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Flexible nanohybrid substrates utilizing gold nanocubes/nano mica platelets with 3D lightning-rod effect for highly efficient bacterial biosensors based on surface-enhanced Raman scattering

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Journal of materials Chemistry B 2024年第13期12卷 3226-3239页

作者： Chen, Yan-Feng Lu, Ming-Chang Lee, Chia-Jung Chiu, Chih-Wei Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei10607 Taiwan Ph.D. Program in Clinical Drug Development of Herbal Medicine College of Pharmacy Taipei Medical University Taipei11031 Taiwan

In this study, gold nanocubes (AuNCs) were quickly synthesized using the seed-mediated growth method and reduced onto the surface of two-dimensional (2D) delaminated nano mica platelets (NMPs), enabling the development of AuNCs/NMPs nanohybrids with a 3D lightning-rod effect. First, the growth-solution amount can be changed to easily adjust the AuNCs average-particle size within a range of 30-70 nm. The use of the cationic surfactant cetyltrimethylammonium chloride as a protective agent allowed the surface of AuNCs and nanohybrids to be positively charged. Positively charged nanohybrid surfaces presented a good adsorption effect for detecting molecules with negative charges on the surface. Additionally, the NMP surfaces were rich in ionic charges and provided a large specific surface area for stabilizing the growth of AuNCs. Delaminated AuNCs/NMPs nanohybrids can generate a 3D hotspot effect through self-assembly to enhance the Raman signal. Surface-enhanced Raman scattering (SERS) is highly sensitive in detecting adenine biomolecules. Its limit of detection (LOD) and Raman enhancement factor reached 10−9 M and 3.6 × 108, respectively. Excellent reproducibility was obtained owing to the relatively regular arrangement of AuNC particles, and the relative standard deviation (RSD) was 10.7%. Finally, the surface of NMPs was modified by adding the hydrophilic poly(oxyethylene)-diamine (POE2000) and amphiphilic PIB-POE-PIB copolymer at different weight ratios. The adjustment of the surface hydrophilicity and hydrophobicity of AuNCs/NMPs nanohybrids led to better adsorption and selectivity for bacteria. AuNCs/POE/NMPs and AuNCs/PIB-POE-PIB/NMPs were further applied to the SERS detection of hydrophilic Staphylococcus aureus and hydrophobic Escherichia coli, respectively. The SERS-detection results suggest that the LOD of hydrophilic Staphylococcus aureus and hydrophobic Escherichia coli reached 92 CFU mL−1 and 1.6 × 102 CFU mL−1, respectively. The AuNCs/POE/NMPs and AuNCs/P

关键词： Substrates

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Dual modifications of sensitizers and lanthanide ions on a two-dimensional zirconium-based metal-organic framework for photoluminescent detection

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CrystEngComm 2024年第22期26卷 2852-2861页

作者： Chang, Jhe-Wei Lin, Tzu-Chi Chen, You-Liang Han, Po-Chun Yang, Shang-Cheng Tsai, Meng-Dian Wu, Kevin C.-W. Kung, Chung-Wei Department of Chemical Engineering National Cheng Kung University Tainan City70101 Taiwan Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Ph. D. Program of Green Materials and Precision Devices College of Engineering National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Chung-Li Taoyuan320 Taiwan

A two-dimensional (2D) zirconium-based metal-organic framework (Zr-MOF) with abundant terminal -OH/-OH2 groups on its nodes, ZrBTB (BTB = 1,3,5-tris(4-carboxyphenyl)benzene), is utilized as a platform for dual post-synthetic modifications (PSM) to immobilize both the benzophenone-based photosensitizer (benzophenone-4,4′-dicarboxylate, bzpdc) and terbium ions onto the 2D Zr-MOF molecular sheets. Terbium ions are installed on the 2D Zr-MOF at various temperatures to adjust the loading of terbium ions on the 2D Zr-MOF while preserving the loading of the photosensitizer. The crystallinity, morphology, porosity, and loadings of both bzpdc ligands and terbium ions are characterized for each material, and the coordinating locations of terbium ions in the Zr-MOF structure are investigated. The photoluminescence (PL) properties of these materials are then examined. Since the installed bzpdc ligand can induce a highly efficient energy transfer to the neighbouring terbium ion upon excitation, the obtained material after dual PSM (ZrBTB-bzpdc-Tb-120) can show strong PL emissions of terbium ions upon the excitation of the bzpdc ligand at 355 nm, with a PL quantum yield of 5.04%. It is more advantageous than the 2D Zr-MOF solely functionalized with terbium ions, which can only exhibit similar emissions upon the excitation of the BTB linker at a less friendly wavelength of 310 nm, with a lower PL quantum yield of 2.94%. Owing to the high chemical stability as well as good dispersity of the luminescent ZrBTB-bzpdc-Tb-120 in water, its performances in selective PL sensing of Fe(iii) ions present in aqueous solutions are investigated. © 2024 The Royal Society of Chemistry.

