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mechanically robust bamboo node and its hierarchically fibrous structural design

National science Review 2023年第2期10卷 199-211页

作者： Si-Ming Chen Si-Chao Zhang Huai-Ling Gao Quan Wang LiChuan Zhou Hao-Yu Zhao Xin-Yu Li Ming Gong Xiao-Feng Pan Chen Cui Ze-Yu Wang YongLiang Zhang HengAn Wu Shu-Hong Yu Department of Chemistry Institute of Biomimetic Materials & Chemistry Anhui Engineering Laboratory of Biomimetic MaterialsDivision of Nanomaterials & Chemistry Hefei National Research Center for Physical Sciences at the Microscale Institute of Energy Hefei Comprehensive National Science Center University of Science and Technology of China CAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern MechanicsEngineering and Materials Science Experiment CenterUniversity of Science and Technology of China Institute of Innovative Materials (I2M) Department of Materials Science and EngineeringDepartment of Chemistry Southern University of Science and Technology

Although short bamboo nodes function in mechanical support and fluid exchange for bamboo survival,their structures are not fully understood compared to unidirectional fibrous ***,we identify the spatial heterostructure of the bamboo node via multiscale imaging strategies and investigate its me chanical properties by multimodal mechanical *** find three kinds of hierarchical fiber reinforcement schemes that originate from the bamboo node,including spatially tightened interlocking,triaxial interconnected scaffolding and isotropic *** reinforcement schemes,built on porous vascular bundles,microfibers and more-refined twist-aligned nanofibers,govern the structural stability of the bamboo via hierarchical *** addition,the spatial liquid transport associated with these multiscale fibers within the bamboo node is experimentally verified,which gives perceptible evidence for life-indispensable multidirectional fluid *** functional integration of mechanical reinforcement and liquid transport reflects the fact that the bamboo node has opted for elaborate structural optimization rather than ingredient *** study will advance our understanding of biological materials and provide insight into the design of fiber-reinforced structures and biomass utilization.

关键词： biological materials bamboo node hierarchical fiber structural reinforcement functional integration

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Accelerated discovery of eutectic compositionally complex alloys by generative machine learning

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npj Computational materials 2024年第1期10卷 1091-1102页

作者： Z.Q.Chen Y.H.Shang X.D.Liu Y.Yang Department of Mechanical Engineering City University of Hong KongHong KongChina City University of Hong Kong(Dongguan) DongguanGuangdongChina College of Mechatronics and Control Engineering Shenzhen UniversityShenzhenChina Department of Materials Science and Engineering City University of Hong KongKowloonChina Department of System Engineering College of EngineeringCity University of Hong KongKowloonChina

Eutectic alloys have garnered significant attention due to their promising mechanical and physical properties,as well as their technological ***,the discovery of eutectic compositionally complex alloys(ECCAs)(*** entropy eutectic alloys)remains a formidable challenge in the vast and intricate compositional space,primarily due to the absence of readily available phase *** address this issue,we have developed an explainable machine learning(ML)framework that integrates conditional variational autoencoder(CVAE)and artificial neutral network(ANN)models,enabling direct generation of *** overcome the prevalent problem of data imbalance encountered in data-driven ECCA design,we have incorporated thermodynamicsderived data descriptors and employed K-means clustering methods for effective data *** our ML framework,we have successfully discovered dual-or even tri-phased ECCAs,spanning from quaternary to senary alloy systems,which have not been previously reported in the *** findings hold great promise and indicate that ourML framework can play a pivotal role in accelerating the discovery of technologically significant ECCAs.

