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Defect Engineering on Carbon‑Based Catalysts for Electrocatalytic CO2 Reduction

Nano-Micro Letters 2021年第1期13卷 56-78页

作者： Dongping Xue Huicong Xia Wenfu Yan Jianan Zhang Shichun Mu College of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001People’s Republic of China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry and College of ChemistryJilin University2699 Qianjin StreetChangchun 130012People’s Republic of China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070People’s Republic of China

Electrocatalytic carbon dioxide(CO2)reduction(ECR)has become one of the main methods to close the broken carbon cycle and temporarily store renewable energy,but there are still some problems such as poor stability,low activity,and *** the most promising strategy to improve ECR activity is to develop electrocatalysts with low cost,high activity,and long-term ***,defective carbon-based nanomaterials have attracted extensive attention due to the unbalanced electron distribution and electronic structural distortion caused by the defects on the carbon ***,the present review mainly summarizes the latest research progress of the construction of the diverse types of defects(intrinsic carbon defects,heteroatom doping defects,metal atomic sites,and edges detects)for carbon materials in ECR,and unveil the structure-activity relationship and its catalytic *** current challenges and opportunities faced by high-performance carbon materials in ECR are discussed,as well as possible future *** can be believed that this review can provide some inspiration for the future of development of high-performance ECR catalysts.

关键词： Electrocatalytic CO2 reduction Carbon-based nanomaterials Intrinsic defects Heteroatom doping defects Metal atomic sites

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Microstrip Antenna Arrays Based on Two-dimensional Titanium Carbide (MXene) Films 15

Microstrip Antenna Arrays Based on Two-dimensional Titanium ...

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15th International Conference on Microwave and Millimeter Wave technology, ICMMT 2023

作者： Guo, Jiannan Zu, Hao-Ran Yang, Runjie Liu, Xueyu Li, Bao-Wen Song, Rongguo He, Daping Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan430070 China Center of Smart Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesisand Processing Wuhan430070 China

ISBN: (纸本)9798350338874

In this work, a microstrip antenna array based on a two-dimensional titanium carbide (MXene) film with an operating frequency of 3.5 GHz is proposed for the first time. MXene film has a conductivity of 5∗105 S/m and a thickness of 15 μm, which has good ductility and flexibility. The radiating units are arranged by 2 units, and the microstrip lines with parallel feeding between the array elements directly feed the antenna. The return loss of the proposed 2∗2 MXene antenna array is -24.3 dB, and the impedance bandwidth of a -10 dB is 11.1% (3.21 GHz-3.66 GHz), and a maximum gain of 5.73 dBi. The results show that the MXene antenna array has excellent performance and verifies the feasibility of preparing high-performance antennas, which have significant potential for future 5G mobile communication. It has crucial application potential in future 5G mobile communication. © 2023 IEEE.

关键词： 5G mobile communication systems

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Three-dimensional-printed Ni-based scaffold design accelerates bubble escape for ampere-level alkaline hydrogen evolution reaction

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Interdisciplinary materials 2024年第4期3卷 595-606页

作者： Jingxuan Chen Gangwen Fu Yu Tian Xingchuan Li Mengqi Luo Xiaoyu Wei Ting Zhang Tian Gao Cheng Chen Somboon Chaemchuen Xi Xu Xing Sun Tongle Bu Francis Verpoort John Wang Zongkui Kou State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina Marine New Materials and Equipment Technology Center Sanya Science and Education Innovation Park of Wuhan University of TechnologySanyaChina Frontiers Science Center for Flexible Electronics Institute of Flexible ElectronicsNorthwestern Polytechnical UniversityXi'anChina Key laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical UniversityNingboChina School of Astronautics Northwestern Polytechnical UniversityXi'anChina Department of Materials Science and Engineering College of Design and EngineeringNational University of SingaporeSingaporeSingapore National University of Singapore(Chongqing)Research Institute Chongqing Liang Jiang New AreaChongqingChina

Alkaline hydrogen evolution reaction(HER)for scalable hydrogen production largely hinges on addressing the sluggish bubble-involved kinetics on the traditional Ni-based electrode,especially for ampere-level current densities and ***,3D-printed Ni-based sulfide(3DPNS)electrodes with varying scaffolds are designed and *** situ observations at microscopic levels demonstrate that the bubble escape velocity increases with the number of hole sides(HS)in the ***,we conduct multiphysics field simulations to illustrate that as the hole shapes transition from square,pentagon,and hexagon to circle,where a noticeable reduction in the bubble-attached HS length and the pressure balance time around the bubbles results in a decrease in bubble size and an acceleration in the rate of bubble ***,the 3DPNS electrode with circular hole configura-tions exhibits the most favorable HER performance with an overpotential of 297 mV at the current density of up to 1000 mA cm^(-2) for 120 *** present study highlights a scalable and effective electrode scaffold design that promotes low-cost and low-energy green hydrogen production through the ampere-level alkaline HER.

