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1st materials Research Society-Indonesia Conference and Congress 2017, MRS-INA C and C 2017

作者： Puspitasari, P. Yazirin, C. Bachtiar, L.A. Dika, J.W. Zaharis, S.M.S.N.S. Mechanical Engineering Department Engineering Faculty Malang State University Semarang street 5 East-Java-Malang Indonesia Center of Nano Research and Advanced Materials Malang State University Semarang street 5 East-Java-Malang Indonesia Master Program of Mechanical Engineering Engineering Faculty Malang State University Semarang street 5 East-Java-Malang Indonesia Bachelor Program Mechanical Engineering Department Malang State University Semarang street 5 East-Java-Malang Indonesia Industrial Chemical Technology Programme Faculty of Science and Technology Universiti Sains Islam Malaysia Bandar Baru Nilai Negeri Sembilan Nilai71800 Malaysia

Fe2O3 has been the interest of many studies due to its applications in various scientific and industrial fields including in environment, corrosion, soil science, and exhaust emissions. Fe2O3 is a chemical mixture that can be applied as a catalyst to reduce exhaust emissions because it is capable of binding CO and HC contained in motorcycle exhaust gases The growth of motor vehicles results in air pollution and an increase in exhaust emissions consisting of 70.50% CO and 18.34% HC. One effort to reduce exhaust emission levels is by applying a catalytic converter to the exhaust system. This research was an experimental research aiming to investigate the difference in emission level of CO and HC between a motorcycle with and without a catalytic converter. The types of fuel used were RON 88, RON 90, RON 92, and RON 98. The results showed that the application of Fe2O3 as a catalyst could reduce the level of CO significantly in RON 88, i.e. 91.43% CO, and the level of HC in RON 88 and RON 92, i.e. 53.27% and 91.07% HC respectively. © Published under licence by IOP Publishing Ltd.

关键词： Catalytic converters

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Anti-Termite Activity of Azadirachta excelsa Seed Kernel and Its Isolated Compound against Coptotermes curvignathus

Journal of the Korean Wood Science and Technology

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Journal of the Korean Wood Science and Technology 2023年第3期51卷 157-172页

作者： Adfa, Morina Wiradimafan, Khafit Pratama, Ricky Febri Sanjaya, Angga Triawan, Deni Agus Yudha S., Salprima Ninomiya, Masayuki Rafi, Mohamad Koketsu, Mamoru Department of Chemistry Faculty of Mathematics and Natural Sciences University of Bengkulu Bengkulu38371 Indonesia Research Center of Sumatera Natural Product and Functional Materials University of Bengkulu Bengkulu38371 Indonesia Master of Chemistry Study Program Faculty of Mathematics and Natural Sciences University of Bengkulu Bengkulu38371 Indonesia Department of Chemistry and Biomolecular Science Faculty of Engineering Gifu University Gifu5011193 Japan Department of Chemistry Faculty of Mathematics and Natural Sciences IPB University Bogor16128 Indonesia Tropical Biopharmaca Research Center-Institute of Research and Community Services IPB University Bogor16128 Indonesia

