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Superacid assisted high-throughput production and solution-processing of pristine two-dimensional materials

Materials Today 2025年 86卷 228-237页

作者： Deng, Qixuan Ma, Jiabin Liu, Minsu Zhou, Yicong Ding, Siyuan Zhan, Ke Zhu, Yuan Xiong, Zhiyuan Su, Yang Yu, Kuang Cheng, Hui-Ming Qiu, Ling Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Laboratory for Simulation and Modelling of Particulate Systems Department of Chemical Engineering Department of Materials Science and Engineering Monash University VIC3800 Australia Monash Suzhou Research Institute Monash University Suzhou Suzhou SIP215000 China School of Microelectronics Southern University of Science and Technology Shenzhen518055 China School of Light Industry and Engineering South China University of Technology Guangzhou510640 China Shenzhen Key Lab of Energy Materials for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences 1068 Xueyuan Road Shenzhen518055 China Faculty of Materials Science and Energy Engineering Shenzhen University of Advanced Technology 291 Louming Road Shenzhen518107 China

Pristine two-dimensional (2D) materials have a multitude of interesting properties, promising a broad spectrum of applications. However, their poor affinity for common solvents and tendency to aggregate impede their effective exfoliation and solution-processing into various structures, such as fibers and membranes, thus limiting their practical use. We report a high-efficiency method for producing pristine 2D nanosheets by direct high-speed shearing exfoliation in trifluoromethanesulfonic acid (TfOH). Typically, this method produces hexagonal boron nitride nanosheets (BNNSs) with an unprecedented throughput of 38.8 mg mL-1h−1. The effective exfoliation is attributed to the strong binding affinity, large dipole moment and steric repulsion of TfOH, which collectively introduce layer edge distortion in hexagonal boron nitride (hBN), facilitating its exfoliation. The mechanical exfoliation and reversible edge interaction introduce no additional functional groups to the exfoliated BNNSs. The resulting pristine BNNS exhibit remarkable stability in TfOH solutions at ultrahigh concentrations of 200 mg mL−1 for over 28 days. The viscosity of the highly concentrated BNNS/TfOH dispersion can be adjusted, enabling techniques to produce BNNS-based spheres, fibers, and membranes with high thermal conductivity and mechanical strength, suitable for advanced thermal management applications. Room temperature processed BNNS-based spheres exhibit superior thermal conductivity compared to high temperature processed commercially available hBN or Al2O3 spheres. Moreover, TfOH can also be used to assist the efficient production and solution-processing of other 2D nanosheets, including graphene, molybdenum disulfide and tungsten disulfide, enabling the fabrication of high-quality bulk assemblies. © 2025 Elsevier Ltd

关键词： Molybdenum disulfide

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Chaotic dynamics of granules-beam coupled vibration: Route and threshold

arXiv

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arXiv 2024年

作者： Li, Hang Li, Jian Fei, Hongzhu Hong, Guangyang Dong, Jinlu Yu, Aibing Key Laboratory of Structural Dynamics of Liaoning Province College of Sciences Northeastern University Shenyang110819 China ARC Research Hub for Computational Particle Technology Department of Chemical Engineering Monash University ClaytonVIC3800 Australia Centre for Simulation and Modelling of Particulate Systems Monash-Southeast University Joint Research Institute Suzhou China

Although granular materials are the second most processed in industry after water, the theoretical study of granules-structure interactions is not as advanced as that of fluid-structure interactions due to the lack of a unified view of the constitutive relation of granular materials. In the previous work [1], the theoretical model of granules-beam coupled vibration was developed and verified by experiments. However, it was also found that the system exhibits significant stiffness-softening Duffing characteristics even under micro-vibration, which implies that chaotic responses may be reached under certain conditions. To reveal the route and critical conditions for the system to enter chaos, in the present work, the chaotic dynamics of the system are studied. In qualitative analysis, Melnikov method is applied to analyze the instability behavior of the perturbed heteroclinic orbit of the system, thus the critical condition for the system to enter Smale horseshoe chaos, i.e., the Melnikov criterion, is obtained. The validity of the criterion is verified numerically. In experimental studies, the existence of chaotic responses and the route to chaos for granules-beam coupled vibrations is revealed. The experimental results suggest that the system response first experiences symmetry-breaking then undergoes a complete period-doubling cascade, and finally enters single-scroll chaos. In addition, although the Additional Dynamic Load (ADL) generated by granular media is highly complicated, a general and simple evolution pattern of the chaos threshold is found by parametric experiments, which is also supported by the Melnikov criterion. In short, the chaotic dynamics of granules-beam coupled vibration is revealed, which is a contribution to the engineering vibration aspect. On the theoretical side, an impressive result lies in that for the first time, the Melnikov criterion of such fractional-order systems is obtained in a global and closed form, which provides, respectively,

