检索结果-内蒙古大学图书馆

Supercritical Water Gasification of Phenol with Metal Cations-A Way to Degrade Coal Industrial Wastewater and Metal-Contaminated Wastewater Simultaneously

SSRN

引用

SSRN 2022年

作者： Cao, Wen Wang, Shaoqi Ma, Lujing Liu, Shi Jin, Hui Wei, Wenwen Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xianning West Road Xi’an710049 China Suzhou Academy of Xi’an Jiaotong University No.99 Ren’ai Road Jiangsu Suzhou215123 China

Phenol is a representative compound in coal industrial wastewater. Metal cations are the main harmful components in the wastewater of the electroplating and dyeing industries. Supercritical water gasification (SCWG) of phenol with metal cations could provide a promising way to degrade coal chemical wastewater and metal-containing wastewater simultaneously. In this study, SCWG of phenol with Mg2+, Mn2+, and Ni2+ was carried out to investigate the effect of metal cations on gasification results. Results showed that gaseous product was mainly composed of H2, CO, CH4 and CO2, and CO2 was the dominant one. Prolonging residence time and increasing the concentration of metal cations significantly increased the gas yield of CO2 and carbon gasification efficiency. Higher concentrations of metal cations facilitated methane-reforming reaction and water-gas shift reaction. Metal cations promoted the generation of 1-Ethoxybutane by the ring-breaking reaction and prevented the polymerization reaction. The order of catalytic effect was ranked as Ni2+>Mn2+>Mg2+. Mg2+, Mn2+ and Ni2+ were finally transformed into the corresponding metal hydroxides and metal oxides which could be recycled for reutilization. NiO could be reduced into metallic Ni, which consumed the H2 but effectively catalyzed SCWG of phenol. © 2022, The Authors. All rights reserved.

关键词： Phenols

来源：评论

学校读者我要写书评

暂无评论

Unveiling the Unexpected C-C Dissociation Capacity and Intrinsic Mechanism of Undercoordinated Pd Cluster/Ceo2 for the Efficient and Stable Catalytic Mineralization of Propane

SSRN

引用

SSRN 2022年

作者： Xia, Lianghui Jian, Yanfei Wang, Jingjing Wang, Yao Chai, Shouning Liu, Yujie Li, Lu Yu, Yanke Albilali, Reem He, Chi State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Shaanxi Xi’an710049 China Department of Chemistry College of Science Imam Abdulrahman Bin Faisal University P.O. Box 1982 Dammam31441 Saudi Arabia National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing101408 China

Light alkanes extensively presented in industrial exhausts have led tremendous harm to the atmospheric environment and human health. However, their stable molecule structure and inferior adsorption and activation efficiency make them as one category of the most intractable pollutants to be efficient controlled. Herein, we developed a Pd single cluster/CeO2 catalyst (Pd/CeO2-SCC-R) by a scalable deposition precipitation strategy, which demonstrates unexpected activity (propane total destructed below 300 oC) and thermal stability (even dramatically treated at 800 oC for multiple cycles) attributed to the strong metal-support interaction (SMSI) and unsaturated Pd metal sites caused by the shorter Pd-O distance. Mechanism studies determine that the Pd/CeO2-SCC-R possesses highly-efficient C-C cleavage ability owing to the persistent formation of large amounts of oxygen vacancies and low-coordinated Pd species, and the addition of H2O intrinsically accelerates propane activation and intermediate mineralization attributed to suppression of by-products by OH species. In comparison, the Pd single atom/CeO2 catalyst is preferentially for C-H bonds cleavage and inactive for C-C bonds cracking due to the saturated Pd sites anchored to the oxygen of supports directly, which generates more non-oxidation by-products as propyne and propylene, inhibiting the continuous decomposition of propane due to the retardatory oxidation of pyruvate species. The present work sheds critical insight to the production of fulfilling products through the directional cleavage of C-C/C-H bonds in the activation of light alkane molecules. © 2022, The Authors. All rights reserved.

