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Synthesis, Characterization, and performance test of modified Zeolite-Si/Al nanocomposite from pumice and waste cans using slow pyrolysis process for removal pollutant parameters from hard water

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Environmental Nanotechnology, Monitoring and Management 2023年 20卷

作者： Gusti Wibowo, Yudha Sudibyo Rianjanu, Aditya Taher, Tarmizi Susanti, Noni Karo Karo, Pulung Suprihatin Iman Supriyatna, Yayat Prasetyo, Erik Bahfie, Fathan Amin, Muhammad Syarifuddin, Hutwan Safitri, Hana Khairurrijal, Khairurrijal Department of Mining Engineering Institut Teknologi Sumatera Lampung-35365 Indonesia Research Center for Mining Technology National Research and Innovation Agency Lampung Indonesia Department of Material Engineering Institut Teknologi Sumatera Lampung-35365 Indonesia Department of Environmental Engineering Institut Teknologi Sumatera Lampung-35365 Indonesia Physics Department Universitas Lampung Lampung Indonesia Department of Environmental Science Postgraduate Program Universitas Jambi Jambi 36122 Indonesia Laboratory of Mine Environmental Department of Mining Engineering Institut Teknologi Sumatera Lampung-35365 Indonesia Department of Physics Institut Teknologi Sumatera Lampung-36365 Indonesia Department of Physics Institut Teknologi Bandung Bandung 40132 Indonesia Center for Green and Sustainable Materials Institut Teknologi Sumatera Indonesia

Hard water is one of crucial problems in the world due to its pollutant parameters. Adsorption is a promising method for treating hard water because of its benefits such as low-cost, easy to use, acceptable, and easy to maintenance. In this study, we utilized zeolite functionalized with silicon/aluminum (Ze-Si/Al) as adsorbent materials for hard water treatment. Ten different ratios of Si/Al were added into zeolite by modifying the solid waste source concentration (pumice and cans). The optimum sample was then further tested with different parameters including contact time, dye concentration, and isotherm models. The zeolite-Si/Al adsorbent was characterized by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), and X-Ray Fluorescence (XRF). Results of this study have showed that the best functionalized zeolite was that with Si/Al ratio 0.67, which has higher sorption ability. In contact time test, the equilibrium was reached after 300 min. This study also informed that the concentration of dyes will give impact on removal of pollutant parameters. Isotherm model of Ze-Si/Al fitted with Langmuir method. This study also discussed the potential development and future research direction. Thus, this study is a crucial report to develop the information about waste utilization as source of Si/Al to increasing quality of zeolite. © 2023 Elsevier B.V.

关键词： Adsorption Hard water Wastewater Wastewater treatment zeolite-Si/Al

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Imaging Atomic-Scale Chemistry from Fused Multi-Modal Electron Microscopy

arXiv

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arXiv 2022年

作者： Schwartz, Jonathan Di, Zichao Wendy Jiang, Yi Fielitz, Alyssa J. Ha, Don-Hyung Perera, Sanjaya D. Baggari, Ismail El Robinson, Richard D. Fessler, Jeffrey A. Ophus, Colin Rozeveld, Steve Hovden, Robert Department of Materials Science and Engineering University of Michigan Ann ArborMI United States Mathematics and Computer Science Division Argonne National Laboratory LemontIL United States Advanced Photon Source Facility Argonne National Laboratory LemontIL United States Dow Chemical Co. MidlandMI United States Department of Material Science and Engineering Cornell University IthacaNY United States School of Integrative Engineering Chung-Ang University Seoul Korea Republic of Department of Physics Cornell University IthacaNY United States The Rowland Institute at Harvard CambridgeMA United States Department of Electrical Engineering and Computer Science University of Michigan Ann ArborMI United States National Center for Electron Microscopy Molecular Foundry Lawrence Berkeley National Laboratory BerkeleyCA United States Applied Physics Program University of Michigan Ann ArborMI United States

Efforts to map atomic-scale chemistry at low doses with minimal noise using electron microscopes are fundamentally limited by inelastic interactions. Here, fused multi-modal electron microscopy offers high signal-to-noise ratio (SNR) recovery of material chemistry at nano- and atomic- resolution by coupling correlated information encoded within both elastic scattering (high-angle annular dark field (HAADF)) and inelastic spectroscopic signals (electron energy loss (EELS) or energy-dispersive x-ray (EDX)). By linking these simultaneously acquired signals, or modalities, the chemical distribution within nanomaterials can be imaged at significantly lower doses with existing detector hardware. In many cases, the dose requirements can be reduced by over one order of magnitude. This high SNR recovery of chemistry is tested against simulated and experimental atomic resolution data of heterogeneous nanomaterials. © 2022, CC BY.

