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Single atom Pd1/ZIF-8 catalyst via partial ligand exchange

Nano Research 2023年第5期16卷 8003-8011页

作者： Xin Li Fengwei Zhang Xu Han Jun-Hao Wang Xiaoqin Cui Peng Xing Huan Li Xian-Ming Zhang Institute of Crystalline Materials Shanxi UniversityTaiyuan 030006China Country College of Chemistry&Chemical Engineering Key Laboratory of Interface Science and Engineering in Advanced MaterialMinistry of EducationTaiyuan University of TechnologyTaiyuan 030024China

A partial ligand exchange strategy for fabricating catalytically active single palladium site immobilized on zeolitic imidazolate framework-8(ZIF-8,Pd1/ZIF-8)is proposed in this *** one-step synthesis simply involves reacting Na_(2)PdCl_(4) with ZIF-8 in *** Cl ligands of Na_(2)PdCl_(4) exchanged with 2-methylimidazole(2-MeIm)of the framework,resulting in the anchoring Pd on the framework and dissociation of Zn into the *** whole synthesis is performed at ambient conditions and the crystalline integrity of ZIF-8 is well *** resulting Pd_(1)/ZIF-8 is extensively characterized by different techniques which confirm the proposed ***_(1)/ZIF-8 is also successfully applied in the size-selective semi-hydrogenation of alkynes.

关键词： single atom catalyst metal-organic frameworks ligand exchange hydrogenation

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Design of pH-universal electrocatalysts for hydrogenevolution reaction

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Carbon Energy 2024年第11期6卷 27-58页

作者： Jingwen Lin Xu Wang Zhenyun Zhao Dongliang Chen Rumin Liu Zhizhen Ye Bin Lu Yang Hou Jianguo Lu State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang UniversityHangzhouChina Institute of Wenzhou Zhejiang UniversityWenzhouChina Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang UniversityHangzhouChina

The path to searching for sustainable energy has never stopped since thedepletion of fossil fuels can lead to serious environmental pollution andenergy *** water electrolysis to produce hydrogen has beenproven to be a prioritized approach for green resource *** is highlycrucial to explore inexpensive and high-performance electrocatalysts foraccelerating hydrogen evolution reaction(HER)and apply them to industrialcases on a large ***,we summarize the different mechanisms of HERin different pH settings and review recent advances in ***,based on the previous efforts,we discuss severaluniversal strategies for designing pH-independent catalysts and showdirections for the future design of pH-universal catalysts.

关键词： design strategy hydrogen evolution reaction pH-universal electrocatalysts

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Some facets of the Mg/Na_(3)VCr_(0.5)Fe_(0.5)(PO_(4))_(3) battery

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Chinese Chemical Letters 2024年第10期35卷 469-473页

作者： Gregorio F.Ortiz Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information DisplaysCollege of Materials Science and EngineeringHuaqiao UniversityXiamen 361021China

Magnesium rechargeable batteries(MRBs)present opportunities for grid-scale energy storage applications as a complement to Li-ion batteries(LIBS).The major challenges are the low reversible capacity,inferior cycling stability and unsatisfactory energy ***_(3)VCr_(0.5)Fe_(0.5)(PO_(4))_(3) with a well-defined NASIONtype structure is used as cathode in Mg ***-electrons reaction(~116 m Ah/g),1.5 V average voltage and 65%of capacity retention over 100 cycles are *** is inserted by a biphasic reaction with the participation of V3+/V4+/V5+redox couples in the electrochemical reaction while the non-active redox couples such as Cr^(3+)/Cr^(4+)and Fe^(2+)/Fe^(3+)served as stabilizer to buffer the volume variation.A thermal stability up to~412℃ is also ***,incorporating a mixture of three transition metal(V/Cr/Fe)in this type of structures will broaden new perspectives for realizing high performance cathodes for MRBs.

