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Achieving an ion-homogenizing and corrosion-resisting interface through nitro-coordination chemistry for stable zinc metal anodes

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Journal of Energy Chemistry 2024年第7期94卷 10-18页

作者： Jizhen Wang Long Jiao Qiaoyun Liu Wei Xin Yechen Lei Tian Zhang Leixin Yang Dengkun Shu Shuo Yang Kaihua Li Chenyang Li Chao Yi Hongyuan Bai Yuchao Ma Huan Li Wenjun Zhang Bowen'Cheng schoolof Light Industry Science and Engineering State Key Laboratory of Biobased Fiber Manufacturing TechnologyTianjin Key Laboratory of Pulp and PaperChina Light Industry Key Laboratory of Papermaking and BiorefineryTianjin University of Science&TechnologyTianjin 300457China Department of Materials Science and Engineering &Center of Super-Diamond and Advanced FilmsCity University of Hong Kong83 Tat Chee AvenueHong Kong 999077China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia

Suppression of uncontrollable dendrite growth and water-induced side reactions of Zn metal anodes is crucial for achieving long-lasting cycling stability and facilitating the practical implementations of aqueous Zn-metal *** address these challenges,we report in this study a functional nitro-cellulose interfacial layer(NCIL)on the surface of Zn anodes enlightened by a nitro-coordination chemistry *** NCIL exhibits strong zincophilicity and superior coordination capability with Zn^(2+)due to the highly electronegative and highly nucleophilic nature of the nitro functional *** characteristic facilitates a rapid Zn-ion desolvation process and homogeneous Zn plating,effectively preventing H_(2) evolution and dendrite ***,the negatively charged surface of NCIL acts as a shield,repelling SO_(4)^(2-)anions and inhibiting corrosive reactions on the Zn ***,reversible and stable Zn plating/stripping is achieved for over 5100 h at a current density of 1 mA cm^(-2),which is nearly 30 times longer than that of bare Zn ***,the Zn/V_(2)O_(5) full cells with the functional interface layer deliver a high-capacity retention of 80.3%for over 10,000 cycles at 5 A g^(-1).This research offers valuable insights for the rational development of advanced protective interface layers in order to achieve ultra-long-lifeZnmetal batteries.

关键词： Zinc metal anode Nitro-cellulose interfacial layer Coordination capability Dendrite-free deposition Long-term cycling

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Microstructure evolution and precipitation behavior of Al-Mg-Si alloy during initial aging

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China Foundry 2023年第1期20卷 57-62页

作者： Ya-ya Zheng Bing-hui Luo Wei Xie Wang Li Department of Materials Engineering Hunan University of HumanitiesScience and TechnologyLoudi 417000HunanChina College of Materials Science and Engineering Central South UniversityChangsha 410083China Key Laboratory of Safety Design and Reliability Technology for Engineering Vehicle Changsha University of Science&TechnologyChangsha 410114China

The microstructure evolution and precipitation behavior of Al-Mg-Si alloy during initial aging were studied using hardness testing, conductivity testing, differential scanning calorimetry(DSC), and high resolution transmission electron microscopy(HRTEM). The results show that the precipitation sequence of the Al-Mg-Si alloy during initial aging can be represented as: supersaturated solid solution → spherical Mg/Si clusters → needle-like Guinier Preston(GP) zone → β″. Clusters are completely coherent with the Al matrix. The GP zone with relatively complete independent lattice parameters that differ slightly from the Al matrix parameters, is oriented along the direction of <111>Aland lying on {111}Alplane. The strength of the Al-Mg-Si alloy is greatly enhanced by the threedimensional strain field that exists between the β″ phase and the two {200}Alplanes. After aging at 170 ℃ for 6 h, the hardness reaches the peak of 127 HV and remains for a long time. At this stage, the electrical conductivity keeps relatively stable due to the formation of coherent precipitates(Mg/Si clusters/GP zones) and the reduction in solute atom concentration in the Al matrix. The severe coarsening and decreased number density of the β″ phase during the over-aging stage result in a significant decrease in the hardness.