关键词： 3D printing alkaline hydrogen evolution reaction ampere-level current densities bubble escape hole sides

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Superhydrophobic Piezoelectric Device for Efficient Raindrop Energy Harvesting

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ACS Applied Energy materials 2025年第11期8卷 7322-7329页

作者： Sun, Qi Tian, Jing Qin, Zhi Li, Hao Shen, Jie Zhang, Pengchao Chen, Wen Zhou, Jing Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and Engineering Wuhan University of Technology Wuhan 430070 China Sanya Science and Education Innovation Park Wuhan University of Technology Sanya 572024 China

Efficiently harvesting the inherent kinetic energy carried by raindrops upon impact offers considerable potential for powering microdevices. However, the conversion efficiency of the raindrop energy is low. In this paper, we present a piezoelectric energy harvesting device with a superhydrophobic and low adhesive surface for significantly improving the raindrop energy conversion efficiency. The piezoelectric energy harvesting device was prepared using a macro fiber composite (MFC) with low operating frequency, high sensitivity, and a large electromechanical coupling coefficient as a functional element. The superhydrophobic surface allowed raindrops to rebound. At the same time, the raindrops can leave the surface of the device quickly after the end of their action so as to reduce the loss of kinetic energy generated by the collision of raindrops with solid surfaces. Compared to the untreated hydrophilic device, the energy conversion efficiency of the superhydrophobic piezoelectric energy harvesting device increased 172%. Under different test conditions, the device achieved a maximum peak power density of 338 W/m3. This approach provides a promising solution for efficient raindrop energy harvesting. © 2025 American Chemical Society.

关键词： energy harvesting macro fiber composite piezoelectric effect rain droplets superhydrophobic

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Perfluorosulfonic acid proton exchange membrane with double proton site side chain for high-performance fuel cells at low humidity

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Journal of materials Science & technology 2023年第35期166卷 155-163页

作者： Hongyun Tan Shengqiu Zhao S.Eltahir Ali Shuhong Zheng Abdullah K.Alanazi Rui Wang Haining Zhang Hala M.Abo-Dief Ben Bin Xu Hassan Algadi Handong Li Priyanka Wasnik Zhanhu Guo Haolin Tang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Science and Technology University College-RanyahTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Chemistry College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200China Integrated Composites Laboratory(ICL) Mechanical and Construction EngineeringNorthumbria UniversityNewcastle Upon Tyne NE18STUK College of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024China Department of Electrical Engineering Faculty of EngineeringNajran UniversityNajran11001Saudi Arabia

Structural optimization of ionomers is an effective strategy for achieving high-performance proton ex-change membranes(PEMs)under low relative humidity(RH)*** this study,sulfonimide group and trifluoromethanesulfonate acid(TFSA)ionic liquids were introduced to the perfluorosulfonic acid(PFSA)side chain,resulting in polymer membranes with varying chain lengths(i.e.,PFC_(2)-TF-SI,PFC_(4)-TF-SI,and PFC_(5)-TF-SI).This dual proton-conducting structure extended the length of the hydrophilic side chain and enhanced the hydrophobic-hydrophilic phase separation,aiding in the formation of proton transport ***,the proton conductivity of PFC_(5)-TF-SI and PFC_(2)-TF-SI membranes reached 7.1 and 10.6 mS/cm at 30%RH and 80℃,respectively,which were approximately 29.1%and 92.7%higher than that of the pristine PFC_(5)-SA membrane(5.5 mS/cm).Furthermore,the maximum power density of the PFC_(5)-TF-SI and PFC_(2)-TF-SI membranes from the built single fuel cell achieved 649 and 763 mW/cm^(2) at 30%RH and 80℃,respectively,which were higher than that of the pristine PFC_(5)-SA membrane(567 mW/cm^(2))by about 14.5%and 34.6%,***,this study provides a strategy for PEM design under low RH conditions.