关键词： Multi-electron reaction Mg batteries NASICON Na_(3)VCr_(0.5)Fe_(0.5)(PO_(4))_(3) Ironand chromium doping

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Mechanical behavior of TiAl alloys

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science China(Technological sciences) 2023年第9期66卷 2457-2480页

作者： XIANG HengGao CHEN Yang QI ZhiXiang ZHENG Gong CHEN FengRui CAO YueDe LIU Xu ZHOU Bing CHEN Guang National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of EducationNanjing University of Science and TechnologyNanjing 210094China

Intermetallic TiAl alloys attract much attention in advanced engineering fields due to their low density(3.9–4.2 g/cm3) and excellent high-temperature properties. After more than half a century of research and development, TiAl alloys have found applications in aerospace, automotive, and related industries. However, as a kind of semi-brittle materials, intermetallic TiAl alloys exhibit different mechanical behavior from metallic and ceramic materials. Thus, it is necessary to systematically understand their mechanical behavior to ensure further developments and safe engineering applications. In this paper, the principal mechanical behavior of Ti Al alloys was reviewed comprehensively, including tension, creep, fatigue, and strengthening mechanisms. The mechanical performance and the corresponding deformation mechanisms are summarized and discussed in detail. The future directions of mechanical research on TiAl alloys are also overviewed to expedite their extensive utilization in engineering fields.

关键词： TiAl tension creep fatigue strengthening mechanisms

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Effect of Ca Micro-Alloying on the Microstructure and Anti-Corrosion Property of Mg0.5Zn0.2Ge Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1147-1160页

作者： Bishan Cheng Depeng Li Baikang Xing Ruiqing Hou Pingli Jiang Shijie Zhu Shaokang Guan School of Materials Science and Engineering and Henan Key Laboratory of Advanced Magnesium Alloys Zhengzhou UniversityZhengzhou450001China Center of Advanced Analysis and Gene Sequencing Zhengzhou UniversityZhengzhou450001China Key Laboratory of Materials Processing and Mold Technology Ministry of EducationZhengzhou450002China

Magnesium and its alloys have attracting rising attention as one of biodegradable metallic ***,the rapid corrosion and severe localized corrosion still hinder their extensive applications in *** this study,micro-alloying of Ca(≤0.1 wt%)into Mg0.5Zn0.2Ge alloy developed in our previous work was explored to further enhance the corrosion resistance and alleviate the localized corrosion of the *** results reveal that the addition of Ca leads to the transformation of the cathodic Mg_(2)Ge phase in Mg0.5Zn0.2Ca alloy into anodic MgCaGe phase in Ca-containing alloys,thereby changing the galvanic couples in alloys during *** preferential dissolution of MgCaGe phase promotes the participation of Ca and Ge into the formation of corrosion products,resulting in the enrichment of Ca and Ge in the outmost of corrosion product layer,which stabilizes and passivates the corrosion product layer on Mg alloy ***,the enrichment of Zn at the corrosion interface seems to further hinder the corrosion of Mg *** of these factors confer a slower and more uniform corrosion on Mg0.5Zn0.2GexCa(x<0.1 wt%)alloy,which provides favorable candidates for the further processing to gain suitable biodegradable Mg alloys.

关键词： Magnesium alloy Micro-alloying Calcium Corrosion resistance

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Ultra-high-temperature application of MXene: Stabilization of 2D Ti_(3)C_(2)T_(x) for cross-scale strengthening and toughening of 3D TiC

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Journal of advanced Ceramics 2024年第1期13卷 1-10页

作者： Lu Liu Guobing Ying Quanguo Jiang Dong Wen Peng Wang Meng Wu Ziying Ji Yongting Zheng Xiang Wang Department of Materials Science and Engineering College of Mechanics and MaterialsHohai UniversityNanjing 211100China Key Laboratory of Superlight Materials&Surface Technology Ministry of EducationHarbin Engineering UniversityHarbin 150001China Shenzhen Key Laboratory for Advanced Materials School of Materials Science and EngineeringHarbin Institute of Technology(Shenzhen)Shenzhen 518055China Center for Composite Materials and Structures Harbin Institute of TechnologyHarbin 150001China

