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Data-driven diagnosis of high temperature PEM fuel cells based on the electrochemical impedance spectroscopy: Robustness improvement and evaluation

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Journal of Energy Chemistry 2024年第9期96卷 544-558页

作者： Dan Yu Xingjun Li Samuel Simon Araya Simon Lennart Sahlin Vincenzo Liso Department of Energy Aalborg UniversityAalborg 9220Denmark Walker Department of Mechanical Engineering The University of Texas at AustinAustinTX 78712USA Materials Research and Technology Development Luxembourg Institute of Science and Technology(LIST)4422 BelvauxLuxembourg

Utilizing machine learning techniques for data-driven diagnosis of high temperature PEM fuel cells is beneficial and meaningful to the system durability. Nevertheless, ensuring the robustness of diagnosis remains a critical and challenging task in real application. To enhance the robustness of diagnosis and achieve a more thorough evaluation of diagnostic performance, a robust diagnostic procedure based on electrochemical impedance spectroscopy (EIS) and a new method for evaluation of the diagnosis robustness was proposed and investigated in this work. To improve the diagnosis robustness: (1) the degradation mechanism of different faults in the high temperature PEM fuel cell was first analyzed via the distribution of relaxation time of EIS to determine the equivalent circuit model (ECM) with better interpretability, simplicity and accuracy;(2) the feature extraction was implemented on the identified parameters of the ECM and extra attention was paid to distinguishing between the long-term normal degradation and other faults;(3) a Siamese Network was adopted to get features with higher robustness in a new embedding. The diagnosis was conducted using 6 classic classification algorithms—support vector machine (SVM), K-nearest neighbor (KNN), logistic regression (LR), decision tree (DT), random forest (RF), and Naive Bayes employing a dataset comprising a total of 1935 collected EIS. To evaluate the robustness of trained models: (1) different levels of errors were added to the features for performance evaluation;(2) a robustness coefficient (Roubust_C) was defined for a quantified and explicit evaluation of the diagnosis robustness. The diagnostic models employing the proposed feature extraction method can not only achieve the higher performance of around 100% but also higher robustness for diagnosis models. Despite the initial performance being similar, the KNN demonstrated a superior robustness after feature selection and re-embedding by triplet-loss method, which sug

关键词： PEM fuel cell Data-driven diagnosis Robustness improvement and evaluation Electrochemical impedance spectroscopy

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Oscillatory Hall effect from magnetoelectronic coupling in flexoelectronic silicon

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Physical Review B 2024年第8期109卷 L081113-L081113页

作者： Paul C. Lou Ravindra G. Bhardwaj Anand Katailiha W. P. Beyermann Sandeep Kumar Department of Mechanical Engineering University of California Riverside California 92521 USA Department of Physics and Astronomy University of California Riverside California 92521 USA Materials Science and Engineering Program University of California Riverside California 92521 USA

Magnetoelectronic coupling can be defined as cross-domain coupling between electronic and magnetic properties, where modulation in magnetic properties changes the electronic properties. In this Letter, explicit experimental evidence of magnetoelectronic coupling is presented, which is uncovered from the oscillatory Hall effect response in Hall measurement. The strain gradient in a MgO (1.8 nm)/p-Si (∼400 nm) freestanding sample leads to transfer of electrons (∼5×1018cm−3) from valence to conduction band due to flexoelectronic charge separation in the p-Si layer. The resulting flexoelectronic polarization gives rise to the temporal magnetic moment from dynamical multiferroicity. The external magnetic field changes the net temporal magnetic moment, which causes modulations in charge carrier concentration and oscillatory Hall effect. The period of oscillatory Hall response is 1.12 T, which is attributed to the magnitude of the temporal magnetic moment. The discovery of the oscillatory Hall effect adds another member to the family of Hall effects.

