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Engineering eg filling of RuO_(2)enables a robust and stable acidic water oxidation

Chinese Chemical Letters 2025年第3期36卷 444-448页

作者： Qing Li Yumei Feng Yingjie Yu Yazhou Chen Yuhua Xie Fang Luo Zehui Yang State Key Laboratory of New Textile Materials&Advanced Processing Technology College of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200China Faculty of Materials Science and Chemistry China University of Geosciences WuhanWuhan 430074China

Efficient and stable electrocatalyst for oxygen evolution reaction(OER)in acidic environment is vital for polymer electrolyte membrane water electrolysis(PEMWE).In this work,we have devised the formation of heterostructured RuO_(2)/MnO_(2)with nanoflower structure for acidic OER *** to commercial RuO_(2),the overpotential at 50mA/cm^(2)is decreased by 36 mV,corresponding to a 3.7-fold better mass *** boosted acidic OER performance is attributed to the heterostructure inducing more electrons are filled in e_(g)orbital of Ru atom triggering a better deprotonation of bridge oxygen atom in Ru-O_(bri)-Mn structure evidenced by pH-independent cyclic voltammetry ***,RuO_(2)/MnO_(2)sustains its acidic OER activity within 20 h,longer than commercial RuO_(2).The membrane electrode assembly(MEA)test suggests than only 2.18 V is required to achieve a current density of 5 A/cm^(2).The theoretical calculation reveals that the e_(g)filling of Ru atom is increased from 2.18 to 2.39 after MnO_(2)incorporation,reducing the energy for the formation of∗OOH moiety.

关键词： Oxygen evolution reaction Polymer electrolyte membrane water electrolysis Deprotonation e_(g)filling Heterostructure

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Scalable graphene foam with ultrahigh conductivity for stabilizing Pt towards efficient hydrogen evolution

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Nano Research 2024年第8期17卷 6968-6976页

作者： Ming Zhao Meng Huang Huihui Jin Dayin He Wei Qian Zixin Zhang Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China School of Information Engineering Wuhan University of TechnologyWuhan 430070China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China

For the carbon-based catalyst to be active and stable,especially in harsh electrochemical environments,the key is to decrease the concentration of defects and raise the degree of graphitization of the carbon ***,we develop a highly graphitized graphene foam with multiplicated structure to fabricate self-supporting Pt-based catalysts for efficient and stable hydrogen evolution reaction(HER)*** foam(GO-2850)is obtained through an ultra-high temperature treatment at 2850℃,with perfect graphene structure and extremely low defect,ensuring high electrical conductivity and corrosion ***,its multiplicated structure provides an inherently favorable environment for the dispersion of Pt nanoparticles(Pt NPs)and offers abundant channels for electrolyte infiltration during the catalytic *** a result,the as-prepared Pt/GO-2850 is far active and stable than the Pt NPs supported on commercial carbon paper(Pt/CP)counterpart toward catalyzing HER,exhibiting an outstanding activity and long-term durability(300 h@10 mA·cm^(−2))in acidic/alkaline/seawater *** can be attributed to the stronger interaction between the lower-defect GO-2850 substrate and Pt,as evidenced by characterization and theoretical *** work extends further insight into the design self-supporting catalysts of high activity and stability with promising prominent application toward green energy devices.

关键词： graphene foam high graphitization Pt nanoparticles hydrogen evolution reaction long-term stability

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Nitrogen doped porous carbon-based bifunctional oxygen electrocatalyst with controllable phosphorus content for zinc-air battery

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Nano Research 2023年第4期16卷 5887-5893页

作者： Shichang Cai Zihan Meng Gaojie Li Yu An Yapeng Cheng Erjun Kan Bo Ouyang Haining Zhang Haolin Tang School of Material Science and Engineering Henan University of TechnologyZhengzhou 450001China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong LaboratoryXianhu Hydrogen ValleyFoshan 528200China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Applied Physics and Institution of Energy and Microstructure Nanjing University of Science and TechnologyNanjing 210094China

