In this study,a pair of dicarboxylic acids as cis-trans isomerism—citraconic acid(CA)and mesaconic acid(MA),was incorporated into polymeric networks of poly(N-isopropylacrylamide)(PNIPAM)-based core-shell microgels v...
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In this study,a pair of dicarboxylic acids as cis-trans isomerism—citraconic acid(CA)and mesaconic acid(MA),was incorporated into polymeric networks of poly(N-isopropylacrylamide)(PNIPAM)-based core-shell microgels via semi-batch precipitation *** demonstrated that the pH-temperature dual responsiveness of the core-shell microgels is highly correlated with the structure and position of the acid *** the cis-trans molecular structure and the crosslinking position of the dicarboxylic acids significantly influenced the hydration capacity and surface charge density of the core-shell *** diverse properties first influenced the swelling behavior,further affecting the interfacial behavior of the microgels,including the oil-water dynamic interfacial tension and air-water compression ***,the rheological behavior of the microgel suspensions also displayed distinct dependences on the frequency and temperature,illustrating that the cis-trans molecular structure and crosslinked position of the dicarboxylic acids also significantly influenced the interparticle clustering in the bulk *** results suggest that the pH sensitivity of the cis-trans dicarboxylic acid isomer affects the ionization and surface charge distribution of the core or shell layers of individual microgels,which further determines the interparticle interaction and cooperative rearrangement at interfaces and in the bulk.
With the rapid development of high-end industries,the demand for high-temperature piezoelectric materials is significantly ***,realizing the ultra-high performance to meet more ap-plications still faces major scientif...
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With the rapid development of high-end industries,the demand for high-temperature piezoelectric materials is significantly ***,realizing the ultra-high performance to meet more ap-plications still faces major scientific and engineering challenges of our ***,a new Nb/Mn co-doped CaBi_(4)Ti_(4)O_(15)(CBT)high-temperature piezoelectric material system of CaBi_(4)Ti_(4-x)(Nb_(2/3)Mn_(1/3))_(x)O_(15)was synthesized by the conventional solid-state sintering *** results show that the addition of the dopants tends to break the long-range ferroelectric chain and soften the flexibility of polarization,resulting in more distorted crystal structure and better ferroelectric properties of CBT *** ultra-high piezoelectric constant(d_(33)=26.8 pC/N)is thus attained in CBT-based ceramics with x=0.12,which is about several times larger than that of pure CBT ***,numerous nano-sized layered domain structures that lie on the lateral plane of grains are observed in ceramics,with lower domain wall energy and better dynamic features under electric fields,mainly responsible for the origin of enhanced ***,excess dopants could make the conductivity mechanism of CBT ceramics transform from p-type to n-type,and also result in a shift of conduction relaxation mechanism from defect dipole rotation polarization to electron relaxation *** work not only provides a promising candidate for high-temperature piezoelectric materials,but also opens a window for opti-mizing performance by tailoring domain structures using chemical modification.
Different amounts of La_(2)O_(3)were added to ZK60 alloy to observe the changes in microstructure and mechanical properties of ZK60-XLa_(2)O_(3)(X=0,0.2 wt%,0.5 wt%)*** findings reveal that within the as-cast ZK60 all...
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Different amounts of La_(2)O_(3)were added to ZK60 alloy to observe the changes in microstructure and mechanical properties of ZK60-XLa_(2)O_(3)(X=0,0.2 wt%,0.5 wt%)*** findings reveal that within the as-cast ZK60 alloy,the Mg-Zn binary phase is manifested as rod-shaped precipitates,exhibiting a dispersed distribution predominantly along the grain boundary *** the increase of La_(2)O_(3)addition,the rod-like Mg-Zn binary phases are gradually replaced by Mg-Zn-La ternary phases,and these Mg-Zn-La ternary phases are semi-continuously distributed around the grain *** ZK602 and ZK605 alloys result in a corresponding improvement in ductility after *** is noteworthy that the ductility of the as-extruded ZK605 alloy is increased by 59.4%compared to ZK60 at the expense of a reduction of only 3.9%in yield *** together,the significant increase in ductility of ZK605 is mainly due to the weakening of the basal texture,which is weakened by the redox reaction of La_(2)O_(3)with the a-Mg matrix,generating the La *** decrease in yield strength of ZK605 in the extruded state is closely related to the observed grain coarsening phenomenon and the basal texture *** the same time,the ultimate tensile strength of ZK605 shows a slight increase,which is mainly due to the second phase *** Mg-Zn-La ternary phase exhibits a notably hard character,and it is evident that the distribution of this phase becomes progressively denser as the La_(2)O_(3)content increases.
In parallel with the proliferation and extension of wireless sensor networks (WSNs), as well as the diversity of their applications, such networks continue to fail to operate for lengthy periods of time due to node fa...
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Maxillofacial injuries that may cause severe functional and aesthetic damage require effective and immediate management due to continuous exposure to diverse microbial populations. Moreover, drug resistance,biofilm fo...