Azadirachta excelsa, is a plant belonging to the same genus as Indian neem (Azadirachta indica), and its use as a pesticide is reported by few studies. Despite being a different species, it is expected to have the same biopesticide potential as A. indica. Therefore, this study aims to investigate the anti-termite activity of n-hexane and methanol extracts of A. excelsa seed kernel at various concentrations against Coptotermes curvignathus. The methanol extract demonstrated greater termicidal activity than n-hexane at doses test of 2%, 4%, and 8%. It also showed 100% termite mortality on the third day of administering the 8% dose. According to the gas chromatography with mass spectrometry data, the putative main components of the n-hexane extract were hexadecanoic acid, ethyl ester (18.99%), 9,12-octadecadienoic acid (Z,Z)-(16.31%), and 9-octadecenal (16.23%). In contrast, the principal constituents of methanol extract were patchouli alcohol (28.1%), delta-guaiene (15.15%), and alpha-guaiene (11.93%). Furthermore, limonoids profiling of A. excelsa methanol extract was determined using Ultrahigh-performance liquid chromatography coupled with quadrupole-Orbitrap high-resolution mass spectrometry. The number of limonoids identified tentatively was fifteen, such as 6-deacetylnimbin, nimbolidin C, nimbolide, 6-acetylnimbandiol, 6-deacetyl-nimbinene, salannol, 28-deoxonimbolide, gedunin, nimbandiol, epoxyazadiradione, azadirone, 2',3'-dihydrosalannin, marrangin, nimbocinol, and azadirachtin. They were the same as those reported in the seed and leaves of A. indica, but its largest component in A. excelsa was 6-deacetylnimbin. As a result, the presence of these compounds may be responsible for the anti-termite activity of A. excelsa seed kernel extract. Additionally, column chromatography of methanol extract yielded 6-deacetylnimbin, which was found to be antifeedant and termiticide against C. curvignathus. © 2023 The Korean Society of Wood Science & Technology.

关键词： Mass spectrometry

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Enhancing Pharmaceutical Wastewater Treatment: Ozone-Assisted Electrooxidation and Precision Optimization Via Response Surface Methodology

SSRN

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SSRN 2023年

作者： Phan, Huy N.Q. Leu, Jyh Hoang Nguyen, Vi N.D. Department of Materials Science and Engineering Feng Chia University Taichung40744 Taiwan Master’s Program of Green Energy Science and Technology Feng Chia University Taichung40744 Taiwan Department of Chemical Engineering Feng Chia University Taichung40744 Taiwan

In this study, the treatment of pharmaceutical wastewater was conducted using electrooxidation (EO) and ozone-assisted electrooxidation (EO/O3) with Pt-coated Ti electrodes (Pt/Ti). The removal of chemical oxygen demand (COD), color, and the UV absorption peak at 300 nm (UV300) was investigated in a batch mode reactor. Highly significant quadratic regression models for both processes were revealed through experimental design and optimization using the Box-Behnken Design (BBD) methodology. Current density, initial pH, and electrolysis time were assigned as independent variables for the statistical models. Under optimal conditions of 110.63 A m−2 current density and an initial pH of 4.5 for 477 minutes, stand-alone electrooxidation achieved the removal of 70.5% of COD, 81.25% color reduction, and a 40.01% decrease in UV300. In contrast, ozone-assisted electrooxidation performed even more effectively, with the removal of 84% for COD, 99.43% for color, and 49.63% for UV300. These results were obtained under optimal conditions of 150 A m−2 current density and an initial pH of 8.79 for 480 minutes. In addition, positive results in the kinetic study also gave this study an appeal. It was seen that ozone-assisted electrooxidation is an effective method for the pharmaceutical wastewater treatment. © 2023, The Authors. All rights reserved.

关键词： Ozone

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Roles of organic acids during exectrooxidation reaction over Pt-supported carbon electrodes in direct methanol fuel cells

Roles of organic acids during exectrooxidation reaction over...

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作者： Wong, Chee Yong Chen, Shi-Kun Lo, An-Ya Tseng, Chuan-Ming Lin, Chiu-Yue Liu, Shang-Bin Department of Materials Science and Engineering Fong Chia University Taichung 40724 Taiwan Green Energy Development Center and Master's Program of Green Energy Science and Technology Fong Chia University Taichung 40724 Taiwan Institute of Physics Academia Sinica Taipei 11529 Taiwan Institute of Atomic and Molecular Sciences Academia Sinica Taipei 10617 Taiwan Department of Chemistry National Taiwan Normal University Taipei 11677 Taiwan

