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Electrical stimulation for brighter persistent luminescence

Light(Science & Applications) 2024年第8期13卷 1590-1601页

作者： Xilin Ma Yuhua Wang Takatoshi Seto Key Laboratory for Special Function Materials and Structural Design of the Ministry of Education National&Local Joint Engineering Laboratory for Optical Conversion Materials and Technology of National Development and Reform CommissionDepartment of Materials ScienceSchool of Materials and EnergyLanzhou UniversityNo.222South Tianshui RoadLanzhouGansu 730000China

An immature understanding of the mechanisms of persistent luminescence(PersL)has hindered the development of new persistent luminescent materials(PersLMs)with increased *** this regard,in-situ direct current(DC)electric field measurements were conducted on a layered structure composed of the SrAl_(2)O_(4):Eu^(2+),Dy^(3+)phosphor,and an *** this study,the photoluminescence(PL)and afterglow properties were investigated with respect to voltage by analyzing the current signal and thermoluminescence(TL)*** intensity of PersL increased due to a novel phenomenon known as“external electric field stimulated enhancement of initial brightness of afterglow”.This dynamic process was illustrated via the use of a rate equation approach,where the electrons trapped by the ultra-shallow trap at 0.022 eV could be transferred through the conduction band during long *** afterglow intensity could reach 0.538 cdm^(-2)at a 6 V electric *** design of an electric field stimulation technique enables the enhancement of the intensity of PersLMs and provides a new perspective for exploring the fundamental mechanics of certain established PersLMs.

关键词： spectroscopy luminescence conduction

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16.48% Efficient solution-processed CIGS solar cells with crystal growth and defects engineering enabled by Ag doping strategy

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Journal of Energy Chemistry 2025年第1期100卷 59-65页

作者： Mengyu Xu Shaocong Yan Ting Liang Jia Jia Shengjie Yuan Dongxing Kou Zhengji Zhou Wenhui Zhou Yafang Qi Yuena Meng Litao Han Sixin Wu Key Laboratory for Special Functional Materials of MOE National&Local Joint Engineering Research Centre for High-efficiency Display and Lighting TechnologySchool of Nanoscience and Materials EngineeringHenan UniversityKaifeng 475004HenanChina

Solution-processed Cu(In,Ga)Se_(2)(CIGS) solar cells suffer from serious carrier recombination and power conversion efficiency(PCE) loss because of the poor film properties and easy formation of ***, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage(VOC) of 662 m V and fill factor(FF) of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.

关键词： CIGS solarcells Solution-processedmethod Ag doping Crystal growth Defects engineering

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从电负性角度选择Cu^(2+)插层:提高水系锌离子电池δ-MnO_(2)正极材料的循环稳定性和倍率性能

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Science China materials 2023年第2期66卷 531-540页

作者：刘振华刘彦鹏张亚男刘晓莉闫德黄娟娟彭尚龙 National&Local Joint Engineering Laboratory for Optical Conversion Materials and Technology School of Materials&EnergyLanzhou UniversityLanzhou 730000China

离子插层已成为提高δ-MnO_(2)作为水系锌离子电池正极材料的循环稳定性和倍率性能的有效策略,但在实践中离子的选择似乎相当随意.本工作选择Cu^(2+)插层δ-MnO_(2),因为Cu^(2+)和Zn^(2+)具有相似的直径,但Cu^(2+)的电负性(1.359)略高于... 详细信息

离子插层已成为提高δ-MnO_(2)作为水系锌离子电池正极材料的循环稳定性和倍率性能的有效策略,但在实践中离子的选择似乎相当随意.本工作选择Cu^(2+)插层δ-MnO_(2),因为Cu^(2+)和Zn^(2+)具有相似的直径,但Cu^(2+)的电负性(1.359)略高于Zn^(2+)(1.347).因此,Cu^(2+)与MnO_(2)晶格具有更强的相互作用,并且在Zn^(2+)和H+的嵌入/脱出循环期间可保持稳定.Cu掺杂的δ-MnO_(2)(CMO)生成了Cu–O键,其电化学性能得到了较大的改善.在2 A g^(-1)的高电流密度下循环600次后,CMO表现出出色的循环稳定性和100%的容量保持率,而原始δ-MnO_(2)的容量保持率仅为23%.当电流密度从0.2增加到2.0 A g^(-1)时,CMO还表现出优异的倍率性能,容量保持率为72%,远高于原始δ-MnO_(2)(32%).由于Cu^(2+)比Zn^(2+)具有更大的电负性,因此Cu–O键作为稳定的“结构之柱”提高了CMO的循环稳定性.Cu^(2+)掺杂还提高了CMO的电子电导率和离子电导率,降低了H+和Zn^(2+)在电极/电解质界面的电荷转移电阻,从而提高了其倍率性能.这项工作为使用插层策略提高电池电化学性能提供了新的见解.

