As mobile technology evolves from 5G to 6G, the demand for third-generation semiconductors such as SiC with higher power and frequency capabilities is increasing. Silicon Carbide power modules generate significant hea...
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materials with heterogenous microstructures have been reported to have an attractive combination of strength and ductility. This is attributed to synergistic strengthening effects from the difference in strength of fi...
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In this study, dissimilar friction stir welding was performed between AA5052 aluminium and AZ31 magnesium alloys using a variety of parameters. The results revealed that the optimal range of welding parameter is betwe...
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We present a phase-based framework for reducing the pressure fluctuations within a spanwise-periodic supersonic turbulent cavity flow with an incoming free-stream Mach number of 1.4 and a depth-based Reynolds number o...
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In this work, for the first time, bronze/SiC/mica hybrid composite has been manufactured using powder metallurgy method. Mixture - process variable design has been applied to design of experiments and optimization of ...
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The present study demonstrates a facile and multistep chemical approach for preparing covalent functionalized graphene oxide (GO) followed by the layer-by-layer assembly of polymer brushes on functionalized GO for aqu...
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The present study demonstrates a facile and multistep chemical approach for preparing covalent functionalized graphene oxide (GO) followed by the layer-by-layer assembly of polymer brushes on functionalized GO for aqueous lubricants. Simultaneous reduction and surface modification of GO with 6-amino-4-hydroxy-2-naphthalenesulfonic acid (ANS) and polyethylenimine (PEI) was performed to synthesize functionalized GO (rGO-ANS and rGO-PEI) through a nucleophilic addition reaction pathway to enhance the thermal and dispersion stability in water. Polymer brush particles were fabricated on modified rGO-PEI using anionic polyelectrolytes to extend the load-bearing ability under water-lubricated conditions. The chemical, structural, wettability, and morphological features of functionalized GO and polymer brush particles were well characterized using standard spectroscopic and microscopic techniques. The macrotribological results showed that rGO-ANS (0.5 wt%) exhibited a steady coefficient of friction (COF) with increasing load-bearing ability up to 500 N load (Pm ∼ 4.8 GPa) compared to GO. Although the ANS chains helped to generate an antifrictional tribofilms, the smeared particle film was unable to decrease the COF and wear with increasing the contact pressure to a lower level. Whereas, the poly(sodium 4-styrenesulfonate) (PSS) containing polymer brush (rGO-PBS) showed a significant reduction of the COF (∼ 61.5 %) and wear volume (∼ 82.9 %) at a 147 N load compared to the GO under water lubricated conditions. rGO-PBS also exhibited higher load-bearing capacity up to 800 N load (Pm ∼ 5.8 GPa) with a significantly lower COF and wear among particles. The sulfonate groups containing PSS in rGO-PBS provided robust interfacial adhesive properties to the steel tribo pairs, which facilitated the formation of antifrictional protective tribofilm through well-hydrated polymeric cushioning layers to reduce the COF, wear, and enhance the load-affording ability. Therefore, the excellent
In this paper, we designed double V-shaped Al/Ni multilayer energy-containing microdevices with different V-angles, and performed finite element modeling and simulation of the heat transfer process of the designed ene...
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Synthesis of ultrathin heterostructures has received much attention in the recent past due to their unique physical and chemical *** this work,we report the synthesis of Fe_(2)TiO_(5)–TiO_(2)heterostructures using a ...
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Synthesis of ultrathin heterostructures has received much attention in the recent past due to their unique physical and chemical *** this work,we report the synthesis of Fe_(2)TiO_(5)–TiO_(2)heterostructures using a simple hydrothermal technique employing natural ilmenite as the *** arranged nanostructures with interconnected nano-petals of thickness around 50 nm are *** electrocatalytic properties of the synthesized Fe_(2)TiO_(5)–TiO_(2)heterostructures are enhanced following the cathodization *** observed enhancement in the synthesized materials’electrocatalytic property can be attributed to the defect-rich Fe_(2-x)TiO_(5-x)-TiO_(2-x)*** current approach and technique discussed in this work offer a simple method to synthesize a nanostructured heterostructure material and create defects for enhancing electrocatalytic activity.
This paper investigates the robust attitude control for wingtip-connected multibody aircraft, using preview-based control compensation mechanism to address the issues of inherent wingtip couplings. A constrained multi...
Corrosion poses major challenges in various industrial sectors such as oil and gas, chemicals, and infrastructure. Traditional corrosion inhibitors have limitations in terms of toxicity and environmental compatibility...
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Corrosion poses major challenges in various industrial sectors such as oil and gas, chemicals, and infrastructure. Traditional corrosion inhibitors have limitations in terms of toxicity and environmental compatibility. Supramolecular complexes are promising as green corrosion inhibitors, as the interaction between host and guest molecules can be tailored for different application needs. This study investigates a β-cyclodextrin (β-CD)/melamine (ME) supramolecular complex. The synthesis of the complex is confirmed by Raman spectroscopy, 1H NMR, and FT-IR methods. A range of characterisation techniques are used to analyse the complex’s structure. Gravimetric and electrochemical tests, including potentiodynamic polarisation and electrochemical impedance spectroscopy, evaluate its corrosion inhibition performance on steel in 0.5 M HCl solution at varying concentrations (25–100 mg/L) and temperatures (303 to 333 K). Computational modelling, including Density Functional Theory, Monte Carlo, and Molecular Dynamics simulations, provides atomic-scale insights into the mechanisms of inhibition. The synthesis, characterisation, and corrosion prevention performance of a novel supramolecular complex, β-cyclodextrin/melamine (β-CD/ME), on St20 steel, in acidic conditions, were the subjects of an inventive investigation that was described in this publication. The complex’s structural alterations, physical interactions, and structure were effectively disclosed, using Raman spectroscopy, 1H NMR, and FT-IR. The β-CD/ME complex’s ability to prevent corrosion in hostile solutions exceeded 92–94%, resulting in the formation of a thin protective film on the metal surface and acting as a mixed-type inhibitor. A novel mix of theoretical and experimental methods is used in this work to comprehend the underlying mechanisms, including the influence of structural factors on corrosion prevention effectiveness and the adsorption energies of the complex on the metal surface. Electrochemical tests
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