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Change of Electrical and Transport Properties of Nickel Oxide by Carrier Concentration and Temperature through First‑Principle Calculations

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Nanomanufacturing and Metrology 2023年第4期6卷 109-118页

作者： Nayem Md.Reza Shah Chang‑Dong Yeo Minyeong Choi Yang‑Ki Hong Jeong H.You Department of Mechanical Engineering Texas Tech UniversityLubbockTX 79409USA Department of Electrical and Computer Engineering and Material Science Ph.D.Program The University of AlabamaTuscaloosaAL 35487USA Department of Mechanical Engineering School of EngineeringUniversity of St.ThomasSt.PaulMN 55105USA

Nickel is typically used as one of the main components in electrical contact devices or *** oxide(NiO)is usually formed on the surfaces of electrodes and can negatively impact system performance by introducing electrical contact *** thermal,electrical,and transport properties of NiO,as a Mott insulator or a p-type semiconductor,can be altered by operating and environmental conditions such as temperature and stress/strain by *** this study,we inves-tigate the fundamental material properties of NiO through the first-principle ***,we obtain and compare the lattice parameter,magnetic moment,and electronic structure for NiO via the WIEN2K simulations with four different poten-tials(i.e.,GGA,GGA+U,LSDA,and LSDA+U).Then,using the WIEN2K simulation results with LSDA+U potential that produces a highly accurate bandgap for NiO,we calculate the electrical conductivity and electrical part of the thermal conductivity of nickel and NiO as a function of temperature and carrier concentration through the BoltzTraP *** simulation results revealed that the electrical conductivity relative to the relaxation time for NiO increases with the carrier concentration,while it shows a slightly decreasing trend with temperature under a fixed carrier *** contrast,the electrical part of the thermal conductivity shows an increasing trend considering carrier concentration and temperature.

关键词： Nickel oxide Magnetic moments Density of states Seebeck coefcient Electrical conductivity

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Effect of Impregnation of Liquid Sodium Silicate on Thermal Properties of Paper

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Palpu Chongi Gisul/Journal of Korea Technical Association of the Pulp and Paper Industry 2022年第6期54卷 60-67页

作者： Park, Gwon-Hui Kim, Younglae Cho, Byoung-Uk Department of Paper Science & Engineering College of Forest and Environmental Sciences Kangwon National University Korea Republic of Program of Paper Material Science & Engineering College of Forest and Environmental Sciences Kangwon National University Korea Republic of

Heat-resistant insulators are the core materials in fire doors and are directly related to people’s safety in a fire. Heverever, there needs to be a material that possesses heat resistance and insulation with reasonable production cost. To develop a core material for fire doors based on recycled paper, such as copy paper and linerboard, were impregnated with liquid sodium silicate and the effects of the sodium silicate content on the thermal properties of paper were investigated. It was observed that liquid soidum silicate can be used as a flame retardant when manufacturing fire door core materials. Imprenation of liquid sodium silicate delayed both glowing and burning temperatures along with an increased weight of residues after combustion over 750℃. Hence, it is possible to manufacture an incombustible material based on recycled papers by adding liquid sodium silicate and inorganic materials that do not themally decompose over 750℃. © 2022 Korean Technical Assoc. of the Pulp and Paper Industry. All rights reserved.

关键词： Impregnation

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Topological graph-based analysis of solid-state ion migration

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npj Computational materials 2023年第1期9卷 1337-1341页

作者： Jimmy-Xuan Shen Haoming Howard Li Ann Rutt Matthew K.Horton Kristin A.Persson Materials Science Division Lawrence Livermore National LaboratoryLivermoreCAUSA Materials Sciences Division Lawrence Berkeley National LaboratoryBerkeleyUSA Department of Material Science and Engineering University of CaliforniaBerkeleyCAUSA Molecular Foundry Lawrence Berkeley National LaboratoryBerkeleyUSA

To accelerate the development of ion conducting materials,we present a general graph-theoretic analysis framework for ion migration in any crystalline *** nodes of the graph represent metastable sites of the migrating ion and the edges represent discrete migration events between adjacent *** from a collection of possible metastable migration sites,the framework assigns a weight to the edges by calculating the individual migration energy barriers between those *** pathways in the periodic simulation cell corresponding to macroscopic ion migration are identified by searching for the lowest-cost cycle in the periodic migration *** exemplify the utility of the framework,we present the automatic analyses of Li migration in different polymorphs of VO(PO_(4)),with the resulting identification of two distinct crystal structures with simple migration pathways demonstrating overall<300 meV migration barriers.

