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Piezoelectricity of strain-induced overall water splitting of Ni(OH)2/MoS2 heterostructure

Journal of materials Chemistry A 2023年第7期11卷 3481-3492页

作者： Le, Kim Tuyen Pham, Nguyet N. T. Liao, Yin-Song Ranjan, Ashok Lin, Hsun-Yen Chen, Po-Han Nguyen, Hoang Lu, Ming Yen Lee, Seung Geol Wu, Jyh Ming Department of Materials Science and Engineering National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan Department of Chemistry University of Science Vietnam National University Ho Chi Minh City Viet Nam School of Chemical Engineering Pusan National University 2 Busandaehak-ro 63 beon-gil Geumjeong-gu Busan46241 Korea Republic of Department of Organic Material Science and Engineering Pusan National University 2 Busandaehak-ro 63 beon-gil Geumjeong-gu Busan46241 Korea Republic of PhD Program in Prospective Functional Materials Industry National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan High Entropy Materials Center National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan Vietnam National University Ho Chi Minh City Linh Trung Ward Thu Duc City Ho Chi Minh City700000 Viet Nam

In this study, we synthesized several active sites of molybdenum disulfide (MoS2) nanoflowers (NFs) decorated with Ni(OH)2 nanoparticles (NPs) to form heterostructures. Our results revealed that Ni(OH)2/MoS2 NF heterostructures caused the splitting of water into hydrogen (H2) and oxygen (O2) gas. The Ni(OH)2/MoS2 NF interface exhibited strain-induced piezoelectric potential (piezopotential) that promoted charge separation, reducing the kinetic barrier in the water splitting process and promoting the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). In high-resolution transmission microscopy images, the measured lattice fringe d spacing was approximately 0.67 nm, which was higher than the reported value. The calculated tensile strain of Ni(OH)2/MoS2 NF heterostructures was approximately 3.5%. The findings based on density-functional theory and using the finite element method indicated that the interfacial piezopotential generated between Ni(OH)2 and MoS2 NFs enhanced charge transfer and electrochemical reactions. To obtain a current density up to 10 mA cm−2, we set the overpotential and Tafel slope of Ni(OH)2/MoS2 NF heterostructures at 155 mV and 62.1 mV dec−1 for the HER and 328 mV and 69.3 mV dec−1 for the OER, respectively. Moreover, a high Faraday efficiency (84.1%) was observed over 48 h, with no significant decline in the HER and OER. © 2023 The Royal Society of Chemistry.

关键词： Molybdenum disulfide

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Passivation of Perovskite Films Using Ionic Liquids

Passivation of Perovskite Films Using Ionic Liquids

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2022 Advances in science and engineering Technology International Conferences, ASET 2022

作者： Alashkar, Adnan Ibrahim, Taleb Khamis, Mustafa Hai Alami, Abdul American University of Sharjah Materials Science and Engineering PhD Program Sharjah United Arab Emirates American University of Sharjah Department of Chemical Engineering Sharjah United Arab Emirates American University of Sharjah Department of Biology Chemistry and Enviromental Sciences Sharjah United Arab Emirates University of Sharjah Department of Sustainable and Renewable Energy Engineering Sharjah United Arab Emirates

ISBN: (纸本)9781665418010

In this paper, the carrier recombination, and dynamics of Perovskite Solar Cells (PSC) are investigated. Ionic Liquids (IL) are presented in the bulk perovskite in an attempt to improve the dynamics of the charge transport layer. Time Resolved Photoluminescence (TRPL) is utilized to study the fast electronic decay of the perovskite samples and the influence of the IL on the stability of the perovskite film. The ILs are added to the perovskite in three ratios (5%, 10%, and 20%). The results showed that the presence of the ILs increases the electron lifetime inside the perovskite layer. In addition, 10% IL/perovskite displayed the highest increase of 72% in the lifetime. Where, for higher ratios, the lifetime started deteriorating. © 2022 IEEE.