关键词： Proton exchange membrane Structural design Dual proton conduction Hydrophilic channel Proton conductivity Fuel cells

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Passivation of PEA^(+)to CsPbI_(3)(110)Surface states:From the First Principles Calculations

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Journal of Renewable materials 2023年第3期11卷 1293-1301页

作者： Wei Hu Fengjuan Si Hongtao Xue Wensheng Li Jun Hu Fuling Tang School of Materials Science and Engineering State Key Laboratory of Advanced Processing and Recycling of Nonferrous MetalsLanzhou University of TechnologyLanzhou730050China Department of Materials Engineering Lanzhou Institute of TechnologyLanzhou730050China School of Peili Mechanical Engineering Lanzhou City CollegeLanzhou730070China School of Chemical Engineering Northwest UniversityXi’an710069China

This work investigates the effect of passivation on the electronic properties of inorganic perovskite CsPbI_(3)materials by using first-principles calculations with density functional theory(DFT).The passivation effect after the addition of Phenylethylamine(PEA+)molecule to CsPbI_(3)(110)surface is *** results of density of states(DOS)calculations show that the CsPbI_(3)(110)surface model with I atom terminated reveals new electronic DOS peaks(surface states)near the Fermi *** surface states are mainly due to the contribution of I-5p orbital and are harmful to the CsPbI_(3)-based solar cells because they reduce the photoelectric conversion *** surface states near the Fermi level are significantly reduced,and the decline rate reaches 38.8%with the addition with PEA+molecule to the CsPbI3(110)surface.

关键词： First-principles calculations surface states passivation

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Regulation of the sintering trajectory of Ho,Pr:Y_(2)O_(3) ceramics for 2.9μm mid-infrared lasers by atmospheric sintering

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Journal of advanced Ceramics 2025年第1期14卷 81-89页

作者： Qing Li Fei Liang Jun Wang Yan Ling Xue Jie Ma Peng Liu Shiyu Sun Zhan Hui Jian Zhang Changhua Zhang Lili Hu Haohai Yu Huaijin Zhang Dingyuan Tang State Key Laboratory of Crystal Materials and Institute of Crystal Materials Shandong UniversityJinan 250100China Jiangsu Key Laboratory of Advanced Laser Materials and Devices School of Physics and Electronic EngineeringJiangsu Normal UniversityXuzhou 221116China Shanghai Key Laboratory of Multidimensional Information Processing School of Communication and Electronics EngineeringEast China Normal UniversityShanghai 200241China Shanghai Branch Hefei National Laboratoryand Shanghai Research Center for Quantum SciencesShanghai 201315China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China Shanghai Institute of Optics and Fine Mechanics Chinese Academy of SciencesShanghai 201800China Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 201899China Future Technology School Shenzhen Technology UniversityShenzhen 518118China

The sintering trajectory of the Ho,Pr:Y_(2)O_(3) ceramics could be effectively adjusted by sintering in a flowing oxygen atmosphere instead of *** final-stage grain growth was significantly suppressed by the use of oxygen atmosphere presintering,resulting in smaller average grain sizes than those of samples sintered under vacuum,while the same relative density was *** hot isostatic pressing(HIP),the oxygen presintered Ho,Pr:Y_(2)O_(3) ceramics achieved excellent optical quality,with transmittance exceeding 80%at a wavelength of 680 *** codoping of Pr^(3+) as deactivating ions effectively depopulated the lower energy level 5I7 during the Ho^(3+):^(5)I_(6)→^(5)I_(7) transition,thereby making the Ho,Pr:Y_(2)O_(3) ceramics more conducive to promoting population inversion in the 2.9μm laser wavelength range.

关键词： Y_(2)O_(3) ceramics sintering trajectory Ho^(3+)/Pr^(2+) mid-infrared laser fluorescence properties

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Enhancing Green Ammonia Electrosynthesis Through Tuning Sn Vacancies in Sn‑Based MXene/ MAX Hybrids

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Nano-Micro Letters 2024年第5期16卷 154-168页

作者： Xinyu Dai Zhen‑Yi Du Ying Sun Ping Chen Xiaoguang Duan Junjun Zhang Hui Li Yang Fu Baohua Jia Lei Zhang Wenhui Fang Jieshan Qiu Tianyi Ma Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials of Liaoning Province College of ChemistryInstitute of Clean Energy ChemistryLiaoning UniversityShenyang 110036People’s Republic of China State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024People’s Republic of China School of Chemistry and Chemical Engineering Anhui UniversityHefei 230601People’s Republic of China School of Chemical Engineering The University of AdelaideAdelaideSA 5005Australia State Key Laboratory of High‑Efficiency Utilization of Coal and Green Chemical Engineering College of Chemistry and Chemical EngineeringNingxia UniversityYinchuan 750021NingxiaPeople’s Republic of China School of Science RMIT UniversityMelbourneVIC 3000Australia Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640People’s Republic of China College of Chemical Engineering State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China