关键词： eutectic alloys alloy

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Rapid Outgassing of Hydrophilic TiO_(2) Electrodes Achieves Long-Term Stability of Anion Exchange Membrane Water Electrolyzers

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Nano-Micro Letters 2025年第8期17卷 219-236页

作者： Shajahan Shaik Jeonghyeon Kim Mrinal Kanti Kabiraz Faraz Aziz Joon Yong Park Bhargavi Rani Anne Mengfan Li Hongwen Huang Ki Min Nam Daeseong Jo Sang-Il Choi Department of Chemistry and Green-Nano Materials Research Center Kyungpook National UniversityDaegu 41566South Korea Department of Mechanical Engineering Kyungpook National UniversityDaegu 41566South Korea Department of Chemistry and Chemistry Institute for Functional Materials Pusan National UniversityBusan 46241South Korea Department of Metallurgical and Materials Engineering National Institute of TechnologyRaipur 492010India College of Materials Science and Engineering Hunan UniversityChangsha 410082HunanPeople’s Republic of China

The state-of-the-art anion-exchange membrane water electrolyzers(AEMWEs)require highly stable electrodes for prolonged *** stability of the electrode is closely linked to the effective evacuation of H_(2) or O_(2) gas generated from electrode surface during the *** this study,we prepared a superhydrophilic electrode by depositing porous nickel–iron nanoparticles on annealed TiO_(2) nanotubes(NiFe/ATNT)for rapid outgassing of such nonpolar *** super-hydrophilic NiFe/ATNT electrode exhibited an overpotential of 235 mV at 10 mA cm^(−2) for oxygen evolution reaction in 1.0 M KOH solution,and was utilized as the anode in the AEMWE to achieve a current density of 1.67 A cm^(−2) at 1.80 *** addition,the AEMWE with NiFe/ATNT electrode,which enables effective outgassing,showed record stability for 1500 h at 0.50 A cm^(−2) under harsh temperature conditions of 80±3℃.

关键词： TiO_(2)nanotubes NiFe Super-hydrophilic electrode Oxygen evolution reaction Anion-exchange membrane water electrolyzer

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Fabrication and Characterization of Willemite Scaffolds Using Corn Stalk as a Novel Bio Template for Bone Tissue engineering Applications

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Journal of Bionic engineering 2023年第1期20卷 16-29页

作者： Zahra Yahay Seyed Mehdi Mirhadi Fariborz Tavangarian Department of Cellular Biotechnology Cell Science Research CenterRoyan Institute for BiotechnologyACECRIsfahan81593-58686Iran Department of Materials Engineering Shahreza BranchIslamic Azad UniversityShahrezaIsfahan86145-311Iran Mechanical Engineering Program School of ScienceEngineering and TechnologyPennsylvania State UniversityHarrisburgMiddletownPA17057USA

In this paper,we used Corn Stalk(CS)as a renewable and economical bio template to fabricate willemite scaffolds with the potential application in skull bone *** was used as a sacrificial template to synthesize the *** scaffolds with the chemical formula of Zn2SiO4 and pore size in the range of 3 to 10µm could be successfully synthesized by soaking CS in the willemite solution for 24 h and sintering at 950°C for 5 *** porosity of the samples was controlled by the soaking time(between 12 and 48 h)in the willemite solution from 5 to 35%,*** properties of these scaffolds showed a good approximation with cranial bone *** addition,cytotoxicity assays(MTT)were performed on Human Bone Marrow Stromal cells(HBMSc)and A172 human glioblastoma cell lines by direct and indirect culture methods to estimate their toxicity for bone and nerve cells,*** Phosphatase(ALP)activity and DAPI/Phalloidin cell staining were also performed to investigate the efficiency of the scaffolds for bone tissue engineering *** results showed that the scaffolds had good biocompatibility with both HBMSC and A172 cells,noticeable improvement on ALP activity,and great apatite formation ability in Simulated Body Fluid(SBF).All the evidence ascertained that willemite scaffolds made by corn stalks could be a useful candidate for bone tissue engineering applications.