关键词： Hall effect Doped semiconductors Electronically polarized systems Flexoelectrics Multiferroics Hall bar

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Intermittent oxidation kinetics and metal/oxide interfacial undulation

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Physical Review B 2024年第8期110卷 085402-085402页

作者： Dongxiang Wu Xianhu Sun Judith C. Yang Guangwen Zhou Department of Mechanical Engineering & Materials Science and Engineering Program Department of Chemical and Petroleum Engineering

The phenomenon of oxygen adsorption induced surface restructuring is widespread across various metal-oxygen systems, yet its impact on initiating bulk oxide formation remains largely unexplored. Through in situ atomic-resolution electron microscopy observations of surface oxidation of Cu(110) and Cu85Au15(110), we unveil intermittent oxide-film growth modulated by oxygen-induced surface restructuring. This modulation is evidenced by repeated pinning of the Cu2O growth front at isolated Cu columns of the c(6×2)-O reconstruction, owing to required long-range diffusion of Cu and O atoms to the Cu2O growth front. We reveal that Cu vacancies, generated at the Cu2O growth front, are injected into the Cu2O/Cu interface, inducing hill and valley undulation of the Cu2O film. In contrast, atomic vacancies produced during the Cu85Au15(110) oxidation preferentially migrate into interfaces between Au-rich and Au-poor regions in the bulk, resulting in a flat and adherent Cu2O film. These findings demonstrate the critical role of oxygen-induced surface restructuring in modulating oxide film growth kinetics and the manipulability of the fate of injected vacancies by alloying, thereby offering insights applicable to a broader range of metal-oxygen systems for fine-tuning oxidation kinetics and enhancing oxide/metal interfacial adhesion.

关键词： Surface & interfacial phenomena Surface reconstruction Surface growth Density functional theory Transmission electron microscopy

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Recycling of Magnesium Alloy Using the Gravity-Driven Multiple-Effect Thermal System (G-METS)

Recycling of Magnesium Alloy Using the Gravity-Driven Multip...

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Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2024

作者： Mc Arthur Sehar, Daniel Telgerafchi, Armaghan Ehsani Iurkovskyi, Artem Opoku, Emmanuel Powell, Adam Materials Science and Engineering Program Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States

ISBN: (纸本)9783031502392

MagnesiumMagnesium metal has been significantly used in commercial applications from automobiles to aluminum alloys to defense weaponry. The surge in structural usage of magnesium over the past years has been due to high strength and excellent stiffness-to-weight ratio. RecyclingRecycling magnesium scrap is a crucial aspect of the sustainability of the economy and environmental welfare. G-METS is an advanced distillationDistillation system used in the conversion of low-grade magnesium scrap into high-purityHigh-purity magnesium metal. This multiple-effect system uses the weight of magnesiumMagnesium as a compressor, to build pressure differences between each effect of the condenser-evaporator, modifying boiling points, and enabling transfer of vaporization enthalpy. This system is exceptionally efficient compared to the energy-intensive conventional distillationDistillation technique. This study compares experiments and models of one- and two-effect distillers. © The Minerals, Metals & materials Society 2024.

关键词： Magnesium alloys

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Fluorine-Free Cosolvent Chemistry Empowering Sodium-Sulfurized Polyacrylonitrile Batteries

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Advanced Energy materials 2025年第0期

作者： Pai, Min-Hao Manthiram, Arumugam Materials Science and Engineering Program & Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States

Localized high-concentration electrolytes (LHCE) show great promise for room-temperature sodium-sulfur batteries. However, the majority of diluents in LHCE systems consist of fluorinated ethers, which are not only dense and expensive but also demonstrate poor reductive stability with sodium metal. Herein, a low-density, non-fluorinated ether electrolyte is presented that demonstrates localized high-concentration behavior. This feature is driven by the weak solvating capabilities of 1,2-dimethoxypropane (DMP) and the ultra-weak solvating nature of cyclopentyl methyl ether (CPME). Impressively, the fluorine-free CPME cosolvent acts as a diluent within the electrolyte. Therefore, the electrolyte achieves a tailored solvation structure characterized by anion-rich species, which fosters the development of a resilient inorganic-rich SEI with superior Na-ion transport. Consequently, with a high sulfur-content sulfurized polyacrylonitrile (SPAN, S content > 45% in SPAN) loading of 4.4 mg cm⁻2 (sulfur loading: 2 mg cm⁻2) and a low electrolyte-to-SPAN ratio of 9 µL mg⁻¹ (E/SPAN = 9), the Na-SPAN cell demonstrates remarkable reversibility of 530 mA h gsulfur⁻¹ after 200 cycles at C/5 rate. This performance surpasses the majority of state-of-the-art Na-SPAN ether-based electrolyte systems reported to date. Hence, this work presents a novel approach for designing cost-effective, high-performance electrolytes for stable, practical Na-SPAN batteries. © 2025 Wiley-VCH GmbH.

