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Study on the Catalytic Performance of Nano-Mesoporous Cobalt-Based Catalysts for Glycerol Dry Reforming

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SSRN 2022年

作者： Dou, Binlin Wang, Yadong Zhang, Hua Wu, Kai Ren, Ruijia Chen, Haisheng Xu, Yujie School of Energy and Power Engineering Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China

Dry reforming is an efficient utilization technology that can convert CO 2 into high-value-added syngas. In this work, nano-mesoporous CeO 2 -supported Co-based catalysts were successfully prepared by the colloidal solution combustion method and used in glycerol dry reforming (GDR) experiments. The characterization results show that the prepared catalyst has a uniform mesoporous structure, and the Co-Fe-Ce catalyst has a higher specific surface area and stronger metal-support interaction than the Co-Ce catalyst. Thermodynamic analysis was conducted using a non-stoichiometric method methodology based on Gibbs free energy minimization. Catalytic experiments were carried out at 650°C to 800°C. The results showed that the Co-Fe-Ce catalyst exhibited higher activity and selectivity in the GDR reaction, and the glycerol conversion of 7CoFeCe at 750 °C reached 84.8%. The 10 h stability experiment shows that the Fe promoter has a positive effect on the stability of the catalyst. The TPO results indicate that Fe doping can suppress filamentous carbon formation. © 2022, The Authors. All rights reserved.

关键词： Catalyst activity

Heavy Oil Upgrading Using Naoh/Cuso4 Composite Catalyst in Aquathermolysis

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SSRN 2022年

作者： Zhou, Yantao Zhao, Qiuyang Miao, Yan Wang, Xuetao Zhang, Yanlong Wang, Yechun Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Xinjin Weihua Institute of Clean Energy Research Foshan528216 China

To obtain an inexpensive and efficient catalyst in the in-situ upgrading of heavy oil, the NaOH/CuSO4 composite catalyst was proposed in this work. Firstly, the experiments found the viscosity of heavy oil increased with addition of CuSO4 under 300°C in aquathermolysis. Then, the addition of NaOH was found to improve the catalyst capacity of CuSO4 significantly. The NaOH/CuSO4 decreased the viscosity by 81.43% under 300°C. The further analysis revealed the Cu atoms of CuSO4 enter into the heavy oil molecules to increase viscosity, and the NaOH inhabits the viscosity increasing reaction. Besides, the Cu and CuOx with a higher catalytic capacity produced with the addition of NaOH. These conclusions are helpful to understand the aquathermolysis upgrading mechanism and develop a type of inexpensive and efficient composite catalyst. © 2022, The Authors. All rights reserved.

关键词： Sulfur compounds

Multi-Objective Optimization Design of a Solar-powered Integrated Multi-Generation System Based On Combined Sco 2 Brayton Cycle and Orc Using Machine Learning Approach

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SSRN 2024年

作者： Zhang, Junyi Wang, Jiangfeng Liu, Wenxing Hu, Bin Lou, Juwei Zhao, Pan Institute of Turbomachinery State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China Nuclear Power Institute of China No. 328 Section 1 Changshun Avenue Sichuan Chengdu610213 China DongFang Electric Engineering& Consulting Co. Ltd 18 Xixin Avenue High-tech West Zone Sichuan Chengdu611731 China

With the rapid development of technology and the accelerated degradation of the global environment, there is an urgent need to find a clean and efficient energy solution to replace traditional fossil fuels for energy production. Additionally, this solution should also meet the growing demand for various energy products for energy user. In particular for remote areas such as islands, coastal regions and deserts which are far from the power grid, regular resources such as power, freshwater, and cooling are all scarce. Therefore, integrating freshwater and cooling subsystems into the power generation system to create a multi-generation system can facilitate achieving energy self-sufficiency in remote regions. This paper proposes an integrated multi-generation system powered by a solar power tower (SPT) according to the principle of cascading energy utilization, which includes a supercritical CO2 (SCO2) Brayton cycle, an Organic Rankine cycle (ORC), an ejector refrigeration cycle (ERC), and a reverse osmosis (RO) unit. A mathematical model is established to analyze the system performance from the perspectives of energy, exergy and economics. Different machine learning algorithms including back propagation neural network (BPNN), support vector regression (SVR), random forest (RF) are used to develop prediction models of the system performance. By comparing and analyzing the predictive performance of different machine learning models, the optimal machine learning model is obtained as a surrogate model for the thermodynamic model of the proposed system to accelerate the optimization process. The results show that the BPNN model demonstrates the highest predictive accuracy and the lowest relative error fluctuation, maintaining a relative error of less than 1% for over 97.5% of the data in the testing set. When comparing the multi-objective optimization results of the BPNN model with those of the thermodynamic model from multiple perspectives, it can be observed that the res