关键词： Carboxylation

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Liquid crystal-templated chiral nanomaterials: from chiral plasmonics to circularly polarized luminescence

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Light(science & Applications) 2022年第8期11卷 1753-1781页

作者： Xuan Zhang Yiyi Xu Cristian Valenzuela Xinfang Zhang Ling Wang Wei Feng Quan Li School of Materials Science and Engineering Tianjin University300350TianjinChina Institute of Advanced Materials and School of Chemistry and Chemical Engineering Southeast University211189NanjingChina Advanced Materials and Liquid Crystal Institute and Chemical Physics Interdisciplinary Program Kent State UniversityKentOH44242USA

Chiral nanomaterials with intrinsic chirality or spatial asymmetry at the nanoscale are currently in the limelight of both fundamental research and diverse important technological applications due to their unprecedented physicochemical characteristics such as intense light-matter interactions, enhanced circular dichroism, and strong circularly polarized luminescence. Herein, we provide a comprehensive overview of the state-of-the-art advances in liquid crystal-templated chiral nanomaterials. The chiroptical properties of chiral nanomaterials are touched, and their fundamental design principles and bottom-up synthesis strategies are discussed. Different chiral functional nanomaterials based on liquid-crystalline soft templates, including chiral plasmonic nanomaterials and chiral luminescent nanomaterials, are systematically introduced, and their underlying mechanisms, properties, and potential applications are emphasized. This review concludes with a perspective on the emerging applications, challenges, and future opportunities of such fascinating chiral nanomaterials. This review can not only deepen our understanding of the fundamentals of soft-matter chirality, but also shine light on the development of advanced chiral functional nanomaterials toward their versatile applications in optics, biology, catalysis, electronics, and beyond.

关键词： chiral circular polarized

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Effect of Surface Roughness on the Magnetism, Nano-indentation, Surface Energy, and Electrical Properties of Co60Fe20Dy20 Films on Si (100) Substrate

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Journal of Electronic materials 2024年第4期53卷 1752-1762页

作者： Liu, Wen-Jen Chang, Yung-Huang Chiang, Chia-Chin Chen, Yuan-Tsung Lin, Chih-Chien Chen, Pei-Ling Lin, Shih-Hung Department of Materials Science and Engineering I-Shou University Kaohsiung840 Taiwan Bachelor Program in Industrial Technology National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Department of Mechanical Engineering National Kaohsiung University of Science and Technology Kaohsiung City80778 Taiwan Graduate School of Materials Science National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Department of Electronic Engineering National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan

In this study, we focused on depositing a target material, cobalt-iron-dysprosium (Co60Fe20Dy20), onto silicon (Si) (100) substrates with thickness varying from 10 nm to 50 nm through a direct-current (DC) magnetron sputtering technique. The subsequent step involved subjecting the samples to an hour-long annealing process in a vacuum annealing furnace at temperatures of 100°C, 200°C, and 300°C. To assess the elemental composition of the CoFeDy films, energy-dispersive X-ray spectroscopy (EDS) was employed. An observed trend indicated an increase in low-frequency alternating-current magnetic susceptibility (χac) with the increasing thickness. Remarkably, the CoFeDy films exhibited their peak χac following annealing at 300°C, with an optimal resonance frequency of 50 Hz. After annealing at 300°C, the CoFeDy film’s surface energy peaked at 50 nm. The magnetic, electrical, and adhesive properties of the CoFeDy films were notably influenced by surface roughness at different annealing temperatures. Atomic force microscopy (AFM) analysis revealed a gradual reduction in film roughness post-annealing, corresponding to smoother surfaces indicative of a weaker domain wall pinning effect, heightened carrier conductivity, and increased liquid spreading. Collectively, these outcomes contributed to diminished χac, reduced electrical resistance, and enhanced adhesion. Graphical Abstract: (Figure presented.) © The Minerals, Metals & materials Society 2024.