关键词： Corn stalk Bio template Bioactive ceramics-Scaffolds Bone tissue engineering

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Investigation on mechanical properties of hybrid polymer composites for automobile applications

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materials Today: Proceedings 2023年 74卷 73-79页

作者： Beer Mohamed, S. Anandhavasan, S. Basheer Ahamed, S. Ajayharish, R. Barathraj, B. Hariprakash, R. Ravichandran, M. Kaviarasu, C. Department of Materials Science Central University of Tamil Nadu Thiruvarur 610005 India Department of Mechanical Engineering Arasu Engineering College Kumbakonam 612501 India Department of Mechanical Engineering K.Ramakrishnan College of Engineering Trichy 621112 India

A novel epoxy-based hybrid polymer composite was developed and the effect of hybridization on the mechanical properties was investigated. Sisal fiber, polypropylene fiber, alumina trihydrate and nano silica are used for hybridization in epoxy resin matrix via hand layup process. Hardness and impact testing were conducted as per the standards ASTM D2240 and ASTM D256 respectively. Both sisal and polypropylene fibers (5 %wt.) without fillers have improved the hardness by 5.8 % and achieved an impact strength of 68 kJ/m2. A small addition of ATH (0.5 % wt.) as filler to inherit the fire retardancy has deteriorated the mechanical properties of hybrid polymers. However, the addition of nano silica (1.5 % wt.) as another filler along with ATH, sisal and polypropylene fibers has improved the mechanical properties, i.e., hardness and impact value of the epoxy resin-based hybrid polymer by 9.4 % and 85.7 % respectively by suppressing the ATH effect in the hybridization. © 2022

关键词： Polypropylenes

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Light-Material Interactions Using Laser and Flash Sources for Energy Conversion and Storage Applications

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Nano-Micro Letters 2024年第12期16卷 468-514页

作者： Jung Hwan Park Srinivas Pattipaka Geon-Tae Hwang Minok Park Yu Mi Woo Young Bin Kim Han Eol Lee Chang Kyu Jeong Tiandong Zhang Yuho Min Kwi-Il Park Keon Jae Lee Jungho Ryu Department of Mechanical Engineering(Department of Aeronautics Mechanical and Electronic Convergence Engineering)Kumoh National Institute of Technology61Daehak-RoGumiGyeongbuk 39177Republic of Korea Department of Materials Science and Engineering Pukyong National University45Yongso-RoNam-GuBusan 48513Republic of Korea Energy Technologies Area Lawrence Berkeley National LaboratoryBerkeleyCA 94720USA Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology(KAIST)291 Daehak-RoYuseong-GuDaejeon 34141Republic of Korea Division of Advanced Materials Engineering Jeonbuk National UniversityJeonju 54896JeonbukRepublic of Korea School of Electrical and Electronic Engineering Harbin University of Science and TechnologyHarbin 150080People’s Republic of China Key Laboratory of Engineering Dielectrics and Its Application Ministry of EducationHarbin University of Science and TechnologyHarbin 150080People’s Republic of China Department of Materials Science and Metallurgical Engineering Kyungpook National University80 Daehak-RoBuk-GuDaegu 41566Republic of Korea School of Materials Science and Engineering Yeungnam UniversityDaehak-RoGyeongsan-Si 38541Gyeongsangbuk-doRepublic of Korea

This review provides a comprehensive overview of the progress in light-material interactions(LMIs),focusing on lasers and flash lights for energy conversion and storage *** discuss intricate LMI parameters such as light sources,interaction time,and fluence to elucidate their importance in material *** addition,this study covers various light-induced photothermal and photochemical processes ranging from melting,crystallization,and ablation to doping and synthesis,which are essential for developing energy materials and ***,we present extensive energy conversion and storage applications demonstrated by LMI technologies,including energy harvesters,sensors,capacitors,and *** the several challenges associated with LMIs,such as complex mechanisms,and high-degrees of freedom,we believe that substantial contributions and potential for the commercialization of future energy systems can be achieved by advancing optical technologies through comprehensive academic research and multidisciplinary collaborations.

关键词： Light Light-material interaction Nanomaterials Energy conversion and storage devices

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Can orientations of directionally solidified dual-phase Al_(2)O_(3)/YAG eutectics be induced by single-phase sapphire seeds?