关键词： Sodium-ion batteries

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Influence of Biomimetic Apatite Coating on the Biobehavior of TiO_(2)Scaffolds

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Journal of Bionic engineering 2024年第4期21卷 1975-1986页

作者： Shima Mahtabian Seyed Mehdi Mirhadi Nahid Hassanzadeh Nemati Melika Sharifi Fariborz Tavangarian Department of Biomedical Engineering University of DelawareNewarkDE19716USA Department of Ceramic Engineering Islamic Azad University(Shahreza Branch)ShahrezaIsfahan86145-311Iran Department of Biomedical Engineering Islamic Azad University(Science and Research Branch)TehranIran Mechanical Engineering Program School of ScienceEngineering and TechnologyPennsylvania State UniversityHarrisburgMiddletownPA17057USA Department of Materials Science&Engineering Islamic Azad University(Najaf Abad Branch)Najaf AbadIsfahan***Iran Biomedical Engineering Department Pennsylvania State UniversityState CollegeUniversity ParkPennsylvania16802USA

Immersion of scaffolds in Simulated Body Fluid(10SBF)is a standardized method for evaluating their bioactivity,simulating in vivo conditions where apatite deposits can be formed on the surface of scaffold,facilitating bone integration and ensuring their suitability for bone implant purposes,ultimately contributing to long-term implant *** effect of apatite deposition on bioactivity and cell behavior of TiO_(2)scaffolds was *** were soaked in 10SBF for different durations to form HAP layer on their *** results proved the development of a hydroxyapatite film resembling the mineral composition of bone Extracellular Matrix(ECM)on the TiO_(2)*** XRD test findings showed the presence of hydroxyapatite layer similar to bone at the depth of 10 nm.A decrease in the specific surface area(18.913 m^(2)g^(−1)),the total pore volume(0.045172 cm^(3)g^(−1)(at p/p0=0.990)),and the mean pore diameter(9.5537 nm),were observed by BET analysis which confirmed the formation of the apatite *** was found that titania scaffolds with HAP coating promoted human osteosarcoma bone cell(MG63)cell attachment and *** seems that immersing the scaffolds in 10SBF to form HAP coating before utilizing them for bone tissue engineering applications might be a good strategy to promote bioactivity,cell attachment,and implant fixation.

关键词： Titania Hierarchical meso/macro porous 10SBF Biomimetic apatite Coating

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Optothermal multimodal manipulation of micro/nanoparticles

Optothermal multimodal manipulation of micro/nanoparticles

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Ding, Hongru Kollipara, Pavana Siddhartha Yao, Kan Zheng, Yuebing Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States Materials Science & Engineering Program Texas Materials Institute The University of Texas at Austin AustinTX78712 United States

ISBN: (纸本)9781957171258

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Optothermal Manipulation at Fluid Interfaces

Optothermal Manipulation at Fluid Interfaces

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Kim, Youngsun Ponce, Carolina Chen, Zhihan Zheng, Yuebing Materials Science & Engineering Program Texas Materials Institute The University of Texas at Austin AustinTX78712 United States Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States

Optothermal manipulation of particles at fluid interfaces was studied with a film of gold nanoparticles assembled at aqueous/oil interfaces. The unique optothermal behaviors of particles and fluid interfaces under opt... 详细信息

ISBN: (纸本)9781957171258

关键词： Gold nanoparticles

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Moderate-Refractive-Index Mie Resonators for Versatile Modulation of Two-Dimensional Excitons

Moderate-Refractive-Index Mie Resonators for Versatile Modul...

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Fang, Jie Zheng, Yuebing Materials Science & Engineering Program Texas Materials Institute The University of Texas at Austin AustinTX78712 United States Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States

ISBN: (纸本)9781957171258

By coupling well-designed moderate-refractive-index Mie resonators to monolayer semiconductors, we have demonstrated efficient modulation of two-dimensional excitons in multiple dimensions: far-field excitonic radiation patterns, intrinsic excitonic quantum dynamics, and bosonic exciton-polariton emission lines. © 2023 The Author(s)

关键词： Resonators

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Vortex Formation of Active Particles within a Confined Geometry by Velocity Alignment

Vortex Formation of Active Particles within a Confined Geome...

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Chen, Zhihan Ding, Hongru Zheng, Yuebing Materials Science & Engineering Program Texas Materials Institute The University of Texas at Austin AustinTX78712 United States Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States

We have developed an optical feedback control system with synchronous control of active particles to study collective motion in nature. Fish-like vortex is observed within a circular confined geometry based on the par... 详细信息

ISBN: (纸本)9781957171258

关键词： Adaptive control systems

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