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Inside Back Cover: A Leaf-Inspired Luminescent Solar Concentrator for Energy-Efficient Continuous-flow Photochemistry (Angew. Chem. Int. Ed. 4/2017)

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Angewandte Chemie International Edition 2016年第4期56卷

作者： Dario Cambié Fang Zhao Prof. Dr. Volker Hessel Dr. Michael G. Debije Dr. Timothy Noël Department of Chemical Engineering and Chemistry Micro Flow Chemistry & Process Technology Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven The Netherlands Department of Chemical Engineering and Chemistry Functional Organic Materials & Devices Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven The Netherlands

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Innenrücktitelbild: A Leaf‐Inspired Luminescent Solar Concentrator for Energy‐Efficient Continuous‐flow Photochemistry (Angew. Chem. 4/2017)

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Angewandte Chemie 2016年第4期129卷

作者： Dario Cambié Fang Zhao Volker Hessel Michael G. Debije Timothy Noël Department of Chemical Engineering and Chemistry Micro Flow Chemistry & Process Technology Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven The Netherlands Department of Chemical Engineering and Chemistry Functional Organic Materials & Devices Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven The Netherlands

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Heat-integrated novel process of liquid fuel production from bioresources - process simulation and costing study

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Chemical Engineering Transactions 2014年第SPECIAL ISSUE期39卷 931-936页

作者： Gürsel, Iris Vural Wang, Qi Noël, Timothy Kolb, Gunther Hessel, Volker Van Veen, Andre C. Eindhoven University of Technology Department of Chemical Engineering and Chemistry Micro Flow Chemistry and Process Technology Den Dolech 2 Eindhoven5600MB Netherlands University of Warwick School of Engineering Library Road CoventryCV United Kingdom

ISBN: (纸本)9788895608303

Innovative ways of providing novel sustainable solutions to reduce the emissions and consumption of exhaustible resources is called for. Production of liquid fuels from bioresources satisfies this call and it is aimed to be achieved with BIOGO project. Proposed process involves coupled reforming of biogas and bio oil followed by methanol production which is then converted to gasoline. This novel route through methanol eliminates challenging separation steps of Fischer-Tropsh process. Decentralized production in modularized small scale plants with process intensified equipment is considered. process simulation reveals that carbon efficiency of 56 % and energy efficiency of 42 % can be achieved. Cost calculations show that with the total cost of production of gasoline at € 0.5/L;it is economically competitive with petroleum-based production and more economical than Fischer-Tropsh process. Comparison of 35 decentralized small modular plants with one centralized large scale plant reveals that the reduced construction time and operating cost of decentralized plants can outweigh the higher investment cost.. Copyright © 2014, AIDIC Servizi S.r.l.

关键词： Gasoline

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flow chemistry and flow process technology–In Fine chemistry and Biocatalysis

Flow Chemistry and Flow Process Technology–In Fine Chemistr...

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2014第五届国际工业酶与生物催化大会

作者： Volker Hessel Micro Flow Chemistry and Process Technology Eindhoven University of Technology

micro process technology has given strong push to continuous chemical manufacture via facilitating heat and mass transfer(transport intensification). The next big step is to develop a tailored process chemistry in flow under highly intensified conditions – which is one essence among the developing field of flow chemistry. This has been coined Novel process Windows and has two research pillars, the exploration of unusual and typically harsh process conditions(chemical intensification) and, in a more holistic picture, a completely new and often simpler process design(processdesign intensification). Reactivity is boosted via high-T, high-p, high-c(solvent-free;alternative solvent) concepts and more. Recently, biotechnology and flow chemistry merged into enzymatic micro-flow reactors. Enzymes are commonly immobilized on porous beads filled into a tube – a micro-flow packed bed reactor. The making of highvalue building blocks for APIs is demonstrated by the formation of alpha amino alcohols with Threonine Aldolase.A transesterification with Lipase underlines how productivity, sufficient at least for pharma level, may be achieved and what bottlenecks are still to overcome. Starting from such new reaction designs, new process designs in flow are developed, with major consequences on CAPEX/OPEX costs, sustainability, and energy consumption(heat integration,pinch analysis). On top of that, the embedment of flow processing into modern compact modular chemical production platforms(‘Future Factories';container) such as Evonik's Evotrainer is discussed. Such modern chemical manufacturing allows a faster return on invest by reducing time-to-market(‘windows of opportunity') especially for high-value chemicals and in volatile markets. First evidence is given by cash-flow analysis, determining the net-present value.