关键词： Electron microscopy

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Collective treadmilling in fire ant rafts permits sustained protrusion growth

arXiv

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arXiv 2020年

作者： Wagner, Robert J. Such, Kristen Hobbs, Ethan Vernerey, Franck J. University of Colorado Boulder Mechanical Engineering Department Material Science and Engineering Program United States University of Colorado Boulder Mechanical Engineer Department United States University of Colorado Boulder Computer Science Department Interdisciplinary Quantitative Biology Program United States University of Colorado Boulder Mechanical Engineer Department Material Science and Engineering Program United States

Condensed active matter is exemplary for its capacity to morph and exhibit internal flows despite remaining cohered. (1) To facilitate understanding of this ability, we investigate the cause of finger-like protrusions that emerge from super-organismal, aggregated rafts of fire ants (Solenopsis invicta). While these features are easily observed, what permits their recuring initiation, growth, and recession is not immediately clear. Ants rafts are comprised of a floating, structural network of interconnected ants on which a layer of freely active ants walks. We show here that sustained shape evolution is permitted by treadmilling defined by the competition between perpetual raft contraction due to displacement of bulk structural ants into the active layer, and outwards raft expansion due to deposition of free ants into the structural network at the edges. Furthermore, we see that protrusions emerge due to asymmetries in the edge deposition rate of surface ants, and we provide strong evidence that these asymmetries occur stochastically due to wall accumulation effects and local alignment interactions. Together these effects permit the cooperative, yet spontaneous formation of protrusions that fire ants utilize for functional exploration and to escape flooded environments. Ant raft dynamics mirror the treadmilling that facilitates morphogenesis and motility of cytoskeletons (2, 3), thus providing another example in which reshaping of condensed active matter is explained by free constituent transport, yet whose continuance relies on perpetual phase transition between structural and free members. © 2020, CC BY-NC-SA.

关键词： Deposition rates

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Profile of bovine teeth potency as hydroxyapatite scaffold

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AIP Conference Proceedings 2023年第1期2536卷

作者： Endanus Harijanto Anita Yuliati Prihartini Widiyanti Dental Material Department Faculty of Dentistry Universitas Airlangga Surabaya Indonesia Biomedical Engineering Study Program Department of Physics Faculty of Science and Technology Universitas Airlangga Surabaya Indonesia

Background: Bone destructions in the oral cavity are due to trauma, chronic infection, congenital malformations, or resection surgery, most often by using an autologous bone graft technique. The problem using this technique are limited donors and suppliers, high cost, host potential imune response becauce accepts foreign bone tissue also potential transmission diseases. Another solution in tissue engineering techniques is using the scaffold. Hidroxyapatite is one of the osteoconductive potentialy ceramic materials in scaffold fabrication. Objective: To prove that bovine teeth hydroxyapatite have characteristic as scaffold for bone tissue regeneration. Methods: HA was obtained by calcining bovine teeth at 1000°C for 3 hours, Fourier Transform Infra Red Spectroscopy (FTIR) test , Energy Dispersive X-Ray (EDX) test and X-Ray Diffraction (XRD) test. Results: Bovine teeth hydroxyapatite to showed of hydroxyl, phosphate and carbonate functional groups (FTIR test). Average Ca/P=1.97. Conclusion: Hydroxyapatite from bovine teeth has potency as scaffold through the chemistry and physical characteristics.