关键词： Granulation

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Boric Acid-Regulated Gelation and Ethanol-Assisted Preparation within Polybenzoxazine Aerogels Toward Excellent Flame Resistance, Alterable Wettability, and Effective Thermal Insulation

SSRN

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SSRN 2023年

作者： Zhou, Jinlong Xiao, Yunyun Liu, Saihui Li, Zeyu Liu, Xinyi Zhang, Sizhao Li, Zhengquan International Institute for Innovation Jiangxi University of Science and Technology Jiangxi Nanchang330013 China Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi Nanchang330013 China School of Energy and Mechanics Jiangxi University of Science and Technology Jiangxi Nanchang330013 China

Polybenzoxazine aerogels have gained widespread attention in recent years, but the prevalent use of hazardous solvents in the preparation process has severely impeded their further development and promotion for practical applications. Herein, using ethanol as a solvent, a strategy of boric acid-induced microstructure regulation is proposed to construct boron-doped polybenzoxazine (BPBz) aerogels, which provides a feasible approach to overcome the above situation. The introduction of boric acid enhances the backbone strength by forming intermolecular bridging structures between PBz chains and allows the use of ambient pressure drying. The resulting BPBz aerogel demonstrates high stiffness (specific modulus up to 266.02 kN·m·kg−1), low bulk density (0.203 g·cm−3), and low thermal conductivity (0.043 W·m−1·K−1), exhibiting excellent fire resistance when exposed to a 1200 °C flame (the self-extinguishing interval less than 1 s). More interestingly, the aerogel demonstrates intrinsic and tunable wettability that correlates with the morphology. Combining the environmentally friendly preparation strategy and these advantages, BPBz aerogels hold promise for thermal management and fire protection applications in energy-saving construction and other harsh conditions. © 2023, The Authors. All rights reserved.

关键词： Boric acid

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Dual-function artificial CA/PVP interlayer for protect Zn anode on improving uniform Zn 2+ ion deposition

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Electrochimica Acta 2025年 535卷

作者： Lanlan Fan Xiangguo Zhang Junwen Deng Lei Cao Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems International Institute for Innovation Jiangxi University of Science and Technology Nanchang 330013 China

Aqueous Zn-ion batteries (ZIBs) have come into the public's view because of their low cost, high theoretical capacity and safety. However, uncontrollable dendrite growth on the Zn anode surface is the key reason restricting the long-cycle stability of ZIBs. Herein, a highly water-soluble polyvinylpyrrolidone and cellulose acetate (CA/PVP) interlayer was used to enhance the lifespan of battery cycles and provide excellent suppression of dendrite growth and side reaction generation. On the one hand, the water-soluble PVP can swell in the electrolyte, forming local electrolyte gelation on the surface of the Zn anode, balancing the transmission of Zn 2+ flow. On the other hand, the synergistic effect of carbon based ( C = O ) and hydroxyl groups (-OH) in the interlayer can facilitate the desolvation of hydrated Zn 2+ . Furthermore, C = O complexes with Zn 2+ ions can increase the hydrophilicity of the Zn anode, reduce interfacial impedance and further optimize Zn 2+ transport kinetics. Subsequently, the Zn||Zn symmetric battery, constructed with a CA/PVP interlayer, is capable of sustaining a prolonged cycling performance exceeding 1000 h at a current density of 0.1 mA cm -2 /0.05 mAh cm -2 . At the same time, the CA/PVP 3 % @Zn full cell demonstrate 94 % of capacity retention after 300 cycles at 0.5 A g -1 . The successful construction of artificial interfacial layers provides an attractive strategy for the development of high-performance aqueous ZIBs.

