As academic demands increase, school-aged children and adolescents often carry heavy backpacks, impacting their posture and musculoskeletal health. This study examines how backpack carriage affects children's gait...
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Temperature and power dependent time-resolved photoluminescence measurements are performed on a novel ultra-stable red-emitting InGaN/GaN heterostructure. PL dynamics at two distinct wavelengths indicate a lateral car...
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Three-dimensional graphene materials have been studied as typical supercapacitors electrode materials by virtue of their ultrahigh specific surface area and good ion transport ***,improvement of the poor volumetric el...
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Three-dimensional graphene materials have been studied as typical supercapacitors electrode materials by virtue of their ultrahigh specific surface area and good ion transport ***,improvement of the poor volumetric electrochemical performance of these graphene materials has been required although they have high gravimetric energy *** this work,nanocellulose/nitrogen and fluorine co-doped graphene composite hydrogels(NC-NFGHs)were prepared through a convenient hydrothermal approach utilizing ammonium fluoride as the heteroatom ***(NC)and high concentration of graphene oxide(GO)were utilized to adjust the structure of NC-NFGHs and increase their packing ***,the aqueous symmetric supercapacitor based on NC-NFGH-80 exhibits remarkable gravimetric(286.6 F·g^(-1))and volumetric(421.3 F·cm^(-3))specific capacitance at 0.3 A·g^(-1),good rate performance,and remarkable cycle stability up to 10,000 ***,the all-solid-state flexible symmetric supercapacitors(ASSC)fabricated by NC-NFGH-80 also delivered a large specific capacitance of 117.1 F·g^(-1)at 0.3 A·g^(-1)and long service life over 10,000 cycles at 10 A·g^(-1).This compact porous structure and heteroatom co-doped graphene material supply a favorable strategy for high-performance supercapacitors.
Facet formation in InGaN disc-in-wire LEDs leads to increased exciton binding energy due to strain relaxation and reduced polarization fields resulting in an ultra-high efficiency of 25.2% for green emission utilizing...
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Graphene nanoplates(GNPs)-reinforced magnesium matrix composites have been attracted great ***,knowledge is lack for the hot deformation behavior of GNP-reinforced magnesium(GNPs/Mg)*** this study,the fine-grained GNP...
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Graphene nanoplates(GNPs)-reinforced magnesium matrix composites have been attracted great ***,knowledge is lack for the hot deformation behavior of GNP-reinforced magnesium(GNPs/Mg)*** this study,the fine-grained GNPs/Mg composite was fabricated by powder metallurgy process followed by *** hot deformation behavior,microstructure evolution and dynamic recrystallization(DRX)mechanism of fine-grained GNPs/Mg composite were investigated by hot compression test and electron back-scatter diffraction(EBSD).The hot compression tests of the composite were conducted at temperatures between 423 and 573 K with the strain rates from 0.001 to 1 s^(-1).The strain compensated power law equation was established to describe the hot deformation behavior of the *** stress exponent and activation energy of the composite are 7.76 and 83.23 kJ/mol,respectively,suggesting that the deformation mechanism is grain boundary slip controlled dislocation climb *** abnormally high stress exponent and activation energy are unattainable in the composite due to the fine grain size of the composites and the absence of Zener pinning and Orowan effects of GNPs *** grain size increases with the decrease in Zener-Hollomn(Z)parameter,which can be well fitted by power-law *** the increase in grain size and decrease in Z parameter,the geometrically necessary dislocation density decreases,which shows the approximately power-law relationship.A random and weak texture was formed after hot *** discontinuous dynamic recrystallization and continuous dynamic recrystallization mechanism dominated the DRX behavior at 473 K/0.001 s^(-1) and 573 K/0.001 s^(-1),respectively.
The electrochemical oxygen evolution reaction(OER)is a half-reaction of water-splitting for hydrogen generation,yet suffers from its sluggish kinetics and large *** is highly desirable to develop efficient and stable ...