关键词： flow chemistry and flow process technology In Fine chemistry and Biocatalysis

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Disulfide‐Catalyzed Visible‐Light‐Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin–Disulfide Charge‐Transfer Complex

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Angewandte Chemie 2016年第3期129卷

作者： Yuchao Deng Xiao‐Jing Wei Hui Wang Yuhan Sun Timothy Noël Xiao Wang CAS Key Lab of Low-Carbon Conversion Science and Engineering Shanghai Advanced Research Institute Chinese Academy of Sciences 100 Haike Road Pudong Shanghai 201210 P.R. China School of Physical Science and Technology ShanghaiTech University Shanghai 201210 P.R. China University of Chinese Academy of Sciences Beijing 100049 P.R. China Department of Chemical Engineering and Chemistry Micro Flow Chemistry and Process Technology Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven The Netherlands Harvard NeuroDiscovery Center Harvard Medical School and Brigham & Women's Hospital 65 Landsdowne Street Cambridge MA 02139 USA

A photocatalytic method for the aerobic oxidative cleavage of C=C bonds has been developed. Electron‐rich aromatic disulfides were employed as photocatalyst. Upon visible‐light irradiation, typical mono‐ and multi‐substituted aromatic olefins could be converted into ketones and aldehydes at ambient temperature. Experimental and computational studies suggest that a disulfide–olefin charge‐transfer complex is possibly responsible for the unconventional dissociation of S−S bond under visible light.

关键词： Disulfid-Katalysatoren Donor-Akzeptor-Komplexe Olefinoxidation Organokatalyse Photokatalyse mit sichtbarem Licht

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Reactor, catalyst and process development for plasma assisted nitrogen fixation reactions 21

Reactor, catalyst and process development for plasma assiste...

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21st International Congress of Chemical and process Engineering, CHISA 2014 and 17th Conference on process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, PRES 2014

作者： Patil, B.S. Wang, Q. Lang, J. Hessel, V. Eindhoven University of Technology Micro Flow Chemistry and Process Technology P. O. Box 513 EindhovenMB5600 Netherlands Evonik Industries AG Innovation Management Verfahrenstechnik and Engineering Rodenbacher Chaussee 4 Hanau-Wolfgang63457 Germany

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18th European Symposium on Radiopharmacy and Radiopharmaceuticals Salzburg, Austria. 7-10 April 2016

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EJNMMI RADIOPHARMACY AND chemistry 2016年第1期1卷 1-37页

作者： [Anonymous] Los Alamos National Laboratory Los Alamos USA Oak Ridge National Laboratory Oak Ridge USA Department of Nuclear Medicine Medical University Innsbruck Innsbruck Austria Department of Radiology & Nuclear Medicine Radboud University Medical Center Nijmegen The Netherlands Institute of Molecular and Translational Medicine Faculty of Medicine and Dentistry Palacky University Olomouc Czech Republic Département de Médecine Nucléaire et Radiobiologie Faculté de Médecine et Sciences de la Santé Université de Sherbrooke Sherbrooke Canada Centre d’Imagerie Moléculaire de Sherbrooke (CIMS) CR-CHUS Sherbrooke Canada Division of Molecular Biology/Biocenter Medical University Innsbruck Innsbruck Austria Department of Nuclear Medicine Radboud University Medical Center Nijmegen The Netherlands IENI-CNR Padua Italy DiSCOG-University of Padua Padua Italy IOV Padua Padua Italy IC-CNR Bari Italy IBB-CNR Naples Italy Laboratory of Radiopharmacy KU Leuven Leuven Belgium Micro Flow Chemistry & Process Technology Chemical Engineering and Chemistry Department TU Eindhoven Eindhoven The Netherlands Laboratory for Radiopharmacy University of Leuven Leuven Belgium Department of Nuclear Medicine and Molecular Imaging University of Leuven Leuven Belgium Department of Medicine and Surgery Tecnomed Foundation University of Milano-Bicocca Milan Italy Dipartimento di Biotecnologie Mediche e Medicina Traslazionale Università degli Studi di Milano Milan Italy Department of Radiology & Nuclear Medicine VU University Medical Center Amsterdam The Netherlands Department of Clinical Pharmacology & Pharmacy VU University Medical Center Amsterdam The Netherlands Université de Lorraine Vandoeuvre les Nancy France NancycloTEP Plateforme d’imagerie expérimentale Vandoeuvre les Nancy France CNRS UMR 7565 SRSMC Vandoeuvre les Nancy France CHU de Nancy-Brabois Vandoeuvre les Nancy France Department of Biomedical Imaging and Image-guided Therapy Division of Nuclear Medicine Medical Univers

