Xenotime rare-earth(RE)phosphates are emerging as promising materials for environmental barrier coatings(EBCs)for SiC-based ceramic-matrix composites(CMCs)because of their close coefficients of thermal expansion(CTEs)...
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Xenotime rare-earth(RE)phosphates are emerging as promising materials for environmental barrier coatings(EBCs)for SiC-based ceramic-matrix composites(CMCs)because of their close coefficients of thermal expansion(CTEs)and resistance to calcium-magnesium-alumina-silicate(CMAS)*** this work,high-entropy(HE)(Sc_(0.2)Lu_(0.2)Yb_(0.2)Er_(0.2)Y_(0.2))PO_(4) and five single-component REPO4(RE=Sc,Lu,Yb,Er,and Y)compounds were synthesized,and their stability,thermal properties,and CMAS corrosion resistance were *** CTE values of four REPO_(4) compounds(RE=Lu,Yb,Er,and Y;~(5.6-6)×10^(−6)℃^(−1))are close to those of SiC-CMC((4.5-5.5)×10^(−6)℃^(−1)),whereas ScPO_(4)(6.98×10^(−6)℃^(−1))and HE(5RE_(0.2))PO_(4)(6.39×10^(−6)℃^(−1))have slightly higher values in the temperature range of 200-1300℃.HE phosphate has the lowest thermal conductivity due to its size and mass *** CMAS corrosion tests at 1300℃ for 5,45,and 96 h revealed that all RE phosphates formed a continuous and dense reaction layer predominantly composed of Ca_(8)MgRE(PO_(4))_(7),effectively impeding CMAS ***,REPO_(4) with smaller RE³−cations displays a slower reaction rate and reduced corrosion kinetics,as evidenced by the smaller thickness of the reaction layer.A larger negative difference in the optical basicity(OB)value between REPO_(4) and CMAS signifies greater corrosion resistance.A mechanistic understanding of CMAS corrosion and elucidation of the effects of critical parameters such as the ionic mass and ionic radius of RE elements on their thermal properties and CMAS corrosion kinetics are useful for the development of novel xenotime-type phosphates as EBCs for SiC-CMCs.
Emerging machine learning(ML)approaches have been adopted in various material systems to predict novel properties with the assistance of the corresponding large *** new materials,however,collecting sufficient data poi...
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Emerging machine learning(ML)approaches have been adopted in various material systems to predict novel properties with the assistance of the corresponding large *** new materials,however,collecting sufficient data points for model training is not feasible,which is the case for gold nanoparticle/polymer hybrid *** this study,an ML approach coupled with finite element modeling was proposed for predicting the optical and photothermal properties of gold nanoparticle/polymer hybrid *** datasets of the optical and photothermal properties were built using results from the ***,finite element analyses were conducted to generate synthetic data to satisfy the quality and quantity of the data required for training *** analysis and model training were performed using the datasets with and without synthetic data to evaluate their effects on predicting the performance of the ML *** relative importance of features to targets(properties)was evaluated by correlation *** models with high accuracy were obtained by training various models from conventional to newly developed ***,weaknesses,and improvement of the synthetic data addition were *** proposed workflow and framework offer reliable prediction of optical and photothermal properties over different combinations of gold nanoparticles and polymer matrices,which can be extended to include more features related to processing parameters and microstructures.
The mechanical and corrosion characteristics of aluminum alloys can be influenced not only by the addition of grain refiners but also by heat treatment that modifies the microstructure and introduces variations in the...
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The simultaneous optimization of the bulk and surface characteristics of photoelectrodes is essential to maximize their photoelectrochemical(PEC)*** report a novel one-pot hydrothermal synthesis of textured and surfac...
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The simultaneous optimization of the bulk and surface characteristics of photoelectrodes is essential to maximize their photoelectrochemical(PEC)*** report a novel one-pot hydrothermal synthesis of textured and surface-reconstructed BiVO_(4)photoanodes(ts-BVO),achieving significant improvements in PEC water *** controlling precursor molarity and ethylene glycol(EG)addition,we developed a stepwise dual reaction(SDR)mechanism,which enables simultaneous bulk texture development and surface *** optimized CoBi/ts-BVO photoanode exhibited a photocurrent density of 4.3 mA∙cm^(−2)at 1.23 V *** hydrogen electrode(RHE)with a high Faradaic efficiency of 98%under one sun *** with nontextured BiVO_(4),the charge transport efficiency increased from 8%to 70%,whereas the surface charge transfer efficiency improved from 9%to 85%.These results underscore the critical role of both bulk and surface engineering in enhancing PEC *** findings offer a streamlined approach for improving the intrinsic properties of photoanodes in solar water splitting.
The Subsea Shuttle Tanker (SST) was presented by the authors as an innovative and cost-effective solution in several research works. This new approach offers a viable alternative to subsea pipelines and shuttle tanker...
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With the increasing use of micro-manufactured devices and the demand for low-cost fabrication techniques, this study presents a simple and scalable surface polishing method for laser etched acrylic using WELD-ON 4 acr...
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The increasing importance of high-purity isopropyl alcohol(IPA) in semiconductor processing technology has led to a higher demand for technologies capable of detecting impurities in I *** accurate and various impurity...
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The increasing importance of high-purity isopropyl alcohol(IPA) in semiconductor processing technology has led to a higher demand for technologies capable of detecting impurities in I *** accurate and various impurity detection technologies have been developed,most of them have limitations in real-time and repeatable detection of ***,for the first time,surface plasmon resonance(SPR) sensor was developed utilizing graphene transferred Au film(Au/graphene) to detect sub-ppm levels of 2,4-dinitrophenol(2,4-DNP) dissolved in IPA and this sensor demonstrates the ability to detect 2,4-DNP in real-time with great reversibility.
In the present work, the microstructure and texture evolution in commercially pure titanium subjected to blast assisted deformation has been investigated by means of electron backscattered diffraction and transmission...
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3D printing (3DP) ranks as one of the more advanced methods in the manufacturing sector. All of the industrial sectors, including automobiles, medical services, aviation, athletics, fabrics, apparel, and fashion indus...
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