检索结果-内蒙古大学图书馆

Electrochemical evolution of a metal oxyhydroxide surface on two-dimensional layered metal phosphorus trisulfides enables the oxidation of amine to nitrile

引用

Carbon Energy 2025年第3期7卷 133-147页

作者： Binglan Wu Karim Harrath Marshet Getaye Sendeku Tofik Ahmed Shifa Yuxin Huang Jing Tai Fekadu Tsegaye Dajan Kassa Belay Ibrahim Xueying Zhan Zhenxing Wang Elisa Moretti Ying Yang Fengmei Wang Alberto Vomiero State Key Laboratory of Chemical Resource Engineering College of ChemistryBeijing University of Chemical TechnologyBeijingChina CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology(NCNST)BeijingChina Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of EducationCollege of Chemistry&Materials ScienceNorthwest UniversityXi'anChina State Key Laboratory of Multiphase Flow in Power Engineering International Research Center for Renewable EnergyXi'an Jiaotong UniversityShaanxiChina Fundamental Science Center of Rare Earths Ganjiang Innovation AcademyChinese Academy of ScienceGanzhouChina Ocean Hydrogen Energy R&D Center Research Institute of Tsinghua University in ShenzhenShenzhenChina Department of Molecular Sciences and Nanosystems Ca'Foscari University of VeniceVenezia MestreItaly Testing and Analysis Center Institute of Chemistry Chinese Academy of SciencesBeijingChina Department of Engineering Sciences and Mathematics Division of Materials ScienceLuleåUniversity of TechnologyLuleåSweden

Selective oxidation of amines to imines through electrocatalysis is an attractive and efficient way for the chemical industry to produce nitrile compounds,but it is limited by the difficulty of designing efficient catalysts and lack of understanding the mechanism of ***,we demonstrate a novel strategy by generation of oxyhydroxide layers on two-dimensional iron-doped layered nickel phosphorus trisulfides(Ni1-xFexPS_(3))during the oxidation of benzylamine(BA).In-depth structural and surface chemical characterizations during the electrocatalytic process combined with theoretical calculations reveal that Ni(1-x)FexPS_(3) undergoes surface reconstruction under alkaline conditions to form the metal oxyhydroxide/phosphorus trichalcogenide(NiFeOOH/Ni1-xFexPS_(3))***,the generated heterointerface facilitates BA oxidation with a low onset potential of 1.39 V and Faradaic efficiency of 53%for benzonitrile(BN)*** calculations further indicate that the as-formed NiFeOOH/Ni1-xFexPS_(3) heterostructure could offer optimum free energy for BA adsorption and BN desorption,resulting in promising BN synthesis.

关键词： 2D layered materials benzylamine oxidation metal phosphorus trichalcogenides surfacereconstructed heterostructure

来源：评论

学校读者我要写书评

暂无评论

Experimental study on combustion, ash fusibility and slagging propensity during co-combustion of organic solid waste and lignite

引用

Journal of the Energy Institute 2023年 106卷

作者： Liu, Hu Wang, Yancheng Xue, Jingwen Zhang, Yankang Yu, Pengfei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an 710049 China

Rapidly growth of organic solid waste (OSW) has caused serious social and environmental problems. Incineration as one of the most good public acceptance and environmentally friendly method attains increasing attention. In this study, the co-combustion characteristics of OSW and lignite, including the ignition and burnout temperature, ash melting and slagging propensity were studied. The experimental results show that the ignition temperature almost remains stable while the burnout temperature of the blends decreases as the increase of the OSW blending ratio, since the heat release during volatile combustion is beneficial for the burnout of coal char, but the polymer may melt and block the pores of the coal char at high temperature when the OSW blending ratio is higher than 30%. Besides, the slagging propensity of blending fuel is severe when the OSW blending ratio is 30%, and special attention should be paid to avoid slagging during the combustion process. © 2022 Energy Institute

关键词： Lignite

来源：评论

学校读者我要写书评

暂无评论

A volume of fluid simulation of the steady deformation and the drag of a single droplet in a flowing gas