Table of contents OP03 Selective extraction of medically-related radionuclides from proton-irradiated thorium targets V. Radchenko, J.W. Engle, C. Roy, J. Griswold, M.F. Nortier, E.R. Birnbaum, M. Brugh, S. Mirzadeh, K. D. John, M.E. Fassbender OP04 Comparison of [68Ga]FSC(succ-RGD)3 and [68Ga]NODAGA-RGD for PET imaging of alpha v beta 3 integrin expression Chuangyan Zhai, Gerben M. Franssen, Milos Petrik, Peter Laverman, Clemens Decristoforo OP05 A new NPY-Y1R targeting peptide for breast cancer PET imaging Ait-Mohand Samia, Dumulon-Perreault Veronique, Guerin Brigitte OP06 The influence of multivalency on CCK 2 receptor targeting D. Summer, A. Kroess, C. Rangger, H. Haas, P. Laverman, F. Gerben, E. von Guggenberg, *** OP07 SPECT Imaging of alpha v beta 3 Expression by [99mTc(N)PNP43]- Bifunctional Chimeric RGD Peptide not Cross-Reacting with alpha v beta 5 Cristina Bolzati, Nicola Salvarese, Fiorenzo Refosco, Laura Melendez-Alafort, Debora Carpanese, Antonio Rosato, Michele Saviano, Annarita Del Gatto, Daniela Comegna, Laura Zaccaro OP09 New dienophiles for the inverse-electron-demand Diels-Alder reaction and for pretargeted PET imaging Emilie Billaud, Muneer Ahamed, Frederik Cleeren, Elnaz Shahbazali, Tim Noel, Volker Hessel, Alfons Verbruggen and Guy Bormans OP10 New complexing agent for Al18F-labelling of heat-sensitive biomolecules: Synthesis and preclinical evaluation of Al18F-RESCA1-HAS Cleeren F, Lecina J, Koole M, Verbruggen A and Bormans G OP11 A novel versatile precursor efficient for F-18 radiolabelling via click-chemistry B. Lugatoa, S. Stucchia, E.A. Turollaa, L. Giulianoa, ***, P. Ferraboschib OP12 A general applicable method to quantify unidentified UV impurities in radiopharmaceuticals R.P. Klok, M.P.J. Mooijer, N.H. Hendrikse, A.D. Windhorst OP13 Development of [F-18]Fluoro-C-glycosides to radiolabel peptides Collet C., Petry N., Chretien F., Karcher G., Pellegrini-Moise N., Lamande-Langle S. OP14 A microfluidic Approach for the 68

关键词： Positron Emission Tomography Single Photon Emission Compute Tomography Standard Uptake Value Positron Emission Tomography Imaging High Pressure Liquid Chromatography

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Inside Cover Picture: Rapid Trifluoromethylation and Perfluoroalkylation of Five-Membered Heterocycles by Photoredox Catalysis in Continuous flow (ChemSusChem 6/2014)

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ChemSusChem 2014年第6期7卷 1492-1492页

作者： Natan J. W. Straathof Hannes P. L. Gemoets Dr. Xiao Wang Prof. Dr. Jaap C. Schouten Prof. Dr. Volker Hessel Dr. Timothy Noël Department of Chemical Engineering and Chemistry Micro Flow Chemistry & Process Technology Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven (The Netherlands) Harvard NeuroDiscovery Center Harvard Medical School and Brigham & Women's Hospital 65 Landsdowne Street Cambridge MA 02139 (USA) Department of Chemical Engineering and Chemistry Chemical Reactor Engineering Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven (The Netherlands) Ghent University Department of Organic Chemistry Krijgslaan 281 (S4) 9000 Ghent (Belgium)

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A Mild, One‐Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous‐flow†

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Angewandte Chemie 2013年第30期125卷

作者： Xiao Wang Gregory D. Cuny Timothy Noël Harvard NeuroDiscovery Center Harvard Medical School and Brigham & Women's Hospital 65 Landsdowne Street Cambridge MA 02139 (USA) Department of Pharmacological and Pharmaceutical Sciences College of Pharmacy University of Houston 549 A Science and Research Bldg 2 Houston TX 77204 (USA) Department of Chemical Engineering and Chemistry Micro Flow Chemistry & Process Technology Eindhoven University of Technology Den Dolech 2 5612 AZ Eindhoven (The Netherlands)

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Macromol. React. Eng. 9/2013

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Macromolecular Reaction Engineering 2013年第9期7卷

作者： Christophe A. Serra Bruno Cortese Ikram Ullah Khan Nicolas Anton Mart H. J. M. de Croon Volker Hessel Tsutomu Ono Thierry Vandamme Université de Strasbourg (UdS) Ecole de Chimie Polymères et Matériaux (ECPM) Institut de Chimie et Procédés pour l'Energie l'Environnement et la Santé (ICPEES) – UMR 7515 CNRS Groupe d'Intensification et d'Intégration des Procédés Polymères (G2IP)F‐67087StrasbourgFrance Eindhoven University of Technology Micro Flow Chemistry/Chemical Reaction Engineering Groups‐ EindhovenThe Netherlands Université de Strasbourg (UdS) Faculté de Pharmacie Laboratoire de Conception et Application de Molécules Bioactives Equipe de Pharmacie Biogalénique – CNRS 719974 route du Rhin BP 60024F‐67401IllkirchCedexFrance College of Pharmacy Government College UniversityFaisalabadPakistan Department of Applied ChemistryGraduate School of Natural Science and TechnologyOkayama University3‐1‐1 Tsushima‐nakaOkayama700‐8530Japan

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