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Texture development and surface reconstruction of BiVO_(4)photoanode via one-pot hydrothermal reaction for enhanced photoelectrochemical water splitting

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Journal of Advanced Ceramics 2025年第3期14卷 133-141页

作者： Sung Won Hwang Yoo Jae Jeong Runfa Tan Indhujasri Saravanan Hyun Soo Han Dong Hoe Kim In Sun Cho Department of Energy Systems Research Ajou UniversitySuwon 16499Republic of Korea Department of Material Science&Engineering Ajou UniversitySuwon 16499Republic of Korea Department of Mechanical Engineering Stanford UniversityStanford 94305USA Department of Material Science&Engineering Korea UniversitySeoul 02841Republic of Korea Materials Science and Engineering Program University of Colorado BoulderBoulder 80303USA

The simultaneous optimization of the bulk and surface characteristics of photoelectrodes is essential to maximize their photoelectrochemical(PEC)*** report a novel one-pot hydrothermal synthesis of textured and surface-reconstructed BiVO_(4)photoanodes(ts-BVO),achieving significant improvements in PEC water *** controlling precursor molarity and ethylene glycol(EG)addition,we developed a stepwise dual reaction(SDR)mechanism,which enables simultaneous bulk texture development and surface *** optimized CoBi/ts-BVO photoanode exhibited a photocurrent density of 4.3 mA∙cm^(−2)at 1.23 V *** hydrogen electrode(RHE)with a high Faradaic efficiency of 98%under one sun *** with nontextured BiVO_(4),the charge transport efficiency increased from 8%to 70%,whereas the surface charge transfer efficiency improved from 9%to 85%.These results underscore the critical role of both bulk and surface engineering in enhancing PEC *** findings offer a streamlined approach for improving the intrinsic properties of photoanodes in solar water splitting.

关键词： BiVO_(4) hydrothermal texture surface reconstruction ethylene glycol(EG) photoelectrochemical water splitting

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Scalable Membraneless Direct Liquid Fuel Cells Based on a Catalyst-Selective Strategy

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Energy & Environmental materials 2018年第1期1卷 13-19页

作者： Xingwen Yu Arumugam Manthiram Materials Science&Engineering Program and Texas Materials Institute The University of Texas at AustinAustinTX 78712USA

This perspective presents a membraneless direct liquid fuel cell(DLFC)concept based on a catalyst-selective *** membraneless DLFCs are operated at low temperatures by employing a non-precious cathode catalyst with a high catalytic *** uniqueness is that the inexpensive cathode catalyst only catalyzes the oxygen reduction reaction but does not catalyze the oxidation reaction of a specific ***,during the operation of DLFCs,the liquid fuel can enter the cathode freely without any concern of fuel *** catalyst-selective approach tactfully avoids the use of high-cost or technically unviable ion-exchange polymer membranes in *** catalyst-selective operating principle also overcomes the scalability issue of the traditional laminar-flow membraneless *** a proper management of the anode and cathode catalysts in the cell,a variety of inexpensive,renewable alcohols,and small-molecule organics can be employed as anode *** innovative approach of membraneless alkaline DLFCs offers a great opportunity for the development of inexpensive energy-generation systems for both mobile and stationary *** addition to summarizing the principle and the research progress of the unique membraneless DLFC platform,the challenges and future research directions are presented.

关键词： catalyst uniqueness overcome

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Efficient predictions of formation energies and convex hulls from density functional tight binding calculations

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Journal of materials science & Technology 2023年第10期141卷 236-244页

作者： Anshuman Kumar Zulfikhar A.Ali Bryan M.Wong Materials Science&Engineering Program University of California-RiversideRiverside92521CAUSA Department of Physics&Astronomy University of California-RiversideRiverside92521CAUSA Materials Science&Engineering Program Department of Chemical&Environmental EngineeringDepartment of Physics&Astronomyand Department of ChemistryUniversity of California-RiversideRiverside92521CAUSA

Defects in materials significantly alter their electronic and structural properties,which affect the per-formance of electronic devices,structural alloys,and functional ***,calculating all the possible defects in complex materials with conventional Density Functional Theory(DFT)can be compu-tationally *** enhance the efficiency of these calculations,we interfaced Density Functional Tight Binding(DFTB)with the Clusters Approach to Statistical Mechanics(CASM)software package for the first *** SiC and ZnO as representative examples,we show that DFTB gives accurate results and can be used as an efficient computational approach for calculating and pre-screening formation ener-gies/convex *** DFTB+CASM implementation allows for an efficient exploration(up to an order of magnitude faster than DFT)of formation energies and convex hulls,which researchers can use to probe other complex systems.

