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Degradation and biocompatibility of one-step electrodeposited magnesium thioctic acid/magnesium hydroxide hybrid coatings on ZE21B alloys for cardiovascular stents

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Journal of Magnesium and Alloys 2024年第1期12卷 120-138页

作者： Zhao-Qi Zhang Bing-Zhi Li Pei-Duo Tong Shao-Kang Guan Li Wang Zheng-Hui Qiu Cun-Guo Lin Rong-Chang Zeng School of Material Science and Engineering&Henan Key Laboratory of Advanced Magnesium Alloy&Key Laboratory of Materials Processing and Mold Technology(Ministry of Education) Zhengzhou University100 Science RoadZhengzhou 450001China State Key Laboratory for Marine Corrosion and Protection Luoyang Ship Material Research InstituteQingdao 266101China Corrosion Laboratory for Light Metals College of Material Science and EngineeringShandong University of Science and TechnologyQingdao 266590China

Constructing a functional hybrid coating appears to be a promising strategy for addressing the poor corrosion resistance and insufficient endothelialization of Mg-based ***,the steps for preparing composite coatings are usually complicated and ***,a novel composite coating,composed of bioactive magnesium thioctic acid(MTA)layer formed by deposition and corrosion-resistant magnesium hydroxide(Mg(OH)_(2))layer grown in situ,is simply fabricated on ZE21B alloys via one-step *** electron microscopy(SEM)shows that the electrodeposited coating has a compact and uniform *** the high adhesion of the MTA/Mg(OH)_(2)hybrid coating is also confirmed by the micro-scratch *** test,scanning kelvin probe(SKP),and hydrogen evolution measurement indicate that the hybrid coating effectively reduces the degradation rate of Mg *** experiment and cell culture trial detect that the composite coating is of fine ***,the preparation mechanism of MTA/Mg(OH)_(2)hybrid coatings is discussed and *** coating shows a great potential application for cardiovascular stents.

关键词： Magnesium alloy Corrosion resistance Hybrid coating Endothelialization Biocompatibility

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Internal magnetic-field-enhanced photogenerated charge separation in ferromagnetic TiO_(2)surface heterojunctions

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Journal of materials Science & technology 2023年第29期160卷 240-247页

作者： Guojing Wang Shirong Xiong Yonghui Chen Chunchang Wang Shasha Lv Ke Jia Yunjie Xiang Jianbo Liu Chong Liu Zhengcao Li School of Materials and Energy Lanzhou UniversityLanzhou 730000China State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials(MOE)School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Laboratory of Dielectric Functional Materials School of Physics and Material ScienceAnhui UniversityHefei 230601China Key Laboratory of Beam Technology Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China School of Materials and Energy Southwest UniversityChongqing 404100China

The use of the internal magnetic field of ferromagnets can effectively promote charge separation and transfer(CST)in photoelectrochemical energy ***,photoelectrochemical materials with a ferromagnetic field are scarce,and the internal magnetic field is negligible in nonferromagnetic *** address this issue,we propose a rational method for preparing ferromagnetic TiO_(2)powder using controllable oxygen vacancies in anatase TiO_(2)with co-exposed{001}and{101}***,an ex-cellent saturation magnetisation of 0.0014 emu/g in TiO_(2)is achieved owing to an asymmetric and uneven charge *** with that of nonferromagnetic TiO_(2),the efficiency of photocatalytic hydro-gen generation of ferromagnetic TiO_(2)is improved by 0.64 *** enhancement of photocatalytic hy-drogen generation is due to the different forces exerted on the electrons and holes in the magnetic field,which significantly improve the photogenerated CST efficiency of ferromagnetic TiO_(2).This result high-lights the significant role of the synergistic regulation of the crystal structure and defects in regulating the ferromagnetic characteristics of *** findings of this study provide guidance for leveraging point defects to promote CST for high-efficiency solar-energy conversion systems.

关键词： Photocatalysis TiO_(2){001}-{101}surface heterojunctions Oxygen vacancies Ferromagnetic

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Modeling of the process-induced stress, damage, microstructure, and deformation evolution during the pyrolysis process manufacturing CMCs

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Journal of advanced Ceramics 2023年第12期12卷 2345-2359页

作者： Qiang Liu Suwan Ma Zeshuai Yuan Yuan Li Xiaodong Gong Junping Li Man Zhu Tianjian Lu State Key Laboratory of Mechanics and Control for Aerospace Structures Nanjing University of Aeronautics and AstronauticsNanjing 210016China Key Laboratory of Advanced Functional Composites Technology Aerospace Research Institute of Materials&Processing TechnologyBeijing 100076China College of Civil Engineering Nanjing Tech UniversityNanjing 211800China

