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Achieving a large field-induced polarization and energy density in BaTiO_(3)films sputter-deposited on Si at 200℃ via a buffer-layer technique

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Journal of advanced Ceramics 2025年第3期14卷 69-78页

作者： Chao Liu Jun Ouyang Yuyao Zhao Hanfei Zhu Hongbu Cheng Zhenyan Liang Li Wang Institute of Advanced Energy Materials and Chemistry Jinan Engineering Laboratory for Multi-scale Functional MaterialsShandong Provincial Key Laboratory of Molecular EngineeringSchool of Chemistry and Chemical EngineeringQilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Key Laboratory of Key Film Materials&Application for Equipments(Hunan Province) Hunan Provincial Key Laboratory of Thin Film Materials and DevicesSchool of Material Sciences and EngineeringXiangtan UniversityXiangtan 411105China Key Laboratory for Liquid–Solid Structure Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061China

Ferroelectric oxide films with a large field-induced polarization can be used in dielectric capacitors for charge or energy storage in microelectronic systems and hence have attracted intense research interest.A high processing temperature is usually required to produce a well-crystallized polar phase and hence a large polarization in the film,corresponding to a high charge or energy ***,high processing temperature not only reduces the charge‒discharge efficiency by producing a sizable remnant polarization but is also incompatible with the integration *** this study,we address this problem by creating a large field-induced polarization(~55.8μC/cm^(2))in BaTiO_(3)films sputter-deposited on Si at 200℃ via a buffer-layer *** large polarization led to a high energy density and efficiency(Wrec≈94.7 J/cm^(3),η≈78.2%@4 MV/cm).The thickness of LaNiO_(3)buffer layer was revealed to be the key factor determining the electric polarization(remnant and field-induced ones).A 50 nm LaNiO_(3)thickness,corresponding to the aforementioned polarization and energy storage performance,not only ensures proper crystallization in the BaTiO_(3)film,but also leads to an optimal combination of polycrystalline grains with a high dielectric *** latter accounts for the majority of the field-induced *** results revealed the key role of a buffer layer in tuning the microstructure of a low-temperature deposited ferroelectric oxide ***,the excellent charge/energy storage performance of these 200℃-deposited BaTiO_(3)films has provided many opportunities for this simple dielectric in microelectronics.

关键词： ferroelectric oxide films field-induced polarization BaTiO_(3) LaNiO_(3) energy density

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Service behavior of triboelectric nanogenerators:Bridging the gap between prototypes and applications

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Nano Research 2023年第9期16卷 11731-11752页

作者： Fangfang Gao Xiaochen Xun Xuan Zhao Liangxu Xu Qi Li Bin Zhao Tian Ouyang Qingliang Liao Yue Zhang Academy for Advanced Interdisciplinary Science and Technology Beijing Advanced Innovation Center for Materials Genome EngineeringUniversity of Science and Technology BeijingBeijing 100083China Beijing Key Laboratory for Advanced Energy Materials and Technologies School of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China

The triboelectric nanogenerators(TENGs),suppling power for freely mobile and distributed electronic equipment from Internet of Things,have been considered as“the energy for the new era”.Research on the service behavior has become increasingly important for achieving the reliability evaluation and life prediction of TENGs,as TENGs advance from prototypes to practical *** to the wide selection of materials,the diversity of device structures,and the complexity of working environment,TENGs show unique characteristics in the service *** dilemmas lead to the fact that systematical summary of service behavior for TENGs is still in its ***,the progresses of the service behavior for TENGs are comprehensively reviewed from the influence of environmental factors on the service performance of TENGs to the impact of TENGs during the service on their *** summed up the performance evolution of TENGs in the real environment and the reproducibility of TENGs of which the electrical output will be restored after ***,the service adaptability of TENG is systematically discussed,including the biological and environmental ***,the challenges and opportunities that the related research faced are proposed to promote the emerging technology from laboratory to factory.