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Particle-Scale modelling of Injected Hydrogen and Coke Co-Combustion in the Raceway of an Ironmaking Blast Furnace

SSRN

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SSRN 2022年

作者： Dianyu, E. Zhou, Peng Ji, Langyong Cui, Jiaxin Xu, Qiang Guo, Liejin Yu, Aibing International Institute for Innovation Jiangxi University of Science and Technology Ganzhou341000 China Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi University of Science and Technology Ganzhou341000 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China ARC Research Hub for Computational Particle Technology Department of Chemical Engineering Monash University VIC3800 Australia Centre for Simulation and Modelling of Particulate Systems Southeast University Monash University Joint Research Institute Suzhou215123 China

Hydrogen is an environmentally friendly fuel that does not produce greenhouse gas (GHG) emissions. Its applications have attracted significant attention from many industries, especially the ironmaking industry, which consumes massive amounts of fossil energy. The injection of hydrogen into a blast furnace (BF) is one of the most promising low-carbon ironmaking routines. In this study, an experimentally validated CFD-DEM model is adopted to investigate the dynamics, microstructure and thermochemical behaviours in the raceway of a BF with hydrogen injection operations (HIOs), which include raceway evolution, force distribution and the co-combustion characteristics of hydrogen and coke. Some significant features are obtained through comparison analyses between HIOs and air injection operations (AIOs). In particular, the effects of the hydrogen injection concentration on the raceway size, gas temperature and components are studied. The simulation results show that a smaller raceway is formed under HIOs in comparison with that of AIOs. In addition, the gas temperature is higher near the tuyere but lower along the tuyere axis, and the oxygen consumption is larger and produces more CO. As the hydrogen injection concentration increases: (i) the raceway size and gas temperature decrease;(ii) the CO is generated at the early stage and the maximum CO2 concentration moves to inlet direction along the tuyere axis. The results provide insights on the fundamental understanding of low-carbon ironmaking BF technology. © 2022, The Authors. All rights reserved.

关键词： Blast furnaces

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Balancing Ventilation Performance and Energy Conservation: An Integrated Multi-Objective Optimization and Preference Decision-Making Model for Optimizing Impinging Jet Ventilation

SSRN

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SSRN 2023年

作者： Dianyu, E. Tan, Cong Li, Jing Shi, Guangsi Liu, Yonggang Liu, Sida Yi, Lei Zhou, Zongyan Cui, Jiaxin Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi University of Science and Technology Nanchang330013 China International Institute for Innovation Jiangxi University of Science and Technology Nanchang330013 China ARC Research Hub for Computational Particle Technology Department of Chemical and Biological Engineering Monash University VIC3800 Australia

Balancing the requirements for thermal comfort (TC) and indoor air quality (IAQ) while minimizing energy consumption (EC) is a challenging trade-off problem in impinging jet ventilation (IJV), which has great potential for energy savings. Multi-criteria decision-making (MCDM) technology is a rapid and effective approach to address this issue in response to changing outdoor weather conditions. However, conflicting ventilation performances, such as TC (e.g. draught rate (DR), predictive mean vote (PMV)), IAQ (e.g. air change efficiency (ACE), local mean age of air (LMAA)) and EC, may present challenges in identifying optimal ventilation parameters. This study therefore proposes an integrated multi-objective optimization (MOO) and MCDM model to overcome this limitation. The former, which yields Pareto solutions, is to maintain ventilation performance indicators with good TC or IAQ standards within an acceptable range (e.g. -0.5 © 2023, The Authors. All rights reserved.

关键词： Energy conservation

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Balancing Ventilation Performance and Energy Conservation: An Integrated Multi-Objective Optimization and Preference Decision-Making Model for Optimizing Impinging Jet Ventilation

SSRN

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SSRN 2023年

作者： Dianyu, E. Tan, Cong Li, Jing Shi, Guangsi Liu, Sida Yi, Lei Zhou, Zongyan Cui, Jiaxin Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi University of Science and Technology Nanchang330013 China International Institute for Innovation Jiangxi University of Science and Technology Nanchang330013 China ARC Research Hub for Computational Particle Technology Department of Chemical and Biological Engineering Monash University VIC3800 Australia

Balancing the requirements for thermal comfort (TC) and indoor air quality (IAQ) while minimizing energy consumption (EC) is a challenging trade-off problem in impinging jet ventilation (IJV), which has great potential for energy savings. Multi-criteria decision-making (MCDM) technology is a rapid and effective approach to address this issue in response to changing outdoor weather conditions. However, conflicting ventilation performances, such as TC (e.g. DR, PMV), IAQ (e.g. ACE, LMAA) and EC, may present challenges in identifying optimal ventilation parameters. This study therefore proposes an integrated multi-objective optimization (MOO) and MCDM model to overcome this limitation. The former, which yields Pareto solutions, is to maintain ventilation performance indicators with good TC or IAQ standards within an acceptable range (e.g. -0.5 © 2023, The Authors. All rights reserved.