关键词： analysis migration metastable

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Coupled Micromagnetic-Electromagnetic Solvers with Truncated Boundaries

Coupled Micromagnetic-Electromagnetic Solvers with Truncated...

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USNC-URSI Radio science Meeting (Joint with AP-S Symposium)

作者： Jiawei Duan Vitaliy Lomakin Dept of ECE Program in Material Science and Engineering Center for Memory and Recording Research University of California San Diego

ISBN: (数字)9789463968119

ISBN: (纸本)9798350359497

Magnetization dynamics in nano- and micro-scale magnetic materials and devices is governed by the Landau-Lifshitz-Gilbert (LLG) equation. This equation links magnetization dynamics to torques arising from various physical interactions, including electromagnetic effects influenced by magnetic field time variations. At low frequencies, these effects are approximated by magnetostatics, but at higher frequencies and device sizes, electrodynamic effects, such as eddy currents, become significant. Dynamic magnetic fields are determined using dynamic Maxwell's equations. Methods to solve Maxwell's equations for eddy current issues include Finite Element Method (FEM) and integral equation-based techniques. Challenges in developing efficient solvers involve computational domain truncation, efficient time stepping, and coupling Maxwell's with LLG equations.

关键词： Electrodynamics Magnetostatics Magnetization Integral equations Nanoscale devices Magnetic materials Finite element analysis

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Physicochemical properties of lard oil and rubber seed oil blends and their comprehensive characterization

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Chinese Journal of Chemical engineering 2024年第11期75卷 1-13页

作者： Amonrat Thangthong Wuttichai Roschat Phongsakorn Pholsupho Aekkaphon Thammayod Sunti Phewphong Tappagorn Leelatam Preecha Moonsin Boonyawan Yoosuk Pathompong Janetaisong Vinich Promarak Program of Environment Science Faculty of Science and TechnologySakon Nakhon Rajabhat UniversityMueang DistrictSakon Nakhon 47000Thailand Biomass Energy Research Laboratory Center of Excellence on Alternative EnergyResearch and Development InstitutionSakon Nakhon Rajabhat UniversityMueang DistrictSakon Nakhon 47000Thailand Program of Chemistry Faculty of Science and TechnologySakon Nakhon Rajabhat UniversityMueang DistrictSakon Nakhon 47000Thailand Innovation in Chemistry for Community Research Unit Faculty of Science and TechnologySakon Nakhon Rajabhat UniversityMueang DistrictSakon Nakhon 47000Thailand Appropriated Technology Center Faculty of Science and TechnologySakon Nakhon Rajabhat UniversityMueang DistrictSakon Nakhon 47000Thailand Program of Chemistry Faculty of ScienceUbon Ratchathani Rajabhat UniversityMueang DistrictUbon Ratchathani 34000Thailand National Energy Technology Center(ENTEC) 114 Thailand Science ParkPhahonyothin RoadKlong LuangPathumthani 12120Thailand Department of Material Science and Engineering School of Molecular Science&EngineeringVidyasirimedhi Institute of Science and TechnologyWangchanRayong 21210Thailand

This research investigates the potential of blending complementary lard oil with rubber seed oil as feedstock for biodiesel *** seed oil,obtained through hexane extraction using the Soxhlet method,contains the major fatty acids of oleic acid(C_(18:1)),palmitic acid(C_(16:0)),linoleic acid(C_(18:2)),and stearic acid(C_(18:0)),while rubber seed oil primarily consists of linoleic acid(C_(18:2)),oleic acid(C_(18:1)),linolenic acid(C_(18:3)),palmitic acid(C_(16:0)),and stearic acid(C_(18:0)).The least acid value of lard oil(0.55 mg KOH/g)can benefit of reducing soap formation of rubber seed oil during transesterification process in biodiesel production due to its substantial-high acid value(16.28 mg KOH/g).Blending at ratios below 80:20 volume ratio produced biodiesel exceeding 85%,utilizing CaO as a *** oil demonstrated a higher reaction rate constant(11.88×10^(-3)min^(-1))than rubber seed oil(2.11×10^(-3)min^(-1)),indicating a significant difference in *** acid value and free fatty acids in rubber seed oil correlated with lower reaction *** a mixture ratio below 80:20 volume ratio optimized reaction rates during biodiesel *** obtained from blends below 80:20 volume ratio met ASTM D6751 and EN 14214 standards,demonstrating suitability for bio-auto *** drawbacks of using rubber seed oil as a raw material for biodiesel production are overcome by blending with lard oil,giving rise to expanding renewable energy options for rural communities,community enterprises,and large-scale biodiesel production.

