检索结果-内蒙古大学图书馆

Recent advances on catalysts for preferential oxidation of CO

Nano Research 2023年第4期16卷 4399-4410页

作者： Huimin Liu Dezheng Li Jiawen Guo Yuqiao Li Aidi Liu Yitong Bai Dehua He School of Chemical and Environmental Engineering Liaoning University of TechnologyJinzhou 121001China Innovative Catalysis Program Key Lab of Organic Optoelectronics&Molecular Engineering of Ministry of EducationDepartment of ChemistryTsinghua UniversityBeijing 100084China

The trace amount of CO in H2-rich gas poisons Pt electrode when it is adopted as feedstock for proton-exchange-membrane fuel *** oxidation of CO(PROX)is a promising approach to selectively oxidize the trace amount of CO while keeping H2 *** plays important roles in *** date,enormous catalysts have been developed for *** the catalysts developed for PROX and unveiling the reaction mechanism could definitely advance this research ***,in this review,according to the nature of the active sites on the catalysts,we classify the catalysts into group VIII metal-based catalyst,group IB metal-based catalysts,group VIII-group IB bimetallic catalysts,transitional metal oxide catalysts as well as others,describe the progress of the catalysts in PROX in the latest five years,and extract the underlying reaction mechanism,with the aim to provide guidance for the rational design of efficient catalysts in the future.

关键词： preferential oxidation of CO group VIII metal-based catalysts group IB metal-based catalysts bimetallic catalysts mechanism exploration

来源：评论

学校读者我要写书评

暂无评论

Nitrogen Pretreatment of Growth Substrates for Vacancy-Saturated MoS2

引用

ACS Applied Materials and Interfaces 2023年第36期15卷 42746-42752页

作者： Yao, Yu-Chi Wu, Bo-Yi Chin, Hao-Ting Yen, Zhi-Long Ting, Chu-Chi Hofmann, Mario Hsieh, Ya-Ping Institute of Atomic and Molecular Sciences Academia Sinica Taipei10617 Taiwan Department of Physics National Taiwan University Taipei10617 Taiwan Graduate Institute of Opto-Mechatronics Department of Mechanical Engineering National Chung Cheng University Chia-Yi62102 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei10617 Taiwan

Two-dimensional transition-metal dichalcogenides (2D TMDCs) are considered promising materials for optoelectronics due to their unique optical and electric properties. However, their potential has been limited by the occurrence of atomic vacancies during synthesis. While post-treatment processes have demonstrated the passivation of such vacancies, they increase process complexity and affect the TMDC’s quality. We here introduce the concept of pretreatment as a facile and powerful route to solve the problem of vacancies in MoS2. Low-temperature nitridation of the sapphire substrate prior to growth provides a nondestructive method to MoS2 modification without introducing new processing steps or increasing the thermal budget. Spectroscopic characterization and atomic-resolution microscopy reveal the incorporation of nitrogen from the sapphire surface layer into chalcogen vacancies. The resulting MoS2 with nitrogen-saturated defects shows a decrease in midgap states and more intrinsic doping as confirmed by ab initio calculations and optoelectronic measurements. The demonstrated pretreatment method opens up new routes toward future, high-performance 2D electronics, as evidenced by a 3-fold reduction in contact resistance and a 10-fold improved performance of 2D photodetectors. © 2023 American Chemical Society

关键词： Molybdenum compounds

来源：评论

学校读者我要写书评

暂无评论

Downsizing and soft X-ray tomography for cellular uptake of interpenetrated metal-organic frameworks

引用

Journal of Materials Chemistry B 2024年第25期12卷 6079-6090页

作者： Yu, Yu-Sheng Liang, Yung-Yi Hsieh, Chia-Chun Lin, Zi-Jing Cheng, Po-Hsiu Cheng, Chih-Chan Chen, Shu-Ping Lai, Lee-Jene Wu, Kevin C.-W. National Taiwan University Department of Chemical Engineering Taipei Taiwan National Health Research Institute Institute of Biomedical Engineering and Nanomedicine Miaoli Taiwan Hsinchu Taiwan International Graduate Program of Molecular Science and Technology Taiwan International Graduate Program Academia Sinica Taipei Taiwan National Taiwan University Taipei Taiwan

Metal-organic frameworks (MOFs) are porous materials with potential in biomedical applications such as sensing, drug delivery, and radiosensitization. However, how to tune the properties of the MOFs for such applications remains challenging. Herein, we synthesized two MOFs, Zr-PEB and Hf-PEB. Zr-PEB can be classified as porous interpenetrated zirconium frameworks (PIZOFs) and Hf-PEB is its analogue. We controlled their sizes while maintaining their crystal structure by employing a coordination modulation strategy. They were designed to serve as sensitizer for X-ray therapy and as potential drug carriers. Comprehensive characterizations of the MOFs' properties have been conducted, and the in vitro biological impacts have been studied. Since viability assay showed that Hf-PEB was more biocompatible compared to Zr-PEB, the cellular uptake of Hf-PEB by cells was evaluated using both fluorescence microscopy and soft X-ray tomography (SXT), and the three-dimensional structure of Hf-PEB in cells was observed. The results revealed the potential of Zr-PEB and Hf-PEB as nanomaterials for biomedical applications and demonstrated that SXT is an effective tool to assist the development of such materials. © 2024 The Royal Society of Chemistry.