关键词： Adhesion

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Crafting chirality in three dimensions via a novel fabrication technique for bound states in the continuum metasurfaces

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Light(science & Applications) 2024年第3期13卷 390-392页

作者： Zaid Haddadin Anna My Nguyen Lisa V.Poulikakos Department of Electrical&Computer Engineering University of California San DiegoLa JollaCAUSA Department of Mechanical&Aerospace Engineering University of California San DiegoLa JollaCAUSA Program of Materials Science&Engineering University of California San DiegoLa JollaCAUSA

An additional deposition step was added to a multi-step electron beam lithographic fabrication process to unlock the height dimension as an accessible parameter for resonators comprising unit cells of quasi-bound stat... 详细信息

关键词： dimensions dimension intrinsic

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Recycling of Magnesium Alloy Using the Gravity-Driven Multiple-Effect Thermal System (G-METS)

Recycling of Magnesium Alloy Using the Gravity-Driven Multip...

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Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2024

作者： Mc Arthur Sehar, Daniel Telgerafchi, Armaghan Ehsani Iurkovskyi, Artem Opoku, Emmanuel Powell, Adam Materials Science and Engineering Program Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States

ISBN: (纸本)9783031502392

MagnesiumMagnesium metal has been significantly used in commercial applications from automobiles to aluminum alloys to defense weaponry. The surge in structural usage of magnesium over the past years has been due to high strength and excellent stiffness-to-weight ratio. RecyclingRecycling magnesium scrap is a crucial aspect of the sustainability of the economy and environmental welfare. G-METS is an advanced distillationDistillation system used in the conversion of low-grade magnesium scrap into high-purityHigh-purity magnesium metal. This multiple-effect system uses the weight of magnesiumMagnesium as a compressor, to build pressure differences between each effect of the condenser-evaporator, modifying boiling points, and enabling transfer of vaporization enthalpy. This system is exceptionally efficient compared to the energy-intensive conventional distillationDistillation technique. This study compares experiments and models of one- and two-effect distillers. © The Minerals, Metals & materials Society 2024.

关键词： Magnesium alloys

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Migration and proliferation drive the emergence of patterns in co-cultures of differentiating vascular progenitor cells

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Mathematical Biosciences and engineering 2024年第8期21卷 6731-6757页

作者： Zamora Alvarado, Jose E. McCloskey, Kara E. Gopinathan, Ajay School of Engineering University of California Merced MercedCA95343 United States Graduate Program in Materials and Biomaterials Science and Engineering University of California Merced MercedCA95343 United States Department of Physics University of California Merced MercedCA95343 United States

Vascular cells self-organize into unique structures guided by cell proliferation, migration, and/or differentiation from neighboring cells, mechanical factors, and/or soluble signals. However, the relative contribution of each of these factors remains unclear. Our objective was to develop a computational model to explore the different factors affecting the emerging micropatterns in 2D. This was accomplished by developing a stochastic on-lattice population-based model starting with vascular progenitor cells with the potential to proliferate, migrate, and/or differentiate into either endothelial cells or smooth muscle cells. The simulation results yielded patterns that were qualitatively and quantitatively consistent with experimental observations. Our results suggested that post-differentiation cell migration and proliferation when balanced could generate between 30–70% of each cell type enabling the formation of vascular patterns. Moreover, the cell-to-cell sensing could enhance the robustness of this patterning. These findings computationally supported that 2D patterning is mechanistically similar to current microfluidic platforms that take advantage of the migration-directed self-assembly of mature endothelial and mural cells to generate perfusable 3D vasculature in permissible hydrogel environments and suggest that stem or progenitor cells may not be fully necessary components in many tissue formations like those formed by vasculogenesis. ©2024 the Author(s)

关键词： Endothelial cells

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Unconventional assemblies of bisacylhydrazones:The role of water for circularly polarized luminescence

Aggregate

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Aggregate 2022年第5期3卷 185-193页

作者： Hye Jin Cho Dong Yeun Jeong Hwihyun Moon Taewoo Kim You Kyoung Chung Yeongdong Lee Zonghoon Lee Joonsuk Huh Youngmin You Changsik Song Department of Chemistry Sungkyunkwan UniversitySuwonGyeonggi 16419Republic of Korea Division of Chemical Engineering and Materials Science Graduate Program in System Health Science and EngineeringEwha Womans UniversitySeoul 03760Republic of Korea Center for Multidimensional Carbon Materials Institute for Basic Science(IBS)Department of Materials Science and EngineeringUlsan National Institute of Science and Technology(UNIST)Ulsan 44919Republic of Korea

