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CLEO: Applications and Technology in CLEO 2024, CLEO: A and T 2024 - Part of Conference on Lasers and Electro-Optics

作者： Nobile, Nicholas A. Lian, Chuanyu Sun, Hongyi Huang, Yi-Siou Mills, Brian Popescu, Cosmin Constantin Callahan, Dennis Hu, Juejun Ríos Ocampo, Carlos A. Youngblood, Nathan Electrical & Computer Engineering Department University of Pittsburgh PittsburghPA15213 United States Department of Materials Science & Engineering University of Maryland College ParkMD20742 United States Institute for Research in Electronics and Applied Physics University of Maryland College ParkMD20742 United States Department of Materials Science & Engineering Massachusetts Institute of Technology CambridgeMA02139 United States Draper Scholar Program The Charles Stark Draper Laboratory Inc. CambridgeMA02139 United States The Charles Stark Draper Laboratory Inc. CambridgeMA02139 United States

Sb2Se3 is used to switch between broadband transparency and enhanced index contrast in two device types leveraging Bragg gratings for tunable stop- and pass-band functionalities. Experimental results highlight fabrication challenges and efficacy of the designs. © Optica Publishing Group 2024, © 2024 The Author(s)

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Reliability of Deployed Organic Photovoltaic Modules 52

Reliability of Deployed Organic Photovoltaic Modules

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52nd IEEE Photovoltaic Specialist Conference, PVSC 2024

作者： Sheriff, Hafiz K. M. Li, Yongxi Saad, Sammy Forrest, Stephen R. Applied Physics Program University of Michigan Ann ArborMI48109 United States Department of Electrical Engineering University of Michigan Ann ArborMI48109 United States Department of Physics University of Michigan Ann ArborMI48109 United States Department of Materials Science and Engineering University of Michigan Ann ArborMI48109 United States

ISBN: (纸本)9781665464260

The commercial future of organic photovoltaics (OPVs) relies on their efficiency and reliability. Recent progress in the field has ensured the achievement of device efficiency comparable to those of commercial silicon-based photovoltaics (Si-PVs) [1]. In pursuit of reliable devices, recent works have demonstrated the intrinsic stability of both small-molecule, vacuum deposited [2] and non-fullerene acceptor (NFA) - polymer-based devices [3] under controlled laboratory conditions. The final step for outdoor deployment is therefore a demonstration of the reliability of large area OPV modules in the field, subjected to fluctuating environmental conditions such as humidity, temperature, rainfall, snow, and solar intensity. In this work, we develop a customized test facility intended for the study of the reliability of large area OPV modules deployed in outdoor environments. The facility is designed for automated in-situ measurements calibrated to 1 sun solar intensity, AM 1.5 G illumination. Initial data show the modules retain more than 95% of their initial performance for 150 h when exposed to varying solar intensities, temperature fluctuations of -2°C to 10°C, and relative humidity as high as 90%. The only significant extrinsic challenge to device stability observed was the ingress of water into the package. This is mitigated by improved packaging which utilizes polyisobutylene (PIB) encapsulation and a customized insulated glass unit (IGU). © 2024 IEEE.

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Development of educational software for stainless steel selection and evaluating usability using the System Usability Scale (SUS)

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International Journal of Mechanical engineering Education 2024年

作者： Nery, Macclarck Pessoa dos Santos Neto, Severiano José Alves, Roberty Santos Santana, João Vitor dos Santos Griza, Sandro Martins, Carlos Otávio Damas Materials Science and Engineering Pos-graduation Program – p2cem from Federal University of Sergipe São Cristovão City Brazil Mechanical Engineering Department Federal University of Sergipe São Cristovão City Brazil Department of Materials Science and Engineering Federal University of Sergipe São Cristovão City Brazil

The use of educational technologies is an important part of the learning process. The development of educational apps and software is one of the pillars of this evolution in teaching. Material selection is one of the most important subjects in professional engineering education. Regarding materials used to manufacture products, the stainless steels are the most commonly used materials after traditional steels. In the industrial environment, fatigue, corrosion-fatigue, and stress corrosion cracking are three very important considerations in the selection of materials. This study evaluates the usability of educational software developed in Java using object-oriented programming using the System Usability Scale and compares it with results obtained from other educational technologies. © The Author(s) 2024.