关键词： Oxygen vacancies

来源：评论

学校读者我要写书评

暂无评论

Evaluation of stability and catalytic activity of Ni catalysts for hydrogen production by biomass gasification in supercritical water

引用

Carbon Resources Conversion 2019年第1期2卷 95-101页

作者： Youjun Lu Hui Jin Rui Zhang State Key Laboratory of Multiphase Flow in Power Engineering(SKLMFPE) Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Supercritical water gasification is a promising technology for wet biomass *** this paper,Ni and other metal catalysts were synthesized by wet *** stability and catalytic activities of Ni catalysts were ***,catalytic activities of Ni,Fe,Cu catalysts supported on MgO were tested using wheat straw as raw material in a batch reactor at 723 K and water density of 0.07 cm^(3)/*** results showed that the order of metal catalyst activity for hydrogen generation was Ni/MgO>Fe/MgO>Cu/***,the influence of different supports on Ni catalysts performance was *** results showed that the order of the Ni catalysts’activity with different supports was Ni/MgO>Ni/ZnO>Ni/Al_(2)O_(3)>Ni/ZrO_(2).Finally,the effects of Ni loading and the amount of Ni catalyst addition on hydrogen production,and the stability of Ni/MgO catalyst were *** was found that serious deactivation of Ni catalyst in the process of supercritical water gasification took *** if carbon deposited on the catalyst surface was removed by high temperature calcination and the catalyst was reduced with hydrogen,the activity of used catalyst was only partially restored.

关键词： Ni catalyst Deactivation Biomass gasification Supercritical water Hydrogen production

来源：评论

学校读者我要写书评

暂无评论

flow visualization study of two-phase flashing spray with iso-pentane 14

Flow visualization study of two-phase flashing spray with is...

引用

14th International Conference on Liquid Atomization and Spray Systems, ICLASS 2018

作者： Wang, J.F. Zhou, Z.F. Yang, T. Chen, B. Wang, G.X. Zhao, L. State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China Department of Mechanical Engineering University of Akron AkronOH44325-3903 United States

The explosive flashing spray commonly occurs during the accidental release of flammable and toxic pressure-liquefied gases in chemical or nuclear industry. This work conducts a small-scale flashing spray experiment in house to simulate the accidental release, aiming to investigate the macroscopic atomization characteristics, which is helpful for the risk assessments and therefore minimizing the impact of the release hazard. The iso-pentane was taken as the working medium, and a transparent straight-tube nozzle with inner diameter of 0.6 mm and length of 40 mm was employed to generate the flashing spray vertically. A high-speed camera was used to record the images of the flashing spray. The whole dynamic evolution was obtained. The effects of injection pressure (0.6 to 2.4 MPa) and initial temperature (40 to 60 oC) were fully explored, respectively. The experiment results indicate that the superheat and injection pressure have a coupled effect on flashing spray. The release of superheat results in phase change with the generation of bubble within liquid, which facilitates the break-up of liquid core and ligament liquid. Meanwhile, the increment of injection pressure can enhance the disturbance of the flow and the number of nucleation. © 2018 Solar Turbines Incorporated.

关键词： Atomization

来源：评论

学校读者我要写书评

暂无评论

Analysis of Frequent Tube Burst of High Temperature Reheater in 600 MW Unit

Analysis of Frequent Tube Burst of High Temperature Reheater...

引用

2020 IEEE Sustainable power and Energy Conference, iSPEC 2020

作者： Sun, Ke Wang, Jiaan Yan, Yu Jiang, Jiahao Deng, Lei Che, Defu China Huadian Electric Power Research Institute Co. Ltd. Hangzhou310030 China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'An Jiaotong University Xi'an710049 China

ISBN: (纸本)9781728191645

The reasons of frequent tube burst of the high temperature reheater in a supercritical 600 MW unit were systematically investigated via the examination of macroscopic inspection, chemical composition, mechanical properties, microstructures, scanning electron microscope and energy disperse spectroscopy detection. It is demonstrated that the tube burst of the high temperature reheater results from not only design factors, but also manufacture quality. Due to the absence of solid solution treatment in spare elbow, the inner dislocations and residual stress increase obviously, which accelerates the precipitation of carbide containing Cr and the formation of Cr depleted zone on grain boundary(GB) subsequently, leading to the decrease of GB corrosion resistance and the final leakage of high temperature reheater tube induced by intergranular corrosion. © 2020 IEEE.