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Effects of chain-chain interaction on the configuration of short-chain alkanethiol self-assembled monolayers on a metal surface

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Journal of Chemical Physics 2024年第21期160卷 214711-214711页

作者： Liao, Chia-Li Faizanuddin, Syed Mohammed Haruyama, Jun Liao, Wei-Ssu Wen, Yu-Chieh Department of Chemistry National Taiwan University Taipei 10617 Taiwan Institute of Physics Academia Sinica Taipei 11529 Taiwan Taiwan International Graduate Program Academia Sinica Taipei 11529 Taiwan Department of Engineering and System Science National Tsing Hua University Hsinchu 300044 Taiwan Solid State Chemistry Laboratory Cluster for Pioneering Research RIKEN Wako 351-0198 Japan Center for Emerging Material and Advanced Devices National Taiwan University Taipei 10617 Taiwan

Surface-specific sum frequency generation vibrational spectroscopy is applied to study the molecular configuration of short-chain n-alkanethiol self-assembled monolayers (SAMs with n = 2-6) on the Au surface. For monolayers with n ≥ 3, the alkanethiols are upright-oriented, with the CH₃ tilt angle varying between ∼33° and ∼46° in clear even-odd dependency. The ethanethiol monolayer (n = 2) is, however, found to exhibit a distinct lying-down configuration with a larger methyl tilt angle (67°-79°) and a smaller CH₂ tilt angle (56°-68°). Such a unique configurational transition from n = 2 to n ≥ 3 discloses the steric effect owing to chain-chain interaction among neighboring molecules. Through density functional theory calculations, the transition is further confirmed to be energetically favorable for thiols on a defective reconstructed Au(111) surface but not on the pristine one. Our study highlights the roles of the chain-chain interaction and the substrate surface atomic structure when organizing SAMs, offering a strategic pathway for exploiting their applications. © 2024 Author(s).

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Preference of Dogs Towards Feeding Toys Made of Natural Rubber, and Their Potential to Improve Canine Behaviour: A Study Based on Owners' Observations

SSRN

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SSRN 2023年

作者： Boonhoh, Worakan Saramolee, Prachid Sriphavatsarakom, Prarom Amaek, Waluka Waran, Natalie Wongtawan, Tuempong Animal Behaviour Research Group Akkhraratchakumari Veterinary College Walailak University Nakhon Si Thammarat80160 Thailand Center of Excellence in Innovation on Essential Oil and Bioactive Compounds Walailak University Nakhon Si Thammarat80160 Thailand One Health Research Center Walailak University Nakhon Si Thammarat80160 Thailand Material Sciences and Engineering Program School of Engineering and Resources Walailak University Nakhon Si Thammarat80161 Thailand Department of Preclinic and Applied Animal Science Faculty of Veterinary Science Mahidol University Nakhon Pathom73170 Thailand College of Graduate Studies Walailak University Nakhon Si Thammarat80160 Thailand Faculty of Education Humanities and Health Science Eastern Institute of Technology Hawke's Bay 4142 New Zealand

Improper feeding methods can be linked to canine behaviour problems, as the conventional bowl-feeding approach fail to mimic natural behaviour and is associated with obesity. Feeding toys can potentially contribute to the enhancement of dog behaviour by mimicking natural hunting behaviour and promoting increased canine activity. Para rubber is a natural rubber with high flexibility and is tolerant of animal teeth, making it safer for animals compared to plastic and silicone. This study had two main objectives: firstly, to examine dogs' preferences for the scent and colour added to a para rubber product;and secondly, to explore the impact of using para rubber feeding toys on dog behaviours. The feeding toys were produced from natural rubber, with added scents and colours incorporated during their production. Subsequently, these toys were distributed to dog owners for evaluation. Owners completed the Thai version of the C-BARQ questionnaire, which evaluate canine behaviour both prior to and following a month of interaction with the toys. The findings indicated that dogs exhibited a preference for yellow toys over blue ones, as well as a preference for vanilla-scented toys compared to those with a beef scent. Following one month of consistent use of the para rubber toy, dogs tended to reduce various undesirable behaviours. Notably, overexcitement behaviour showed a nearly threefold decrease, and this reduction was statistically significant (p = 0.003). These outcomes emphasise the potential of natural rubber feeding toys in mitigating excitation-related behaviours, while also highlighting dogs' preference towards specific colours and scents. Consequently, there is a suggestion that enhancing toys with appealing scents or colours might foster greater interaction between dogs and their toys, potentially leading to a positive influence on their overall behavioural welfare. © 2023, The Authors. All rights reserved.