关键词： Al-Mg-Si alloy precipitation behavior strengthening mechanism strain field β″

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Recent advances in iron-based sulfides electrocatalysts for oxygen and hydrogen evolution reaction

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Chinese Chemical Letters 2024年第1期35卷 181-195页

作者： Jing Mei Yuqing Deng Xiaohong Cheng Xing Wang Qi Wu State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China Hubei Key Laboratory of Pollutant Analysis&Reuse Technology College of Chemistry and Chemical EngineeringHubei Normal UniversityHuangshi 435002China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China

Increasing environmental pollution and shortage of conventional fossil fuels have made it urgent to develop renewable and clean energy sources. Electrocatalytic water splitting, with its abundant raw materials, simple process, and zero carbon emission, is considered one of the most promising processes for producing carbon-neutral hydrogen which has excellent energy conversion efficiency and high gravimetric energy density. Among them, oxygen evolution reaction (OER) electrocatalysts and hydrogen evolution reaction (HER) electrocatalysts are critical to decreasing the intrinsic reaction energy barrier and boosting the hydrogen evolution efficiency. Therefore, it is imperative to develop and design low-cost, highly active, and stable OER and HER electrocatalysts to lower the overpotential and drive the electrocatalytic reactions. Transition metal sulfides, especially iron-based sulfides, have attracted extensive exploration by researchers as a result of its high abundance in the Earth's crust and near-metallic conductivity. Consequently, in this review, we systematically and comprehensively summarize the progress in the application of iron-based sulfides and their composites as OER and HER electrocatalysts in electrocatalysis. Detailed descriptions and illustrations of the special relationships among their composition, structure, and electrocatalytic performance are presented. Finally, this review points out the challenges and future prospects of iron-based sulfides in practical applications for designing and fabricating more promising iron-based sulfide OER and HER electrocatalysts. We believe that iron-based sulfide materials will have a wide range of application prospects as OER and HER electrocatalysts in the future.

关键词： Iron-based sulfides Electrocatalysts Doping Composites Water splitting

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Superior stable high-voltage LiCoO_(2) enabled by modification with a layer of lithiated polyvinylidene fluoride-derived LiF

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Carbon Energy 2024年第10期6卷 28-38页

作者： Qihang Ding Zewen Jiang Kean Chen Hui Li Jingzhe Shi Xinping Ai Dingguo Xia Hubei Key Lab of Electrochemical Power Sources College of Chemistry&Molecular ScienceWuhan UniversityWuhanChina Beijing Key Laboratory of Theory and Technology for Advanced Batteries Materials College of EngineeringPeking UniversityBeijingChina State Key Laboratory of New Textile Materials&Advanced Processing Technologies Wuhan Textile UniversityWuhanChina Wuhan Britain-China School WuhanChina

High-voltage LiCoO_(2) (LCO) can deliver a high capacity and therefore significantly boost the energy density of Li-ion batteries (LIBs). However, its cyclability is still a major problem in terms of commercial applications. Herein, we propose a simple but effective method to greatly improve the high-voltage cyclability of an LCO cathode by constructing a surface LiF modification layer via pyrolysis of the lithiated polyvinylidene fluoride (Li-PVDF) coating under air atmosphere. Benefitting from the good film-forming and strong adhesion ability of Li-PVDF, the thus-obtained LiF layer is uniform, dense, and conformal;therefore, it is capable of acting as a barrier layer to effectively protect the LCO surface from direct exposure to the electrolyte, thus suppressing the interfacial side reactions and surface structure deterioration. Consequently, the high-voltage stability of the LCO electrode is significantly enhanced. Under a high charge cutoff voltage of 4.6 V, the LiF-modified LCO (LiF@LCO) cathode demonstrates a high capacity of 201 mA h g^(−1) at 0.1 C and a stable cycling performance at 0.5 C with 80.5% capacity retention after 700 cycles, outperforming the vast majority of high-voltage LCO cathodes reported so far.