关键词： Carbides

来源：评论

学校读者我要写书评

暂无评论

Startup transient thermal-hydraulic analysis of a lithium heat pipe cooled reactor Core

Startup transient thermal-hydraulic analysis of a lithium he...

引用

2020 International Topical Meeting on Advances in Thermal Hydraulics, ATH 2020

作者： Liu, Xiao Tian, Zhixing Wang, Chenglong Tian, Wenxi Qiu, Suizheng Su, Guanghui Shanxi Engineering Research Center of Advanced Nuclear Energy School of Nuclear Science and Technology Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an710049 China

ISBN: (纸本)9780894487774

Heat pipe cooled reactor has been proposed for applying in the space station and underwater exploration featured with high reliability, low noise level and compact structure. A typical design of a heat pipe cooled reactor system is HP-STMCs designed by the University of New Mexico. It is conceptually designed as a fast reactor, lithiumfilled heat pipes that transfer heat to potassium heat pipes radiator and thermoelectric generators. In this paper, a code is developed for studying the operating thermal-hydraulic characteristics of the reactor core, which consists of core thermal-hydraulic model, neutron kinetics model and heat pipe startup model. The highest temperatures of fuel and matrix in reactor core shows at the 2nd channel, which reach 1720K and 1545K from the results of steady-state. As for the startup transient, the code for heat pipe cooled reactor core successfully predicts key parameters during startup transient, such as each layer material temperature of reactor core, a single heat pipe's temperature response and heat rejection power. The code has initially predicted the transient response of the heat pipe cooled reactor under 800W/s and130W/s power increasing rates. It is discussed that the startup strategy of power increasing rates is based on heat pipe transition temperature (916K). This research provides valuable experience for designing and formulating control strategies of the heat pipe cooled reactor. © ATH 2020 - International Topical Meeting on Advances in Thermal *** rights reserved.

关键词： Heat pipes

来源：评论

学校读者我要写书评

暂无评论

Failure analysis of tube-burst on T91 platen superheater of 600 MW supercritical boiler

Failure analysis of tube-burst on T91 platen superheater of ...

引用

2020 International Conference on Artificial Intelligence and Electromechanical Automation, AIEA 2020

作者： Sun, Ke Wang, Jia'An Yan, Yu Jiang, Jiahao Deng, Lei State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'An Jiaotong University Xi'an710049 China China Huadian Electric Power Research Institute Co. Ltd. Hangzhou310030 China

ISBN: (纸本)9781728182889

In this paper, the specimen of the bursting tubes, original tube and oxide-like debris are analysed in-depth by macroscopic examination, chemical composition analysis, mechanical properties, metallographic examination, scanning electron microscopy and energy spectrum analysis etc.,. It shows that the main reason for the tube-burst is that the original oxide matters or time-original oxide matters blocks the tube, reducing the cooling effect of the steam, and resulting in a short-term overheating of the tube. It is recommended to control the internal cleanliness of boiler equipment and pipest. © 2020 IEEE.

关键词： Scanning electron microscopy

来源：评论

学校读者我要写书评

暂无评论

A systematic improvement of the high-quality temperature field reconstruction for acoustic pyrometry

引用

Case Studies in Thermal engineering 2025年 72卷

作者： Jingkao Tan Na Li Qulan Zhou Yanyuan Hu Lehang Chen Zhongquan Gao Jie Zhou State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Xi'an Aerospace Propulsion Institute Xi'an 710100 China