关键词： Neural network models

Hydrogen Production from Chemical Looping Steam Reforming of Biomass Waste Cooking Oil

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SSRN 2022年

作者： Zeng, Pingchao Dou, Binlin Zhang, Hua Wang, Yadong Wu, Kai Zhao, Longfei Chen, Haisheng Xu, Yujie School of Energy and Power Engineering Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China

For highly efficient transformation and utilization of waste cooking oil, a new method for hydrogen production by indirect and auto-thermal chemical looping steam reforming (CLSR) of waste cooking oil (WCO) was developed in this work. In conventional and direct CLSR using WCO at a temperature of 650 °C, gas production, hydrogen selectivity, and fuel conversion were low due to the insufficient amount of reducing Ni and heating. Thus, the reactor temperature was increased to 750 °C to pyrolyze enough reducing gas to reduce OCs. Although 84% WCO conversion and 88% hydrogen selectivity were obtained, the OCs deactivated at the last 15 minutes due to the high-temperature sintering of the reduced Ni particles. On this basis, a new type of indirect CLSR with high-temperature steam-assisted pyrolysis of WCO in a two-stages fixed-bed reactor with high stability was developed, which fitted WCO feeding and avoided OCs sintering. The experimental results show that about 90% WCO conversion and about 89% hydrogen selectivity were obtained in indirect CLSR, and the highest hydrogen yield and selectivity were obtained under the conditions of upper pyrolysis temperature of 800 ℃ with a lower CLSR temperature of 600 ℃ and S/C=4.12. In addition, the effect of in-situ CO 2 capture on indirect CLSR achieves the feasibility of hydrogen production and minus carbon emissions. The multiple cycles experiments of indirect CLSR obtained about 90% hydrogen selectivity and fuel conversion, close to 0 CH 4 selectivity, and 24%~26% steam conversion. © 2022, The Authors. All rights reserved.

关键词： Hydrogen production

Improvement and experimental study of scroll expander for organic rankine cycle

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Energy engineering: Journal of the Association of Energy engineering 2020年第4期117卷 225-235页

作者： Li, Lei Tao, Leren Gou, Yanan Zhang, Shan Zaozhuang University Zaozhuang277160 China University of Shanghai for Science and Technology Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093 China

The scroll expander used in organic Rankine cycle (ORC) system is improved, and its performance is analyzed experimentally. The modified profile and inlet hole of the scroll expander are enhanced, and the performance of the scroll expander before and after the improvement is analyzed. The results show that when the inlet pressure exceeds 0.7 MPa, the waist-shaped hole with a larger area is preferable. The scroll expander with a waist-shaped hole has a larger output power and wider optimal pressure range, and when the inlet pressure is 1.6 MPa, the maximum output power increases by 230 W. The output power and isentropic efficiency of the scroll expander can be improved by modifying the profile. When the inlet pressure is 1.6 MPa and the rotational speed is 1750 r/min, the maximum output power of the scroll expander is 1235 W, which is 120 W higher than that before the improvement. © 2020, Tech Science Press. All rights reserved.

关键词： Rankine cycle

Zif-8 Loaded Ag/Zno Electrospun Nanofibers Enabling High-Performance H2 Gas Sensing for Battery Safety Early Warning

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SSRN 2024年

作者： Wang, Ze Zhu, Lei Zhang, Jiaxin Wang, Jingzhao Cui, Xiangming Chen, Xin Liu, Wenbiao Ma, Hang Wang, Jianan Yan, Wei Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University 28 Xianning West Road Xi’an710049 China School of Physics and Electrical Engineering Weinan Normal University Chaoyang Street Weinan714099 China Center of Research & Development Yunnan Yuntianhua Co. LTD 1417 Dianchi Road Kunming650228 China

Safety issues triggered by battery thermal runaway have become the most crucial obstacle to the future development of the high-energy-density energy storage systems. As hydrogen (H2) will be inevitably generated along with heat release caused by the side reactions in the early stages of battery thermal runaway, rapid monitoring of trace H2 is considered as an effective measure enabling the battery safety early warning. Herein, to develop high-performance H2 sensing materials to monitor of low-concentration H2 leakage, ZIF-8 loaded Ag/ZnO electrospun nanofibers (ZAZ NFs) were designed by electrospinning and self-sacrificial template methods. Benefiting from all the enrichment and sieving effects of ZIF-8 shell, the catalytic and sensitization effects of Ag and abundant active sites provided by Ag and ZIF-8 loading, the ZAZ sensor enables ppb-level limit of detection toward H2, fast response (9 s), high selectivity and excellent humidity resistance (36.1 to 100 ppm H2 at 95% RH). Furthermore, this ZAZ sensor also enabled the safety early warning (67.79 s before battery bulge) for practical pouch lithium cells, highlighting its great application potential in future advanced battery safety management system. © 2024, The Authors. All rights reserved.