关键词： Ionic liquids

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Improved camptothecin encapsulation and efficacy by environmentally sensitive block copolymer/chitosan/fucoidan nanoparticles for targeting lung cancer cells

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International Journal of Biological Macromolecules 2024年第Part2期277卷 133901页

作者： Don, Trong-Ming Hong, Yu-Ting Jheng, Pei-Ru Chuang, Er-Yuan Huang, Yi-Cheng Department of Chemical and Materials Engineering Tamkang University New Taipei City Taiwan College of Life Sciences Department of Food Science National Taiwan Ocean University Keelung Taiwan Graduate Institute of Biomedical Materials and Tissue Engineering International PhD Program in Biomedical Engineering Taipei Medical University Taipei Taiwan Cell Physiology and Molecular Image Research Center Taipei Medical University–Wan Fang Hospital Taipei Taiwan

In this study, thermo-sensitive poly(N-isopropyl acrylamide) (PNP) was polymerized with pH-sensitive poly(acrylic acid) (PAA) to prepare a PAA-b-PNP block copolymer. Above its cloud point, the block copolymer self-assembled into nanoparticles (NPs), encapsulating the anticancer drug camptothecin (CPT) in situ. Chitosan (CS) and fucoidan (Fu) further modified these NPs, forming Fu-CPT-NPs to enhance biocompatibility, drug encapsulation efficiency (EE), and loading content (LC), crucially facilitating P-selectin targeting of lung cancer cells through a drug delivery system. The EE and LC reached 82 % and 3.5 %, respectively. According to transmission electron microscope observation, these Fu-CPT-NPs had uniform spherical shapes with an average diameter of ca. 250 nm. They could maintain their stability in a pH range of 5.0–6.8. In vitro experimental results revealed that the Fu-CPT-NPs exhibited good biocompatibility and had anticancer activity after encapsulating CPT. It could deliver CPT to cancer cells by targeting P-selectin, effectively increasing cell uptake and inducing cell apoptosis. Animal study results showed that the Fu-CPT-NPs inhibited lung tumor growth by increasing tumor cell apoptosis without causing significant tissue damage related to generating reactive oxygen species in lung cancer cells. This system can effectively improve drug-delivery efficiency and treatment effects and has great potential for treating lung cancer. © 2024 Elsevier B.V.

关键词： Nanoparticles

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Advances in liposomal nanotechnology: from concept to clinics

RSC Pharmaceutics

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RSC Pharmaceutics 2024年第5期1卷 928-948页

作者： Reem M. Senjab Nour AlSawaftah Waad H. Abuwatfa Ghaleb A. Husseini Biomedical Engineering Program College of Engineering American University of Sharjah Sharjah P.O. Box 26666 United Arab Emirates ghusseini@aus.edu Materials Science and Engineering Ph.D. Program College of Arts and Sciences American University of Sharjah Sharjah P.O. Box 26666 United Arab Emirates Department of Chemical and Biological Engineering College of Engineering American University of Sharjah Sharjah P.O. Box 26666 United Arab Emirates Biosciences and Bioengineering PhD Program College of Engineering American University of Sharjah Sharjah P.O. Box 26666 United Arab Emirates

Liposomes, spherical phospholipid vesicles with a unique morphology mimicking that of body cells, have emerged as versatile nanoparticles for drug delivery. Their biocompatibility, low cytotoxicity, targeted delivery, and hydrophobic and hydrophilic characteristics make them stand out over traditional drug delivery systems. Liposomes can be tailored in size, composition, lamellarity, and surface charge, offering a unique level of customization for various applications. Extensive research in liposome technology has led to the development of a wide range of liposomal formulations with enhanced functionalities, such as PEGylated liposomes, ligand-targeted liposomes, and stimuli-responsive liposomes. Beyond their crucial role in cancer treatment, liposomes play a significant role in influenza, COVID-19, cancer, and hepatitis A vaccines. They are also utilized in pain management, fungal treatment, brain targeting, and topical and ocular drug delivery. This review offers insight into the types of liposomes, their composition, preparation methods, characterization methods, and clinical applications. Additionally, it discusses challenges and highlights potential future directions in liposome-based drug delivery.