关键词： Organometallics

来源：评论

学校读者我要写书评

暂无评论

Extracellular matrix-templating fibrous hydrogels promote ovarian tissue remodeling and oocyte growth

引用

Bioactive Materials 2024年第2期32卷 292-303页

作者： Claire E.Nason-Tomaszewski Emily E.Thomas Daniel L.Matera Brendon M.Baker Ariella Shikanov Department of Biomedical Engineering University of MichiganAnn ArborMI 48109USA Department of Chemical Engineering University of MichiganAnn ArborMI 48109USA Department of Obstetrics and Gynecology University of MichiganAnn ArborMI 48109USA Cellular and Molecular Biology Program University of MichiganAnn ArborMI 48109USA

Synthetic matrices which mimic the extracellular composition of native tissue create a comprehensive model for studying development and ***,we have engineered a composite material which retains cell-secreted ECM for the culture of ovarian follicles by embedding electrospun dextran fibers functionalized with basement membrane binder(BMB)peptide in PEG *** the presence of ECM-sequestering fibers,encapsulated immature primordial follicles and ovarian stromal cells aggregated into large organoid-like structures with dense deposition of laminin,perlecan,and collagen I,leading to steroidogenesis and significantly greater rates of oocyte survival and *** determined that cell aggregation restored key cell-cell interactions critical for oocyte survival,whereas oocyte growth was dependent on cell-matrix interactions achieved in the presence of *** we have shown that sequestration and retention of cell-secreted ECM along synthetic fibers mimics fibrous ECM structure and restores the cell-cell and cell-matrix interactions critical for engineering an artificial ovary.

关键词： Biomimetic matrix Ovarian follicle Fibrous hydrogels

来源：评论

学校读者我要写书评

暂无评论

Low-Temperature Methanolysis of Polycarbonate over Solid Base Sodium Aluminate

引用

Langmuir 2024年第10期40卷 5338-5347页

作者： Krisbiantoro, Philip Anggo Sato, Miyu Lin, Tzu-Ming Chang, Yu-Chia Peng, Tzu-Yun Wu, Yun-Chih Liao, Weisheng Kamiya, Yuichi Otomo, Ryoichi Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei11529 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering College of Engineering National Taiwan University Taipei10617 Taiwan Graduate School of Environmental Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Faculty of Environmental Earth Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Center of Atomic Initiative for New Materials National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan320 Taiwan

Herein, a low-cost and readily available sodium aluminate (NaAlO2) was used as a solid base catalyst for the depolymerization of polycarbonate (PC) via methanolysis in the presence of tetrahydrofuran (THF) as a solvent. NaAlO2 was highly active for the reaction, and the performance was comparable to that of soluble strong base SrO and much higher than those of MgO and CaO. By the reaction over the catalyst, a highly pure and crystalline bisphenol A (BPA) was obtained. Among tested organic solvents, THF was the best in aiding PC methanolysis over NaAlO2 due to the polarity similar to PC according to Hansen solubility parameters (HSPs). At 60 °C, 98.1% PC conversion and 96.8% BPA yield were achieved within just 2 h. NaAlO2 was reusable without any severe catalyst deactivation in at least four runs. The mechanistic study revealed that the reaction proceeded via the methoxide pathway, with THF aiding the dissolution of PC. The reaction over NaAlO2 possessed a low apparent activation energy (Ea) of 75.1 kJ mol-1, which is the lowest ever reported so far for the reaction over solid catalysts. © 2024 The Authors. Published by American Chemical Society.