关键词： cycling stability high-voltage LiCoO_(2) LiF layer lithiated polyvinylidene fluoride surface modification

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One Step and In Situ Synthesis of Edible Lubricant-infused Surface Using All-in-one Solution

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Journal of Bionic Engineering 2023年第5期20卷 1879-1890页

作者： Daheng Wang Jinxia Huang Zhiguang Guo State Key Laboratory of Refractories and Metallurgy Wuhan University of Science&TechnologyWuhan430081China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou730000China Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials Hubei UniversityWuhanChina

Edible Lubricant-Infused Surface(ELIS)was fabricated through antisolvent method by adding ethyl oleate(lubricant/antisolvent),ethanol(solvent)and shellac(solute/base layer of ELIS)into an all-in-one solution to in-situ prepare ELIS through single step of solvent *** ELIS comprising sub-micro-to micro-scaled shellac particles shows water and food liquid slippery,transparency,stability against abrasion and lubricant retaining ability against sheer *** all edible material to fabricated ELIS is a more efficient route for application when compared with other Lubricant-Infused Surface(LIS).Traditional fabrication for LIS included steps such as:base layer fabrication,lubricant infusion,excess lubricant removal,UV light treatment and chemical *** method proposed in this article could further simplify the preparation to an all-in-one solution and simplify the synthesis process to only 60-degree ***,Shellac ELIS coating could withstand abrasion and hold performance when compared with other ELIS coatings.

关键词： Bionic Wax particles Edible Hydrophobic Shellac

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Interaction betweenamylose,fattyacid,andβ-lactoglobulinto study multiplebiomacromoleculesself-assemblyandapplication

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Aggregate 2024年第4期5卷 182-198页

作者： Chen Chao Shiqing Huang Cuiping Wang Rong Sun Jinglin Yu Les Copeland Shujun Wang State Key Laboratory of Food Nutrition and Safety School of Food Science and EngineeringTianjin University of Science&TechnologyTianjinChina School of Life and Environmental Sciences The University of SydneySydneyNew South WalesAustralia

New concept for the development of supramolecular assemblies from intricate inter-actions between different classes of biomacromolecules(polysaccharides,proteins and lipids)is yet to come,due to their intrinsic chemical and structural complex-ity and ***,we report an interaction mechanism among multiple biomacromolecules,and the structural and digestive properties of their assemblies using amylose(AM),lauric acid(LA),andβ-lactoglobulin(βLG)as ***,LA,andβLG interact to form a water-soluble ternary complex through van der Waals forces between AM and LA and high affinity binding between AM andβLG,which can further assemble into uniform-sized,semi-crystalline nanospheres under certain thermodynamic *** nanospheres are substantially resis-tant to amylolysis,thus can be well utilized by gut microbiota,including increasing short-chain fatty acid levels and shaping bacterial *** the com-plexation of AM,LA,andβLG and their assemblies from disorder to order,this work offers potential rationale of assemblies for multiple biomacromolecules driven by non-covalent interactions and substantial potentials for supramolecular biomaterials development.

关键词： amylose–lipid–protein complex biomacromolecules gut microbiota multicomponent interaction polymeric nanospheres supramolecular self-assembly

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Novel synthesis of fine γ-AlON powders from the hydrolysis of Al metal

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Journal of Advanced Ceramics 2024年第11期13卷 1872-1880页

作者： Jian Yang Weijie Han Huibing Li Qiming Chen Wentao Xu Youfu Zhou Maochun Hong Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China Key Laboratory of Optoelectronic Materials Chemistry and Physics Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100039China