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Study of chlorine removal from shredder residue: Thermal dechlorination and water leaching

Sustainable Chemistry for the Environment

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Sustainable Chemistry for the Environment 2024年 6卷

作者： Manera, Christian Perondi, Daniele Restelatto, Danielle Godinho, Marcelo Vilela, Antônio Cezar Faria Graduate Program in Mining Metallurgical and Materials Engineering Federal University of Rio Grande do Sul (UFRGS) Rio Grande do Sul Porto Alegre Brazil Graduate Program in Process Engineering and Technologies University of Caxias do Sul (UCS) Rio Grande do Sul Caxias do Sul Brazil Graduate Program in Materials Science and Engineering University of Caxias do Sul (UCS) Rio Grande do Sul Caxias do Sul Brazil

Shredder residue (SR) is an inevitable waste in the production of steel by scrap melting, and the presence of chlorine is the main responsible for its non-use of energy. This study aimed to remove chlorine from SR by thermal dechlorination and water leaching. Thermal dechlorination was first studied from a PVC sample to evaluate the optimum parameters of temperature, heating rate, residence time and atmosphere (N₂ or steam). Under optimal conditions for PVC dechlorination, chlorine removals of 73.7 (N₂) and 68.0% (steam) were achieved. Optimal parameters were applied to thermal dechlorination of a Brazilian SR with a chlorine content of 2.12 wt%. Reductions in chlorine content to 0.95 and 0.51 wt% were observed with N₂ and steam atmospheres, respectively. In an additional evaluation (conducted also with the Brazilian SR and in order to investigate the reactor rotation effect), it was observed that the reactor rotation does not influence the release of chlorine during the thermal treatment but modifies the granulometry of the produced solid. Samples obtained from this test were subjected to a water leaching study to further reduce the chlorine content. The parameters studied were the type of water (tap and distilled), granulometry and carbonation (contact with CO₂) in a total of five washing cycles. Carbonation and use of distilled water achieved the highest chlorine removal resulting in a reduction of chlorine content from 1.13 to 0.45 wt%. The obtained results show directions for chlorine removal aiming at the energetic use of shredder residue. © 2024 The Authors

关键词： Carbonation Chlorine leaching Design of experiment Polyvinyl chloride Shredder residue

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Ni-based bimetallic surface alloy catalysts for enhanced poisoning resistance in steam methane reforming: A combined DFT and experimental study

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International Journal of Hydrogen Energy 2025年 144卷 152-164页

作者： Hwa-Woong Cha Giseong Song Kyeongseok Min Shedrack G. Akpe Junseong Kim Sung Pil Yoon Sung-Hyeon Baeck Hyung Chul Ham Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University Incheon 22212 Republic of Korea Center for Hydrogen Fuel Cell Research Korea Institute of Science and Technology 5 Hwarang-ro 14-gil Seongbuk-gu Seoul 02792 Republic of Korea Program in Energy Process Innovation Convergence Inha University Incheon 22212 Republic of Korea

This study investigates the activities of Ni-M (M = transition metals) bimetallic catalysts in Molten Carbonate Electrolysis Cells (MCEC) for hydrogen production via steam methane reforming (SMR) under electrolyte poisoning conditions by using the density functional theory (DFT) and experimental approach. Focusing on the cost-effective and high-activity Ni (211) catalyst, the study addresses the challenge of electrolyte (Li 2 CO 3 , K 2 CO 3 ) evaporation leading to catalyst deactivation. Utilizing DFT, we examined partially electrolyte-poisoned Ni (211) slab models, particularly assessing potassium (K) atom effects. The study proposes bimetallic Ni-M surface alloy catalysts, such as Ni–V, demonstrating enhanced electrolyte poisoning resistance and superior catalytic activity compared to pure Ni. The findings highlight the potential of these catalysts to improve MCEC system efficiency, offering a more economical alternative to precious metal catalysts.