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The electrochemical oxygen evolution reaction(OER)is a half-reaction of water-splitting for hydrogen generation,yet suffers from its sluggish kinetics and large *** is highly desirable to develop efficient and stable OER electrocatalysts for the advancement of ***,by means of density functional theory(DFT)calculations,we systematically investigated a series of two-dimensional(2D)dual-atom catalysts(DACs)on a novel synthesized covalent organic framework(COF)material as potential efficient catalysts toward the *** designed 6 homonuclear(2TM-COF)and 15 heteronuclear(TM1TM2-COF)DACs all exhibit good *** is a strong scaling relationship between the adsorption Gibbs free energies of HO*and HOO*intermediates,and the OER overpotential(η^(OER))volcano curve can be plotted as a function ofΔGO*−ΔGHO*.RhIr-COF shows the best OER catalytic activity with aη^(OER)value of 0.29 V,followed by CoNi-COF(0.33 V),RuRh-COF(0.34 V),and NiIrCOF(0.37 V).These four OER DACs exhibit lower onset potential and higher current density than that of the IrO2(110)benchmark *** by the descriptor identification study,the Bader charge that correlated with the Pauling electronegativity of the embedded dual-metal atoms was found to be the most important factor governing the catalytic activity of the *** work highlights a potentially efficient class of 2D COF-based DACs toward the OER.
Nitrocellulose is an important kind of energetic material produced by replacing hydroxyl of cellulose molecule to nitro, which has a wide application range in social life. During transportation and storage, inevitably...
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In this research,un-doped CeO_(2) and Ce_(0.85)La_(0.10)MO_(0.05)O_(2)(M:Sm,Er,Y) compounds were synthesized by hydrothermal method and the multi-functional properties are *** defects were created with the additives o...
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In this research,un-doped CeO_(2) and Ce_(0.85)La_(0.10)MO_(0.05)O_(2)(M:Sm,Er,Y) compounds were synthesized by hydrothermal method and the multi-functional properties are *** defects were created with the additives of rare earth *** electrical and luminescence behaviors of the synthesized compounds were investigated in accord with the types of *** synthesized products were characterized by X-ray diffraction(XRD) analysis,Brunauer-Emmett-Teller(BET) measurement,UV-vis diffuse reflectance spectroscopy(DRS),scanning electron microscopy(SEM),photoluminescence(PL)spectroscopy and electrochemical impedance spectroscopic(EIS).All synthesized compounds are found to be nano-structured and have cubic *** total conductivity of all samples was ***,the total conductivity of un-doped CeO_(2),Ce_(0.85)La_(0.10)Y_(0.05)O_(2),Ce_(0.85)La_(0.10)Er_(0.05)O_(2) and Ce_(0.85)La_(0.10)Sm_(0.05)O_(2) is found to be 2.07×10^(-10),5.70×10^(-4),1.0×10^(-3) and 0.0747 S/cm,***,bandgap energy(E_(g)) of these samples calculated from UV visible absorption spectra is discussed,and the optical results show variation between 3.2 and 2.15 ***,the luminescence properties of the compounds were investigated and different emissions occur depending on the additive ***,photoluminescent emission spectra of Ce_(0.85)La_(0.10)Y_(0.05)O_(2),Ce_(0.85)La_(0.10)Er_(0.05)O_(2) and Ce_(0.85)La_(0.10)Sm_(0.05)O_(2) phosphors indicate that these phosphors have red,green and orange-red colors,respectively.
The effect of the structure that is printed inside an object, known as infill pattern, on fatigue life of 3D printed specimens made of ABS was investigated in this paper. There are several infill pattern geometries, e...
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The shortage of tissues and organs for transplantation is an urgent clinical *** situ 3D printing is an advanced 3D printing technique aimed at printing the new tissue or organ directly in the *** ink for this process...
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The shortage of tissues and organs for transplantation is an urgent clinical *** situ 3D printing is an advanced 3D printing technique aimed at printing the new tissue or organ directly in the *** ink for this process is central to the outcomes,and must meet specific requirements such as rapid gelation,shape integrity,stability over time,and adhesion to surrounding healthy *** natural materials,silk fibroin exhibits fascinating properties that have made it widely studied in tissue engineering and regenerative ***,further improvements in silk fibroin inks are needed to match the requirements for in situ 3D *** the present study,silk fibroin-based inks were developed for in situ applications by exploiting covalent crosslinking process consisting of a pre-photo-crosslinking prior to printing and in situ enzymatic *** different silk fibroin molecular weights were characterized and the synergistic effect of the covalent bonds with shear forces enhanced the shift in silk secondary structure towardβ-sheets,thus,rapid *** hydrogels exhibited good mechanical properties,stability over time,and resistance to enzymatic degradation over 14 days,with no significant changes over time in their secondary structure and swelling ***,adhesion to tissues in vitro was demonstrated.
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