关键词： Biodiesel oil Rubber seed oil Lard oil High free fatty acid Physicochemical properties Liquid biofuels

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An IoT-based Parameter Extraction Platform for Powder Metallurgy Sintering Furnace 11

An IoT-based Parameter Extraction Platform for Powder Metall...

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11th International Conference on Internet of Things: Systems, Management and Security, IOTSMS 2024

作者： Chang, Shih-Man Lin, Hao Pu Han, Chin-Chuan Wu, Yu-Chi National United University Dept. of Computer Science and Information Engineering Miao-Li Taiwan National United University Program in Material and Chemical Engineering MiaoLi Taiwan National United University Dept. of Electrical Engineering Miao-Li Taiwan

ISBN: (纸本)9798350366501

Internet of Things (IoT) technology has widely used in industrial production. Most cases focused on designing new equipment or processes. However, small and medium enterprises especially the powder metallurgy manufacturers in Taiwan would not replace existing production equipment due to the finical problems. In this study, an IoT-based platform is conducted to extract the sintering parameters for technology to augment sintering furnaces by installing sensors and data transmission modules, setting a sintering parameter extraction platform for powder metallurgy sintering furnace. Long-term monitoring and remote control are the main technologies for solving three problems during the sintering process, i.e., temperature, atmosphere, and time. Monitoring targets include checking whether the heaters are damaged, ensuring stable air flow meter readings, and verifying the normal speed of the conveyor belt. Additionally, remote control technology has been developed to execute cooling and reheating processes on the sintering furnace. The staying time on-site for personnel is reduced and the sintering time is increased for production increase during working hours. © 2024 IEEE.

关键词： Belt conveyors

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Accurate prediction of oxygen vacancy concentration with disordered A-site cations in high-entropy perovskite oxides

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npj Computational materials 2023年第1期9卷 2053-2065页

作者： Jiyun Park Boyuan Xu Jie Pan Dawei Zhang Stephan Lany Xingbo Liu Jian Luo Yue Qi School of Engineering Brown UniversityProvidenceRI 02912USA Department of Physics Brown UniversityProvidenceRI 02912USA Department of Chemical Engineering and Materials Science Michigan State UniversityEast LansingMI 48824USA Program of Materials Science and Engineering University of California San DiegoLa JollaCA 92093USA Materials Science Center National Renewable Energy LaboratoryGoldenCO 80401USA Department of Mechanical and Aerospace Engineering Benjamin M.Statler College of Engineering and Mineral ResourcesWest Virginia UniversityMorgantownWV 26506USA Department of NanoEngineering University of California San DiegoLa JollaCA 92093USA

Entropic stabilized ABO_(3) perovskite oxides promise many applications,including the two-step solar thermochemical hydrogen(STCH)*** binary and quaternary A-site mixed{A}FeO_(3) as a model system,we reveal that as more cation types,especially above four,are mixed on the A-site,the cell lattice becomes more cubic-like but the local Fe–O octahedrons are more *** comparing four different Density Functional Theory-informed statistical models with experiments,we show that the oxygen vacancy formation energies(E^(f)_(V))distribution and the vacancy interactions must be considered to predict the oxygen non-stoichiometry(δ)*** STCH applications,the E^(f)_(V) distribution,including both the average and the spread,can be optimized jointly to improveΔδ(difference ofδbetween the two-step conditions)in some hydrogen production *** model can be used to predict the range of water splitting that can be thermodynamically improved by mixing cations in{A}FeO_(3) perovskites.

关键词： perovskite vacancy oxides

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In vitro evaluation of degradation,cytocompatibility and antibacterial property of polycaprolactone/hydroxyapatite composite coating on bioresorbable magnesium alloy

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Journal of Magnesium and Alloys 2022年第8期10卷 2252-2265页

作者： Zhang Chunyan Cheng Lan Lin Jiajia Sun Dongwei Zhang Jun Liu Huinan School of Materials Science&Engineering Chongqing University of TechnologyNo.69 Hongguang AvenueChongqing 400054China Department of Bioengineering and the Materials Science and Engineering ProgramUniversity of CaliforniaRiverside900 University AvenueMSE 205RiversideCA 92521USA