关键词： Energy conservation

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Balancing Ventilation Performance and Energy Conservation: An Integrated Multi-Objective Optimization and Preference Decision-Making Model for Optimizing Impinging Jet Ventilation

SSRN

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SSRN 2023年

关键词： Energy conservation

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Study on Effects of Operation Parameters on Ventilation Performances for a Floor-Standing Air Conditioner

SSRN

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SSRN 2022年

作者： Dianyu, E. Tan, Cong Li, Jing Liu, Sida Zhou, Zongyan Cui, Jiaxin Yi, Lei Jiangxi Provincial Key Laboratory for Simulation and Modelling of Particulate Systems Jiangxi University of Science and Technology Nanchang330013 China International Institute for Innovation Jiangxi University of Science and Technology Nanchang330013 China ARC Research Hub for Computational Particle Technology Department of Chemical and Biological Engineering Monash University VIC3800 Australia

The floor-standing air conditioners (FSACs) have been widely used in civil and office buildings because of its advantages of high cooling/heating capacity and easy installation. The major challenge of FSACs is to meet the requirements of thermal comfort and indoor air quality (IAQ) while the operation energy consumption should be minimized. This study extensively examines the effects of some key operation parameters on the FSAC performance using validated computational fluid dynamics (CFD) method. The operation parameters include controllable supply vane angle, supply air velocity, supply air temperature, and uncontrollable outdoor weather condition. The main ventilation performance is assessed by indices such as predicted mean vote (PMV), predicted percent dissatisfied (PPD), draught rate (DR), local mean age of air (LMAA), and energy consumption (P system ). The relative importance of the operation parameters for each ventilation performance index is identified through evaluating the individual effects of the operation parameters on the ventilation performance. By comparing the individual effects and combined effects of the operation parameters on the ventilation performance, it is found that the variations of PMV, PPD, DR, LMAA and P system caused by the combined effects can be accounted by the corresponding most important operation parameters by 90.6%, 97.4%, 77.1%, 95.1% and 79.2%, respectively. Additionally, the outdoor weather conditions do not significantly affect DR, PPD and LMAA, but can shift PMV to uncomfortable levels. Finally, the constant-air-volume (CAV) system is recommended for FSACs during the steady stage and a simplified and optimized operation strategy is proposed. © 2022, The Authors. All rights reserved.

关键词： Sensitivity analysis

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Advances in reduction of NO_x and N_2O emission formation in an oxy-fired fluidized bed boiler

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Chinese Journal of Chemical Engineering 2019年第2期27卷 426-443页

作者： Khalid El Sheikh Mohammad Jakir Hossain Khan Mahar Diana Hamid Siddhartha Shrestha Brahim Si Ali G.A.Ryabov Lya A.Dolgushin Mohd Azlan Hussain Tatiana V.Bukharkina Elena A.Gorelova Dmitry Mendeleev University of Chemical Technology of Russia Department of Chemical Engineering Faculty of Engineering University of Malaya Laboratory for Simulation and Modelling of Particulate Systems Department of Chemical Engineering Monash University All-Russian Thermal Engineering Institute VTI

Fossil fuel combustion is one of the major means to meet the mounting global energy demand. However, the increasing NO_x and N_2 O emissions arising from fossil fuel combustion process have hazardous effects. Thus, mitigating these gases is vital to attain a sustainable environment. Interestingly, oxy-fuel combustion in fluidized bed for carbon capture and minimized NO_x emissions is strongly sustainable compare to the other approaches. It was assessed that NO_x formation and fuel-N conversion have significant limitation under oxy-fluidized bed compared to air mode and the mechanism of NO_x formation is still deficient and requires further development. In addition, this review paper discussed the potential of primary measure as low emission process with others supplementary techniques for feasible NO_x reduction. The influences of combustion mode, operating parameters, and reduction techniques such as flue gas recirculation, oxygen staging, biomass co-firing, catalyst, influence of fluidized bed design and structure, decoupling combustion and their merges are respectively evaluated. Findings show that significant minimization of NO_x emission can be achieved through combination of primary and secondary reduction techniques.

关键词： Oxy-fuel combustion Fluidized bed technology Biomass blend Primary/secondary measures NOx emission

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