A comprehensive study has been made to explore the role of organic acids on electrocatalytic performances of platinum (Pt) nanoparticles supported on carbon porous materials (CPMs) in proton exchange membrane fuel cells (PEMFCs). In particular, the effects of carboxylic acids (R-COOH), viz. formic acid, acetic acid, propionic acid, and butyric acid on catalytic activity, stability, and durability of anodic Pt/CPM electrocatalyst in direct methanol fuel cells (DMFCs) were investigated. In the presence of doped carboxylic acids, the electrooxidative activity of Pt/CPM follows the trend: HCOOH 3COOH 2H5COOH 3H 7COOH, revealing a consistent increase in the severity of catalyst deactivation with the number of carbons on the alkyl chain of the dopant. The Pt/CPM was found to exhibit electrocatalytic performances and tolerance for poisoning than a commercial Pt/XC-72 catalyst with a similar Pt loading (20 wt%). Moreover, a notable increase in mass activity up to ca. 150% over the spent Pt/CPM catalyst was observed up on removing the organic acid in the feed stream, indicating that catalyst poisoning by deactivation may be revived, even to its "intrinsic" activity. © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

关键词： Electrocatalysts

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Dielectrophoretic force characteristics toward Lactobacillus casei on an oblique-patterned electrode 10

Dielectrophoretic force characteristics toward Lactobacillus...

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10th Asian Physics Symposium 2023, APS 2023

作者： Khazanna Fitriyani, S. Safitri, R. Lahna, K. Yusibani, E. Irwansyah Iswardy, E. Master Program in Physics Department of Physics Faculty of Mathematics and Natural Sciences Universitas Syiah Kuala Banda Aceh23111 Indonesia Department of Dental Materials Faculty of Dentistry Universitas Syiah Kuala Banda Aceh23111 Indonesia Department of Physics Faculty of Mathematics and Natural Sciences Universitas Syiah Kuala Banda Aceh23111 Indonesia Department of Mechanical Engineering Faculty of Engineering Universitas Syiah Kuala Banda Aceh23111 Indonesia Research Center Universitas Syiah Kuala Banda Aceh23111 Indonesia

Dielectrophoresis-based biochips with various microelectrode configurations have been extensively studied within the last five deca des. However, wide-field application is still challenging. This study aims to fabricate an oblique-configuration microelectrode and then utilizes it to determine the dielectrophoretic (DEP) characteristics of Lactobacillus casei based on the generated non-uniform electric field. The electric field distribution on microelectrodes was simulated with Quickfield 6.6 student version. The microelectrodes were fabricated using a copper film on a glass substrate. The DEP characteristic of Lactobacillus casei was investigated by applying a sinusoidal AC signal to microelectrodes in medium solution with an electrical conductivity of 0.05 S/m. The electric-field simulations show that the strongest electric-field was generated on the tip of electrodes spacing, and the weakest electric-field was generated on the inner of electrodes spacing. The negative-DEP force on Lactobacillus casei was observed at the frequency of 60-130 kHz, while the positive-DEP force was observed at the frequency of 380-700 kHz, both at voltage of 2-6 Vpp. The nDEP force led Lactobacillus casei to be pushed toward the weak electric field on the inner of electrodes spacing, and the pDEP force induced Lactobacillus casei to be attracted toward the strong electric-field on the tip of electrodes spacing. This study implies that the proposed oblique-microelectrode platform has promising application for bioparticles separation. © Published under licence by IOP Publishing Ltd.

关键词： Microelectrodes

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Evaluation of Sound Absorption Capability from PET Mesh to PET/PU Composite Board

Evaluation of Sound Absorption Capability from PET Mesh to P...

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The 2014 International Conference on materials Science and engineering Technology(MSET 2014)

作者： YuCheng Liu JinHuang Huang ChenHung Huang MinHon Tsai YuChun Chuang Master's Program of Electro-Acoustics Feng Chia University Department of Mechanical and Computer-Aided Engineering Feng Chia University Department of Aerospace and Systems Engineering Feng Chia University Laboratory of Fiber Application and Manufacturing Department of Fiber and Composite MaterialsFeng Chia University