关键词： Software testing

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Transparent Porphyrin-Based Hybrid Films for Spectral Selective Solar Harvesting and Energy Generation

SSRN

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SSRN 2022年

作者： Shi, Donglu Lin, Jou Wang, Yuxin Lyu, Mengyao Deng, Zicheng The Materials Science and Engineering Program Department of Mechanical Materials Engineering College of Engineering and Applied Science University of Cincinnati CincinnatiOH45221 United States

Spectral-selectively solar harvest is achieved in designated frequency regions for photothermal energy generation. In this study, we have designed and synthesized porphyrin-based hybrids that typically exhibit two absorption peaks respectively near 400 nm (blue-violet) and 700 nm (NIR). To be able to tune the optical absorptions for more efficient solar harvest especially in the IR region, unique porphyrin hybrids are developed by incorporating another porphyrin compound such as phthalocyanine, and inorganic Fe 3 O 4 @Cu 2-x S nanoparticles with different absorption characteristics. By controlling the ratio of the components, the hybrids exhibit gradual and consistent changes in the optical spectra, showing high spectral tunability. Transparent thin films of the hybrids are deposited on glass substrates and constructed in parallel for 3D solar harvesting in a cuboid photothermal generator. Solar light is able to pass through the multilayers of thin films, generating significant thermal heat on each one for enhanced energy density. The structural features of the hybrids are well correlated to the optical behaviors based on Raman studies. Also discussed is the operating mechanisms underlying the photothermal behaviors associated with the hybrid structures. © 2022, The Authors. All rights reserved.

关键词： Multilayers

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Novel Enclosed Delamination Injection Repair Process for Strength Restoration 37

Novel Enclosed Delamination Injection Repair Process for Str...

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37th Technical Conference of the American Society for Composites, ASC 2022

作者： Massey, Justin Romasko, Barrett Kim, Hyonny Materials Science and Engineering Program University of California La Jolla San DiegoCA92093 United States Department of Structural Engineering University of California La Jolla San DiegoCA92093 United States

ISBN: (纸本)9781605956909

Delaminations are a common damage mechanism that occurs on composite structures due to in-service impacts. Enclosed damages less than 50 mm in diameter are of particular interest for repair. Current practices for repair of delaminations include: cut out of the damage and applying a patch or doubler to the cutout site, or injection using a repair resin. The use of a bonded doubler repair is more invasive and requires a cutout that acts as a stress concentration in the area of the repair. Injection repairs have traditionally been a faster, less expensive way to repair composite delaminations. However, the aerospace industry has not accepted injection repair as a strength restorative process. Questions about quantifying delamination internal contamination and ensuring percentage of repair resin fill within a delamination have been primary reasons why injection repairs have not been credited with strength restoration. Development of a new quantitative internal surface cleaning, preparation and repair process for delaminated composite materials is required to provide justification for strength restoration using injection repair. Fabricating representative local delaminations was performed with a modified end-notch flexure (ENF) test. A unidirectional 24-ply panel was fabricated to simulate damage to laminates. Intentional contamination was introduced into the induced delamination of each panel type. Contamination removal and surface preparation using solvent and atmospheric plasma cleaning were completed on the modified ENF coupon and verified utilizing in-line monitoring with Quantitative Gas Analysis (QGA) and post processing inspection with Fourier Transform Infrared Spectroscopy (FTIR). A modified low-viscosity injection resin was developed and utilized to repair the post-tested ENF coupons. The modified epoxy exhibited comparable shear strength characteristics to un-modified neat resin while achieving a >97% reduction in viscosity. Each ENF panel type was assessed f

关键词： Resins

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Resolving Contradictory Estimates of Band Gaps of Bulk PdSe2: A Wannier-Localized Optimally-Tuned Screened Range-Separated Hybrid Density Functional Theory Study

arXiv

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arXiv 2025年

作者： Florio, Fred Camarasa-Gómez, María Ohad, Guy Naveh, Doron Kronik, Leeor Ramasubramaniam, Ashwin Department of Mechanical and Industrial Engineering University of Massachusetts Amherst AmherstMA01003 United States Department of Molecular Chemistry and Materials Science Weizmann Institute of Science Rehovoth7610001 Israel Institute for Nanotechnology and Advanced Materials Bar-Ilan University Ramat Gan52900 Israel Materials Science and Engineering Graduate Program University of Massachusetts Amherst AmherstMA01003 United States

Palladium diselenide (PdSe2)—a layered van der Waals material—is attracting significant attention for optoelectronics due to the wide tunability of its band gap from the infrared through the visible range as a function of the number of layers. However, there continues to be disagreement over the precise nature and value of the optical band gap of bulk PdSe2, owing to the rather small value of this gap that complicates experimental measurements and their interpretation. Here, we design and employ a Wannier-localized optimally-tuned screened range-separated hybrid (WOT-SRSH) functional to investigate the electronic bandstructures and optical absorption spectra of bulk and monolayer PdSe2. In particular, we account carefully for the finite exciton center-of-mass momentum within a time-dependent WOT-SRSH framework to calculate the indirect optical gap and absorption onset accurately. Our results agree well with the best available photoconductivity measurements, as well as with state-of-the-art many-body perturbation theory calculations, confirming that bulk PdSe2 has an optical gap in the mid-infrared (upper-bound of 0.44 eV). More generally, this work further bolsters the utility of the WOT-SRSH approach for predictive modeling of layered semiconductors. Copyright © 2025, The Authors. All rights reserved.