关键词： triboelectric nanogenerator self-powered sensor service behavior environmental influence

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Non-negligible role of gradient porous structure in superelasticity deterioration and improvement of NiTi shape memory alloys

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Journal of materials science & Technology 2024年第19期186卷 48-63页

作者： Yintao Zhang Daixiu Wei Yang Chen Lechun Xie Liqiang Wang Lai-Chang Zhang Weijie Lu Guang Chen State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of EducationNanjing University of Science and TechnologyNanjing 210094China Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of TechnologyWuhan 430070China School of Engineering Edith Cowan University270 Joondalup DriveJoondalupWA 6027Australia

Bone-mimicking gradient porous NiTi shape memory alloys(SMAs)are promising for orthopedic im-plants due to their distinctive superelastic functional ***,premature plastic deformation in weak areas such as thinner struts,nodes,and sharp corners severely deteriorates the superelasticity of gradient porous NiTi *** this work,we prepared gradient porous NiTi SMAs with a porosity of 50%by additive manufacturing(AM)and achieved a remarkable improvement of superelasticity by a simple solution treatment *** solution treatment,phase transformation temperatures dropped signif-icantly,the dislocation density decreased,and partial intergranular Ti-rich precipitates were transferred into the *** to as-built samples,the strain recovery rate of solution-treated samples was nearly doubled at a pre-strain of 6%(up to 90%),and all obtained a stable recoverable strain of more than 4%.The remarkable superelasticity improvement was attributed to lower phase transformation tem-peratures,fewer dislocations,and the synergistic strengthening effect of intragranular multi-scale Ti-Ni ***,the gradient porous structure played a non-negligible role in both superelasticity deterioration and *** microstructure evolution of the solution-treated central strut after constant 10 cycles and the origin of the stable superelastic response of gradient porous NiTi SMAs were *** work provides an accessible strategy for improving the superelastic performance of gra-dient porous NiTi SMAs and proposes a key strategy for achieving such high-performance architectured materials.

关键词： Shape memory alloys Superelasticity Gradient porous structure Solution treatment Stable recoverable strain

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Highly electrically conductive MOF/conducting polymer nanocomposites toward tunable electromagnetic wave absorption

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材料科学技术（英文版） 2025年第2期205卷 258-269页

作者： Xin Wu Peiyuan Kang Yinghan Zhang Haocheng Guo Shuoying Yang Qi Zheng Lianjun Wang Wan Jiang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Engineering Research Center of Advanced Glasses Manufacturing Technology Ministry of EducationDonghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering Donghua UniversityShanghai 201620China Institute of Functional Materials Donghua UniversityShanghai 201620China

Metal-organic frameworks(MOFs)have attracted significant interest as self-templates and precursors for the synthesis of carbon-based composites aimed at electromagnetic wave(EMW)***,the utilization of high-temperature treatments has introduced uncertainties regarding the compositions and microstructures of resulting ***,complete carbonization has led to diminished yields of the produced carbon composites,significantly limiting their practical ***,the exploration of pristine MOF-based EMW absorbers presents an intriguing yet challenging endeavor,primarily due to inherently low electrical *** this study,we showcase the utilization of struc-turally robust Zr-MOFs as scaffolds to build highly conductive Zr-MOF/PPy composites via an inner-outer dual-modification approach,which involves the production of conducting polypyrrole(PPy)both within the confined nanoporous channels and the external surface of Zr-MOFs via post-synthetic *** interconnection of confined PPy and surface-lined PPy together leads to a consecutive and extensive conducting network to the maximum *** therefore entails outstanding conductivity up to～14.3 S cm-1 in Zr-MOF/PPy composites,which is approximately 1-2 orders of magnitude higher than that for conductive MOF nanocomposites constructed from either inner or outer *** from the strong and tunable conduction loss,as well as the induced dielectric polarization originated from the porous structures and MOF-polymer interfaces,Zr-MOF/PPy exhibits excellent microwave attenuation capabilities and a tunable absorption frequency ***,with only 15 wt.％loading,the mini-mum reflection loss(RLmin)can reach up to-67.4 dB,accompanied by an effective absorption bandwidth(EAB)extending to 6.74 ***,the microwave absorption characteristics can be tailored from the C-band to the Ku-band by adjusting the loading of *** work provide

关键词： Conductive mof nanocomposites Electromagnetic wave absorption MOF/conducting polymer Electrical conductivity Zr-MOF/PPy

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Nucleus-targeting orange-emissive carbon dots delivery adriamycin for enhanced anti-liver cancer therapy

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Chinese Chemical Letters 2024年第6期35卷 421-426页

作者： Qiang Li Jiangbo Fan Hongkai Mu Lin Chen Yongzhen Yang Shiping Yu The Second Hospital of Shanxi Medical University Taiyuan 030001China Shanxi Medical University Taiyuan 030001China Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of EducationTaiyuan University of TechnologyTaiyuan 030024China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030032China