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Maxillofacial injuries that may cause severe functional and aesthetic damage require effective and immediate management due to continuous exposure to diverse microbial populations. Moreover, drug resistance,biofilm formation, and oxidative stress significantly impede timely bacterial removal and immune function,making the exploration of advanced materials for maxillofacial wound healing an appealing yet highly challenging task. Herein, a near-infrared photothermal sterilization agent was designed, encapsulated with liposomes and coated with ascorbic acid known for its antioxidant and immune-regulatory functions. The resulting nanoparticles, 4TPE-C6T-TD@AA, effectively neutralize reactive oxygen species generated by lipopolysaccharides, facilitate the conversion of pro-inflammatory M1 macrophages to anti-inflammatory M2 macrophages, and eliminate >90% of Staphylococcus aureus and Escherichia coli by disrupting bacterial physiological functions upon exposure to 808 nm laser irradiation. In vivo experiments demonstrate that 4TPE-C6T-TD@AA rapidly eliminates bacteria from infected wounds in the maxillofacial region of rats,and significantly promotes healing in S. aureus-infected wounds by enhancing collagen formation and modulating the inflammatory microenvironment. In conclusion, this study presents a promising therapeutic strategy for effectively combating bacterial infections and excessive inflammation in treating maxillofacial injuries.
The effect of pre-deformation on nanoscale precipitates and hardness of a maraging stainless steel strengthened by the coprecipitation of Ni_(3)Ti,Mo-enriched and Cr-enriched precipitates was systematically studied us...
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The effect of pre-deformation on nanoscale precipitates and hardness of a maraging stainless steel strengthened by the coprecipitation of Ni_(3)Ti,Mo-enriched and Cr-enriched precipitates was systematically studied using electron back scattered diffraction,transmission electron microscopy and atom probe tomography(APT).Hardness measurements showed that the hardness of specimen with a deformation ratio of 90%peaked at HV 718 aged for 24 h,which is higher than that in the undeformed specimen(HV 603)aged for 72 h at 480℃.APT characterization revealed that pre-deformation could shorten the incubation time of the Mo-enriched and Cr-enriched *** the early-aged stage,pre-deformation increased the stain energy that inhibited the nucleation of Ni_(3)Ti precipitates,but accelerated the rejection of Mo from Ni-Ti ***,the strengthening model indicated that strain hardening(43%)makes a larger contribution to the hardness at the early-aged condition,while precipitation hardening(58%)has most contribution to the hardness at the peak-aged conditition.
We designed a femtosecond(fs)+picosecond(ps)double-pulse sequence by using a Mach-Zehnder-like apparatus to split a single 120 fs pulse into two sub-pulses,and one of them was stretched to a width of 2 ps by a four-pa...
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We designed a femtosecond(fs)+picosecond(ps)double-pulse sequence by using a Mach-Zehnder-like apparatus to split a single 120 fs pulse into two sub-pulses,and one of them was stretched to a width of 2 ps by a four-pass grating *** observing the ripples induced on the ZnO surface,we found the ionization rate appeared to be higher for the sequence in which the fs pulse arrived *** electron rate equation was used to calculate changes of electron density distribution for the sequences with different delay *** suggest that using a temporally shaped fs+ps pulse sequence can achieve nonlinear ionization control and influence the induced ripples.
Microwave absorption(MA) materials have been captured extensive attentions due to the serious electromagnetic(EM) pollution. Numerous interests focus on the MA performances of core-shell structural composites with mag...
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Microwave absorption(MA) materials have been captured extensive attentions due to the serious electromagnetic(EM) pollution. Numerous interests focus on the MA performances of core-shell structural composites with magnetic constituents as cores and dielectric constituents as shells, which inevitably suppressed the magnetic coupling causing the decrease of magnetic loss to some extent. Herein, the coreshell structural carbon(C) microsphere/magnetic metal composites were fabricated through the combination of an electrostatic assembly approach and subsequent in-situ reduction reaction. The complex permittivity and permeability of core-shell C@magnetic metal composite system can be effective adjusted by the constituent and microstructure of shells. Thanks to the distinct magnetic coupling from the subtle designed structures and the promotion of the magnetic-dielectric synergy, the C@magnetic metal composite exhibited enhanced MA properties. The optimal reflection loss(RL) of C@Ni composite was-54.1 dB with a thickness of 3.4 mm, meanwhile the effective absorbing band could reach over 5.5 GHz at only a1.8 mm thickness. Broad absorption bandwidth with RL below-10 d B could achieve 6.0 GHz and 6.7 GHz for C@Co and C@Ni Co composites with a thin 2.1 mm thickness, respectively. Our exciting findings might lead a guide on the novel structure design for the functional core-shell structural composites used for microwave absorption.
The increase in population and the expansion of transportation, agriculture, and industry drive the need for energy, leading to a reliance on fossil fuels as the primary energy source. This reliance results in heighte...
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