In plunging-Type tests, a cutting tool is given a sinusoidal movement as the work material with a web on its surface is rotated at a constant speed. If the amplitude and feed rate of the cutting tool and rotational sp...
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The effect of pre-deformation on nanoscale precipitates and hardness of a maraging stainless steel strengthened by the coprecipitation of Ni_(3)Ti,Mo-enriched and Cr-enriched precipitates was systematically studied us...
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The effect of pre-deformation on nanoscale precipitates and hardness of a maraging stainless steel strengthened by the coprecipitation of Ni_(3)Ti,Mo-enriched and Cr-enriched precipitates was systematically studied using electron back scattered diffraction,transmission electron microscopy and atom probe tomography(APT).Hardness measurements showed that the hardness of specimen with a deformation ratio of 90%peaked at HV 718 aged for 24 h,which is higher than that in the undeformed specimen(HV 603)aged for 72 h at 480℃.APT characterization revealed that pre-deformation could shorten the incubation time of the Mo-enriched and Cr-enriched *** the early-aged stage,pre-deformation increased the stain energy that inhibited the nucleation of Ni_(3)Ti precipitates,but accelerated the rejection of Mo from Ni-Ti ***,the strengthening model indicated that strain hardening(43%)makes a larger contribution to the hardness at the early-aged condition,while precipitation hardening(58%)has most contribution to the hardness at the peak-aged conditition.
Flow diverter devices are small stents used to divert blood flow away from aneurysms in the brain,stagnating flow and inducing intra-aneurysmal thrombosis which in time will prevent aneurysm *** devices are formed fro...
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Flow diverter devices are small stents used to divert blood flow away from aneurysms in the brain,stagnating flow and inducing intra-aneurysmal thrombosis which in time will prevent aneurysm *** devices are formed from thin(~25μm)wires which will remain in place long after the aneurysm has been *** their continued presence could lead to secondary complications,an absorbable flow diverter which dissolves into the body after aneurysm occlusion is *** absorbable metals investigated to date struggle to achieve the necessary combination of strength,elasticity,corrosion rate,fragmentation resistance,radiopacity,and *** work proposes and investigates a new composite wire concept combining absorbable iron alloy(FeMnN)shells with one or more pure molybdenum(Mo)*** wire configurations are produced and drawn to 25–250μm *** testing revealed high and tunable mechanical properties on par with existing flow diverter *** vitro degradation testing of 100μm wire in DMEM to 7 days indicated progressive corrosion and cracking of the FeMnN shell but not of the Mo,confirming the cathodic protection of the Mo by the FeMnN and thus mitigation of premature fragmentation *** vivo implantation and subsequentμCT of the same wires in mouse aortas to 6 months showed meaningful corrosion had begun in the FeMnN shell but not yet in the Mo filament *** total,these results indicate that these composites may offer an ideal combination of properties for absorbable flow diverters.
Abstract: The role of Cu and Y on characteristics of the FeCoNiCrCu HEAs synthesized by mechanical alloying was studied. The XRD results suggest that the addition of Cu promotes the formation of the FCC1 and FCC2 phas...
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As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the hea...
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As the miniaturization of electronic devices and complication of electronic packaging,there are growing demands for thermal interfacial materials with enhanced thermal conductivity and the capability to direct the heat toward heat sink for highly efficient heat ***-based carbon fiber(CF)with ultrahigh axial thermal conductivity and aspect ratios exhibits great potential for developing thermally conductive composites as ***,it is still hard to fabricate composites with aligned carbon fiber in a general approach to fully utilize its excellent axial thermal conductivity in specific ***,three types of CF scaffolds with different oriented structure were developed via magnetic field-assisted Tetris-style stacking and carbonization *** regulating the magnetic field direction and initial stacking density,the self-supporting CF scaffolds with horizontally aligned(HCS),diagonally aligned and vertically aligned(VCS)fibers were *** embedding the polydimethylsiloxane(PDMS),the three composites exhibited unique heat transfer properties,and the HCS/PDMS and VCS/PDMS composites presented a high thermal conductivity of 42.18 and 45.01 W m^(−1)K^(−1)in fiber alignment direction,respectively,which were about 209 and 224 times higher than that of *** excellent thermal conductivity is mainly ascribed that the oriented CF scaffolds construct effective phonon transport pathway in the *** addition,fishbone-shaped CF scaffold was also produced by multiple stacking and carbonization process,and the prepared composites exhibited a controlled heat transfer path,which can allow more versatility in the design of thermal management system.