The controllable construction of non-noble metal based bifunctional catalysts with high activities towards oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is of great significance,but remains a ***,we reported an effective method to synthesize cobalt-nitrogen doped mesoporous carbon-based bifunctional oxygen electrocatalyst with controllable phosphorus content(Co-N-P_(X)-MC,X=0.5,1.0,1.5,2.0).The mesoporous carbon substrate endowed the asprepared samples with more exposed active surface(236.50 m^(2)·g^(−1))and the most appropriate doping ratio of phosphorus had been investigated to be 1.5(Co-N-P1.5-MC).For ORR,Co-N-P1.5-MC exhibited excellent catalytic activity with more positive onset potential(1.01 V)and half-wave potential(0.84 V)than the other *** OER,Co-N-P1.5-MC also showed a low overpotential of 415 *** experimental results and density-functional theory(DFT)calculations,the outstanding bifunctional catalytic performance of Co-N-P1.5-MC was due to the synergistic cooperation between the P and N dopants,which could reduce the reaction barriers and was favorable for ORR and ***,the Zn-air battery using Co-N-P1.5-MC as the cathode showed remarkable battery performance with high stability(could operate stably for over 160 h at 10 mA·cm^(−2))and maximum power density(119 mW·cm^(−2)),demonstrating its potential for practical *** work could provide significant enlightenment towards the design and construction of bifunctional oxygen electrocatalyst for next-generation electrochemical devices.

关键词： cobalt-nitrogen doped porous carbon phosphorus doping bifunctional electrocatalyst oxygen reduction reaction(ORR)and oxygen evolution reaction(OER) Zn-air battery

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Defects in the grain interiors of 3 mol%yttria-stabilized tetragonal zirconia polycrystal ceramics with 0.25 wt%alumina

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Journal of advanced Ceramics 2024年第4期13卷 469-477页

作者： Yan Xiong Lian Luo Yao Cheng Zhi Liu Qi Liu Weimin Wang Wei Ji School of Materials&Chemical Engineering Hubei Province Key Laboratory of Green Materials for Light IndustryHubei University of TechnologyWuhan 430068China Fujian Institute of Research on the Structure of Mater Chinese Academy of SciencesFuzhou 350002China Jiangxi Provincial Engineering Research Center for Multifunction Zirconia Materials Jiangxi Size Materials Co.Ltd.Jiujiang 332500China State Key Laboratory of Advance Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The presence of high-density defects is rarely observed in bulk 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TZP)ceramics obtained through conventional pressureless *** the present work,fine-grained dense 147 nm 3Y-TZP ceramics were prepared by pressureless sintering of commercial 0.25 wt%alumina-doped zirconia powders at 1300℃.A novel discovery was reported in which large amounts of defects were present in the grain interiors of the *** phenomenon was further examined using three types of powder samples,and the reasons for defect formation were investigated by microstructural characterization using high-resolution transmission electron microscopy(HRTEM)analysis and Rietveld *** results confirmed the essential dependence of the defect formation on the alumina *** authors attributed the defect formation to the significant difference in ionic radii of the solvent and solute during the dissolution of alumina into the zirconia *** sintering kinetics were proposed to be enhanced by the presence of substantial defects,which consequently favored the low-temperature sintering of the alumina-doped zirconia ceramics.

关键词： 3 mol%yttria-stabilized tetragonal zirconia polycrystal(3Y-TzP)ceramics alumina addition microstructure defect

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Design and high-strength origin of novel (CoFeNi)_(80)Ti_(5)V_(15) medium entropy alloy with “fcc + L1_(2) ”structure

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Journal of materials Science & technology 2023年第18期149卷 154-160页

作者： Lei Wang Xinyuan Wu Yuan Wu Gang Liu Zhenhua Han Yunpeng Zhang Yanning Su Shengfeng Kang Jun Shen Guojun Zhang School of Materials Science and Engineering Xi’an University of TechnologyXi’an 710048China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China

*** The multi-component high entropy alloys(HEAs)or medium entropy alloys(MEAs)attract reseachers’extensive attention,in particular,the single-face center cubic(fcc)HEAs or MEAs due to their some advantages,such as excellent ductility[1,2],good corrosion resistance[3]and high radiation tolerance[4].However,their strength is commonly insufficient for engineering ***,many investigations are ongoing to improve their strength by traditional strengthening mechanisms,like fine-grained strengthening[5,6],solid strengthening[6-8],strain strengthening[9],polyphase strengthening[10-12],and precipitation strength-ening[13-15].Among these strengthening mechanisms,the co-herent L1_(2)-type nanoparticles precipitation strengthening has been proven to be a very effective way to improve their strength[13-15].

