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Nickel-copper alloying arrays realizing efficient co-electrosynthesis of adipic acid and hydrogen

Journal of Energy Chemistry 2025年第2期101卷 7-15,I0001页

作者： Xuhui Ren Qianyu Zhang Yun Tong Guorong Zhou Cong Lin Yanying Zhao Pengzuo Chen School of Chemistry and Chemical Engineering Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018ZhejiangChina

Constructing electrocatalytic overall reaction technology to couple the electrosynthesis of adipic acid with energy-saving hydrogen production is of significant for sustainable energy ***,the development of highly-active bifunctional electrocatalysts remains a ***,3D hierarchical nickel-copper alloying arrays with dendritic morphology are manufactured by a simple electrodeposition process,standing for the excellent bifunctional electrocatalyst towards the co-production of adipic acid and H_(2)from cyclohexanone and *** membrane-free flow electrolyzer of Cu_(0.81)Ni_(0.19)/NF shows the superior electrooxidation performance of ketone-alcohol(KA)oil with high faradaic efficiencies of over 90%for adipic acid and H_(2),robust stability over 200 h as well as a high yield of 0.6 mmol h^(-1) for adipic acid at 100 mA cm^(-2).In-situ spectroscopy indicates the Cu_(0.81)Ni_(0.19)alloy contributes to forming more active NiOOH species to involve in the conversion of cyclohexanone to adipic acid,while the proposed reaction pathway undergoes the 2-hydroxycyclohexanone and 2,7-oxepanedione ***,the theoretical calculations confirm that the optimal electronic interaction,boosted reaction kinetics as well as improved adsorption free energy of reaction intermediates,synergistically endows Cu_(0.81)Ni_(0.19)alloy with superior bifunctional performance.

关键词： Cu_(0.81)Ni_(0.19)alloy Adipic acid Hydrogen fuel Cyclohexanone oxidation reaction Hydrogen evolution reaction

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Intermediate Temperature Fatigue Induced Precipitation and Associated Corrosion in CrMnFeCoNi High Entropy Alloy

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Acta Metallurgica Sinica(English Letters) 2023年第11期36卷 1857-1869页

作者： Tiezhuang Han Jing Wang Bo Li Shuang Li Kaisheng Ming Fucheng Wang Bin Miao Shijian Zheng Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and EngineeringHebei University of TechnologyTianjin300401China

Understanding the corrosion behavior of high entropy alloys(HEAs)after intermediate temperature fatigue is critical to prevent their catastrophic failures from the reduction of corrosion ***,we investigated the corrosion behavior of CrMnFeCoNi HEA after 500℃ fatigue test with strain amplitudes of 0.2%and 0.5%.The intermediate temperature fatigue induced two types of precipitates,which were determined as Cr-richσphase and NiMn-rich L10 *** strain amplitude not only promoted precipitates generations but also spread the nucleation sites from intergranular to both intergranular and ***,we found that the deterioration in corrosion resistance of the alloy was derived from the increase of precipitates,which destroyed the stability of the passive *** above results revealed that intermediate temperature fatigue impaired the stabilization of the solid solution state and subsequent corrosion resistance of CrMnFeCoNi HEA,where the higher strain amplitude led to more precipitates and more severe corrosion.

关键词： High entropy alloy Corrosion Intermediate temperature fatigue Phase stability Precipitate

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Microstructure and mechanical properties of a cast TRIP-assisted multiphase stainless steel

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China Foundry 2024年第3期21卷 221-228页

作者： Meng-xin Wang Zi-xiang Wu Jing-yu He Xiang Chen School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Advanced Materials Processing Technology Ministry of EducationBeijing 100084China

Stainless steels are used in a wide range of complex environments due to their excellent corrosion *** stainless steels can offer an excellent combination of strength,toughness and corrosion resistance due to the coexistence of different *** microstructure and mechanical properties of a novel cast multiphase stainless steel,composed of martensite,ferrite,and austenite,were investigated following appropriate heat treatment processes:solution treatment at 1,050℃ for 0.5 h followed by water quenching to room temperature,and aging treatment at 500℃ for 4 h followed by water quenching to room *** show reversed austenite is formed by diffusion of Ni element during aging process,and the enrichment of Ni atoms directly determines the mechanical stability of *** austenite with a lower Ni content undergoes a martensitic transformation during plastic *** tensile strength of the specimen exceeds 1,100 MPa and the elongation exceeds 24%after solid solution,and further increases to 1,247 MPa and 25%after aging *** enhancement is due to the TRIP effect of austenite and the precipitation of the nanoscale G-phase pinning dislocations in ferrite and martensite.

