compounds in water: factors determining reaction outcomes

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Frontiers of environmental science & engineering 2023年第5期17卷 13-25页

作者： Zhe Wang Wenjuan Zhang Zhiwei Wang Jing Chang School of Environmental Science and Safety Engineering Tianjin University of TechnologyTianjin 300384China School of Environmental and Municipal Engineering Tianjin Key Laboratory of Aquatic Science and TechnologyTianjin Chengjian UniversityTianjin 300384China Tianjin Municipal Engineering Design&Research Institute Co. Ltd.Tianjin 300384China

For aromatic monomer compounds (AMCs), ozonation outcomes were usually predicted by the substituents of the benzene ring based on the electron inductive effect. However, the predicted results were occasionally unreliable for complex substituents, and other factors caused concern. In this study, p-chloronitrobenzene (p-CNB) and ibuprofen (IBP) were selected for ozonation. According to the electron inductive theory, p-CNB should be less oxidizable, but the opposite was true. The higher rates of p-CNB were due to various sources of assistance. First, the hydroxyl radical (•OH) contributed 90 % to p-CNB removal at pH 7.0, while its contribution to IBP removal was 50 %. Other contributions came from molecular O3 oxidation. Second, p-CNB achieved 40 % of the total organic carbon (TOC) removal and fewer by-product types and quantities, when compared to the results for IBP. Third, the oxidation of p-CNB started with hydroxyl substitution reactions on the benzene ring;then, the ring opened. However, IBP was initially oxidized mainly on the butane branched chain, with a chain-shortening process occurring before the ring opened. Finally, the degradation pathway of p-CNB was single and consumed fewer oxidants. However, both branches of IBP were attacked simultaneously, and three degradation pathways that relied on more oxidants were proposed. All of these factors were determinants of the rapid removal of p-CNB.

关键词： Ozonation Aromatic compound Oxidizing specie By-product Initial reaction position Degradation pathway

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