Polycaprolactone/hydroxyapatite(PCL/HA)composite coating was fabricated by a combination of hydrothermal and dipping methods to delay the degradation of Mg alloy AZ31 as bioresorbable *** PCL/HA coating was composed of nano rod-shape HA crystals and PCL filled in the space of HA *** with the single HA coating,the binding strength between the PCL/HA composite coating and Mg alloy was obviously improved and the PCL/HA coating still adhered to the surface of AZ31 substrate even after 38 days of *** electrochemical corrosion rate of HA coated sample was reduced by ten times after being filled by *** electrochemical impedance spectroscopy(EIS)and immersion test results showed that the PCL/HA composite coating could provide a more effective barrier for Mg substrate than the HA coating *** cytocompatibility and the antibacterial property of HA coating and PCL/HA coating were evaluated by culturing with bone marrow-derived mesenchymal stem cells(BMSCs)and methicillin-resistant staphylococcus aureus(MRSA)for 24 h under direct culture conditions,*** PCL/HA composite coating showed better BMSC cell compatibility,more suitable for BMSC adhesion than HA coating alone and showed a potential application prospect as a biological ***,from the perspective of clinical applications,the antibacterial property of PCL/HA composite coating needs to be further improved.

关键词： Mg alloy PCL/HA coating Corrosion resistance Cytocompatibility Antibacterial property

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High-Throughput Independent Component Analysis Processor for Full Duplex Systems

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IEEE Journal on Selected Areas in Communications 2023年第9期41卷 2821-2832页

作者： Cheng, Jen-Hao Chang, Tien-Min Shen, Chung-An Fouda, Mohammed E. Eltawil, Ahmed M. National Taiwan University of Science and Technology Department of Electronic and Computer Engineering Taipei10607 Taiwan University of California at Irvine Electrical Engineering and Computer Science Department IrvineCA92697 United States King Abdullah University of Science and Technology Electrical and Computer Engineering Program Thuwal23955 Saudi Arabia

This paper presents the algorithm and very-large-scale integration (VLSI) architecture of a high-throughput and highly efficient independent component analysis (ICA) processor for self-interference cancellation (SIC) in in-band full-duplex (IBFD) systems. This is the first VLSI architecture reported in the literature based on the state-of-the-art entropy bound minimization (EBM) approach. A novel ICA algorithm is presented in this paper with momentum gradient descent optimization. Simulation results show that the number of iterations for the proposed algorithm is significantly reduced compared to the conventional ICA algorithms. Furthermore, a novel early-distribution estimation scheme is proposed in the designed ICA processor to compute multiple distribution functions with low latency and low complexity. The processing flow and the efficiency for the hardware utilization are specifically designed so that the processing speed is maximized with minimum employment of hardware components. The proposed ICA processor is designed and implemented based on the application-specific-integrated circuit (ASIC) flow. The post-layout estimations show that compared with the conventional EBM-based scheme, the proposed design improves the throughput and efficiency by 30x. In addition, compared to prior designs shown in the literature, the proposed ICA processor also demonstrates a significant enhancement in terms of throughput and efficiency. © 1983-2012 IEEE.

关键词： VLSI circuits

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The Indoor People Tracking and Counting System

The Indoor People Tracking and Counting System

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2023 International Automatic Control Conference, CACS 2023

作者： Lin, Hao-Pu Han, Chin-Chuan Liao, Jun-Wei Ciou, Chong-Han Hong, Yi-Cheng Tan, Ming-Lun National United University Ph. D. Program in Material and Chemical Engineering MiaoLi Taiwan National United University Department of Computer Science and Information Engineering MiaoLi Taiwan

ISBN: (纸本)9798350306354

COVID-19 outbreaks and becomes serious from 2019 winter. Taking body temperature, wearing masks, recording footprint and avoiding crowds become important tasks and require a lot of manpower support for the prevention of the epidemic in every. In this study, we have integrated the infrared thermometer devices to measure people temperature and the people identities through RGB images at the entrance of buildings. Using the computer vision and deep learning methods, we would like to build a 24/7 and region-wide coverage assistance system to automatically record the footprint of a specific people in the building. We also detect if people taking off their masks in the yard at any time. The processing videos are grabbed from the existing CCTV systems. The developed system also locates the crowd and calculate the number of people in a specified area, and the manager can know the number of people and control the access in real time. It will reduce the burden of manpower. In addition, we have optimized the system performance to handle multiple camera videos and to reduce the hardware cost at the same time. © 2023 IEEE.

关键词： Access control

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