关键词： CASM DFTB DFT Formation energy Convex hull

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Optical Patterning of Two-Dimensional materials

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Research 2020年第1期2020卷 1064-1078页

作者： Pavana Siddhartha Kollipara Jingang Li Yuebing Zheng Walker Department of Mechanical Engineering The University of Texas at AustinAustinTX 78712USA Materials Science&Engineering Program and Texas Materials Institute The University of Texas at AustinAustinTX 78712USA

Recent advances in the field of two-dimensional(2D)materials have led to new electronic and photonic devices enabled by their unique properties at atomic *** 2D materials into desired patterns on substrates is often an essential and foremost step for the optimum performance of the functional *** this regard,optical patterning of 2D materials has received enormous interest due to its advantages of high-throughput,site-specific,and on-demand *** years have witnessed scientific reports of a variety of optical techniques applicable to patterning 2D *** this minireview,we present the state-of-the-art optical patterning of 2D materials,including laser thinning,doping,phase transition,oxidation,and *** applications based on optically patterned 2D materials will be discussed as *** further developments,optical patterning is expected to hold the key in pushing the frontiers of manufacturing and applications of 2D materials.

关键词： frontier doping optimum

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In vitro evaluation of degradation,cytocompatibility and antibacterial property of polycaprolactone/hydroxyapatite composite coating on bioresorbable magnesium alloy

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Journal of Magnesium and Alloys 2022年第8期10卷 2252-2265页

作者： Zhang Chunyan Cheng Lan Lin Jiajia Sun Dongwei Zhang Jun Liu Huinan School of Materials Science&Engineering Chongqing University of TechnologyNo.69 Hongguang AvenueChongqing 400054China Department of Bioengineering and the Materials Science and Engineering ProgramUniversity of CaliforniaRiverside900 University AvenueMSE 205RiversideCA 92521USA

Polycaprolactone/hydroxyapatite(PCL/HA)composite coating was fabricated by a combination of hydrothermal and dipping methods to delay the degradation of Mg alloy AZ31 as bioresorbable *** PCL/HA coating was composed of nano rod-shape HA crystals and PCL filled in the space of HA *** with the single HA coating,the binding strength between the PCL/HA composite coating and Mg alloy was obviously improved and the PCL/HA coating still adhered to the surface of AZ31 substrate even after 38 days of *** electrochemical corrosion rate of HA coated sample was reduced by ten times after being filled by *** electrochemical impedance spectroscopy(EIS)and immersion test results showed that the PCL/HA composite coating could provide a more effective barrier for Mg substrate than the HA coating *** cytocompatibility and the antibacterial property of HA coating and PCL/HA coating were evaluated by culturing with bone marrow-derived mesenchymal stem cells(BMSCs)and methicillin-resistant staphylococcus aureus(MRSA)for 24 h under direct culture conditions,*** PCL/HA composite coating showed better BMSC cell compatibility,more suitable for BMSC adhesion than HA coating alone and showed a potential application prospect as a biological ***,from the perspective of clinical applications,the antibacterial property of PCL/HA composite coating needs to be further improved.

关键词： Mg alloy PCL/HA coating Corrosion resistance Cytocompatibility Antibacterial property

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Superhydrophobic fluoride conversion coating on bioresorbable magnesium alloy——fabrication,characterization,degradation and cytocompatibility with BMSCs

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Journal of Magnesium and Alloys 2021年第4期9卷 1252-1266页

作者： Chunyan Zhanga Shiyu Zhang Dongwei Sun Jiajia Lin Fancheng Meng Huinan Liu School of Materials Science&Engineering Chongqing University of TechnologyNo.69 Hongguang AvenueChongqing 400054China Department of Bioengineering and the Materials Science and Engineering ProgramUniversity of CaliforniaRiverside900 University AvenueMSE 205RiversideCA 92521USA