关键词：倍率性能正极材料锌离子电池循环稳定性离子电导率电子电导率电化学性能电负性

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Complementary multicolor electrochromic devices with excellent stability based on porous tin oxide nanosheet scaffold

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Nano Research 2024年第4期17卷 3035-3042页

作者： Chenchen Bian Jinhui Wang Huanhuan Liu Yin Yan Ping Zhang Weilong Yang Sensen Jia Xiaodan Guo Guofa Cai Key Laboratory for Special Functional Materials of Ministry of Education National&Local Joint Engineering Research Center for High-Efficiency Display and Lighting TechnologySchool of Materials and Engineeringand Collaborative Innovation Center of Nano Functional Materials and ApplicationsHenan UniversityKaifeng 475004China

Electrochromic devices(ECDs)have been extensively investigated as promising candidates in broad cutting-edge applications,such as smart windows,electronic labels,adaptive camouflage,***,they have suffered from either inadequate color variations or poor cycling stability for a long ***,we developed a general strategy to boost the cyclic stability and enrich the color variations of ECDs by scrupulous design of the composition and nanostructure of electrodes,in which porous tin oxide(SnO_(2))nanosheets serve as the scaffold and typical metal oxides or conducting polymers as the active electrochromic *** electrochromic composite materials,including polyaniline(PANI)@SnO_(2),V2O5@SnO_(2),and WO_(3)@SnO_(2) heterostructured nanoarrays were prepared by the facile wet-chemical *** composite electrodes exhibit remarkable electrochromic performances,e.g.,superior cycling stability(more than 2000 cycles),rich color variations(more than 5 colors for PANI@SnO_(2)),and enlarged optical *** excellent performances account for the heterogenous porous nanoarrays,which not only facilitate the intercalation/extraction of ions but also relieve the stress generated during the electrochemical *** addition,diverse prototypes of complementary multicolor ECD with excellent cycling stability(over thousands of cycles)and rich color variations(8 colors)were realized for the first *** believe that our work put forward a general strategy for developing high-quality multicolor complementary electrochromic devices.

关键词： electrochromism tin oxide metal oxide cycling stability multicolor complementary device

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Impact of oxygen incorporation on interface optimization and defect suppression for efficiency enhancement in Cu_(2)ZnSn(S,Se)_(4)solar cells

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Journal of Energy Chemistry 2024年第8期95卷 77-85,I0003页

作者： Shicheng Deng Songfan Wang Yuanyuan Wang Qian Xiao Yuena Meng Dongxing Kou Wenhui Zhou Zhengji Zhou Zhi Zheng Sixin Wu Key Laboratory for Special Functional Materials of MOE National&Local Joint Engineering Research Centre for High-efficiency Display and Lighting TechnologySchool of MaterialsHenan UniversityKaifeng 475004HenanChina Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province Institute of Surface Micro and Nano MaterialsCollege of Chemical and Materials EngineeringXuchang UniversityXuchang 461000HenanChina

Kesterite Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)solar cells suffer from severe carrier recombination,limiting the photovoltaic *** energy band alignment at the p-n junction and defective front interface are two main ***,oxygen incorporation in CZTSSe via absorber air-annealing was developed as a strategy to optimize its surface photoelectric property and reduce the *** optimized oxygen incorporation conditions,the carrier separation and collection behavior at the front interface of the device is *** particular,it is found that oxygen incorporated absorber exhibits increased band bending,larger depletion region width,and suppressed absorber *** indicate the dynamic factors for carrier separation become ***,the increased potential difference between grain boundaries and intra grains combined with the decreased concentration of interface deep level defect in the absorber provide a better path for carrier *** a consequence,the champion efficiency of CZTSSe solar cells has been improved from 9.74%to 12.04%with significantly improved open-circuit voltage after optimized air-annealing *** work provides a new insight for interface engineering to improve the photoelectric conversion efficiency of CZTSSe devices.