The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conve...
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The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conventional NiCoCrAlY coating deposited on the same *** AlCoCrFeNiY bond coat exhibits lower oxide growth rates due to its large columnar grains and low Al activity at the oxide scale/bond coat ***,AlCoCrFeNiY has higher resistance to oxide spallation than NiCoCrAlY,which is attributed to the formation of a clean and defect-free metal/oxide *** interdiffusion occurs across the AlCoCrFeNiY/superalloy substrate *** experimental evidence and thermody-namic modelling suggest that Fe accelerates interdiffusion and destabilizes theγ’phase,thereby causing the formation of a thick andγ’-depleted interdiffusion *** addition,the AlCoCrFeNiY bond coat un-dergoes more Al depletion and subsequentβtoγtransformation compared with *** on the findings in this work,a novel AlCoCrFeNiY/NiCoCrAlY double-layer bond coat was designed,tested and validated to achieve optimal balance between oxidation and interdiffusion.
All-solid-state lithium batteries(ASSLBs)are promising for safety and high-energy-density large-scale energy *** this contribution,we propose a Li_(3–4x)Zr_(x)PS_(4)(LZPS)by Zr-dopedβ-Li_(3)PS_(4)(LPS)as a novel sol...
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All-solid-state lithium batteries(ASSLBs)are promising for safety and high-energy-density large-scale energy *** this contribution,we propose a Li_(3–4x)Zr_(x)PS_(4)(LZPS)by Zr-dopedβ-Li_(3)PS_(4)(LPS)as a novel solid electrolyte(SE)for ASSLBs based on experimental and simulation *** structure,electronic property,mechanical property,and ionic transport properties of LZPS(x=0,0.03,0.06,and 0.1)are investigated with first-principles ***,LZPS is prepared by solid states reaction *** combining experimental analysis and first-principles calculations,it is confirmed that a small amount of Zr4+can be successfully doped into the framework ofβ-LPS composites without significantly compromising structural *** the Zr^(4+)concentration is x=0.03,the doped material Li_(2.88)Zr_(0.03)PS_(4)exhibits the highest ionic conductivity(5.1×10^(−4)S·cm^(−1))at 30℃,and the Li-ion migration energy barrier is the *** Li_(2.88)Zr_(0.03)PS_(4)SE has obtained the best mechanical properties,the good ductility,and shear deformation resistance,which can better maintain the structural stability of the *** addition,the Li/Li symmetrical cell is assembled,which shows excellent electrochemical stability of electrolyte against *** constructed all-solid-state batteries(LiCoO_(2)-Li_(6)PS_(5)Cl|Li_(2.88)Zr_(0.03)PS_(4)|Li-In)delivers an initial discharge capacity of 130.4 mAh·g^(−1)at 0.2 C and a capacity retention of 85.1%after 100 cycles at room *** study provides a promising electrolyte for the application of ASSLBs with high ionic conductivity and excellent stability against lithium.
The exfoliation of bulk 2H-molybdenum disulfide(2H-MoS_(2))into few-layer nanosheets with 1T-phase and controlled layers represents a daunting challenge towards the device applications of MoS_(2).Conventional ion inte...
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The exfoliation of bulk 2H-molybdenum disulfide(2H-MoS_(2))into few-layer nanosheets with 1T-phase and controlled layers represents a daunting challenge towards the device applications of MoS_(2).Conventional ion intercalation assisted exfoliation needs the use of hazardous n-butyllithium and/or elaborate control of the intercalation potential to avoid the decomposition of the MoS_(2).This work reports a facile strategy by intercalating Li ions electrochemically with ether-based electrolyte into the van der Waals(vdW)channels of MoS_(2),which successfully avoids the decomposition of MoS_(2)at low *** co-intercalation of Li+and the ether solvent into MoS_(2)makes a first-order phase transformation,forming a superlattice phase,which preserves the layered structure and hence enables the exfoliation of bulk 2H-MoS_(2)into bilayer nanosheets with *** with the pristine 2H-MoS_(2),the bilayer 1T-MoS_(2)nanosheets exhibit better electrocatalytic performance for the hydrogen evolution reaction(HER).This facile method should be easily extended to the exfoliation of various transition metal dichalcogenides(TMDs).
An externally wetted emitter array with longitudinally grooved structures for ionic liquid electrospray thrusters was fabricated to improve ionic liquid transport to the emitter tips. Two grooved emitter shapes with d...
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