关键词： Steam reforming

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Flake-like structure of SrTiO3 nanoparticles dispersed on graphene oxide: A selective and sensitive electrochemical sensor for determination of chloramphenicol in milk and honey samples

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Food Chemistry 2024年 444卷

作者： Sakaleshpur Kumar, Gagankumar Ballur Prasanna, Sanjay Lokesh Marenahalli, Bhuvan Shadakshari, Sandeep Arehalli Shivamurthy, Santhosh Rajabathar, Jothi Ramalingam Chimatahalli Shanthakumar, Karthik Han, Young-Kyu Department of Chemistry SJCE JSS Science and Technology University Karnataka570006 India Department of Energy and Materials Engineering Dongguk University-Seoul Seoul100-715 Korea Republic of Taipei10608 Taiwan International PhD Program for Biomedical Engineering Taipei Medical University 250 Wuxing St Taipei11031 Taiwan N.M.K.R.V. College for Women's Karnataka 560011 India Department of Chemistry College of Science King Saud University P.O. Box. 2455 Riyadh11451 Saudi Arabia

The use of Chloramphenicol (CAP), a potent antibiotic with broad-spectrum capabilities in food-producing animals has been restricted by the European Union and several other countries due to its severe side effects. Thus, CAP must be detected quickly and sensitively. In this investigation, the preparation of SrTiO3 nanoparticles was carried out utilizing a hydrothermal technique. The as-synthesized strontium titanate was decorated on the graphene oxide (SrTiO3/GO) using an ultrasonication method. An electrochemical sensor was developed by employing a modified electrode consisting of SrTiO3/GO, which can accurately detect CAP in food samples. The synergistic effect of SrTiO3 and GO could improve the peak current response. Remarkably, the SrTiO3/GO-modified glassy carbon electrode has a LOD and sensitivity of 6.08 µM nM and 2.771 µA·μM−1·cm−2, respectively. This modified electrode was evaluated in food samples and had an outstanding reaction with a high percentage of recovery, which makes it a potential electrocatalyst for CAP detection. © 2024 Elsevier Ltd

关键词： Titanium compounds

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Comparative analysis of various oxygen production techniques using multi-criteria decision-making methods

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International Journal of Thermofluids 2023年 17卷

作者： Aljaghoub, Haya Alasad, Shamma Alashkar, Adnan AlMallahi, Maryam Hasan, Ranem Obaideen, Khaled Alami, Abdul Hai Department of Industrial Engineering and Engineering Management University of Sharjah Sharjah United Arab Emirates Mechanical Engineering Department American University of Sharjah Sharjah United Arab Emirates Materials Science and Engineering PhD Program American University of Sharjah Sharjah United Arab Emirates Department of Mechanical and Aerospace Engineering United Arab Emirates University Al Ain City United Arab Emirates Department of Sustainable and Renewable Energy Engineering University of Sharjah Sharjah United Arab Emirates Sustainable Energy and Power Systems Research Center RISE University of Sharjah Sharjah United Arab Emirates Center for Advanced Materials Research University of Sharjah Sharjah United Arab Emirates

The current pandemic has adversely affected oxygen production and supply chain, where oxygen treatment is essential for the emergency treatment protocol of patients infected by the virus. This work reports on various techniques of oxygen generation methods, as well as the challenges facing its production, storage, and transportation. Moreover, this study offers a comparative analysis of various oxygen production techniques using Multi-Criteria Decision-Making Methods (MCDM). Technique for Order Preference by Similarity to Ideal Solution (TOPSIS), in addition to the weighting methodologies, Multiplicative Exponential Weighting (MEW) and Simple Additive Weighting (SAW) are chosen as tools to carry out the statistical analysis and rank the oxygen production methods. The ranking criteria includes cost, performance, environmental impact and safety. Moreover, this paper utilizes the Entropy Weight Method (EWM), Criteria Importance Through Inter-criteria Correlation (CRITIC) method, and the Stochastic Dominance (SD) method to distribute the criteria weights. The results show thar oxygen production using membrane technologies is the optimal technique based on all the provided tools and criteria. as it attained the maximum Entropy and Sd values of 0.548 through the TOPSIS method, and the highest CRITIC value through SAW and MEW methods which were 0.260 and 0.236, respectively. © 2022 The Author(s)

关键词： Stochastic systems

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Photoresponse of Thermally Evaporated Copper Oxide-Based Solar Cells

Photoresponse of Thermally Evaporated Copper Oxide-Based Sol...

