Mg alloys possess an inherent plastic anisotropy owing to the selective activation of deformation mechanisms depending on the loading *** characteristic results in a diverse range of flow curves that vary with a defor...
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Mg alloys possess an inherent plastic anisotropy owing to the selective activation of deformation mechanisms depending on the loading *** characteristic results in a diverse range of flow curves that vary with a deformation *** study proposes a novel approach for accurately predicting an anisotropic deformation behavior of wrought Mg alloys using machine learning(ML)with data *** developed model combines four key strategies from data science:learning the entire flow curves,generative adversarial networks(GAN),algorithm-driven hyperparameter tuning,and gated recurrent unit(GRU)*** proposed model,namely GAN-aided GRU,was extensively evaluated for various predictive scenarios,such as interpolation,extrapolation,and a limited dataset *** model exhibited significant predictability and improved generalizability for estimating the anisotropic compressive behavior of ZK60 Mg alloys under 11 annealing conditions and for three loading *** GAN-aided GRU results were superior to those of previous ML models and constitutive *** superior performance was attributed to hyperparameter optimization,GAN-based data augmentation,and the inherent predictivity of the GRU for *** a first attempt to employ ML techniques other than artificial neural networks,this study proposes a novel perspective on predicting the anisotropic deformation behaviors of wrought Mg alloys.
Nickel-rich layered oxides are attractive cathode for lithium-ion batteries(LIBs)because of the high energy density and low *** critical problem is capacity fading caused by the highly reactive metastable phases under...
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Nickel-rich layered oxides are attractive cathode for lithium-ion batteries(LIBs)because of the high energy density and low *** critical problem is capacity fading caused by the highly reactive metastable phases under voltages of higher than 4.15 ***,we find that facile Ar/H2 plasma treating could produce oxygen vacancies that will readily transform into homogeneous spinel layer(~6 nm)on the LiNi_(0.8)CO_(0.1)Mn_(0.1)O_(2)(NCM811)surface after a few cycles of lithiation/delithiation *** to the structural matching between spinel and layered structure,the diffusion of Li ions could remain fast upon ***,the spinel layer is electrochemically inert,which guarantees surface stabilization and inhibits the detrimental phase transition from H2 to H3 at high *** the protection of the homogeneous spinel layer,the NCM_(811) electrode shows superior capacity retention of 91.2% after 200 cycles at the current density of 100 mA·g^(−1).This work proposes a novel strategy of surface reconstruction to stabilize nickel-rich layered oxide materials for LIBs.
A reasonable process plan is an important basis for implementing wire arc additive and subtractive hybrid manufacturing(ASHM),and a new optimization method is ***,the target parts and machining tools are modeled by le...
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A reasonable process plan is an important basis for implementing wire arc additive and subtractive hybrid manufacturing(ASHM),and a new optimization method is ***,the target parts and machining tools are modeled by level set ***,the mathematical model of the additive direction optimization problem is established,and an improved particle swarm optimization algorithm is designed to decide the best additive ***,the two-step strategy is used to plan the hybrid manufacturing alternating *** target parts are directly divided into various processing regions;each processing region is optimized based on manufacturability and manufacturing efficiency,and the optimal hybrid manufacturing alternating sequence is obtained by merging some processing ***,the method is used to outline the process plan of the designed example model and applied to the actual hybrid manufacturing process of the *** manufacturing result shows that the method can meet the main considerations in hybrid *** addition,the degree of automation of process planning is high,and the dependence on manual intervention is low.
Lithium(Li)metal anodes(LMAs)have garnered significant attention as a potential solution for developing high-energy density batteries,given their theoretical specific capacity and redox ***,safety concerns and interna...
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Lithium(Li)metal anodes(LMAs)have garnered significant attention as a potential solution for developing high-energy density batteries,given their theoretical specific capacity and redox ***,safety concerns and internal cycling stability issues originated from uncontrollable Li dendrite growth have impeded the practical application of *** the interface between Li metal and electrolyte is a crucial process that offers valuable insights into the characteristics and regularity of primary circular *** illustrate the intrinsic characteristic of Li metal batteries(LMBs)in spatial and temporal,it is imperative to employ electron microscopes to characterize the structural components distribution of Li with atomic *** paper summarizes the progress in the characterization and analysis of the interfaces in LMBs with electron microscopes based on the principles of electron-matter ***,future trends and the potential of electron microscopes are also discussed to advance our understanding of LMBs.
Generating reduced-order,synthetic grain structure datasets that accurately represent the measured grain structure of a material is important for reducing the cost and increasing the accuracy of computational crystal ...
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Generating reduced-order,synthetic grain structure datasets that accurately represent the measured grain structure of a material is important for reducing the cost and increasing the accuracy of computational crystal plasticity *** study introduces a machine-learning-based approach,termed texture adaptive clustering and sampling(TACS),for generating representative Euler angle datasets that accurately mimic the crystallographic *** TACS approach employs K-means clustering and density-based sampling in a closed-loop iteration to create representative Euler angle ***-of-principle experiments were performed on rolled and recrystallized low-carbon *** of the TACS approach was extended to twenty-two datasets,varying lattice structures,and complex crystallographic textures,thereby encompassing a broad range of materials and crystal ***-Smirnov(K-S)test comparisons underscore the performance of the TACS approach over traditional electron backscatter diffraction EBSD dataset reduction techniques,with average K-S test scores nearing 0.9,indicating a high-fidelity representation of the original *** contrast,conventional methods display scores below 0.3,indicating less reliability of the structure *** independence of the TACS approach from material texture and its capability to autonomously generate datasets with predetermined data points demonstrates its unbiased potential in streamlining dataset preparation for crystallographic analysis.