关键词： Kesterite Thin film solar cell Interface optimization Surface oxidation Defect suppression

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NiCo_(2)S_(4)/N microspheres grown on N,S co-doped reduced graphene oxide as an efficient bifunctional electrocatalyst for overall water splitting in alkaline and neutral pH

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Nano Research 2022年第2期15卷 950-958页

作者： Haoquan Li Long Chen Pengfei Jin Yafei Li Jianxiang Pang Juan Hou Shanglong Peng Gang Wang Yulin Shi Key Laboratory for Green Process of Chemical Engineering of Xinjiang Bingtuan School of Chemistry and Chemical EngineeringShihezi UniversityShihezi 832003China National&Local Joint Engineering Laboratory for Optical Conversion Materials and Technology School of Physical Science and TechnologyLanzhou UniversityLanzhou 730000China

It is of vital importance to design efficient and low-cost bifunctional catalysts for the electrochemical water splitting under alkaline and neutral pH *** this work,we report an efficient and stable NiCo_(2)S_(4)/N,S co-doped reduced graphene oxide(NCS/NS-rGO)electrocatalyst for water splitting,in which NCS microspheres are composed of one-dimentional(1D)nanorods grown homogeneously on the surface of NS-rGOs).The synergetic effect,abundant active sites,and hybridization of NCS/NS-rGO endow their outstanding electrocatalytic performance for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in both alkaline and neutral ***,NCS/NS-rGO employed as both anode and cathode in a two-electrode alkaline and neutral system electrolyzers deliver 10 mA/cm^(2) with the low cell voltage of 1.58 V in alkaline and 1.91 V in neutral *** results illustrate the rational design of carbon-supported nickel-cobalt based bifunctional materials for practical water splitting over a wide pH range.

关键词： wide pH range bifunctional electrocatalyst overall water splitting NiCo_(2)S_(4)/N Sco-doped reduced graphene oxide(NCS/NS-rGO)

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Mn,N co-doped Co nanoparticles/porous carbon as air cathode for highly efficient rechargeable Zn-air batteries Hide Author's Information

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Nano Research 2022年第3期15卷 1942-1948页

作者： Hanzhen Zheng Fei Ma Hongcen Yang Xiaogang Wu Rui Wang Dali Jia Zhixia Wang Niandi Lu Fen Ran Shanglong Peng National&Local Joint Engineering Laboratory for Optical Conversion Materials and Technology School of Physical Science and TechnologyLanzhou UniversityLanzhou 730000China State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals School of Material Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

Oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)are generally catalyzed by precious metals(Pt)and metal oxides(IrO_(2))which still have many shortages including expensive price,poor selectivity and undesirable *** this work,we report a Mn0-doped CoN_(x) on N-doped porous carbon(Mn-CoN_(x)/N-PC)composite from carbonizing metal-organic framework(MOF)derivative as the dual-functional catalyst to boost both the ORR and OER *** to the strong coordination effect between nitrogen and metal elements,the introduction of N can obviously improve the content of Co-N-C active sites for ***,the Mn-doping significantly regulates the electronic structure of the Co element and increases the content of Co^(0) which provide efficient OER active ***-CoN_(x)/N-PC catalyst delivers super dual-functional activity with a half-wave potential of 0.85 V,better than the 20%Pt/C catalyst(0.82 V).When used in Zn-air batteries for testing,Mn-CoN_(x)/N-PC electrocatalyst shows a high power density(145 mW·cm^(−2))and good cycle performance.

关键词： bifunctional electrocatalysts Co-N-C Mn-doped Zn-air batteries

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Sb^(3+)and Sm^(3+)co-doped lead-free Cs_(2)NaInCl_(6)double perovskite nanocrystals for single-component cold white emitter

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Journal of Rare Earths 2024年第9期42卷 1646-1651,I0001页

作者： Biao Zhou Xiangtong Zhang Ranran Hu Ruixue Hou William W.Yu Key Laboratory for Special Functional Materials of Ministry of Education National&Local Joint Engineering Research Centre for High-Efficiency Display and Lighting TechnologySchool of Materials and EngineeringCollaborative Innovation Centre of Nano Functional Materials and ApplicationsHenan UniversityKaifeng475000China School of Chemistry and Chemical Engineering Shandong UniversityJinan250100China