关键词： Color

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Response to Comment on (Novel two-dimensional porous graphitic carbon nitride C6N7 monolayer: A First-principle calculations [Appl. Phys. Lett. 2021, 119, 142102])

arXiv

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arXiv 2022年

作者： Bafekry, Asadollah Faraji, Mehrdad Fadlallah, Mohamed M. Sarsari, I. Abdolhosseini Jappor, Hamad R. Fazeli, Sara Ghergherehchi, Mitra Department of Radiation Application Shahid Beheshti University Tehran Iran Micro and Nanotechnology Graduate Program TOBB University of Economics and Technology Sogutozu Caddesi No 43 Sogutozu Ankara06560 Turkey Department of Physics Faculty of Science Benha University Benha13518 Egypt Department of Physics Isfahan University of Technology Isfahan84156-83111 Iran Department of Physics College of Education for Pure Sciences University of Babylon Hilla Iraq Department of Material Science and Engineering Sharif University of Technology PO Box 11155-9466 Tehran Iran Department of Electrical and Computer Engineering Sungkyunkwan University Suwon16419 Korea Republic of

Recently, reported a comments on the our paper [Appl. Phys. Lett. 119, 142102(2021)]. With our response, the APL journal rejected their non scientificcomments. There are some ambiguities about their claim: 1-They can check thephonon dispersion of their structure to see ZA out-of-plane mode. 2-They reportthe uniaxial stress-strain responses in Fig 2., which is unrelated to ourpaper. For a more helpful understanding of the mechanical properties of thenovel C6N7 monolayer, they can publish a paper. 3-They mentioned: Using the DFTmethod and with assuming a thickness of 3.35 A for the C6N7 monolayer based ongraphene thickness. Why did they choose this thickness while we know our C6N7monolayer is at without buckling? The distance of ZA out-of-plane movement ofions in C6N7 is different from Graphene. © 2022, CC BY.

关键词： Monolayers

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3D-printed micro-pore evaporator for increasing concentration of analytes in aqueous solutions

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Lab on a chip 2025年 2025 May 27页

作者： Yufeng Su Tanya Hutter Walker Department of Mechanical Engineering The University of Texas at Austin Austin TX 78712 USA. tanya.hutter@utexas.edu. Materials Science and Engineering Program and Texas Material Institute The University of Texas at Austin Austin TX 78712 USA.

To address the detection limit challenges of analytical instruments at low concentrations, this study explores the development of a concentrator, fabricated micro-3D printing technology, relying on solvent evaporation through micro-pores. The operating temperature can be as low as room temperature, allowing for compatibility with biomolecules that are sensitive to high temperatures. Moreover, the device is suitable for processing small sample volumes ranging from hundreds to tens of microliters. There are three designs of the hydrophilic biocompatible polymer tube, each featuring micro-pores with diameters of 30, 50 and 70 μm, spaced at distances of 150, 250 and 350 μm, respectively. All designs have the same total length of 16 mm and identical contact surface area. The tube is surrounded by an outer tube for a sweeping gas at a flow between 20 and 100 mL min for evaporation rate control. Theoretical calculations and experimental data were used to quantify device's performance and capabilities. Experiments conducted with deionized water and with aqueous glucose solutions demonstrate the device's capability to achieve up to a 10-fold concentration increase. The study also addresses potential issues such as analyte loss and the influence of various parameters like sweeping gas flow rates and liquid feeding rates on the concentration process. This work demonstrates the potential of the micro-3D printed device as a reliable and efficient method for sample concentration, critical for enhancing detection sensitivities for various applications such as bioassays and biosensors.

关键词： Bioassay

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Tailoring acid-base properties on metal-free zeolite from Indonesia kaolin to enhance the CO₂ hydrogenation to CH₄

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Case Studies in Chemical and Environmental engineering 2024年 10卷