关键词： strengthening strength alloy

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Defect engineering in molybdenum-based electrode materials for energy storage

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eScience 2022年第3期2卷 278-294页

作者： Weixiao Wang Fangyu Xiong Shaohua Zhu Jinghui Chen Jun Xie Qinyou An State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan528200China

Molybdenum-based materials have stepped into the spotlight as promising electrodes for energy storage systems due to their abundant valence states,low cost,and high theoretical ***,the performance of conventional molybdenum-based electrode materials has been limited by slow diffusion dynamics and deficient *** defect engineering to molybdenum-based electrode materials is a viable method for overcoming these intrinsic limitations to realize superior electrochemical performance for energy ***,we systematically review recent progress in defect engineering for molybdenum-based electrode materials,including vacancy modulation,doping engineering,topochemical substitution,and *** particular,the essential optimization mechanisms of defect engineering in molybdenum-based electrode materials are pre-sented:accelerating ion diffusion,enhancing electron transfer,adjusting potential,and maintaining structural *** also discuss the existing challenges and future objectives for defect engineering in molybdenum-based electrode materials to realize high-energy and high-power energy storage devices.

关键词： Energy storage Molybdenum-based electrode materials Defect engineering

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TiO_(2)/In_(2)S_(3)S-scheme photocatalyst with enhanced H_(2)O_(2)-production activity

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Nano Research 2023年第4期16卷 4506-4514页

作者： Yi Yang Bei Cheng Jiaguo Yu Linxi Wang Wingkei Ho State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of Geosciences388 Lumo RoadWuhan 430074China Department of Science and Environmental Studies The Education University of Hong KongTai PoHong Kong 999077China

Photocatalytic production of hydrogen peroxide(H_(2)O_(2))is an ideal pathway for obtaining solar ***,an S-scheme heterojunction is constructed in hybrid TiO_(2)/In_(2)S_(3)photocatalyst,which greatly promotes the separation of photogenerated carriers to foster efficient H_(2)O_(2)*** composite photocatalysts show a high H_(2)O_(2)yield of 376μmol/(L·h).The mechanism of charge transfer and separation within the S-scheme heterojunction is well studied by computational methods and *** functional theory and in-situ irradiated X-ray photoelectron spectroscopy results reveal distinct features of the S-scheme heterojunction in the TiO_(2)/In_(2)S_(3)hybrids and demonstrate charge transfer *** density functional theory calculation and electron paramagnetic resonance results suggest that O_(2)reduction to H_(2)O_(2)follows stepwise one-electron ***_(2)S_(3)shows a much stronger interaction with O_(2)than TiO_(2)as well as a higher reduction ability,serving as the active sites for H_(2)O_(2)*** work provides a novel design of S-scheme photocatalyst with high H_(2)O_(2)evolution efficiency and mechanistically demonstrates the improved separation of charge carriers.

关键词： step-scheme heterojunction photocatalytic H_(2)O_(2)production TiO_(2)/In_(2)S_(3)nanofibres

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A comprehensive review on Bi_(2)Te_(3)-based thin films: Thermoelectrics and beyond

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Interdisciplinary materials 2022年第1期1卷 88-115页

作者： Xinfeng Tang Ziwei Li Wei Liu ingjie Zhang Ctirad Uher State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina Department of Physics University of MichiganAnn ArborMichiganUSA