关键词： multiphase stainless steel mechanical properties TRIP effect reversed austenite G-phase

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Emerging probing perspective of two-dimensional materials physics:terahertz emission spectroscopy

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Light(science & Applications) 2024年第7期13卷 1278-1298页

作者： Yifei Wu Yuqi Wang Di Bao Xiaonan Deng Simian Zhang Lin Yu-chun Shengxian Ke Jianing Liu Yingjie Liu Zeli Wang Pingren Ham Andrew Hanna Jiaming Pan Xinyue Hu Zhengcao Li Ji Zhou Chen Wang State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials of Ministry of EducationSchool of Materials Science and EngineeringTsinghua University100084 BeijingChina Beijing Advanced Innovation Center for Integrated Circuits 100084 BeijingChina

Terahertz(THz)emission spectroscopy(TES)has emerged as a highly effective and versatile technique for investigating the photoelectric properties of diverse materials and nonlinear physical processes in the past few ***,research on two-dimensional(2D)materials has experienced substantial growth due to their atomically thin structures,exceptional mechanical and optoelectronic properties,and the potential for applications in flexible electronics,sensing,and ***,these materials offer advantages such as tunable bandgap,high carrier mobility,wideband optical absorption,and relatively short carrier *** applying TES to investigate the 2D materials,their interfaces and heterostructures,rich information about the interplay among photons,charges,phonons and spins can be unfolded,which provides fundamental understanding for future *** it is timely to review the nonlinear processes underlying THz emission in 2D materials including optical rectification,photon-drag,high-order harmonic generation and spin-to-charge conversion,showcasing the rich diversity of the TES employed to unravel the complex nature of these *** applications based on THz emissions,such as THz lasers,ultrafast imaging and biosensors,are also *** further,we analyzed the unique advantages of spintronic terahertz emitters and the future technological advancements in the development of new THz generation mechanisms leading to advanced THz sources characterized by wide bandwidth,high power and integration,suitable for industrial and commercial *** continuous advancement and integration of TES with the study of 2D materials and heterostructures promise to revolutionize research in different areas,including basic materials physics,novel optoelectronic devices,and chips for post-Moore’s era.

关键词： optoelectronic versatile exceptional

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Membrane-less MoO_(3-x)@TiO_(2)-bromine battery with excellent rate capability and cyclic stability

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Journal of Energy Chemistry 2024年第6期93卷 316-321,I0008页

作者： Wenjie Huang Hui Wang Bin Yuan Liuzhang Ouyang Lichun Yang Min Zhu School of Materials Science and Engineering Guangdong Provincial Key Laboratory of Advanced Energy Storage MaterialsSouth China University of TechnologyGuangzhou 510640GuangdongChina

Bromine has attracted significant attention as a cathode material for aqueous batteries due to its high reduction potential of 1.05 V(Br_(3)^(-)+2e~-■3Br~-),impressive theoretical specific capacity of 223 mA h g^(-1),and rapid reaction kinetics in the ***,searching for compatible anode materials to match with bromine has posed a challenge due to its highly corrosive *** this study,we developed oxygen-deficient MoO_(3) with TiO_(2) coating(referred to as MoO_(3-x)@TiO_(2))as an anode material to pair with a bromine cathode in static full *** oxygen deficiency contributes to enhanced electronic and protonic diffusion within the MoO_(3-x)lattice,while the TiO_(2) coating mitigates structural dissolution and proton trapping during *** MoO_(3-x)@TiO_(2) demonstrates fast charge storage kinetics and excellent resistance to bromine *** impressive compatibility between MoO_(3-x)@TiO_(2) and bromine enables the construction of membrane-less full batteries with exceptional rate capability and cyclic *** MoO_(3-x)@TiO_(2)-bromine battery achieves an energy density of70.8 W h kg^(-1)at a power density of 328.1 W kg^(-1),showcasing an impressive long-term cyclic life of 20,000 *** study provides valuable insights for the development of high-performance aqueous secondary batteries.