作者： Sholeha, Novia Amalia Dewanto, Bintang Jovita, Stella Nugraha, Reva Edra Taufiq-Yap, Yun Hin Ulfa, Maria Fauzi, Anees Ameera Jalil, Aishah Abdul Bahruji, Hasliza Prasetyoko, Didik College of Vocational Studies Bogor Agricultural University (IPB University) Jalan Kumbang No. 14 Bogor 16151 Indonesia Department of Chemistry Faculty of Science Institut Teknologi Sepuluh Nopember Keputih Sukolilo Surabaya 60111 Indonesia Department of Chemical Engineering Faculty of Engineering Universitas Pembangunan Nasional “Veteran” Jawa Timur Surabaya 60294 Indonesia Department of Chemistry Faculty of Science Universiti Putra Malaysia Serdang Selangor Malaysia Chemistry Education Study Program Faculty of Teacher Training and Education Sebelas Maret University Jl. Ir. Sutami 36A Surakarta 57126 Indonesia Research Center for Biomass and Bioproduct National Research and Innovation Agency (BRIN) Indonesia Department of Chemical Engineering Faculty of Chemical and Energy Engineering Universiti Teknologi Malaysia UTM Skudai Johor Johor Bahru 81310 Malaysia Centre of Hydrogen Energy Institute of Future Energy Universiti Teknologi Malaysia UTM Skudai Johor Johor Bahru 81310 Malaysia Centre of Advanced Material and Energy Science Universiti Brunei Darussalam Jalan Tungku Link BE 1410 Brunei Darussalam

The catalytic thermal conversion of carbon dioxide is essential for carbon capture, storage, and utilization, helping to reduce CO2 emissions and potentially stimulating future economic activities. Zeolite Y, ZSM-5, B... 详细信息

The catalytic thermal conversion of carbon dioxide is essential for carbon capture, storage, and utilization, helping to reduce CO₂ emissions and potentially stimulating future economic activities. Zeolite Y, ZSM-5, BEA, and A were synthesized using the hydrothermal technique from Indonesian kaolin to examine the potential use of zeolite as a catalyst without metal nanoparticles. In the absence of metal, catalytic activity for CO₂ methanation relies solely on textural properties and basicity-acidity. Zeolite Y exhibits the highest CO₂ conversion at 36.64 % and attained 100 % of CH₄ selectivity at 400 °C. The exceptional CO₂ conversion of zeolite Y relies on a high basicity level of 1.02 mmol/g, as shown by CO₂-TPD analysis, and a relatively low acid site concentration of 1.48 mmol/g, as determined by NH₃-TPD analysis. ZSM-5, BEA, and zeolite A, demonstrated CO₂ conversion of 29.85 %, 23.86 %, and 12.15 %, respectively. Stability studies revealed ZSM-5 maintains methane (CH₄) selectivity of 94 %, which is only slightly lowered by 6 % for 30 hours, while zeolite Y achieved 90 % selectivity for 26 hours. The presence of mesopores in zeolite ZSM-5 reduced coke or carbon production, maintaining crystalline framework. © 2024 The Authors

关键词： Basicity Greenhouse carbon dioxide Metal free catalyst Methane Zeolite

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Electromagnetic-polarization selective composites with quasi-1D van der Waals metallic fillers

arXiv

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arXiv 2021年

作者： Barani, Zahra Kargar, Fariborz Ghafouri, Yassamin Baraghani, Saba Sudhindra, Sriharsha Mohammadzadeh, Amirmahdi Salguero, Tina T. Balandin, Alexander A. Center Department of Electrical and Computer Engineering University of California RiversideCA92521 United States Department of Chemical and Environmental Engineering University of California RiversideCA92521 United States Department of Chemistry University of Georgia AthensGA30602 United States Material Science and Engineering Program University of California RiversideCA92521 United States

We report on the preparation of flexible polymer composite films with aligned metallic fillers comprised of atomic chain bundles of the quasi-one-dimensional (1D) van der Waals material tantalum triselenide, TaSe3. The material functionality, embedded at the nanoscale level, is achieved by mimicking the design of an electromagnetic aperture grid antenna. The processed composites employ chemically exfoliated TaSe3 nanowires as the grid building blocks incorporated within the thin film. Filler alignment is achieved using the "blade coating" method. Measurements conducted in the X-band frequency range demonstrate that the electromagnetic transmission through such films can be varied significantly by changing the relative orientations of the quasi-1D fillers and the polarization of the electromagnetic wave. We argue that such polarization-sensitive polymer films with quasi-1D fillers are applicable to advanced electromagnetic interference shielding in future communication systems. Copyright © 2021, The Authors. All rights reserved.

关键词： Van der Waals forces

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