关键词： Sodium Aluminate

来源：评论

学校读者我要写书评

暂无评论

Porphyrin-Grafted Poly(ethylene terephthalate) as a Reusable and Highly Selective Colorimetric Probe for Mercuric Ion Contaminants in Aqueous Samples

引用

ACS Applied Materials and Interfaces 2024年第30期16卷 39195-39205页

作者： Atayde, Eduardo C. Takenaka, Yasumasa Abe, Hideki Wu, Ming-Rou Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Department of Chemistry National Tsing Hua University Department of Chemical Engineering National Taiwan University Bioplastic Research Team RIKEN Center for Sustainable Resource Science Department of Chemical Engineering and Materials Science Yuan Ze University Department of Chemical Engineering Chung Yuan Christian University

Heavy metals are the most hazardous water pollutants, with severe health and environmental consequences. Among these, mercuric (Hg2+) ions are known to cause detrimental health issues in both humans and aquatic life. ... 详细信息

Heavy metals are the most hazardous water pollutants, with severe health and environmental consequences. Among these, mercuric (Hg²⁺) ions are known to cause detrimental health issues in both humans and aquatic life. Due to this, several analytical techniques have been devised to detect and quantify the amount of this ion. However, most of these require advanced instrumentation, prolonged analysis time, and sample preparation. In this study, a low-cost and highly reusable colorimetric probe was developed by grafting porphyrin to poly(ethylene terephthalate) sheets using an oxazoline polymer as covalent adhesive. Upon exposure to trace amounts of Hg²⁺ in solution, the fabricated material visually transitioned from faint brownish pink to green by the complexation mechanism. Additionally, the transparency of this probe allowed the quantitative spectrophotometric determination of the Hg²⁺ concentration in aqueous samples. It was also shown that the material is highly stable, which can be reused for more than 50 times without significant decline in its performance, hence, making it suitable for the onsite monitoring of mercuric ion contamination in different bodies of water. © 2024 The Authors. Published by American Chemical Society.

关键词： colorimetric probe mercuric ion oxazoline PET porphyrin

来源：评论

学校读者我要写书评

暂无评论

The fermented milk can be a natural ally against obesity? Investigation of bovine milk fermentation by Lacticaseibacillus casei LBC 237, screening, and In silico predictions of bioactive peptides for obesity control

Intelligent Pharmacy

引用

Intelligent Pharmacy 2024年第4期2卷 467-484页

作者： Bellaver, Emyr Hiago Militão da Costa, Ingrid Redin, Eduarda Eliza Moroni, Liziane Schittler Kempka, Aniela Pinto Santa Catarina State University Department of Animal Production and Food Science Multicentric Graduate Program in Biochemistry and Molecular Biology SC Lages Brazil Santa Catarina State University Department of Food Engineering and Chemical Engineering SC Pinhalzinho Brazil

The increasing quest for therapeutic alternatives in treating non-communicable chronic diseases like obesity has propelled research into bioactive peptides, with a particular focus on milk due to its rich protein composition and associated health benefits. Milk fermentation, a traditional process in dairy production, enhances the bioactivity of peptides, broadening their potential therapeutic uses. This study investigated the anti-obesity potential of peptides from bovine milk fermented by Lacticaseibacillus casei LBC 237, identifying 143 peptides, notably LGPV and EVPMP. In silico analyses revealed that LGPV and EVPMP biopeptides exhibited significant interactions with target proteins, employing various molecular interactions such as Van der Waals forces, hydrogen bonds, and electrostatic interactions. These peptides shared common binding sites in some enzymes, suggesting a similar mode of interaction between molecule and target protein, akin to key pharmaceuticals recommended for treating these pathologies. Furthermore, amino acid characteristics present in the peptides, including hydrophobic residues like Leucine, Glutamate, Valine, and Proline, proved essential for their bioactive and inhibitory activities. These findings highlight the potential of LGPV and EVPMP biopeptides as therapeutic agents in managing obesity and metabolic disorders. They provide important insights into their mechanisms of action, paving the way for future research to apply them practically in preventing and treating metabolic conditions. © 2024 The Authors

关键词： Biopeptides FAS HMG-CoAR molecular docking PL

来源：评论

学校读者我要写书评

暂无评论

Highly stable hybrid single-micelle:A universal nanocarrier for hydrophobic bioimaging agents

引用

Nano Research 2022年第5期15卷 4582-4589页

作者： Qiaoyu Zhou Tiancong Zhao Mengli Liu Dongrui Yin Minchao Liu Ahmed AElzatahry Fan Zhang Dongyuan Zhao Xiaomin Li Department of Chemistry State Key Laboratory of Molecular Engineering of PolymersiChemShanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200433China Materials Science and Technology Program College of Arts and SciencesQatar UniversityPO Box 2713DohaQatar