Bi_(2)Te_(3)-based materials are not only the most important and widely used room temperature thermoelectric(TE)materials but are also canonical examples of topological insulators in which the topological surface states are protected by the time-reversal ***-performance thin films based on Bi_(2)Te_(3)- have attracted worldwide attention during the past two decades due primarily to their outstanding TE performance as highly efficient TE coolers and as miniature and flexible TE power generators for a variety of electronic ***,intriguing topological phenomena,such as the quantum anomalous Hall effect and topological superconductivity discovered in Bi_(2)Te_(3)-based thin films and heterostructures,have shaped research directions in the field of condensed matter *** Bi_(2)Te_(3)-based films and heterostructures,delicate control of the carrier transport,film composition,and microstructure are prerequisites for successful device operations as well as for experimental verification of exotic topological *** review summarizes the recent progress made in atomic defect engineering,carrier tuning,and band engineering down to a nanoscale regime and how it relates to the growth and fabrication of high-quality Bi_(2)Te_(3)-based *** review also briefly discusses the physical insight into the exciting field of topological phenomena that were so dramatically realized in Bi_(2)Te_(3)-and Bi_(2)Se_(3)‐based *** is expected that Bi_(2)Te_(3)-based thin films and heterostructures will play an ever more prominent role as flexible TE devices collecting and converting low-level(body)heat into electricity for numerous electronic *** is also likely that such films will continue to be a remarkable platform for the realization of novel topological phenomena.

关键词： Bi_(2)Te_(3)-based thin films and heterostructures device applications thermoelectric topological phenomena

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In-situ selective surface engineering of graphene micro-supercapacitor chips

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Nano Research 2022年第2期15卷 1492-1499页

作者： Yiming Chen Minghao Guo Lin Xu Yuyang Cai Xiaocong Tian Xiaobin Liao Zhaoyang Wang Jiashen Meng Xufeng Hong Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China Faculty of Materials Science&Chemistry China University of GeosciencesWuhan 430074China

Surface modification of graphene oxide(GO)is a powerful strategy to develop its energy density for electrochemical energy ***,pre-modified GO always exhibits unsatisfactory hydrophilia and its ink-relevant utilization is extremely *** GO ink is widely utilized in fabricating micro energy storage devices via extrusion-based 3D-printing,simultaneously obtaining satisfactory hydrophilia and high energy density still remains a *** this work,an in-situ surface engineering strategy was employed to enhance the performance of GO micro-supercapacitor *** dimensionally printed GO micro-supercapacitor chips were treated with pyrrole monomer to achieve selective and spontaneous anchoring of polypyrrole on the microelectrodes without affecting interspaces between the finger *** interface-reinforced graphene scaffolds were edge-welded and exhibited a considerably improved specific capacitance,from 13.6 to 128.4 mF·cm^(-2).These results are expected to provide a new method for improving the performance of micro-supercapacitors derived from GO inks and further strengthen the practicability of 3D printing techniques in fabricating energy storage devices.

关键词： 3D-printing in-situ modification selective surface engineering edge-welded graphene micro-supercapacitors

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High micropore-utilization carbon aerogel with controlled nanostructures via adjusting aggregation state of polyacrylonitrile for energy storage systems

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SusMat 2024年第4期4卷 27-38页

作者： Yuanyou Peng Yihan Fu Meimei Yu Lei Zhao Huanzhong Zeng Shengtao Niu Jie Zhang Junlong Chen Guang Liu Youzhi Wu Fen Ran State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Department of Polymeric Materials EngineeringSchool of Material Science and EngineeringLanzhou University of TechnologyLanzhouChina

Designing and optimizing the pore structure of porous carbon electrodes is essen-tial for diverse energy storage *** this study,an innovative approach spray phase-inversion strategy was developed for the rapid and efficient fabri-cation of controlled porous carbon ***,the aggregation structure of polyacrylonitrile is controlled by adjusting the Hansen’s solubility parameter,thereby regulating the electrode material ***,the theoretical analysis of the spray phase-inversion process revealed that this regulation pro-cess is jointly regulated by solvent hydrodynamic diameter and phase-inversion *** optimization,a novel porous carbon material was obtained that exhibited excellent performance as an electrode *** utilized in supercapacitors for energy storage,it demonstrated a high specific capacitance of 373.1 F g^(-1) in a 6 M KOH electrolyte ***,it has been observed that the preparation strategy for porous electrodes offers notable advan-tages in terms of excellent designability,broad universality,simplicity,and high efficiency,thereby holding promise for large-scale fabrication of diverse porous electrode materials and various types of electrodes for diverse energy storage applications.

关键词： aggregation structure electrode materials phase inversion porous carbon supercapacitors

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