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Journal of materials science & Technology 2023年第11期142卷 216-224页

作者： Liangting He Xu Wang Jiaze Li Wangshuai Xiang Fuxue Yan Bailing Jiang Qiaodan Hu School of Materials Science and Engineering Xi’an University of Technology5 South Jinhua RoadXi’an 710048China Center for Advanced Structural Materials Department of Mechanical EngineeringCity University of Hong KongHong Kong 999077China School of Materials Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China

Directionally solidified dual-phase Al_(2)O_(3)/Y_(3)Al_(5)O_(12)(YAG)eutectic ceramics(DSECs)typically exhibit strong *** improve their properties,various single-phase sapphire seeds,including r-axis[1-102],m-axis[10-10],c-axis[0001],and a-axis[11-20],were used as seeds to induce the orientation of the Al_(2)O_(3)/YAG *** results showed that Al_(2)O_(3) in the eutectics could be governed by the sapphire *** YAG in each induced eutectic had a specific growth direction endowed by Al_(2)O_(3) in the asinduced eutectics or the sapphire ***,we calculated the planar lattice misfits and interfacial strain energies of four crystallographic orientation relationships based on the constructed lattice *** was elucidated the constraint of the sapphire seed caused YAG to grow following the rule of mini-mizing the interfacial strain *** revealed the reason why Al_(2)O_(3)/YAG DSECs orientation can be successfully *** results may provide a novel method for the design of high-performance eu-tectic ceramic materials.

关键词： Al_(2)O_(3)/Y_(3)Al_(5)O_(12) Directional solidification Single-phase sapphire seed Crystallographic orientation relationship Interfacial strain energy

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Surface-modified Ag@Ru-P25 for photocatalytic CO_(2) conversion with high selectivity over CH_(4) formation at the solid–gas interface

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Carbon Energy 2024年第1期6卷 182-196页

作者： Chaitanya B.Hiragond Sohag Biswas Niket SPowar Junho Lee Eunhee Gong Hwapyong Kim Hong Soo Kim Jin-Woo Jung Chang-Hee Cho Bryan M.Wong Su-Il In Department of Energy Science&Engineering Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea Department of Chemical&Environmental Engineering Materials Science&Engineering ProgramDepartment of ChemistryDepartment of Physics&AstronomyUniversity of California-RiversideRiversideCaliforniaUSA Department of Physics and Chemistry Daegu Gyeongbuk Institute of Science and Technology(DGIST)DaeguRepublic of Korea NiceScience Corporation DaeguRepublic of Korea

Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO_(2) reduction to solar fuels.A surface-modified Ag@Ru-P25 photocatalyst with H_(2)O_(2) treatment was designed in this study to convert CO_(2) and H_(2)O vapor into highly selective *** doping followed by Ag nanoparticles(NPs)cocatalyst deposition on P25(TiO_(2))enhances visible light absorption and charge separation,whereas H_(2)O_(2) treatment modifies the surface of the photocatalyst with hydroxyl(–OH)groups and promotes CO_(2) ***-resonance transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray absorption near-edge structure,and extended X-ray absorption fine structure techniques were used to analyze the surface and chemical composition of the photocatalyst,while thermogravimetric analysis,CO_(2) adsorption isotherm,and temperature programmed desorption study were performed to examine the significance of H_(2)O_(2) treatment in increasing CO_(2) reduction *** optimized Ag1.0@Ru1.0-P25 photocatalyst performed excellent CO_(2) reduction activity into CO,CH4,and C2H6 with a~95%selectivity of CH4,where the activity was~135 times higher than that of pristine TiO_(2)(P25).For the first time,this work explored the effect of H_(2)O_(2) treatment on the photocatalyst that dramatically increases CO_(2) reduction activity.