ISBN: (纸本)9783038351023

This article completely investigates from nonwoven to PET/PU composite board on the variations of absorption coefficient by using standard impedance tube with four microphonesRecently, PET/PU composite board is becoming one popular and functional material because of the high flexibility in the abilities, such as thermal-protection, chemical-proof, acoustic-resistance and ***, it is important to realize the variations of absorption capability from single material to complete composite material, and feedback some suggestions to the designerResults shows that nonwoven only has a stable increase in absorption coefficient with the frequencies because of the inherent porous characteristicsWith the substantial properties, foam has lower absorption coefficient and two peaks occurring in the higher frequenciesBoth two peaks are caused by the resonance between wave and foam at specified frequencyWith an additional nonwoven in the rear side of composite foam, absorption coefficient of PET/PU composite board will effectively increaseBased on the diverse applications, absorption coefficient of PET/PU composite board can be flexible modulated to consistent with the requirements.

关键词： absorption coefficient,nonwoven,foam,PU composite board,impedance tube

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Study on the preparation of recrystallization and the analysis of explosion sensitivity for spherical RDX particles

Chung Cheng Ling Hsueh Pao/Journal of Chung Cheng Institute ...

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Chung Cheng Ling Hsueh Pao/Journal of Chung Cheng Institute of Technology 2014年第2期43卷 187-198页

作者： Hsu, Mi-Ch Lu, Kai-Tai Li, Jin-Shuh Yeh, Tsao-Fa Master Program of Chemical Engineering Chung Cheng Institute of Technology NDU Taiwan Department of Chemical and Materials Engineering Chung Cheng Institute of Technology NDU Taiwan

This study uses the Soxhlet extraction method to prepare the recrystallized RDX (Cycotrimethylenetrinitramine) particles under various operating condition, and then the scanning electron microscope (SEM) and the particle size distribution analyzer (PSDA) were used to observe the morphology of particles and measure the size of particles. The experimental results can be used to evaluate the optimum operating condition for preparing spherical RDX particles. Afterward the thermo-stability of spherical RDX particles is analyzed by means of differential scanning calorimeter (DSC) and thermo gravimetric analyzer (TGA) and the mechanical sensitivity is measured by means of the drop hammer impact tester and friction apparatus. The experimental results show that the impact sensitivity of recrystallized spherical RDX particles is more insensitive than one of raw RDX particles, but the friction sensitivity of recrystallized spherical RDX particles is more sensitive. The research results will contribute to improve the manufacturing process of RDX particles for military arsenal.

关键词： Recrystallization (metallurgy)

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Carbon nitride- and graphene-based materials for the photocatalytic degradation of emerging water pollutants

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materials Advances 2024年第7期5卷 2668-2688页

作者： Indra Jaya Budiarso Valentinus Alphano Dabur Riska Rachmantyo Hermawan Judawisastra Chechia Hu Arie Wibowo Master Program in Materials Science and Engineering Faculty of Mechanical and Aerospace Engineering Institut Teknologi Bandung Ganesha 10 Bandung 40132 West Java Indonesia Doctoral Program in Materials Science and Engineering Faculty of Mechanical and Aerospace Engineering Institut Teknologi Bandung Ganesha 10 Bandung 40132 West Java Indonesia Materials Science and Engineering Faculty of Mechanical and Aerospace Engineering Institut Teknologi Bandung Ganesha 10 Bandung 40132 West Java Indonesia ariewibowo@itb.ac.id Department of Chemical Engineering National Taiwan University of Science and Technology Taipei 106 Taiwan R&D Center for Membrane Technology Chung Yuan Christian University Taoyuan 320 Taiwan Research Center for Nanoscience and Nanotechnology Institut Teknolgi Bandung Ganesha 10 Bandung 40132 West Java Indonesia