Transition metal carbide/nitride cores within MXenes make them considerably useful for ultra-high-temperature ***,extensive research on Ti_(3)C_(2)T_(x) MXene has revealed its tendency to undergo a phase transition to TiCy at temperatures above 800℃due to high activity of a superficial Ti atomic ***,spark plasma sintering of Ti_(3)C_(2)T_(x) and TiC is performed to prevent the Ti_(3)C_(2)T_(x) phase transition at temperatures up to 1900℃through the fabrication of composites at a pressure of 50 *** a focused ion beam scanning electron microscope to separate layered substances in the composites and examining selected area diffraction spots in a transmission electron microscope enabled identification of non-phase-transitioned ***-principles calculations based on density functional theory indicated the formation of strong chemical bonding interfaces between Ti_(3)C_(2)T_(x) and TiC,which imposed a stability constraint on the Ti atomic layer at the Ti_(3)C_(2)T_(x) *** performance tests,such as three-point bending and fracture toughness analysis,demonstrated that the addition of Ti_(3)C_(2)T_(x) can effectively improve the cross-scale strengthening and toughening of the TiC matrix,providing a new path for designing and developing two-dimensional(2D)carbides cross-scale-enhanced three-dimensional(3D)carbides with the same elements relying on a wide variety of MXenes.

关键词： MXene ultra-high-temperature phase stability interface bonding cross-scale strengthening and toughening structural ceramic composites

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Strengthening and toughening bulk Ni_(2)CoFeV_(0.5) medium-entropy alloy via thermo-mechanical treatment

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Journal of materials science & Technology 2023年第20期151卷 19-29页

作者： Lei Gu Rui Hou Yi Liu Guang Chen Jihua Liu Gong Zheng Ruisheng Zhang Yonghao Zhao National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of EducationNanjing University of Science and TechnologyNanjing 210094China

Single-phase face-centered cubic(fcc)medium-and high-entropy alloys(MEAs/HEAs)have high ductility but low yield *** this work,the microstructures of single-phase fcc Ni_(2)CoFeV_(0.5) MEAs were tailored by cold-rolling and subsequent annealing and typical heterogeneous lamella(HL)structures composed of recrystallized micro-grain lamellae(with an averaged grain size of∼4μm)and nonrecrystallized nano-/ultrafine-grain lamellae were *** tests revealed that most HL samples exhibited excellent strength and ductility *** HL sample with∼23 vol%recrystallized grains annealed at 590℃ for 1 h had a high yield strength of 1120 MPa and a good fracture elongation of 12.3%,which increased by 5%and 46%,respectively compared with those of as-rolled ***-induced yield strength increase is attributed to high-density annealing twin boundaries(TBs)in the recrystallized grains,the annihilation of mobile dislocations inside the non-recrystallized grains,and extra heterodeformation-induced strengthening produced by the HL ***-Petch relationship of Ni_(2)CoFeV_(0.5) MEA can be reasonably described by counting both TBs and grain boundaries,with lattice friction stress of 87.3 MPa and coefficient of 722.8 MPaμm1/*** work provides optional and controllable solutions for preparing MEAs/HEAs with excellent mechanical properties by low-cost and high-efficiency thermomechanical treatments.

关键词： Medium-entropy alloys Microstructures Strength and ductility Heterogeneous lamella structure Cold-rolling Annealing

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Anisotropic growth of nano-precipitates governed by preferred orientation and residual stress in an Al-Zn-Mg-Cu alloy

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Journal of materials science & Technology 2024年第21期188卷 234-251页

作者： Runze Wang Hongyun Luo Sujun Wu Tianshu Zhao Xin Wang Robert O.Ritchie School of Materials Science and Engineering Beihang UniversityBeijing 100191China Key Laboratory of Aerospace Materials and Performance Beihang UniversityBeijing 100191China Beijing Key Laboratory of Advanced Nuclear Materials and Physics Beihang UniversityBeijing 100191China Beijing Advanced Innovation Centre for Biomedical Engineering Beihang UniversityBeijing 100191China Surface Engineering Institution AECC Beijing Institute of Aeronautical MaterialsBeijing 100095China Department of Materials Science and Engineering University of CaliforniaBerkeleyCA 94720USA