The emerging concept of multi-caloric effects, introduced in 2010, entails the application of multiple interplay fields to a thermodynamic system. While multi-caloric effects are the main focus of experimental endeavo...
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The emerging concept of multi-caloric effects, introduced in 2010, entails the application of multiple interplay fields to a thermodynamic system. While multi-caloric effects are the main focus of experimental endeavors, theoretical considerations fall short of providing a thorough understanding. This paper introduces a comprehensive presentation on multi-caloric effects,employing the method and theory of exterior derivative formations. It addresses every aspect of thermodynamic systems, showcasing its applicability to multi-caloric materials(both singlephase and multi-phase materials), and its adaptability to different scenarios(either in single or multiple force fields). The formulation of Maxwell relationships, characterized by their generality and universality, enables a clear prediction in entropy and temperature, facilitating a distinct identification between independent and interdependent contributions from multi-caloric effects. These insights hold significant importance in designing and developing specialized thermodynamic materials, optimizing functional performances and exploring innovative mechanisms.
Tribological applications of polytetrafluoroethylene(PTFE)are often limited by technological complexity to overcome its poor wear ***,a PTFE/polyetheretherketone(PEEK)heterolayer(HL)was proposed and evaluated as a new...
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Tribological applications of polytetrafluoroethylene(PTFE)are often limited by technological complexity to overcome its poor wear ***,a PTFE/polyetheretherketone(PEEK)heterolayer(HL)was proposed and evaluated as a new solid lubrication ***-on-disk tribometry found the lowest friction coefficient(μ)of 0.031 and ultralow wear for the PEEK/HL under typical *** friction coefficient of the HL surpasses those of the state-of-the-art polymeric coatings/composites by at least 200%,and approaches that of highly lubricated *** investigations revealed multi-length physical and chemical heterogeneity of the HL that best facilitates a tribofilm with high subsurface stability and surface *** technological simplicity and robustness of the HL’s high lubricity make it a promising new type of solid lubrication toward greater reliability and longevity.
The dissolution behavior of complex inclusions in refining slag was studied using confocal laser scanning *** on the dissolution curve of complex inclusions,the main rate-limiting link of CaO-SiO_(2)-Al_(2)O_(3)comple...
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The dissolution behavior of complex inclusions in refining slag was studied using confocal laser scanning *** on the dissolution curve of complex inclusions,the main rate-limiting link of CaO-SiO_(2)-Al_(2)O_(3)complex inclusions was the diffusion in the molten *** dissolution rate of CaO-SiO_(2)-Al_(2)O_(3)complex inclusions was affected by the composition and size of *** functional relationship between the dimensionless inclusion capacity(Zh)and the dimensionless dissolution rate(Ry)of CaO-SiO_(2)-Al_(2)O_(3)complex inclusions was calculated as Ry=2.10×10^(-6)Zh^(0.160),while it was Ry=2.10×10^(-6)Zh^(0.0087)for Al_(2)O_(3)-CaO complex *** this basis,the complete dissolution time and rate of the complex inclusions were calculated by using the function relation between the Zh and Ry numbers.
To explore the effect of temperature on the phase transformation of HCP→FCC during compression, the uniaxial compression process of AZ31 magnesium alloy was simulated by the molecular dynamics method, and the changes...
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To explore the effect of temperature on the phase transformation of HCP→FCC during compression, the uniaxial compression process of AZ31 magnesium alloy was simulated by the molecular dynamics method, and the changes of crystal structure and dislocation evolution were observed. The effects of temperature on mechanical properties, crystal structure, and dislocation evolution of magnesium alloy during compression were analyzed. It is concluded that some of the Shockley partial dislocation is related to FCC stacking faults. With the help of TEM characterization, the correctness of the correlation between some of the dislocations and FCC stacking faults is verified. Through the combination of simulation and experiment, this paper provides an idea for the in-depth study of the solid-phase transformation of magnesium alloys and provides reference and guidance for the design of magnesium alloys with good plasticity and formability at room temperature.
The distribution of inclusions at the bottom of a Ce-treated heavy steel ingot was detected and *** three-dimensional morphology and spatial distribution of CeAlOs clusters were characterized using the electrolytic ex...
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The distribution of inclusions at the bottom of a Ce-treated heavy steel ingot was detected and *** three-dimensional morphology and spatial distribution of CeAlOs clusters were characterized using the electrolytic extraction and Micro-CT detection.A model of inclusion collision to predict the aggregation of CeAlO_(3) inclusions in the ingot was established and validated by measured *** were mainly CeAlO_(3) and a small amount of Ce_(2)O_(2)S in the tundish after cerium *** collision and aggregation of inclusions led to the formation of large clusters in the ingot during the solidification *** slag entrainment inclusions,large CeAO_(3) clusters and small CeAlO_(3) particles were observed from the center to the edge of the ingot *** inclusions were mainly concentrated at the *** number density of inclusions larger than 200μm was 0.21 mm^(-3).The maximum diameter of CeA1O_(3) clusters was 1340μ*** the edge to the radial center and from the bottom to the top,the average diameter of inclusions gradually increased due to the longer solidification time of the ingot.
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