关键词： gas-phase CO_(2) reduction H_(2)O_(2) treatment plasmonic nanoparticles solar fuel photocatalyst surface modification

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Fabrication of crack-free aluminum alloy 6061 parts using laser foil printing process

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Rapid Prototyping Journal 2024年第4期30卷 722-732页

作者： Wang, Yu-Xiang Hung, Chia-Hung Pommerenke, Hans Wu, Sung-Heng Liu, Tsai-Yun Department of Mechanical Engineering National Cheng Kung University Tainan Taiwan Department of Materials Science and Engineering Missouri University of Science and Technology RollaMO United States Department of Mechanical and Aerospace Engineering Missouri University of Science and Technology RollaMO United States Core Facility Center National Cheng Kung University Tainan Taiwan

Purpose: This paper aims to present the fabrication of 6061 aluminum alloy (AA6061) using a promising laser additive manufacturing process, called the laser-foil-printing (LFP) process. The process window of AA6061 in LFP was established to optimize process parameters for the fabrication of high strength, dense and crack-free parts even though AA6061 is challenging for laser additive manufacturing processes due to hot-cracking issues. Design/methodology/approach: The multilayers AA6061 parts were fabricated by LFP to characterize for cracks and porosity. mechanical properties of the LFP-fabricated AA6061 parts were tested using Vicker’s microhardness and tensile testes. The electron backscattered diffraction (EBSD) technique was used to reveal the grain structure and preferred orientation of AA6061 parts. Findings: The crack-free AA6061 parts with a high relative density of 99.8% were successfully fabricated using the optimal process parameters in LFP. The LFP-fabricated parts exhibited exceptional tensile strength and comparable ductility compared to AA6061 samples fabricated by conventional laser powder bed fusion (LPBF) processes. The EBSD result shows the formation of cracks was correlated with the cooling rate of the melt pool as cracks tended to develop within finer grain structures, which were formed in a shorter solidification time and higher cooling rate. Originality/value: This study presents the pioneering achievement of fabricating crack-free AA6061 parts using LFP without the necessity of preheating the substrate or mixing nanoparticles into the melt pool during the laser melting. The study includes a comprehensive examination of both the mechanical properties and grain structures, with comparisons made to parts produced through the traditional LPBF method. © 2024, Emerald Publishing Limited.

关键词： 3D printing

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Process parameter optimization for directed laser deposition of hot work tool steel Dievar

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International Journal of Advanced Manufacturing Technology 2025年第3期138卷 1129-1142页

作者： Belsvik, Marius Aga Hansen, Vidar Department of Mechanical and Structural Engineering and Materials Science University of Stavanger Stavanger4021 Norway Kverneland Group Operations Norway as Klepp4353 Norway

Tool steel utilized in hot work applications are prone to costly and time-consuming maintenance repair due to wear generated on the tool surface from static and dynamic high temperature loading during the production processes. Traditionally, the repair is mainly done by subtractive machining of the tool profile. Implementation of an additive manufacturing technology such as directed laser deposition can greatly reduce maintenance time by targeting specifically the worn areas of the tool surface. In the presented work, a commercially available hybrid additive manufacturing and computer numerical control system is used to deposit a powdered hot work tool steel called Dievar. The central composite design is used in the experimental setup to optimize the most influential input parameters;powder feed rate, traverse speed, and laser power by analyzing single track geometry. The presented process window produced defect free parts without the need for preheating, Applying a powder feed rate of 6.5 g/min, traverse speed of 550 mm/min, and laser power of 1500 W, yielding an average as-built hardness of 610 HV0.5 while retaining the required pre-hardened properties in the heat-affected zone in the substrate, with a minor hardness reduction of 4–5% post-deposition. Additionally, the research revealed that the established boundary conditions for aspect ratio and dilution is not an absolute requirement to achieve a fully dense part without lack of fusion or cracks. Engineers working in the field of additive manufacturing may use the presented method to find optimal process parameters and qualify the implementation of directed laser deposition in their industry, avoiding a unnecessarily large selection of samples for testing and thus saving time and resources. © The Author(s) 2025.

关键词： Hot working

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