Through an understanding of diffusion,precise control of the size distribution of nano-precipitates can be essential to developing superior properties in precipitation-strengthened *** a significant influence of crystallographic orientation on the diffusion process is known to exist in low-symmetry hexagonal close-packed alloys,such anisotropic diffusion is still unidentified in high-symmetry cubic *** this work,we reveal the diffusion-controlled coarsening induced anisotropic growth process of nano-precipitates in an Al-Zn-Mg-Cu *** experimental and theoretical studies demonstrate that with an increase in the residual stress,the diffusion-controlled coarsening rate is slow along the<112>fiber texture in the alloy matrix with smaller grain *** such,we find that the diffusion activation energy will be increased along the preferred orientation with largest residual stress,which leads to a reduced diffusion-controlled coarsening ***,we demonstrate that the increase in the volume fraction of nano-precipitates originates from the rapid grain-boundary controlled coarsening of the grainboundary *** on these results,an underlying microstructural design strategy is proposed,involving the crystallographic orientation,the residual stress and the grain boundaries to manipulate the precipitate size distribution in this class of alloys.

关键词： Aluminum alloy Precipitate coarsening behavior Preferred orientation Diffusion coefficient Residual stress

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Perspective about gasoline soot combustion over ceria catalysts:A close look into the"active oxygen"enigma

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Journal of Rare Earths 2025年第4期43卷 641-659,I0001页

作者： Zilin Tu Gongde Wu Changlong Zheng Xiaodong Wu Jie Wan Shuang Liu School of Materials Science and Engineering Ocean University of ChinaQingdao266100China Energy Research Institute Nanjing Institute of TechnologyNanjing211167China Key Laboratory of Advanced Materials of Ministry of Education of China School of Materials Science and EngineeringTsinghua UniversityBeijing100084China

Catalyzed gasoline particulate filters(cGPFs)are being developed to enable compliance with the particulate number limits for passenger cars equipped with gasoline direct injection(GDI)engines in China and Europe,It is appealing to build catalysts with ceria—an irreplaceable"reducible"component in three-way converters—to help eliminate the soot particles trapped in cGPFs via O_(2)-assisted *** research aiming at understanding how these recipes function has continued for more than two decades,a universal model elucidating the roles of different"active oxygen"species is yet to be *** this perspective,by critically assessing the reported data about gasoline soot catalytic combustion over ceria catalysts,it is suggested that ceria ignites soot through contributing its lattice oxygen,giving rise to a"hot ring"region at the periphery of soot-catalyst *** the"re-oxidation"semi-cycles,electrophilic superoxides and/or peroxides(O_(x)^(n-))are produced at the Ce^(3+)and oxygen vacancy sites enriched in this collar-like region,and then work as key reactive phases for soot deep *** on this"O_(x)^(n-)assisted"Mars-van Krevelen mechanism,several guidelines for ceria catalyst designing are proposed,ending with a summary about where future opportunities and challenges may lie in developing efficient and practical cGPF catalysts.

关键词： Gasoline particulate filter Soot combustion Ceria catalysts Rare earths Reaction mechanism Catalyst design

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Effect of Mn alloying on the hydrogen-assisted cracking behavior in multiphase/duplex stainless steel

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材料科学技术（英文版） 2025年第4期207卷 126-141页

作者： Menghao Liu Cuiwei Du Xiaogang Li Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Key Laboratory for Corrosion and Protection of the Ministry of Education Institute of Advanced Materials & TechnologyUniversity of Science and Technology BeijingBeijing 100083China National Materials Corrosion and Protection Data Center University of Science and Technology BeijingBeijing 100083China

There remains debate on whether Mn is beneficial or detrimental to hydrogen embrittlement in stainless *** this work,a series of stainless steels were designed to study the change of hydrogen embrit-tlement sensitivity,crack propagation,and hydrogen trapping behaviors upon Mn *** results suggest that adding 4 wt.％Mn increased hydrogen embrittlement susceptibility,whereas adding 8 wt.％Mn decreased hydrogen embrittlement *** banded α'-martensite through austenitic grain is the main reason for the increased hydrogen embrittlement sensitivity when adding 4 wt.％Mn,by ad-sorbing hydrogen,promoting crack initiation,and accelerating crack propagation.

关键词： Hydrogen-assisted cracking Multiphase stainless steel Manganese

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