关键词： Organometallics

Under-Deposit Corrosion Behavior and Dynamic Deliquescence Properties of Ammonium Salts Covered on Pipelines and Components in a Crude Oil Distillation Column: Experimental and Theoretical Studies

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SSRN 2022年

作者： Li, Ruidong Chen, Jukai Wang, Yueshe State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi'An710049 China School of Chemical Engineering & Technology China University of Mining and Technology Xuzhou221116 China

Electrochemical experiments based on the interdigital electrodes of SAE 1020 steel and atomic simulation were performed to investigate the under-deposit corrosion behavior and dynamic deliquescence properties of ammonium salts. In-situ electrochemical measurements demonstrate that the deliquescence of ammonium salts affects the evolution of the interface, and the surface characterization results proved that the critical state of moisture absorption leads to the most severe corrosion. Additional ab initio molecular dynamics simulations suggest that the H transport chain impacted by the hydrolysis of NH4+ leads to a variation in the charge state of the system, which may triggering corrosion. © 2022, The Authors. All rights reserved.

关键词： Steel corrosion

Experimental study on potassium catalyzed gasification of large particle size biomass with CO2

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Journal of the Energy Institute 2023年 111卷

作者： Huang, Xiaole Li, Yuhang Ren, Jiyun Yang, KaiXuan Li, Ruiyu Bai, Yang Deng, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an710049 China Xi'an Thermal Power Research Institue Co. Ltd. Xi'an710032 China Shanghai Power Equipment Research Institute Co. Ltd. Shanghai 200240 China Shunde Institue of Inspection Guangdong Institue of Special Equipment Inspection and Research Foshan528300 China

Candlenut wood with large particle size is selected to investigate the biomass gasification catalyzed by potassium. The sample pore structure, the spatial distribution of potassium, and the effects of potassium salt species on the biomass gasification with CO2 are examined. The results show that the large particle candlenut wood exhibits obvious spatial anisotropy and that the pore structure is mainly distributed along the axial direction. Large particle candlenut wood has a more uniform distribution of potassium salts along the axial direction. Part of the potassium salt releases outward during the gasification, which reduces the potassium salt content in the sample center. The average potassium contents of sample loaded with KCl and biochar of sample loaded with KCl are 9.273% and 7.745%, respectively. The synthesis of polycyclic aromatic hydrocarbons in tar could be inhibited by potassium, which could also catalyze the gasification and methane removal reactions of biochar and facilitate the formation of CO and H2. Compared to raw sample (28.99%), the syngas yields from the gasification of sample loaded with KCl, sample loaded with K2CO3, and sample loaded with K2SO4 are 40.22%, 52.16%, and 41.72%, separately. The catalysis of potassium is closely related to its occupation of the active sites on biochar. The chemical bonds formed by potassium and biochar are repeatedly broken and formed during the gasification, which promotes the decomposition of organic matter. Compared with KCl and K2SO4, K2CO3 has a better catalytic effect. © 2023 Energy Institute

关键词： Biomass

Kinetic Characteristics of Passivation Behavior in OFP-Cu and OF-Cu

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SSRN 2024年

作者： Ning, Zhiyuan Wen, Du Zhou, Qulan Li, Na Macdonald, Digby D. State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Departments of Nuclear Engineering and Materials Science and Engineering University of California at Berkeley BerkeleyCA94720 United States Industrial Process and Energy Systems Engineering Ećole Polytechnique Fédérale de Lausanne EPFL SionCH-1951 Switzerland

This research presents a comprehensive comparative analysis of the passivation kinetics of OFP-Cu and OF-Cu in simulated repository electrolyte. The study employs a range of techniques, including potentiodynamic polarization, multi-step potentiostatic polarization, electrochemical impedance spectroscopy, and Mott-Schottky analysis, to explore the intricacies of corrosion behavior. The Point Defect Model (PDM) is used to interpret the steady-state physicochemical processes. Utilizing the results of PDM optimization, defect distribution diagrams within the passivation film were constructed, shedding light on the pivotal transition from p-type to n-type semiconductor properties of the film. The study concludes with an interpretation of the experimental data, highlighting the enhancement of copper's corrosion resistance due to phosphorus doping, as elucidated by the Solute-Vacancy Interaction Model. © 2024, The Authors. All rights reserved.

关键词： Copper corrosion