引用

Journal of Hydrodynamics 2021年第2期33卷 334-346页

作者： Zhi-bin Wang Zhong-wei Yang Lie-jin Guo Ren-jie Zhao State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChendu 610500China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

A method is proposed to investigate the steady deformation and the drag of a single droplet in a flowing gas at a high Reynolds *** volume of fluid(VOF)method is used to model the droplet surface *** direct numerical simulation(DNS)method is used to model the gas flow *** order to avoid the effect of the droplet acceleration on the drag and reduce the computation cost,a body force is added to the droplet to make it fixed at a constant *** body force is determined by using the Newton iteration *** simulated droplet aspect ratio and the drag coefficient agree well with the published experimental ***,the sources of the drag are analyzed and the effect of the Reynolds number and the Weber numbers on the droplet deformation and the drag are *** drag mainly comes from the pressure difference between the droplet-leading zone and the trailing zone,and the turbulence wake would increase the drag.

关键词： Droplet deformation steady drag volume of fluid(VOF) turbulent flow drag force

来源：评论

学校读者我要写书评

暂无评论

Analysis of Different Control Strategies Considering Individual Regulation of Heat User 3

Analysis of Different Control Strategies Considering Individ...

引用

3rd International Conference on Electrical engineering and Mechatronics Technology, ICEEMT 2023

作者： Xun, Zhiwei Wang, Huijie Wang, Liyuan Yang, Long Gao, Yunfang Liu, Ming Guoneng Jinjie Energy Co. Ltd Yulin China Xi'an Jiaotong University Xi'an China Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an China

ISBN: (纸本)9798350303698

In the process of outdoor temperature change, it is beneficial to improve the comfort of thermal users to formulate adjustment and control strategies according to the actual needs of each user. In this paper, different adjustment modes are established according to the thermal comfort of users, and the control strategies of rising and cooling within 0, 30 and 60 minutes are proposed, and the indoor temperature control effect and heating energy consumption of each adjustment mode under different control strategies are analyzed. The results show that: in different modes, when the rise and cooling time increase, compared with the design room temperature, the indoor temperature difference under the control mode is smaller, but the time needed to reach stability is longer. At the same time, the total heat load is unchanged, but the total pump work decreases. © 2023 IEEE.

关键词： Energy utilization

来源：评论

学校读者我要写书评

暂无评论

Chalcogen heteroatoms doped nickel-nitrogen-carbon single-atom catalysts with asymmetric coordination for efficient electrochemical CO_(2) reduction

引用

Chinese Journal of Catalysis 2024年第9期64卷 54-65页

作者： Jialin Wang Kaini Zhang Ta Thi Thuy Ng Yiqing Wang Yuchuan Shi Daixing Wei Chung-Li Dong Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049ShaanxiChina Department of Physics Tamkang UniversityNew Taipei City 25137TaiwanChina

The electronic configuration of central metal atoms in single-atom catalysts(SACs)is pivotal in electrochemical CO_(2) reduction reaction(eCO_(2)RR).Herein,chalcogen heteroatoms(e.g.,S,Se,and Te)were incorporated into the symmetric nickel-nitrogen-carbon(Ni-N_(4)-C)configuration to obtain Ni-X-N_(3)-C(X:S,Se,and Te)SACs with asymmetric coordination presented for central Ni *** these obtained Ni-X-N_(3)-C(X:S,Se,and Te)SACs,Ni-Se-N_(3)-C exhibited superior eCO_(2)RR activity,with CO selectivity reaching~98% at-0.70 V versus reversible hydrogen electrode(RHE).The Zn-CO_(2) battery integrated with Ni-Se-N_(3)-C as cathode and Zn foil as anode achieved a peak power density of 1.82 mW cm^(-2) and maintained remarkable rechargeable stability over 20 ***-situ spectral investigations and theoretical calculations demonstrated that the chalcogen heteroatoms doped into the Ni-N_(4)-C configuration would break coordination symmetry and trigger charge redistribution,and then regulate the intermediate behaviors and thermodynamic reaction pathways for eCO_(2)***,for Ni-Se-N_(3)-C,the introduced Se atoms could significantly raise the d-band center of central Ni atoms and thus remarkably lower the energy barrier for the rate-determining step of ^(*)COOH formation,contributing to the promising eCO_(2)RR performance for high selectivity CO production by competing with hydrogen evolution reaction.