关键词： Layered semiconductors

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Development of High Temperature Lead-free Solders in the Al-95Zn + xSn Systems

Development of High Temperature Lead-free Solders in the Al-...

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International Conference on Electronics Packaging (ICEP)

作者： Andromeda Dwi Laksono Yee-Wen Yen Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei Taiwan R.O.C Study Program of Materials and Metallurgical Engineering Institut Teknologi Kalimantan Balikpapan East Kalimantan Indonesia

The high-temperature lead-free solder alloys of Al-95Zn with the modification of the addition of Sn have been investigated. Its proportion is used to adjust the metallographic microstructure, solidified precipitate phase, and liquidus temperature of the solder alloy. The characterization results, such as scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD), and differential scanning calorimeter (DSC), will be discussed in this study. The study results show that the Al-Sn-Zn-based alloy has (Zn)+β- Sn+(Al) precipitates when heat-treated at 900°C for 36 h. Its liquidus temperature of Al-95Zn + xSn is between 342-385°C, and increased Sn content will decrease its liquidus temperature.

关键词： Heating systems Scanning electron microscopy X-ray scattering Lead X-ray diffraction Microstructure Dispersion

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Low-Voltage Graphene Interface-Engineered Organic Ferroelectric Tunnel Junction Devices

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ACS Applied materials and Interfaces 2025年第22期17卷 32773-32781页

作者： Natani, Shreyam Khajanji, Pranjali Cheng, Li Eshraghi, Kassra Zhang, Zichen Shipley, Wade Tao, Andrea R. Bandaru, Prabhakar R. Department of Mechanical Engineering University of California La Jolla San DiegoCA92093 United States Program in Materials Science University of California La Jolla San DiegoCA92093 United States

It has been indicated that the path forward for the widespread usage of ferroelectric (FE) materials may be considerably facilitated through the reduction of programming voltages to on-chip logic-compatible values of ... 详细信息

关键词： Ferroelectric materials

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Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle Life of Zinc Ion Capacitors

Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle...

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International Flexible Electronics Technology Conference (IFETC)

作者： Jinwook Jung Chanho Shin Tse Nga Ng Program in Materials Science and Engineering University of California San Diego La Jolla USA Department of Electrical and Computer Engineering University of California San Diego La Jolla USA

ISBN: (数字)9798331529468

ISBN: (纸本)9798331529475

We investigated the effect of copper ion concentration in zinc-copper dual-ion electrolytes to suppress dendrites and extend the cycle life of zinc ion capacitors. The devices were characterized in terms of changes in microstructure and cycling stability. The nuclei size was decreased in the optimal copper ion concentration to promote lateral deposition and avoid vertical dendrites. The device exhibited stable cycling performance with a capacitance retention of 95% after 10,000 redox cycles, compared to the device with single zinc ion electrolyte which short circuited at around 1,250 redox cycles.

关键词： Performance evaluation Capacitors Redox Ions Electrolytes Dendrites (neurons) Copper Microstructure Zinc Tuning

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Molecular simulation-guided and physics-informed mechanistic modeling of multifunctional polymers

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Acta Mechanica Sinica 2021年第5期37卷 725-745,I0002页

作者： Guang Chen Weikang Xian Qiming Wang Ying Li Department of Mechanical Engineering University of ConnecticutStorrsCT 06269USA Sonny Astani Department of Civil and Environmental Engineering University of Southern CaliforniaLos AngelesCA 90089USA Department of Mechanical Engineering and Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsCT 06269USA

Polymeric materials have a broad range of mechanical and physical *** have been widely used in material science,biomedical engineering,chemical engineering,and mechanical *** introduction of active elements into the soft matrix of polymers has enabled much more diversified functionalities of polymeric materials,such as self-healing,electroactive,magnetosensitive,pH-responsive,and many *** further enable applications of these multifunctional polymers,a mechanistic modeling method is required and of great significance,as it can provide links between materials’micro/nano-structures and their macroscopic mechanical *** this goal,molecular simulation plays an important role in understanding the deformation and evolution of polymer networks under external loads and *** molecular insights provide physical guidance in the formulation of mechanistic-based continuum models for multifunctional *** this perspective,we present a molecular simulation-guided and physics-informed modeling framework for polymeric ***,the physical theory for polymer chains and their networks is briefly *** serves as the foundation for mechanistic-models of polymers,linking their chemistry,physics,and mechanics ***,the deformation of the polymer network is used to derive the strain energy density ***,the corresponding continuum models can capture the intrinsic deformation mechanisms of polymer *** then highlight several representative examples across multiphysics coupling problems to describe in detail for this proposed *** but not least,we discuss potential challenges and opportunities in the modeling of multifunctional polymers for future research directions.

关键词： Molecular simulation Multiphysics modeling Multiscale modeling Multifunctional polymers Soft Matter

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