关键词： Molybdenum trioxide Oxygen deficiency TiO_(2)coating Compatibility Bromine-based battery

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Growth process,defects,and dopants of bulk β-Ga_(2)O_(3) semiconductor single crystals

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China Foundry 2024年第5期21卷 491-506页

作者： Yan-shen Wang Ming-zhi Zhu Yuan Liu School of Materials Science and Engineering Tsinghua UniversityBeijing 100084China Key Laboratory for Advanced Materials Processing Technology(Ministry of Education) Beijing 100084China

β-gallium oxide(β-Ga2O3),as the typical representative of the fourth generation of semiconductors,has attracted increasing attention owing to its ultra-wide bandgap,superior optical properties,and excellent tolerance to high temperature and *** to the single crystals of other semiconductors,high-quality and large-size β-Ga_(2)O_(3) single crystals can be grown with low-cost melting methods,making them highly *** this review,the growth process,defects,and dopants ofβ-Ga_(2)O_(3) are primarily ***,the growth process(e.g.,decomposition,crucible corrosion,spiral growth,and development)ofβ-Ga_(2)O_(3) single crystals are summarized and compared in ***,the defects of β-Ga_(2)O_(3) single crystals and the influence of defects on Schottky barrier diode(SBD)devices are emphatically ***,the influences of impurities and intrinsic defects on the electronic and optical properties ofβ-Ga_(2)O_(3) are also briefly *** this comprehensive analysis,the article offers a concise summary of the current state,challenges and prospects ofβ-Ga_(2)O_(3) single crystals.

关键词： β-Ga_(2)O_(3) single-crystal growth defects dopants semiconductor

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In situ investigation of hydrogen embrittlement induced by δ phase in selective laser-melted GH4169 superalloy

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材料科学技术（英文版） 2025年第8期211卷 145-158页

作者： Zhao Xu Saiyu Liu Yujie Zhu Rongjian Shi Kewei Gao Xiaolu Pang Beijing Advanced Innovation Center for Materials Genome Engineering School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China Beijing Advanced Innovation Center for Materials Genome Engineering School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China State Key Laboratory of Nuclear Power Safety Technology and Equipment University of Science and Technology BeijingBeijing 100083China

Direct evidence of hydrogen-assisted crack nucleation and propagation associated with the δ phase in the selective laser melted GH4169 superalloy was *** analysis of hydrogen trapping sites using thermal desorption spectroscopy revealed that the δ phase exhibits strong hydrogen capture capability,with a hydrogen desorption activation energy of 35.45±2.51 kJ/*** addition,spatially resolved hy-drogen mapping conducted by scanning Kelvin probe force microscopy and hydrogen microprint tech-nique provided further evidence for the δ phase as a deep hydrogen trapping *** atomic-scale characterization sufficiently reveals the deformation mechanism of the δ phase induced by dislocation ***-promoted dislocation slip localization facilitates the formation of microvoid de-fects in the δ phase,which is the main reason for the δ phase fracture,and induces intergranular and transgranular cracks.

关键词： Hydrogen embrittlement Nickel-based superalloy Δ phase Hydrogen-assisted cracking Hydrogen trapping

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Controllable photooxidation of 1-phenylethanol integrated with hydrogen evolution by a polyoxometalate/ZnIn_(2)S_(4)/WO_(3)catalytic system

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Nano Research 2025年第4期18卷 116-124页

作者： Jiaxin Yang Yongkang Liu Yun Qin Zhenheng Diao Yuanyuan Dong Hongjin Lv School of Chemical Engineering Advanced Institute of Materials ScienceChangchun University of TechnologyChangchun 130012China MOE Key Laboratory of Cluster Science Beijing Key Laboratory of Photoelectric/Electrophotonic Conversion MaterialsSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 102488China

The photocatalytic oxidation of 1-phenylethanol coupling with hydrogen evolution represents a promising strategy for the full utilization of the photogenerated electrons and holes to accomplish the maximum conversion of solar energy into chemical *** date,however,the controllable of reaction path and product distribution has yet not to be ***,we report an efficient coupled catalytic system composed of ZnIn_(2)S_(4)/WO_(3)S-scheme heterojunction and Ni-containing polyoxometalate([Ni_(4)(H_(2)O)_(2)(PW_(9)O_(34))_(2)]^(10-)(Ni_(4)P_(2))),which exhibited excellent photocatalytic activities towards the oxidation valorization of 1-phenylethanol coupling with hydrogen *** addition of Ni_(4)P_(2)can efficiently control the product ***,1-phenylethanol was preferentially converted to pinacol(86.0% selectivity)via C-C coupling over ZnIn_(2)S_(4)/WO_(3)S-scheme heterojunction accompanied by hydrogen production(202.4μmol),whereas it would be converted to acetophenone(93.8% selectivity)by photogenerated holes with concomitant hydrogen formation(183.1μmol)over the coupled Ni_(4)P_(2)/ZnIn_(2)S_(4)/WO_(3) catalytic *** studies revealed that the hydrogen evolution cocatalyst Ni4P2,with its excellent electron storage capacity,can compete with the oxidation product acetophenone for electrons,and thus its addition can significantly inhibit the reduction of acetophenone,resulting in the inability to generate the coupling product pinacol.