关键词： Electrochemical CO_(2) reduction reaction Chalcogen heteroatoms Single-atom catalysts Asymmetric coordination CO production

来源：评论

学校读者我要写书评

暂无评论

Flocculation of suspended cohesive particles in Rayleigh-Bénard turbulence

引用

Physical Review Fluids 2025年第2期10卷 024305-024305页

作者： Han Huang Shuaiqi Zhao Rui Zhang Binbin Pei Kunpeng Zhao Bofeng Bai State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Key Laboratory of Mechanics on Disaster and Environment in Western China The Ministry of Education of China Lanzhou University Lanzhou 730000 China

We employ a four-way coupled numerical approach to investigate the dynamics of suspended cohesive particles in Rayleigh-Bénard turbulence. The Stokes drag, cohesive, and direct contact forces between primary particles are captured in detail, yielding the phenomena of flocs' aggregation, breakage, and deformation. The momentum and thermal exchange between primary particles and the fluid are considered based on the Source-in-Cell method. We found that the initial increase of the average floc size indicates a temporary flocculation phase, which is followed by an equilibrium phase where the average floc size becomes stable, reflecting the balance between aggregation and breakage. Different from the traditional perspective, which attributed the local accumulation of particles to their gravity, we found that the suspended particles still tend to accumulate in the bottom hot boundary layer region. This accumulation is primarily driven by the temperature-induced variation in aggregation strength and the nonuniform spatial distribution of floc inertia. Additionally, the stronger cohesion yields a reduction in momentum intensity of the thermal plumes, primarily due to the more pronounced weakening of fluid momentum by the larger flocs.

关键词： Momentum

来源：评论

学校读者我要写书评

暂无评论

Experimental and modeling investigation of zero net liquid flow in hilly terrain pipeline

引用

Petroleum Science 2025年第5期22卷 2183-2202页

作者： Huang, Bo Xu, Qiang Chang, Ying-Jie Cao, Ye-Qi Yu, Hai-Yang Li, Yu-Wen Guo, Lie-Jin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'an710049 China College of Petroleum Engineering Xi'an Shiyou University Shaanxi 710065 China

Hilly terrain pipeline is a common form of pipeline in oil and gas storage and transportation industry. Due to the hilly terrain influence, the liquid at the elbow of the gathering pipeline is easy to flow back and accumulate to form slug flow, so it is necessary to remove the accumulated liquid by gas purging. In this paper, experiment is carried out in hilly terrain pipelines. Three flow patterns of stratified flow, slug flow and stratified entrained flow are observed. The process of gas purging accumulated liquid is divided into four stages, namely liquid accumulation, liquid rising;continuous outflow and tail outflow. At the same time, the flow pattern maps of each stage are drawn. The pressure drop signal is analyzed in time domain and frequency domain, and the contour map of pressure drop distribution is drawn. It is found that the ratio of range to average value can well distinguish the occurrence range of each flow pattern. Based on visualization, the transition process of slug flow to stratified flow and stratified entrained flow is studied, and the transition boundary prediction model is established. An image processing method is proposed to convert the image signal into a similarity curve, and PSD analysis is performed to calculate the slug frequency. The normal distribution is used to fit the slug frequency, and the predicted correlation is in good agreement with the experimental data. © 2025 The Authors

关键词： Optical flows

来源：评论

学校读者我要写书评

暂无评论

Experimental study on the thermochemical reduction of supercritical CO2 by guaiacol

Experimental study on the thermochemical reduction of superc...