In this study, fine aluminum oxynitride (γ-AlON) powder was synthesized from a solid-state hydrolysis byproduct for the first time through in-depth research on the hydrolysis of metal Al powder. Hydrolysis begins on the surface of the Al particles, the initial solid-state hydrolysis byproduct is AlOOH and then Al(OH)_(3), and during the reaction stage, a unique core‒shell structure with a hollow outer core composite precursor is formed. Pure-phase AlON powder can be synthesized by utilizing a composite precursor with an appropriate Al_(2)O_(3)/Al ratio (Al_(2)O_(3)/Al = 10.27) under a flowing N_(2) atmosphere. The core‒shell structure decreases the diffusion distance between raw materials and reduces the nitridation temperature (1700 °C). Furthermore, the unique hollow structure of the composite precursor results in some of the synthesized AlON powder also having a hollow structure, which is conducive to powder crushing, and fine nanoscale (D50 = 292 nm) powder can be obtained only via a grinding process. The combination of Al–H_(2)O reaction and direct nitridation (DN) methods has led to the development of a new synthesis method for AlON powder and provides a new method for the recovery of the solid-state hydrolysis byproduct of metal Al powder.

关键词： hydrolysis aluminum oxynitride(y-AlON) core-shell structure Al-H_(2)O reaction

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Tree Ring‑Inspired Fibrous Helix for UV Shielding and Warning Based on Photo‑electricity‑Acoustic Energy Conversion

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Advanced Fiber Materials 2023年第2期5卷 681-693页

作者： Yan Wang Ziyi Guo Jie Xiong Jingchong Liu Yong Zhao Fengyun Guo Key Laboratory of Intelligent Textile and Flexible Interconnection of Zhejiang Province School of Textile Science and Engineering(International Silk Institute)Zhejiang Sci-Tech UniversityHangzhou 310018China Key Laboratory of Bioinspired Intelligent Interface Science and Technology Ministry of Education School of Chemistry Beihang UniversityBeijing 100191China Beijing Key Laboratory for Bioengineering and Sensing Technology Daxing Research InstituteSchool of Chemistry and Biological EngineeringUniversity of Science and Technology BeijingBeijing 100083China

Flexible wearable ultraviolet(UV)shielding,monitoring and warning devices have important applications in civil and mili-tary ***,most flexible wearable UV devices show unsatisfactory performance due to their poor stability and easy failure at large ***,inspired by tree rings,we engineered a hierarchical composite nanofibrous helix with an alternately stacked Archimedes spiral structure via a cost-effective *** on a photo-electricity-acoustic energy conversion system,we fabricated an all-in-one device exhibiting strain-insensitive UV protection at 0–500%strain for UV shielding as well as strain-sensitive UV monitoring at 500–1500%strain for UV early *** with previously reported common nanofibrous membrane devices,the as-prepared composite nanofibrous helix shows great advantages in terms of stability and UV protection,especially at large ***,the helix demonstrates multiple functions of wear resistance,antibacterial properties,biodegradation and *** versatile strategy holds great promise for wearable electronics and multifunctional devices.

关键词： Electrospinning Nanofibrous helix Energy conversion UV shielding and warning Multifunction Flexible electronics

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Rational design of natural leather-based water evaporator for electricity generation and functional applications

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Journal of Energy Chemistry 2024年第9期96卷 129-144页

作者： Bingyuan Zhang Xiaoyu Guan Qingxin Han Haoxiang Guo Sai Zheng Xuhui Sun Afnan H.El-Gowily Mohammed A.Abosheasha Yanxia Zhu Motoki Ueda Meng An Haojun Fan Yoshihiro Ito College of Bioresources Chemical and Materials Engineering Key Laboratory of Auxiliary Chemistry and Technology for Chemical IndustryMinistry of EducationShaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and TechnologyShaanxi University of Science&TechnologyXi'an 710021ShaanxiChina Nano Medical Engineering Laboratory RIKEN Cluster for Pioneering Research2-1 HirosawaWako 351-0198SaitamaJapan Key Laboratory of Leather Chemistry and Engineering(Sichuan University) Ministry of EducationChengdu 610065SichuanChina College of Mechanical and Electrical Engineering Shaanxi University of Science&TechnologyXi'an 710021ShaanxiChina Biochemistry Division Chemistry DepartmentFaculty of ScienceTanta UniversityTanta 31527Egypt