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Solar Conference (MENA-SC), Middle East and North Africa

作者： Abdul Hai Alami Mohamad Ayoub Adnan Alashkar Shamma Alasad Ayman Mdallal Siren Khuri Haya Aljaghoub Sustainable and Renewable Energy Engineering Department Sustainable Energy & Power Systems Research Centre University of Sharjah Sharjah United Arab Emirates Materials Science and Engineering PhD Program American University of Sharjah Sharjah United Arab Emirates Mechancial Engineering Department American University of Sharjah Sharjah United Arab Emirates Sustainable Energy & Power Systems Research Centre University of Sharjah Sharjah United Arab Emirates Industrial Engineering and Engineering Management Department University of Sharjah Sharjah United Arab Emirates

This study reports on the fabrication and characterization of a copper oxide (CuO)-based photoactive cell. Copper was thermally evaporated onto two substrates and post-treated using chemical and thermal treatments to obtain different semiconducting types of CuO. Absorption measurements were conducted to obtain the bandgaps of CuO, which were found to be 1.51 eV and 1.21 eV, for the chemically and thermally treated CuO, respectively. Finally, a chronoamperometry test was conducted to confirm the photoresponse of the cell, which showed a doubling of output current values under light conditions compared to dark conditions.

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Bulk passivation of perovskite films utilizing halide anion ionic liquids

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International Journal of Thermofluids 2023年 20卷

作者： Alashkar, Adnan Ayoub, Mohamad Ibrahim, Taleb Khamis, Mustafa Nancarrow, Paul Alami, Abdul Hai Tabet, Nouar PhD Program in Materials Science and Engineering American University of Sharjah Sharjah 26666 United Arab Emirates Sustainable and Renewable Energy Engineering Department University of Sharjah Sharjah 27272 United Arab Emirates Sustainable Energy & Power Systems Research Centre RISE University of Sharjah Sharjah 27272 United Arab Emirates Department of Chemical Engineering American University of Sharjah Sharjah 26666 United Arab Emirates Department of Biology Chemistry and Environmental Sciences College of Arts and Sciences American University of Sharjah Sharjah 26666 United Arab Emirates Center for Advanced Materials Research Research Institute of Science and Engineering University of Sharjah Sharjah 27272 United Arab Emirates Department of Applied Physics and Astronomy University of Sharjah Sharjah 27272 United Arab Emirates

Chemical additives to perovskite precursors constitute a predominant route to passivate defects in perovskite films and improve carrier charge dynamics. In this work, ionic liquids (ILs) with chloride and iodide anions are used as additives for bulk passivation of perovskite films. The ionic liquids in the form of 1‑butyl‑4-methylpyradinium iodide (IL-I) and 1-ethylimidazolium chloride (IL-Cl) are mixed individually with a precursor of Cesium Formamidinium Lead Triiodide and Methylammonium Chloride (CsFAPbI3−MACl). The decay of charge carriers within the perovskite film before and after passivation with ILs was measured by Time Resolved Photoluminescence Spectroscopy (TRPL). The effect of added ILs on the recombination rate of the photocarriers was investigated by analyzing the decay of the TRPL signal in all samples. The average lifetimes obtained within one day of preparations were 79 ns, 73 ns and 275 ns for pristine perovskite, IL-I passivated perovskite and IL-Cl passivated perovskite films, respectively. These values show that the presence of the IL with chloride anion greatly improves the average lifetime of the charge carrier by around 250%, while IL with iodide anion decreased the lifetime by 32% as compared with the pristine perovskite sample. This finding renders the IL-Cl passivated perovskite films as a valuable resource in applications ranging from photoelectric to hydrogen generation devices. © 2023

关键词： Ionic liquids

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