Obtaining an accurate temperature distribution in furnaces for industrial combustion devices is critical. Acoustic pyrometry (AP) is a promising methodology for high-quality temperature field reconstruction, which is widely used in the monitoring of atmosphere, room, and furnace. However, due to the harsh working environment and the engineering limitations, the number of installed acoustic transducers is restricted, which in turn results in sparse valid data and an ill-posed AP problem. We used multiple means of improvement to improve the reconstruction performance of AP in a gradual and systematic manner. The fast finite-difference shooting method, the adaptive grid evolution strategy (AGES) and the radial basis function approximation with polynomial reproduction (RBFPR) were proposed and integrated into the sequential process optimization approach we concluded to systematically improve the reconstruction performance over the initial algorithm. In this approach, we optimized the parameters used for the reconstruction sequentially, analyzed the effectiveness of various means of improvement, finalized and validated an algorithm that takes into account universality and precision. Qualitative and quantitative analyses of the simulation and experimental results show the validity of the finalized algorithm and the sequential process optimization approach, demonstrating its significance for furnace temperature field measurement, combustion control, and environmental protection.

关键词： Inverse problem Acoustic pyrometry Acoustic tomography Acoustic refraction Algorithm improvement Domain discretization Temperature field reconstruction

来源：评论

学校读者我要写书评

暂无评论

Frequency characteristics and slug velocities of severe slugging in pipeline-riser systems

引用

Ocean engineering 2025年 336卷

作者： Yuwen Li Qiang Xu Yeqi Cao Haiyang Yu Bo Huang Liejin Guo State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China College of Petroleum Engineering Xi'an Shiyou University Xi'an 710065 China

The frequency characteristics and slug velocities of severe slugging are crucial for assessing fatigue damage and ensuring flow safety in offshore pipeline-riser systems. The flow pattern distributions and flow characteristics of severe slugging were obtained for the small-scale ( L H = 20 m, L I = 3 m, H R = 2 m) and kilometer-scale long-distance ( L H = 1657 m, L I = 30 m, H R = 29 m) pipeline-riser systems. Due to the periodicity of severe slugging, the local flow pattern in the riser was a composite pattern of alternating slug flow, bubble flow, and liquid flow. The significant decrease of the differential pressure in the riser induced slug flow in the horizontal pipe. A quantitative correlation was established among structural parameters, dimensionless gas and liquid Froude numbers, and severe slugging frequency. The average percent absolute relative error of the prediction was reduced from 58.31 % to 28.42 %. The peak velocities of liquid slugs in the small-scale and kilometer-scale systems can reach 7.5 and 22.9 times the inlet mixture velocities, respectively. A mechanism prediction model for liquid slug peak velocity considering the average void fraction in the riser was proposed. Approximately 85 % of the predicted values were within the error range of ±20 %.

关键词：

来源：评论

学校读者我要写书评

暂无评论

CdS nanocrystallites sensitized ZnO nanorods with plasmon enhanced photoelectrochemical performance

引用

Chinese Chemical Letters 2019年第12期30卷 2363-2367页

作者： Li Cai Yuanchang Du Xiangjiu Guan Shaohua Shen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering (MFPE) Xi’an Jiaotong University (XJTU)

A novel architecture of CdS/ZnO nanorods with plasmonic silver(Ag) nanoparticles deposited at the interface of ZnO nanorods and CdS nanocrystallites,was designed as a photoanode for solar hydrogen generation,with photocurrent density achieving 4.7 mA/cm^2 at 1.6 V(***),which is 8 and 1.7 times as high as those of pure ZnO and CdS/ZnO nanorod films,***,with optical absorption onset extended to^660 nm,CdS/Ag/ZnO nanorod film exhibits significantly increased incident photo-tocurrent efficiency(IPCE) in the whole optical absorption region,reaching 23.1% and 9.8% at 400 nm and500 nm,*** PEC enhancement can be attributed to the one-dimensional ZnO nanorod structure maintained for superior charge transfer,and the extended visible-light absorption of CdS ***,the incorporated plasmonic Ag nanoparticles could further promote the interfacial charge carrier transfer process and enhance the optical absorption ability,due to its excellent plasmon resonance effect.

关键词： ZnO nanorods Plasmonic Ag nanoparticles CdS nanocrystallites Photoelectrochemical water splitting Synergistic effect

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：