An insightful understanding of the formation mechanism of process-inherent defects anddeformation is increasingly important for the property evaluation and structural design of ceramicmatrix composites (CMCs). For this purpose, a coupled thermal–diffusive–mechanical modelingapproach was proposed by considering three important phenomena that occur during the pyrolysisprocess for manufacturing CMCs: variations of the physical and mechanical properties of theconstituents, generation and diffusive of pyrolysis gas, and multiple thermal deformations. Thesynergistic effects of these three phenomena on the stress, damage development, microstructuralmorphology, and process deformation of SiC matrix composites were investigated using finiteelement simulations. This new approach was validated by comparing the simulation and experimentalresults. Significant volume shrinkage of the matrix during the polymer-to-ceramic transformationresulted in large tensile stresses and subsequent highly fragmented microstructure in CMCs. Thepyrolysis-gas-induced expansion on the matrix under a damage state may yield a positive processdeformation of CMCs at the macroscale, overcoming the effects of the volume shrinkage of the bulkmatrix at the microscale. The modeling approach is expected to guide high-quality manufacturing ofCMCs and comprehensive studies of structure–processing–property relationships.

关键词： SiC pyrolysis gas process simulation damage process deformation

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Bioactive calcium and mangnesium phosphate bone adhesive for enhanced vascularization and bone regeneration

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Journal of materials Science & technology 2023年第33期164卷 246-257页

作者： Jiawei Liu Honglei Kang Wenying Wei Rong Tu Takashi Goto Feng Li Honglian Dai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei ProvinceWuhan University of TechnologyWuhan 430070China Department of Orthopedics Tongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430030China Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory Chaozhou 521000China New Industry Creation Hatchery Center Tohoku UniversitySendai 980-8579Japan

Bone adhesive is a promising material for the treatment of bone fractures,which is helpful for the fast and effective reduction and fixation of broken ***,the existing adhesives bond weakly to bone tissues,and are non-absorbable,or hard to cure under wet ***,inspired by the cement-based adhesive used in the industry field,we report a bioactive calcium and magnesium phosphate bone adhesive(MPBA)with the properties of facile preparation,robust adhesion,and *** is equipped with similar strength to cancellous bones and shows reliable bonding performance for various interfaces,such as Ti6Al4V,Al2O3,and poly(ether-ether-ketone).MPBA achieves excellent bonding ability for the above interfaces with the bonding strengths of 2.28±0.47,2.32±0.15,and 1.44±0.38 MPa,***,it also shows reliable fixation ability for bovine bone *** bonding behavior to materials and bones suggests that MPBA could be used for both fracture treatment and implant ***,MPBA possesses good biological activity,which could promote the vascularization process and osteogenic ***,in vivo experiments confirmed MPBA can effectively restore bone strength and promote bone regeneration.

关键词： Fracture Calcium magnesium phosphate cement Bone adhesives

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Bifunctional optical probe based on La_(3)Mg_(2)SbO_(9):Mn^(4+)phosphors for temperature and pressure sensing

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Journal of materials Science & technology 2024年第27期194卷 98-109页

作者： Zhanglin Chen Songmo Du Fei Li Shijia Zhang Shuo Zhao Zhaobo Tian Jie Zhang Xuanyi Yuan Guanghua Liu Kexin Chen State Key Laboratory of New Ceramics&Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China School of Microelectronics Southern University of Science and TechnologyShenzhen 518055China Advanced Ceramics and Structures Center Yongjiang LaboratoryNingbo 315021China Beijing Key Laboratory of Optoelectronic Functional Materials&Micro-nano Devices Department of PhysicsRenmin University of ChinaBeijing 100872China

Photoluminescent materials,serving as optical probes,constitute a significant medium for reliable re-mote sensing of fundamental state parameters such as temperature and ***,we report a novel Mn^(4+)-activated perovskite-type La_(3) Mg2 SbO9 phosphor(LMS:Mn^(4+))for bifunctional application in both thermometry and *** excitation with 341 nm,LMS:Mn^(4+)(0.7%Mn^(4+))emits a bright narrow-band red light peaking at 705 nm with an FWHM(full width at half maximum)of 32 *** a thermometer,when the temperature surpasses 298 K,non-radiative transitions from the ^(2)Eg excited state lead to a sharp decrease in decay lifetimes with increasing *** allows for lifetime-based luminescence thermometry with a relative sensitivity of 2.52%K^(−1) at 391 ***,LMS:Mn^(4+)was processed into a temperature-sensing coating and its non-contact thermometry functionality was *** manometry applications,the LMS:Mn^(4+)probe experiences substantial pressure-dependent redshift with a sensitivity of 1.20 nm GPa^(−1) in the testing range of 9.48 GPa,which is about 3.3 times that of conventional ruby ***,its FWHM consistently remains below 37 nm,which con-tributes to a high reliability of pressure *** above results indicate that the LMS:Mn^(4+)constitutes a promising bifunctional luminescence probe material in thermometry and manometry.