引用

International Multidisciplinary Conference on Computer and Energy Science (SpliTech)

作者： Yimeng Wei Jiadela Kuanibieke Hui Jin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University China

The continuous growth of CO 2 emissions is one of the global problems facing humanity, and how to convert and exploit the stock of CO 2 has become an urgent issue. Biomass as an activity of CO 2 thermal reduction medium has become the focus of human attention in general. Supercritical CO 2 (SCCO 2 ) has the advantages of near-liquid density and high solubility, which can further strengthen the reduction process (T≥31.26℃, P≥72.9 atm). This paper described a SCCO 2 reduction method of guaiacol on an intermittent Kettle Reactor to investigate the effects of reaction temperature (400-700℃), residence time (5-20 min) and reactant concentration (4 wt%-16wt%) on the three-phase products. The experimental results indicated that the carbon gasification efficiency (CE) and hydrogen gasification efficiency (HE) were 43.7% and 56.7%, respectively, when the carbon dioxide consumption reached 16.15 mol/kg. As the temperature increased, the consumption of carbon dioxide increased and the concentration of reactants increased with opposite results.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Numerical Simulation of flow Distribution and Transient Thermal Stratification Characteristics of Passive Residual Heat Removal Heat Exchangers

引用

Yuanzineng Kexue Jishu/Atomic Energy Science and Technology 2025年第5期59卷 1006-1015页

作者： He, Shaopeng Wang, Mingjun Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Nuclear Thermal-hydraulic Laboratory Xi’an Jiaotong University Xi’an710049 China

The passive residual heat removal heat exchanger (PRHR HX) is a key component of the third-generation advanced pressurized water reactor (PWR) nuclear power plant’s passive safety systems. The PRHR HX has numerous heat transfer tubes with varying lengths and arrangements on the primary side, leading to different flow distributions and resistance characteristics. The secondary side experiences various physical processes, including natural convection, mixed convection, and boiling heat transfer, significantly impacting the heat exchanger’s natural circulation and residual heat removal capacity. Current numerical analysis methods for PRHR HX inadequately consider flow distribution and resistance characteristics on the primary side. A porous medium-pipe-level coupling calculation method was established, introducing a parallel C-shaped pipe-level flow distribution and resistance iterative solution model. A matching strategy for grid control volumes on both sides and physical field communication was proposed, and a mathematical-physical model suitable for natural circulation and two-phase boiling conditions was developed for the PRHR HX, enabling coupling analysis between the primary side’s pipe-level resolution physical field and the secondary side’s porous medium computational domain. Based on data from Japan’s ROSA test facility, program validation was conducted, comparing heat transfer amounts, primary side outlet temperatures, and temperature profiles under single-phase and two-phase conditions, with good agreement between calculated and experimental values. flow distribution and resistance characteristics on the primary side under coupled conditions of the AP1000 reactor’s PRHR HX was explored. The variation of secondary side thermal stratification with different operational parameters was analyzed. Results indicate that when the total flow rate on the primary side increases, the proportion of frictional pressure drop in the total pressure drop increases, diminishin

关键词： Natural convection

来源：评论

学校读者我要写书评

暂无评论

Homojunction photocatalysts for water splitting

引用

Nano Research 2022年第12期15卷 10171-10184页

作者： Xiangjiu Guan Shichao Zong Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an710049China Suzhou Academy of Xi’an Jiaotong University Suzhou215123China Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region Ministry of EducationSchool of Water and EnvironmentChang’an UniversityXi’an710064China

Charge-carrier separation is regarded as one of the critical issues of photocatalytic water splitting and could be accelerated by constructing microscopic junctions in *** photocatalysts consisting of different forms of semiconductor with identical compositions could inherit the advantages of heterojunction-based photocatalysts in charge separation due to the built-in electric field,while omitting the potential drawbacks of interfacial lattice distortion by providing continuous band ***,homojunction-based photocatalysts have recently drawn growing attention in water *** this review,the synthetic approaches to preparing photocatalysts with various homojunction structures including p-n junction,phase junction,and facet junction were introduced,together with a comprehensive analysis and discussion on the latest progress in the application of photocatalytic water *** review work is expected to inspire more related work with promoted research on designing efficient homojunction-based photocatalytic systems for water splitting.

关键词： photocatalytic water splitting homojunction charge separation

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：