关键词： S-scheme heterojunction ZnIn_(2)S_(4) polyoxometalates dehydrocoupling hydrogen evolution photocatalysis

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Local charge homogenization strategy enables ultra-high voltage tolerance of polyether electrolytes for 4.7 V lithium metal batteries

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National science Review 2025年第2期12卷 219-229页

作者： Yuanlong Wu Piao Luo Kexin Su Mao Yu Xin Song Lianzhan Huang Shaocong Zhang Huiyu Song Li Du Weishu Liu Zhiming Cui Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical EngineeringSouth China University of Technology Department of Materials Science and Engineering Southern University of Science and Technology Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology School of Software Engineering South China University of Technology

In-situ fabricated polyether electrolytes have been regarded as one of the most promising solid electrolyte systems. Nevertheless, they cannot match high-voltage cathodes over 4.3 V due to their poor oxidative stability. Herein, we propose an effective local charge homogenization strategy based on the triglycidyl isocyanurate（TGIC） crosslinker, achieving ultra-high-voltage electrochemical stability of polyether electrolytes（viz. PTIDOL） at cutoff voltages up to 4.7 V. The introduction of TGIC optimizes the Li+solvation environment, thereby homogenizing the charge distribution at ether oxygen（EO） sites, resulting in significantly enhanced oxidative stability of the polyether main chain. Consequently, the Li|PTIDOL|LiNi0.6Co0.2Mn0.2O2（NCM622） cell achieves long-term operation at an ultra-high cutoff voltage with a capacity retention of 81.8% after 400 cycles, one of the best results reported for polyether electrolytes to date. This work provides significant insights for the development of polyether electrolytes with high-voltage tolerance and the advancement of high-energy-density batteries.

关键词： lithium metal batteries solid polymer electrolytes polymerization high voltage local charge homogenization

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Decomposition of pre-existing Au-P clusters induced in situ a-Fe grains uniformization in Fe-P-based nanocrystalline alloys

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Rare Metals 2024年第10期43卷 5242-5255页

作者： Min-Hao Han Cheng Sun Guo-Guo Xi Yang Meng Qiang Luo Xue-Qian Yu Wen-Feng Zhang Hao Liu Hong-Jie Xu Tao Zhang Key Laboratory of Aerospace Materials and Performance(Ministry of Education) School of Materials Science and EngineeringBeihang UniversityBeijing 100191China Laboratory of Functional Fiber Materials Institute of Bast Fiber CropsChinese Academy of Agricultural ScienceChangsha 410205China School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic MaterialsSoutheast UniversityNanjing 211189China Institute for Advanced Materials North China Electric Power UniversityBeijing 102206China Center for Advanced Analysis and Computational Science Zhengzhou UniversityZhengzhou 450001China

In Fe-based amorphous-/nanocrystalline ribbons,the uniformization and refinement of a-Fe grains are key aspects for optimizing their soft magnetic and mechanical ***,the Fe-P-C-B nanocrystalline alloy system was selected for *** produced as-spun ribbons with pre-existing nanocrystals through melt-quenching and then obtained a well-distributed a-Fe nanocrystalline structure through annealing below the first crystallization onset temperature(633 K)resulting in excellent magnetic properties(saturation magnetization of 1.65 T and coercivity of 1.6 A·m^(-1))ultra-wide annealing temperature window(from 613 to 733 K),and extremely high annealing stability(up to 480 min at 633 K).Furthermore,we propose a new in situ two-step mechanism for the uniformization of a-Fe nanocrystals,which is separately induced by the decomposition of the Au-P clusters and the pre-existing a-Fe nanocrystals during *** work underscores the crucial significance of micro-alloying via metastable clusters primarily influenced by metal-phosphide interactions in the process of refining a-Fe ***,i introduces a new principle for optimizing the comprehensive properties of Fe-based amorphous/nanocrystalline alloys.

关键词： Fe-based nanocrystalline alloys Soft magnetic property In-situ nano-crystallization Microalloying

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