As the first-line technology,micelles play a pivotal role in in vivo delivery of theranostic agents because of their high biocompatibility and ***,in complex physiological environments(extreme dilution,pH,and oxidation or reduction,etc.),they generally suffer from structural instability and insufficient protection for encapsulated *** is urgent to reinforce the structural stability of the micelles at the single-micelle *** using the FDA-approved Pluronic F127 surfactants and indocyanine green(ICG)bioimaging agents as model,herein,we propose the silane-crosslinking assisted strategy to reinforce the structural stability of the *** from the traditional silane hydrolysis under the harsh experimental conditions(acidic,alkaline,and high temperature hydrothermal,etc.),the ICG loaded F127@SiO_(2) hybrid single-micelles(ICG@H-micelles)with controllable sizes(15-35 nm)are synthesized at neutral pH and room temperature,which is crucial for the maintenance of the physicochemical properties of the encapsulated *** the ultra-thin SiO_(2)(<5 nm)at hydrophilic layer of the single-micelle,the structural and fluorescence stability of ICG@H-micelles are much higher than the conventional micelle(ICG@micelles)in the simulated physiological environments of dilution,oxidation or reduction,and low *** of the high structural and fluorescence stability,the ICG@H-micelles also exhibit longer duration time in the tumor and gastrointestinal tract bioimaging.

关键词： micelle SiO_(2) inorganic-organic hybrid mesoporous material bioimaging

来源：评论

学校读者我要写书评

暂无评论

IS607 TnpB is a hypercompact RNA-guided DNA endonuclease

引用

细胞研究（英文版） 2024年第7期34卷 473-474页

作者： Hui Yang Dinshaw J.Patel Key Laboratory of RNA Innovation Science and EngineeringShanghai Institute of Biochemistry and Cell BiologyCenter for Excellence in Molecular Cell ScienceChinese Academy of SciencesUniversity of Chinese Academy of SciencesShanghaiChina Structural Biology Program Memorial Sloan-Kettering Cancer CenterNew YorkNYUSA

The Zhiwei Huang lab report on a hypercompact IS607 TnpB protein that naturally co-occurs with the conserved RAGATH-18 RNA,thereby identifying a new family of compact RNA-guided DNA *** an IS607 TnpB-based approach for programmable genome editing in both Escher-ichia coli and human cells,combined with its structural and target-adjacent motif divergence from earlier reported IS200/IS605 TnpB systems,highlights the diversity of the non-Cas genome editor toolbox.

关键词： endonuclease hypercompact rna-guided tnpb

来源：评论

学校读者我要写书评

暂无评论

Matrix confinement modulates 3D spheroid sorting and burst-like collective migration

引用

Acta Biomaterialia 2024年 179卷 192-206页

作者： Cai, Grace Li, Xinzhi Lin, Shan-Shan Chen, Samuel J. Rodgers, Nicole C. Koning, Katherine M. Bi, Dapeng Liu, Allen P. Applied Physics Program University of Michigan Ann ArborMI United States Department of Physics Carnegie Mellon University PittsburghPA United States Institute of Molecular Medicine College of Medicine National Taiwan University Taipei Taiwan Department of Mechanical Engineering University of Michigan Ann ArborMI United States Cellular and Molecular Biology Program University of Michigan Ann ArborMI United States Department of Physics Northeastern University BostonMA United States Department of Biomedical Engineering University of Michigan Ann ArborMI United States Department of Biophysics University of Michigan Ann ArborMI United States

While it is known that cells with differential adhesion tend to segregate and preferentially sort, the physical forces governing sorting and invasion in heterogeneous tumors remain poorly understood. To investigate this, we tune matrix confinement, mimicking changes in the stiffness and confinement of the tumor microenvironment, to explore how physical confinement influences individual and collective cell migration in 3D spheroids. High levels of confinement lead to cell sorting while reducing matrix confinement triggers the collective fluidization of cell motion. Cell sorting, which depends on cell-cell adhesion, is crucial to this phenomenon. Burst-like migration does not occur for spheroids that have not undergone sorting, regardless of the degree of matrix confinement. Using computational Self-Propelled Voronoi modeling, we show that spheroid sorting and invasion into the matrix depend on the balance between cell-generated forces and matrix resistance. The findings support a model where matrix confinement modulates 3D spheroid sorting and unjamming in an adhesion-dependent manner, providing insights into the mechanisms of cell sorting and migration in the primary tumor and toward distant metastatic sites. Statement of significance: The mechanical properties of the tumor microenvironment significantly influence cancer cell migration within the primary tumor, yet how these properties affect intercellular interactions in heterogeneous tumors is not well understood. By utilizing calcium and calcium chelators, we dynamically alter collagen-alginate hydrogel stiffness and investigate tumor cell behavior within co-culture spheroids in response to varying degrees of matrix confinement. High confinement is found to trigger cell sorting while reducing confinement for sorted spheroids facilitates collective cell invasion. Notably, without prior sorting, spheroids do not exhibit burst-like migration, regardless of confinement levels. This work establishes that matrix confin

关键词： Tumors

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：