Photocatalytic degradation is a promising way to treat emerging pollutants in wastewater. Recently, metal-free photocatalysts such as carbon nitride- and graphene-based materials have attracted much interest in the photocatalytic degradation of emerging water pollutants owing to their visible light activity and unique electrical properties, respectively. Graphitic carbon nitride (GCN) is considered a superior visible light–active photocatalyst because of its suitable bandgap (2.7 eV). Moreover, the facile synthesis process and the high chemical and thermal stability of GCN make it one of the research hotspots in photocatalytic wastewater treatment. Besides GCN, graphene and its derivatives are utilized to support main photocatalysts by enhancing their light absorption, pollutant adsorption, and photogenerated charge separation. Furthermore, the vast modification of these materials has promoted various outstanding performances in carbon nitride- and graphene-based photocatalysts in the application of pollutant degradation. In this review, we highlight recent developments in carbon nitride- and graphene-based photocatalysts (2018–2023), focusing on the strategies to improve the activity of GCN as a visible light–active photocatalyst and the role of graphene and its derivatives as supporting materials in wastewater pollutant remediation applications.

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Development of an Optical Biosensor Based on Gold Nanoparticles

Development of an Optical Biosensor Based on Gold Nanopartic...

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IEEE Conference on Nanotechnology

作者： Amanda Anatasya Yong-Joon Choi Tsugumi Sakae Gilang Gumilar Ni Luh Wulan Septiani Go Kawamura Kazuaki Sawada Brian Yuliarto Faculty of Industrial Technology Master's Program in Engineering Physics Institut Teknologi Bandung Bandung Indonesia Department of Electrical and Electronic Information Engineering Toyohashi University of Technology Aichi Japan Engineering Physics Department Advanced Functional Materials (AFM) Laboratory Institut Teknologi Bandung Bandung Indonesia Research Center for Advanced Materials National Research and Innovation (BRIN) Komplek Puspiptek South Tangerang Indonesia

This paper describes an experimental study of SARS-CoV-2 detection using plasmonic gold nanoparticles, which overcomes the limitations of traditional detection techniques known for their time-consuming and a tendency to produce high false negative results. The transmission spectrum of gold nanoparticles (AuNPs) was recently estimated to be in filter-free wavelength sensors as a miniaturization detection system. Additionally, we demonstrate that wide-ranging absorption will manifest within the visible spectrum when the virus is partially coated with gold nanoparticles at a particular percentage of coverage. This extensive absorption can be harnessed to direct the advancement of a reliable and precise colorimetric plasmon sensor for the detection of COVID-19. The transmission value resulting from the gold nano seed is around 507–540 nm. In addition, plasmonic gold nanoparticles can detect SARS-CoV-2 well from the range of 100-1,000 ng/ml. We expect a miniaturization biosensor system with qualitative diagnosis to be realized by the development method.

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Structural and optical properties of buried InAs/GaAs quantum dots on GaAsSb buffer layer

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Journal of Physics D: Applied Physics 2009年第18期42卷

作者： Wu, Y.H. Chang, Li Lin, P.Y. Chiang, C.H. Chen, J.F. Chi, T.W. Department of Materials Science and Engineering National Chiao-Tung University Hsinchu 30050 Taiwan Industrial Technology Research and Development Master Program on Semiconductor Materials and Processing National Chiao-Tung University Hsinchu 30050 Taiwan Department of Eletrophysics National Chiao-Tung University Hsinchu 30050 Taiwan Electronics and Optoelectronics Research Laboratories Industrial Technology Research Institute Hsinchu 30050 Taiwan

In this work, we investigated the effect of a 1 nm thick GaAs 94.3Sb0.57 buffer layer on structural and optical properties of buried InAs quantum dots (QDs) and wetting layers (WLs) in GaAs using photoluminescence (PL) and transmission electron microscopy (TEM). The density and emission wavelength of the QDs on the buffer were increased due to the size and the shape modification in comparison with those without a buffer. PL analysis of the ground-state (GS) peak of the QDs on the buffer showed a red-shift of 18 meV with an enhanced intensity. In addition, PL and TEM show that the buffer has a weak effect on the WLs and no apparent changes occur for the buffer during QD deposition and the capping process. © 2009 IOP Publishing Ltd.

关键词： Buffer layers

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