Renewable energy driven N_(2) electroreduction with air as nitrogen source holds great promise for realizing scalable green ammonia ***,relevant out-lab research is still in its ***,a novel Sn-based MXene/MAX hybrid with abundant Sn vacancies,Sn@Ti_(2)CTX/Ti_(2)SnC–V,was synthesized by controlled etching Sn@Ti_(2)SnC MAX phase and demonstrated as an efficient electrocatalyst for electrocatalytic N2 *** to the synergistic effect of MXene/MAX heterostructure,the existence of Sn vacancies and the highly dispersed Sn active sites,the obtained Sn@Ti2CTX/Ti_(2)SnC–V exhibits an optimal NH_(3) yield of 28.4μg h^(−1) mg_(cat)^(−1) with an excellent FE of 15.57% at−0.4 V versus reversible hydrogen electrode in 0.1 M Na_(2)SO_(4),as well as an ultra-long ***,this catalyst represents a satisfactory NH3 yield rate of 10.53μg h^(−1) mg^(−1) in the home-made simulation device,where commercial electrochemical photovoltaic cell was employed as power source,air and ultrapure water as feed *** as-proposed strategy represents great potential toward ammonia production in terms of financial cost according to the systematic technical economic *** work is of significance for large-scale green ammonia production.

关键词： Green ammonia synthesis N2 electroreduction Renewable energy Sn MXene/MAX hybrid

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Effects of Cracks on the Mass Transfer of Polymer Electrolyte Membrane Fuel Cell with High Performance Membrane Electrode Assembly

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Journal of Wuhan University of technology(materials Science) 2021年第3期36卷 318-330页

作者： SHI Jinrong ZHAN Zhigang ZHANG Di YU Yuan YANG Xiaoxiang HE Luyan PAN Mu Foshan Xianhu Laboratory Foshan 528000China State Key Laboratory of Advanced Technology for Materials Synthesis and Pro-cessing Wuhan University of TechnologyWuhan 430070China

A two-dimensional geometric model is developed for a polymer electrolyte based on the liquid water penetration mechanism in the membrane electrode assemblies under the action of capillary *** effects of the diameter,number,and distribution of cracks in the micro-pore layers(MPLs)of the modeled MEA on the performance of the PEMFC are simulated to investigate the influence of mass transfer across the *** results indicate that liquid water in the catalyst layer(CL)of the MEA can be discharged to gas channels through the cracks in MEA under the action of capillary pressure,thereby alleviating the flooding in the CL and enhancing the diffusion of oxygen to the *** the proportion of the total area of cracks in the active area of the MEA was 8%-12%,crack diameter was 20-30μm,and cracks were distributed *** with and without cracks were prepared,fuel cells were assembled,and their performance was *** effects of cracks on mass transfer were then *** study helps prepare MEAs with controllable cracks.

关键词： PEMFC MEA cracking liquid saturation oxygen concentration transfer

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Significantly enhanced energy storage performance of BaTiO3-based amorphous thin films through the synergistic function of variable valence ions

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Ceramics International 2025年

作者： Yao, Yiming Tao, Cheng Huang, Rui Zhang, Jian Zhang, Tianyu Hao, Hua Yao, Zhonghua Liu, Hanxing Cao, Minghe State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China International School of Materials Science and Engineering Wuhan University of Technology Wuhan430070 China

Amorphous thin films have been widely studied due to the excellent breakdown strength in recent years. However, their practical application faces significant challenges primarily caused by low polarization and energy density. Herein, we propose a multi-variable valence ions doping strategy to enhance the energy storage performance of BaTiO3-based amorphous thin films. The Ba0.92Bi0.08Ti1-x(Ni0.5Mn0.5)xO3(BBTNM) amorphous thin films were fabricated by chemical solution deposition method. In addition, the synergistic effects of variable valence ions (Ni, Mn) on the microstructure, dielectric and energy storage properties of the films were systematically studied. Compared with the undoped Ba0.92Bi0.08TiO3(BBT) film, the polarization and energy storage performance of the BBTNM film have been significantly improved owing to the defect dipoles generated by the incorporation of variable valence ions. Notably, a high discharge energy density of 93.3 J/cm3 together with an energy efficiency of 83 % could be achieved in the x = 0.08 film at 7.05 MV/cm. Simultaneously, the film exhibits excellent thermal stability within the range of 20 °C–160 °C, and still maintains favorable performance after 105 cycles. Overall, this work introduces a new approach for designing BaTiO3-based thin film materials. © 2025

关键词： Amorphous films

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