Carbon dots(CDs)with precise targeting function show great potential in the field of drug delivery *** this study,the functionalized nucleus-targeting orange-emissive CDs with nuclear localization sequence(NLS)were loaded with adriamycin(DOX)to obtain a nucleus-targeting orange-emissive CDs drug delivery system(CDs-NLS-DOX),which delivered DOX to tumor cell nuclei to enhance its anti-tumor *** drug carrier orange-emissive CDs showed excitation-independent behavior,stable and enhanced imaging capability and good biocompatibility in vitro and in ***,the CDs-NLS could target the nuclei efficiently,and the CDs-NLS-DOX complexes had a high drug loading rate(59.4%)after loading DOX,exhibiting p H-dependent DOX release behavior through breaking acylhydrazone bond in a weak acidic *** addition,the CDs-NLS-DOX complexes exhibited an enhanced killing activity against human hepatoma cells(HepG2).The in vivo therapeutic effects on HepG2 nude mice transplanted tumors indicated the CDs-NLS-DOX had a stronger ability to inhibit tumor growth compared to free *** short,CDs-NLS-DOX is expected to be a precise and efficient nucleus-targeting nano-drug delivery system for tumor treatment.

关键词： Carbon dots Nucleus-targeting Adriamycin Drug delivery system Liver cancer therapy

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Improved interfacial adhesion for stable flexible inverted perovskite solar cells

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Journal of Energy Chemistry 2023年第1期76卷 288-294,I0008页

作者： Jie Dou Qizhen Song Yue Ma Hao Wang Guizhou Yuan Xueyuan Wei Xiuxiu Niu Sai Ma Xiaoyan Yang Jing Dou Shaocheng Liu Huanping Zhou Cheng Zhu Yihua Chen Yujing Li Yang Bai Qi Chen Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications MIIT Key Laboratory for Low-dimensional Quantum Structure and DevicesExperimental Center of Advanced MaterialsSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China School of Materials Science and Engineering Peking UniversityBeijing 100871China

Flexible perovskite solar cells have attracted widespread attention due to their unique advantages in lightweight,high flexibility,and easy deformation,which are suitable for portable ***,the inverted(p-i-n)structured devices suffer from poor stability largely due to the low adhesion at the brittle interface(the hole transport layer/perovskite).Herein,zeolitic imidazolate framework-67(ZIF-67)is applied to inverted structured cells to optimize the interface and prolong the device *** a result,the flexible devices based on ZIF-67 obtain the champion power conversion efficiency of 20.16%.Over 1000 h under continuous light irradiation,the device retains 96%and 80%of its original efficiency without and with bias,***,devices show mechanical endurance with over 78%efficiency retention after 10,000 cycles of consecutive bending cycles(R=6 mm).The introduction of ZIF-67 suppresses the cracking in device bending,which results in improved environmental stability and bending durability.

关键词： ZIF-67 Flexible perovskite solar cells Interfacial adhesion Stability

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Selective oxidation of emerging organic contaminants in heterogeneous Fenton-like systems

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Nano Research 2024年第11期17卷 9300-9325页

作者： Sheng Wang Yuxin Lu Shangkun Pei Xiang Li Bo Wang Key Laboratory of Cluster Science Ministry of Education Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials Advanced Technologies Research Institute (Jinan) Advanced Research Institute of Multidisciplinary Science School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing 100081 China

Heterogeneous Fenton-like reaction shows great potential for eliminating organic substances (e.g. emerging organic contaminants (EOCs)) in water, which has been widely explored in recent decades. However, the catalytic mechanisms reported in current studies are extremely complicated because multiple mechanisms coexist and contribute to the removal efficiencies. Most importantly, heterogeneous systems show selective oxidation properties, which are crucial for improving the efficiencies in the catalytic elimination of organic substances. Thus, this critical review summarizes and compares the diverse existing mechanisms (non-radical and radical pathways) in heterogeneous catalytic processes based on recent studies. The typical oxidation mechanisms during selective advanced oxidation of EOCs were systematically discussed based on the following sections, including the selective adsorption and generation of reactive oxygen species (ROS) in photo/electron-Fenton and Fenton-like systems. Moreover, the non-radical pathways are discussed in depth by the singlet oxygen, high-valent metal-oxo, electron transfer process, etc. Moreover, the direct oxidative transfer process for the removal of EOCs was introduced in recent studies. Finally, the cost, feasibility as well as the sustainability of heterogeneous Fenton-like catalysts are summarized. This review offers useful guidance for developing suitable strategies to develop materials for decomposing the organic substrates.