A micro-nano structure CaF_(2)chemical conversion layer was prepared on fluoride-treated AZ31 alloy,then the composite fluoride conversion film(CaF_(2)/MgF_(2))was modified by stearic acid(SA)and fabricated a superhydrophobic *** fluoride-treated magnesium,fluoride conversion film and superhydrophobic coating were characterized by SEM,EDS,XRD and *** properties of coatings1 adhesion and corrosion resistance were evaluated via tape test and electrochemical *** cytocompatibility of the MgF_(2),CaF_(2)and superhydrophobic CaF_(2)/SA surface was investigated with bone marrow-derived mesenchymal stem cells(BMSCs)by direct culture for 24 *** results showed that the superhydrophobic fluoride conversion coating composed of inner MgF_(2)layer and the outer CaF_(2)/SA composite layer had an average water contact angle of 152°.SA infiltrated into the micro-nano structure CaF_(2)layer and formed a strong adhesion with CaF_(2)***,the super-hydrophobic coating showed higher barrier properties and corrosion resistance compared with the fluoride conversion film and fluoride-treated AZ31 *** BMSC adhesion test results demonstrated MgF_(2)CaF_(2)and CaF_(2)/SA coatings were all nontoxic to *** the condition of in direct contact with cells,MgF_(2)showed higher cell density and enhanced the BMSCs proliferation,while CaF_(2)and CaF_(2)/SA coating showed no statistically difference in cell density compared with glass reference but the CaF_(2)and CaF_(2)/SA coating were not conducive to BMSCs adhesion.

关键词： Biodegradable Magnesium alloy Superhydrophobic Fluoride conversion film Cytocompatibility

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Automating selective area electron diffraction phase identification using machine learning

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Journal of Materiomics 2024年第4期10卷 896-905页

作者： M.Mika N.Tomczak C.Finney J.Carter A.Aitkaliyeva Nuclear Engineering Program in Department of Materials Science University of Florida100 Rhines HallGainesville32611FLUSA Department of Materials Science&Engineering Case Western Reserve University2111 Martin Luther King Jr DrCleveland44106OHUSA

Selective area electron diffraction(SAED)patterns can provide valuable insight into the structure of a ***,the manual identification of collected patterns can be a significant bottleneck in the overall phase classification *** this work,we utilize the recent advances in computer vision and machine learning(ML)to automate the indexing of SAED *** performance of six different ML algorithms is demonstrated using metallic plutonium-zirconium *** most successful approach trained a neural network(NN)to make a classification of the phase and zone axis,and then utilized a second NN to synthesize multiple independent predictions of different tilts in a single sample to make an overall phase *** results demonstrate that automated SAED phase identification using ML is a viable route to accelerate materials characterization.

关键词： Selective area electron diffraction Machine learning Phase identification Metallic fuels Pu alloys

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Surface-modified Ag@Ru-P25 for photocatalytic CO_(2) conversion with high selectivity over CH_(4) formation at the solid–gas interface

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Carbon Energy 2024年第1期6卷 182-196页

作者： Chaitanya B.Hiragond Sohag Biswas Niket SPowar Junho Lee Eunhee Gong Hwapyong Kim Hong Soo Kim Jin-Woo Jung Chang-Hee Cho Bryan M.Wong Su-Il In Department of Energy Science&Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea Department of Chemical&Environmental Engineering Materials Science&Engineering ProgramDepartment of ChemistryDepartment of Physics&AstronomyUniversity of California-RiversideRiversideCaliforniaUSA Department of Physics and Chemistry Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea NiceScience Corporation DaeguRepublic of Korea

Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO_(2) reduction to solar fuels.A surface-modified Ag@Ru-P25 photocatalyst with H_(2)O_(2) treatment was designed in this study to convert CO_(2) and H_(2)O vapor into highly selective *** doping followed by Ag nanoparticles(NPs)cocatalyst deposition on P25(TiO_(2))enhances visible light absorption and charge separation,whereas H_(2)O_(2) treatment modifies the surface of the photocatalyst with hydroxyl(–OH)groups and promotes CO_(2) ***-resonance transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray absorption near-edge structure,and extended X-ray absorption fine structure techniques were used to analyze the surface and chemical composition of the photocatalyst,while thermogravimetric analysis,CO_(2) adsorption isotherm,and temperature programmed desorption study were performed to examine the significance of H_(2)O_(2) treatment in increasing CO_(2) reduction *** optimized Ag1.0@Ru1.0-P25 photocatalyst performed excellent CO_(2) reduction activity into CO,CH4,and C2H6 with a~95%selectivity of CH4,where the activity was~135 times higher than that of pristine TiO_(2)(P25).For the first time,this work explored the effect of H_(2)O_(2) treatment on the photocatalyst that dramatically increases CO_(2) reduction activity.

关键词： gas-phase CO_(2) reduction H_(2)O_(2) treatment plasmonic nanoparticles solar fuel photocatalyst surface modification

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Nitrate additives for lithium batteries:Mechanisms,applications,and prospects

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escience 2021年第2期1卷 108-123页

作者： Xiang Li Ruxin Zhao Yongzhu Fu Arumugam Manthiram College of Chemistry Zhengzhou UniversityZhengzhou450001PR China Materials Science&Engineering Program and Texas Materials Institute The University of Texas at AustinAustinTX78712United States

Lithium-metal batteries(LMBs)are considered as one of the most promising energy storage devices due to the high energy density and low reduction potential of the Li-metal ***,the growth of lithium dendrites results in accumulated dead Li and safety issues,limiting the practical application of ***_(3)is a well-known additive in lithium-sulfur batteries to regulate the solid-electrolyte interphase(SEI),effectively suppressing the redox shuttle of ***,other nitrates have been investigated in various electrolyte and battery systems,yielding improved SEI stability and cycling *** this review,we provide an overview of various nitrates,including LiNO_(3)for lithium batteries,focusing on their mechanisms and *** first discuss the effect of nitrate anions on SEI formation,as well as the cathode-electrolyte interphase(CEI).The solvation behavior regulated by nitrates is also extensively *** strategies to improve the solubility of LiNO_(3)in ester-based electrolytes are then summarized,followed by a discussion of recent progress in the application of nitrates in different ***,further research directions are presented,along with *** review provides a comprehensive understanding of nitrates and affords new and interesting ideas for the design of better electrolytes and battery systems.

关键词： Nitrate additive Lithium battery Mechanism Application

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Optothermally Assembled Nanostructures

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Accounts of materials Research 2021年第5期2卷 352-363页

作者： Jingang Li Yuebing Zheng Materials Science&Engineering Program Texas Materials Instituteand Walker Department of Mechanical EngineeringThe University of Texas at AustinAustinTexas 78712United States

CONSPECTUS:Nanofabrication is one of the core techniques in rapidly evolving nanoscience and *** top-down nanofabrication approaches such as photolithography and electron beam lithography can produce high-resolution nanostructures in a robust ***,these methods usually involve multistep processing and sophisticated instruments and have difficulty in fabricating three-dimensional complex structures of multiple materials and ***,bottom-up techniques have emerged as promising alternatives to fabricating nanostructures via the assembly of individual building *** comparison to top-down lithographical methods,bottom-up assembly features the on-demand construction of superstructures with controllable configurations at single-particle *** size,shape,and composition of chemically synthesized building blocks can also be precisely tailored down to the atomic scale to fabricate multimaterial architectural structures of high *** techniques have been reported to assemble individual nanoparticles into complex structures,such as self-assembly,DNA nanotechnology,patchy colloids,and optically controlled *** them,the optically controlled assembly has the advantages of remote control,site-specific manipulation of single components,applicability to a wide range of building blocks,and arbitrary configurations of the assembled *** this Account,we provide a concise review of our contributions to the optical assembly of architectural materials and structures using discrete nanoparticles as the building *** exploiting entropically favorable optothermal conversion and controlling optothermal−matter interactions,we have developed optothermal assembly techniques to manipulate and assemble individual *** techniques can be operated both in solution and on solid ***,we discuss the opto-thermoelectric assembly(OTA)of colloidal particles into superstructures by co

关键词： structures architectural printing

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