Understanding the precise molecular arrangement of chiral supramolecular polymers is essential not only to comprehend complex superstructures like proteins and DNA but also for the development of next-generation optoelectronic materials,including materials displaying high-performance circularly polarized luminescence(CPL).Herein,we report the first chiral supramolecular polymer systems based on hydrazone–pyridinium conjugates comprising alkyl chains of different lengths,which afforded control of the apparent supramolecular *** supramolecular chirality is governed basically by the remote chiral centers of alkyl chains,helicity inversion was achieved by controlling the conditions under which the hydrazone building blocks underwent aggregation(i.e.,solvent compositions or temperature).More importantly,the addition of water to the system led to aggregationinduced hydrazone deprotonation,which resulted in a completely different selfassembly *** water molecules played an essential role,forming the assembly’s channel-like backbone,around which hydrazone molecules gathered as a result of hydrogen bonding *** co-assembly of an achiral hydrazone luminophore with the given supramolecular polymer system allowed the fabrication of a novel CPL-active hydrazone-based material exhibiting a high maximum value for the photoluminescence dissymmetry factor of -2.6×10^(-2).

关键词： circularly polarized luminescence(CPL) helicity control hydrazone self-assembly structural water supramolecular polymerization

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Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production

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Chinese Journal of Chemical engineering 2024年第3期67卷 247-256页

作者： Porapak Suriya Shanshan Xu Shengzhe Ding Sarayute Chansai Yilai Jiao Joseph Hurd Daniel Lee Yuxin Zhang Christopher Hardacre Prasert Reubroycharoen Xiaolei Fan Department of Chemical Engineering School of EngineeringThe University of ManchesterManchester M139PLUnited Kingdom Program of Petrochemistry and Polymer Science Faculty of ScienceChulalongkorn UniversityBangkok10330Thailand Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Liaoning Academy of Materials Shenyang 110167China Center of Excellence in Catalysis for Bioenergy and Renewable Chemicals(CBRC) andDepartment of Chemical TechnologyFaculty of ScienceChulalongkorn UniversityBangkok 10330Thailand Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute University of Nottingham Ningbo ChinaNingbo315100China

Compared to reforming reactions using hydrocarbons,ethanol steam reforming(ESR)is a sustainable alternative for hydrogen(H_(2))production since ethanol can be produced sustainably using *** work explores the catalyst design strategies for preparing the Ni supported on ZSM-5 zeolite catalysts to promote ***,two-dimensional ZSM-5 nanosheet and conventional ZSM-5 crystal were used as the catalyst carriers and two synthesis strategies,i.e.,in situ encapsulation and wet impregnation method,were employed to prepare the *** on the comparative characterization of the catalysts and comparative catalytic assessments,it was found that the combination of the in situ encapsulation synthesis and the ZSM-5 nanosheet carrier was the effective strategy to develop catalysts for promoting H_(2) production via ESR due to the improved mass transfer(through the 2-D structure of ZSM-5 nanosheet)and formation of confined small Ni nanoparticles(resulted via the in situ encapsulation synthesis).In addition,the resulting ZSM-5 nanosheet supported Ni catalyst also showed high Ni dispersion and high accessibility to Ni sites by the reactants,being able to improve the activity and stability of catalysts and suppress metal sintering and coking during ESR at high reaction ***,the Ni supported on ZSM-5 nanosheet catalyst prepared by encapsulation showed the stable performance with~88% ethanol conversion and~65% H_(2) yield achieved during a 48-h longevity test at 550-C.

关键词： ZSM-5 nanosheet In situ encapsulation Ni catalyst Ethanol steam reforming Hydrogen production

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Chiral phonon-induced magnetization in cerium fluorides

Chiral phonon-induced magnetization in cerium fluorides

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CLEO: Fundamental science, CLEO:FS 2024 - Part of Conference on Lasers and Electro-Optics, CLEO 2024

作者： Luo, Jiaming Lin, Tong Zhang, Junjie Chen, Xiaotong Blackert, Elizabeth R. Xu, Rui Yakobson, Boris I. Zhu, Hanyu Department of Materials Science and Nano Engineering Rice University Houston United States Applied Physics Graduate Program Rice University Houston United States

We report that circularly polarized terahertz light pulses can drive chiral phonons, which then induce an effective quasi-static magnetic field on the order of 1 tesla to polarize the paramagnetic cerium fluoride. ... 详细信息

ISBN: (纸本)9781957171395

关键词： Phonons

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