In recent years,water evaporation-induced electricity has attracted a great deal of attention as an emerging green and renewable energy harvesting *** abundant materials have been developed to fabricate hydrovoltaic devices,the limitations of high costs,inconvenient storage and transport,low environmental benefits,and unadaptable shape have restricted their wide ***,an electricity generator driven by water evaporation has been engineered based on natural biomass leather with inherent properties of good moisture permeability,excellent wettability,physicochemical stability,flexibility,and *** numerous nano/microchannels together with rich oxygen-bearing functional groups,the natural leather-based water evaporator,Leather_(Emblic-NPs-SA/CB),could continuously produce electricity even staying outside,achieving a maximum output voltage of∼3 V with six-series ***,the leather-based water evaporator has enormous potential for use as a flexible self-powered electronic floor and seawater demineralizer due to its sensitive pressure sensing ability as well as its excellent photothermal conversion efficiency(96.3%)and thus fast water evaporation rate(2.65 kg m^(−2)h^(−1)).This work offers a new and functional material for the construction of hydrovoltaic devices to harvest the sustained green energy from water evaporation in arbitrary ambient environments,which shows great promise in their widespread applications.

关键词： Energy conversion Water evaporation-induced electricity Functional leather Flexible self-powered sensor Desalination

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Biomimetic,fire-resistant,ultralight and porous carbon fiber sponges enabling safe and efficient remediation of crude oil spills in harsh environments

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Journal of Materials science & technology 2023年第27期158卷 77-85页

作者： Yushan Li Songjun Yao Song Yan Mei Xu Long Zheng Fei Pan Yeqiang Tan Xianze Yin College of Materials Science and Engineering State Key Laboratory of New Textile Materials&Advanced Processing TechnologyWuhan Textile UniversityWuhan 430200China National Local Joint Laboratory for Advanced Textile Processing and Clean Production Wuhan Textile UniversityWuhan 430200China Engineering Research Center of Ministry of Education for Clean Production of Textile Printing and Dyeing Wuhan Textile UniversityWuhan 430200China College of School of Environmental Engineering Wuhan Textile UniversityWuhan 430200China State Key Laboratory of Bio-Fibers and Eco-Textiles Collaborative Innovation Center of Marine Biobased Fiber and Ecological Textile Technology Institute of Marine Biobased MaterialsCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China

Advanced absorbents must meet the requirements of superior hydrophobic/oleophilic behavior,favorable adsorption efficiency,and high photothermal and Joule heating performance to handle frequent crude oil ***,current carbon-based absorbents suffer from poor fire resistance,thus severely limiting their application in harsh ***,inspired by a bird’s nest,a polymer“welding”strategy is proposed to design a versatile absorbent in which the polymer serves as a“binder”to interconnect discontinuous fibers together to form a 3D welded *** continuous conductive networks endow the absorbent with high photothermal and Joule heating effect,thus achieving all-weather adsorption,and improving the adsorption efficiency of crude oil via the self-heating *** with other absorbents,the absorbent prepared via polymer welding technology exhibited preferable comprehensive performance,such as superhydrophobicity,high fire resistance,and high absorption ***,the noninflammable absorbent can restrain the combustion of crude oil,thereby reducing its combustion in case of *** versatile absorbent is expected to provide a promising solution for the safe and effi-cient cleanup of crude oil spills in harsh ***,the unique polymer welding strategy can be developed into a universal strategy for other material systems to expand their applications.

关键词： Polymer welding strategy Photothermal effect Joule heating effect Fire resistance Crude oil recovery

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