关键词： Perovskite Phosphors Thermometry Manometry

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Engineering surface framework TiO6 single sites for unprecedented deep oxidative desulfurization

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National Science Review 2024年第5期11卷 303-314页

作者： Shen Yu Zhan Liu Jia-Min Lyu Chun-Mu Guo Xiao-Yu Yang Peng Jiang Yi-Long Wang Zhi-Yi Hu Ming-Hui Sun Yu Li Li-Hua Chen Bao-Lian Su Laboratory of Living Materials at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Nanostructure Research Center Wuhan University of Technology School of Chemistry Chemical Engineering and Life ScienceWuhan University of Technology Laboratory of Inorganic Materials Chemistry University of Namur

Catalytic oxidative desulfurization（ODS） using titanium silicate catalysts has emerged as an efficient technique for the complete removal of organosulfur compounds from automotive fuels. However, the precise control of highly accessible and stable-framework Ti active sites remains highly challenging. Here we reveal for the first time by using density functional theory calculations that framework hexa-coordinated Ti（TiO6） species of mesoporous titanium silicates are the most active sites for ODS and lead to a lower-energy pathway of ODS. A novel method to achieve highly accessible and homogeneously distributed framework TiO6active single sites at the mesoporous surface has been developed. Such surface framework TiO6species exhibit an exceptional ODS performance. A removal of 920 ppm of benzothiophene is achieved at60°C in 60 min, which is 1.67 times that of the best catalyst reported so far. For bulky molecules such as4,6-dimethyldibenzothiophene（DMDBT）, it takes only 3 min to remove 500 ppm of DMDBT at 60°C with our catalyst, which is five times faster than that with the current best catalyst. Such a catalyst can be easily upscaled and could be used for concrete industrial application in the ODS of bulky organosulfur compounds with minimized energy consumption and high reaction efficiency.

关键词： electrostatic interactions framework hexa-coordinated Ti site oxidative desulfurization mesoporous materials self-assembly

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Effect of long-term aging treatment on the tensile strength and ductility of GH 605 superalloy

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Progress in Natural Science:materials International 2022年第3期32卷 375-384页

作者： Yixuan He Xudong Liu Chenxu Xing Zhangchi Bian Qing Zhou Jun Wang Haifeng Wang Jinshan Li State Key Laboratory of Solidification Processing Northwestern Polytechnical University Center of Advanced Lubrication and Seal Materials Northwestern Polytechnical University National Key Laboratory for Precision Hot Processing of Metals Harbin Institute of Technology Harbin

Aging treatment is an effective way to optimize the mechanical properties of Co-based superalloys. In this study,commercial GH 605 superalloy was subjected to aging treatment at 650℃ in a wide time range up to 1000 h. The effects of aging time on the tensile characteristics, microstructure evolution and mechanical properties were systematically investigated at room temperature（RT） and 900℃. The results showed that the volume fractions of M6C and M23C6carbide increased with the aging time. After long-term aging treatment, the yield strength（YS） at RT was enhanced from 490.3 MPa to 805.9 MPa, while the alloy still had high tensile ductility（above 20%）.Microscopic observations by transmission electron microscopy（TEM） indicated that the strengthening mechanism was related to carbide precipitation inside the grains and the change in the dislocation slipping mode. Moreover,long-term aging treatment can increase the elongation from 24.1% to 47.3% at 900℃ accompanied by a slight increase of YS from 299.3 MPa to 313.9 MPa. Based on detailed microstructure analysis the strengthening mechanism can be attributed to the refined grains as well as carbide precipitation inside the grains and around the grain boundaries.