Metal halide perovskites exhibit promising prospect in light-emitting diodes,solar cells,photodetectors and ***,the workhorse of metal halide perovskites relies on toxicity lead element,which severely damages human body and *** lead-free perovskites,Cs_(2)NaInCl_(6)double perovskite is one of the most promising candidates because of its great stability and easy synthesis,but suffers inadequate optical ***,we doped Sb^(3+)and Sm^(3+)into Cs_(2)NaInCl_(6)nanocrystals by a hot injection ***_(2)NaInCl_(6):Sb^(3+)exhibits blue emission at 447 ***_(2)NaInCl_(6):Sm^(3+),Sb^(3+)nanocrystals simultaneously generate the blue emission of Sb^(3+)and the multiple emissions of Sm^(3+)at 565,602,650 and 710 *** the increase of Sm^(3+)feed ratio,the emission color of Cs_(2)NaInCl_(6):Sm^(3+),Sb^(3+)gradually moves to cold white region at(0.27,0.28)in CIE chromaticity diagram and correlated color temperature of 11840 *** work shows the potential application of Cs_(2)NaInCl_(6):Sm^(3+),Sb^(3+)nanocrystals as a single-component cold white emitter.

关键词： Lead-free Double perovskites Single component White emitter Doping Rare earths

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Synthesis of MXene and its application for zinc-ion storage

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SusMat 2022年第3期2卷 293-318页

作者： Jie Chen Yubin Ding De Yan Juanjuan Huang Shanglong Peng National and Local Joint Engineering Laboratory for Optical Conversion Materials and Technology School of Materials and EnergyLanzhou UniversityLanzhouP.R.China

Since 2020,some new breakthroughs in the field of MXene synthesis scheme such as water-free etching,HCl-based hydrothermal etching,halogen etching,and other novel synthesis methods have been *** only that,the application of MXene in zinc-ion storage devices has also made great progress in the past 2 *** understanding of zinc-ion storage mechanism of MXene has undergone profound changes,and its applications have also become diversified,demonstrating the great potential of MXene for high performance zinc-ion storage *** this review,we have summarized the preparation and synthesis of MXene materials and systematically investigated the progress of MXene in aqueous zinc-ion storage *** particular,for the synthesis of MXene,we added recent reports of conventional synthesis schemes that have been widely reported to help understand their development and combined with recent novel synthesis schemes to provide a distinct partition *** addition,for the application of MXene,we discussed the cognitive change of zinc-ion storage mechanism of MXene and conducted an in-depth discussion about the design philosophy of MXene and their ***,a comprehensive perspective on the future development of MXene in the synthetic strategy and aqueous zinc-ion storage applications have been outlined.

关键词： electrochemical energy storage MXene MXene-based materials zinc-ion batteries zinc-ion capacitors

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Hierarchical porous yolk-shell Co-N-C nanocatalysts encaged in graphene nanopockets for high-performance Zn-air battery

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Nano Research 2023年第7期16卷 8893-8901页

作者： Yisi Liu Zongxu Li Shizhu Wang Jinnan Xuan Dongbin Xiong Lina Zhou Jianqing Zhou Jun Wang Yahui Yang Yue Du Institute for Advanced Materials Hubei Normal UniversityHuangshi 435002China Jiangsu Key Laboratory of Materials and Technology for Energy Conversion College of Material Science and EngineeringNanjing University of Aeronautics and AstronauticsNanjing 210016China National&Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical EngineeringHunan Normal UniversityChangsha 410081China

The rational design and preparation of promising cathode electrocatalysts with excellent activity and strong stability for metal-air batteries is a huge *** this work,we innovate an approach of combining solvothermal with high-temperature pyrolysis utilizing zeolitic imidazolate framework(ZIF)-8 and ZIF-67 as the template to synthesize a novel hybrid material of hierarchical porous yolk-shell Co-N-C polyhedron nanocatalysts engaged in graphene nanopocket(yolk-shell Co-N-C@GNP).The obtained catalyst exhibits prominent bifunctional electrocatalytic performance for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)in the alkaline condition,in which the half-wave potential is 0.86 V for ORR,and the over-potential for OER is 0.42 V at 10 mA·cm^(-2).The rechargeable aqueous Zn-air battery fabricated with yolk-shell Co-N-C@GNP cathode deliveries an open circuit voltage(OCV)of 1.60 V,a peak power density of 236.2 mW·cm^(-2),and excellent cycling stability over 94 h at 5 mA·cm^(-2).The quasi-solid-state Zn-air battery(ZAB)using yolk-shell Co-N-C@GNP displays a high OCV of 1.40 V and a small voltage gap of 0.88 V in continuous cycling tests at 2 mA·cm^(-2).This work provides a valuable thought to focus attention on the design of high-efficient bifunctional catalysts with hierarchical porous yolk-shell framework and high-density metal active sites for metal-air battery technologies.

关键词： zeolitic imidazolate framework(ZIF)-67@ZIF-8 yolk-shell graphene nanopocket Bi-functional catalysts Zn-air battery

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