关键词： emerging organic contaminants heterogeneous advanced oxidation process heterogeneous activators selectivity

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Entropy engineering Activates Cu-Fe Inertia Center From Prussian Blue Analogs With Micro-Strains for Oxygen Electrocatalysis in Zn-Air Batteries

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Carbon Energy 2025年第5期7卷 130-139页

作者： Han Man Guanyu Chen Fengmei Wang Jiafeng Ruan Yihao Liu Yang Liu Fang Fang Renchao Che Department of Materials Science Fudan University Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative Materials Academy for Engineering & Technology Advanced Coatings Research Center of Ministry of Education of China Fudan University Yiwu Research Institute of Fudan University

By the random distribution of metals in a single phase, entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures, realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy, hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates. Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts, implemented by entropy-engineered Prussian blue analogs(PBA) as precursors to enhance the catalytic activity of primary Cu-Fe active sites. Through the introduction of the micro-strains driven by entropy engineering, density functional theory(DFT)calculations and geometric phase analysis(GPA) using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates. Furthermore, the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area, maximizing the catalytic activity for both ORR and OER. Notably, the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay. This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions.

关键词： Prussian blue analog strains transition metal-based catalyst zinc-air battery

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Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix

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Chinese Chemical Letters 2025年第2期36卷 202-205页

作者： Tianyi Yang Fangxi Su Dehuan Shi Shenghong Zhong Yalin Guo Zhaohui Liu Jianfeng Huang State Key Laboratory of Coal Mine Disaster Dynamics and Control Institute of Advanced Interdisciplinary StudiesSchool of Chemistry and Chemical EngineeringChongqing UniversityChongqing 400044China Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesCollege of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

Propane dehydrogenation(PDH)is a vital industrial process for producing propene,utilizing primarily Cr-based or Pt-based *** catalysts often suffer from challenges such as the toxicity of Cr,the high costs of noble metals like Pt,and deactivation issues due to sintering or coke formation at elevated *** introduce an exceptional Ru-based catalyst,Ru nanoparticles anchored on a nitrogendoped carbon matrix(Ru@NC),which achieves a propane conversion rate of 32.2%and a propene selectivity of 93.1%at 550°C,with minimal coke deposition and a low deactivation rate of 0.0065 h^(-1).Characterizations using techniques like TEM and XPS,along with carefully-designed controlled experiments,reveal that the notable performance of Ru@NC stems from the modified electronic state of Ru by nitrogen dopant and the microporous nature of the matrix,positioning it as a top contender among state-of-the-art PDH catalysts.

关键词： Propane dehydrogenation Ru nanoparticles Porous carbon matrix Ru@NC Electronic interaction

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Machine learning design of 400 MPa grade biodegradable Zn-Mn based alloys with appropriate corrosion rates

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International Journal of Minerals,Metallurgy and materials 2024年第12期31卷 2727-2736页

作者： Wangzhang Chen Wei Gou Yageng Li Xiangmin Li Meng Li Jianxin Hou Xiaotong Zhang Zhangzhi Shi Luning Wang Beijing Advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China Institute of Materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China School of Computer and Communication Engineering Shunde Innovation SchoolUniversity of Science and Technology BeijingShunde 528399China

The commonly used trial-and-error method of biodegradable Zn alloys is costly and *** this study,based on the self-built database of biodegradable Zn alloys,two machine learning models are established by the first time to predict the ultimate tensile strength(UTS)and immersion corrosion rate(CR)of biodegradable Zn alloys.A real-time visualization interface has been established to design Zn-Mn based alloys;a representative alloy is *** tensile mechanical properties and immersion corrosion rate tests,its UTS reaches 420 MPa,and the prediction error is only 0.95%.CR is 73μm/a and the prediction error is 5.5%,which elevates 50 MPa grade of UTS and owns appropriate corrosion ***,influences of the selected features on UTS and CR are discussed in *** combined application of UTS and CR model provides a new strategy for synergistically regulating comprehens-ive properties of biodegradable Zn alloys.

关键词： Zn alloys machine learning alloy design performance prediction

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