关键词： GH 605 superalloy Long-term aging treatment Carbide Strengthening mechanism

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A solvent-free process enabling ZnO/porous carbon with enhanced microwave absorption

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Journal of materials Science & technology 2023年第18期149卷 255-264页

作者： Qi Chen Xing Liu Tingting Wang Xiaogang Su Meng Liu Somboon Chaemchuen Francis Verpoort State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China School of Mathematical&Physical Sciences Wuhan Textile UniversityWuhan 430200China National Research Tomsk Polytechnic University Lenin Avenue 30634050 TomskRussian Federation School of Materials Science and Engineering North University of ChinaTaiyuan 030051China

Exploring a simple,rapid,solvent-free synthetic method for mass production of cheap,broadband mi-crowave absorbers remains the main ***,a mild solvent-free procedure is reported to syn-thesize zinc oxide nanoparticles(ZnO NPs)embedded in porous carbon derived from mixing sucrose and zinc nitrate *** characteristic morphology and the ZnO NPs distribution in these compos-ites were tuned using the different raw materials *** mesoporous structure of porous car-bon benefits the compositional advantages between carbon foam and ZnO *** optimal synthesized ZnO/C-2 carbon material demonstrates the strongest absorption of-41.7 dB with a frequency of 14.5 GHz at a thin thickness of 2 mm,and its widest effective absorption is close to 6 GHz(12.2-17.8 GHz).This work produces a feasible route for the sensible design of other effective microwave absorbers for large-scale production.

关键词： Solvent-free method Porous carbon Dielectric materials Interfacial polarization Microwave broadband absorption

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Unraveling the reaction reversibility and structure stability of nickel sulfide anodes for lithium ion batteries

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Journal of Energy Chemistry 2023年第5期80卷 392-401,I0010页

作者： Yu Huang Chunyuan Liang Yueling Cai Yi Zhou Bingkun Guo Jipeng Cheng Heguang Liu Peng Wang Qianqian Li Anmin Nie Hongtao Wang Jinsong Wu Tongyi Zhang Materials Genome Institute Shanghai UniversityShanghai 200444China Center for X-mechanics Zhejiang UniversityHangzhou 310027ZhejiangChina School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027ZhejiangChina School of Materials Science and Engineering Xi'an University of TechnologyXi'an 048ShaanxChin Shanghai Key Laboratory of Mechanics in Energy Engineering Shanghai Institute of Applied Mathematics and MechanicsSchool of Mechanics and Engineering ScienceShanghai UniversityShanghai 200444China Center for High Pressure Science State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004HebeiChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Nanostructure Research CenterWuhan University of TechnologyWuhan 430070HubeiChina

The electrochemical performance of lithium-ion batteries,*** capacity and cyclability,is primarily determined by chemical reversibility and structural stability of the electrodes in *** we have investigated the fundamental reaction behaviors of nickel sulfide(NixSy)as lithium-ion battery anodes by in-situ *** find that Ni_(3)S_(2)is the electrochemically stable phase,which appears in the first cycle of the *** the second cycle,conversion between Ni_(3)S_(2)and Li_(2)S/Ni is the dominant electrochemical *** lithiation,the NixSynanoparticles evolve into a mixture of Ni nanocrystals embedded in Li_(2)S matrix,which form a porous structure upon full lithiation,and with the recrystallization of the Ni_(3)S_(2)phase in delithiation,a compact and interconnected network is *** stability in cycles is susceptible to particle size and substrate *** substrate can certainly improve the tolerance for size-dependent pulverization of *** NixSynanoparticle exceeds the critical size value,the morphology of the particle is no longer well maintained even under the constraints of the carbon *** work deepens the understanding of electrochemical reaction behavior of conversiontype materials and helps to rational design of high-energy density battery anodes.

关键词： Nickel sulfide anodes Reaction reversility Structure rebuilding In-situ TEM Lithium-ion battery

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Rejuvenating LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode directly from battery scraps

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eScience 2023年第2期3卷 112-122页

作者： Yaqing Guo Chi Guo Pengjie Huang Qigao Han Fuhe Wang Hao Zhang Honghao Liu Yuan-Cheng Cao Yonggang Yao Yunhui Huang State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074 China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China Key Laboratory of Optoelectronic Chemical Materials and Devices Ministry of EducationSchool of Optoelectronic Materials&TechnologyJianghan UniversityWuhan 430056China

Battery recycling is indispensable for alleviating critical material shortages and enabling sustainable battery ***,current methods mostly focus on spent batteries,which not only require sophisticated disassembly and material extraction but also have unknown chemistries and states of health,resulting in high costs and extreme challenges to achieve ***,we propose the direct recycling and effective regeneration of air-degraded LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2)(NCM523)cathode directly from battery scraps generated during battery *** NCM523 shows surface degradation only a few nanometers deep and accordingly can be regenerated without adding Li,achieving restored properties(170 mAh g^(-1) at 0.1 C,92.7%retention after 1000 cycles)similar to those of fresh commercial *** analysis shows that scrap recycling has a profit of$1.984 kg^(-1),which is~10 times higher than conventional recycling,making it practical and economical to rejuvenate slightly degraded electrode materials for sustainable battery manufacturing.

关键词： Battery scrap Battery recycling Air degradation Cathode regeneration Techno-economic analysis

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