检索结果-内蒙古大学图书馆

Stabilizing alkaline hydrogen evolution activity of heterogeneous metal-oxide-nitride cathode by dynamic reconstruction and doping engineering

引用

稀有金属（英文版） 2025年第2期44卷 1084-1095页

作者： Jin-Di He Han-Du Wang Xu-Ming Zhang Li Huang Yun Li Lu Xia Chao-Ran Pi Jian-Ping Li Yang Zheng Biao Gao Kai-Fu Huo The State Key Laboratory of Refractories and Metallurgy and Institute of Advanced Materials and Nanotechnology Wuhan University of Science and TechnologyWuhan 430081China Guizhou Wujiang Hydropower Development Co. LTD.Guiyang 550002China The College of Resources and Environment Engineering and Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources Wuhan University of Science and TechnologyWuhan 430081China Wuhan National Laboratory for Optoelectronics(WNLO) School of Optical and Electronic InformationHuazhong University of Science and TechnologyWuhan 430074China

The development of cost-effective,highly effi-cient and stable catalysts is critical to promote the indus-trial alkaline hydrogen evolution reaction(HER).However,single-component catalysts often cannot handle the multiple kinetic steps during hydrogen *** address this challenge,a heterogeneous catalyst comprising metal Co,CoO and carbon-doped Mo2N(Co-CoO-C/Mo2N/CC)was synthesized by heat treatment of carbon cloth-supported CoMoO4 microrods in a mixed reduction *** resulting catalyst has rich interfaces,exhibiting excellent initial HER activity with an overpotential of 27 mV at 10 mA·cm-2 and a Tafel slope of 37 mV·*** studies show that the activity and stability of the catalyst can be tailored by the dynamic surface reconfiguration and doping *** carbon doping and high crystallinity in Mo2N help to reduce the dissolution of Mo and the surface metal Co is preferentially converted into stable Co(OH)2,thus stabilizing the struc-ture of the catalyst and coordinating various reaction *** an electrolyzer comprising a heterogeneous Co-CoO-C/Mo2N cathode and NiFe layered double hydroxides(LDH)anode,only 1.58 V is required to achieve a current density of 50 mA·cm-2,outperforming Pt/RuO *** continuous electrolysis for 100 h,the potential increases by merely 19 mV from the initial 1.58 V,indicating excellent *** study presents a novel strategy for developing highly active and stable heterogeneous catalysts,offering insights into the dynamic evolution of catalyst structures and laying the groundwork for designing efficient and stable composite catalysts for energy conversion applications.

关键词： Heterogeneous catalyst Dynamic reconstruction Doping engineering Hydrogen evolution reaction Nitride

来源：评论

学校读者我要写书评

暂无评论

A tree-growing graphic model for asymmetrical phantom networks in polymeric gels undergoing dynamic mechanochemical coupling

引用

science China(Technological sciences) 2024年第2期67卷 558-567页

作者： SHI WeiLin ZHOU Jian LU HaiBao ELMARAKBI Ahmed FU Yong-Qing National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of TechnologyHarbin 150080China College of Mechanical and Vehicle Engineering Hunan UniversityChangsha 410082China Faculty of Engineering and Environment University of NorthumbriaNewcastle upon Tyne NEI 8STUK

Network structures of various polymers have significant effects on their mechanical properties;therefore,numerous studies have investigated the constitutive relationship between symmetrical network structures and their rubber elasticity in ***,few studies have focused on asymmetrical network structures in polymers that undergo bond exchange reactions,selfassembly,or mechanochemical coupling—all of which are induced by transition probabilities of chemical bonding *** this study,an extended constraint junction and phantom network model is formulated using the tree-growing theory to establish a constitutive relationship between asymmetrical network structures and their rubber elasticity in polymers.A free-energy equation is further developed to explore working principles of configurational transitions on the dynamic rubber elasticity of symmetrical and asymmetrical network *** constitutive relationship between dynamic rubber elasticity and symmetrical and asymmetrical network structures has also been proposed for the gels undergoing mechanochemical and hydromechanical ***,the effectiveness of this newly proposed tree-growing model has been verified by comparing with the classical affine network model,finite element analysis,and the experimental results of gels reported in literature.

关键词： gel polymer network rubber elasticity asymmetric

来源：评论

学校读者我要写书评

暂无评论

Response of partitioning to cooling rate for different solutes in aluminum alloys

引用

Journal of Materials science & technology 2024年第18期185卷 155-164页

作者： Jiang You Cheng Wang Dong Qiu Si-Yu Chen Ze-Tian Liu Hui-Yuan Wang National Key Laboratory of Automotive Chassis Integration and Bionics Jilin UniversityChangchun 130025China Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Jilin UniversityChangchun 130025China State Key Laboratory of Reliability and Intelligence of Electrical Equipment School of Material Science and EngineeringHebei University of TechnologyTianjin 300130China Center for Additive Manufacturing School of EngineeringRMIT UniversityMelbourneVIC 3001Australia

It is commonly recognized that the cooling rate has a substantial effect on solute partitioning and its resultant microsegregation during *** classical dendrite tip undercooling theory clarifies the mitigation of microsegregation by increasing the cooling ***,most of the studies focused on binary alloys,leaving an open question as to whether the microsegregation of different solutes in a multi-component alloy system exhibits a relieving degree similar to increasing cooling *** a widely used 6022-type Al alloy(Al-0.76Mg-0.93Si-0.2Fe)as a model alloy,the current study reveals that the microsegregation of Mg gets alleviated to the greatest extent,followed by those of Si and Fe when the cooling rate increases from 5 to 128 K/*** phenomenon is attributed to the solute-based difference in response to partitioning to cooling rate(denoted as Rk).We propose a theoretical equation to quantify Rk,and the R_(k)values of solute Mg,Si,and Fe successfully explain the rank of solute partitioning in ***,a broad range of R_(k)values of other commonly used alloying elements in Al alloys were calculated and ranked,delivering a handy tool to predict the microsegregation behavior and sol-ubility of different solute elements upon sub-rapid solidification,which is consistent with experimental *** framework can also be extended to other multi-component alloy systems.

关键词： Solidification Cooling rate Microsegregation Aluminum alloys Solute partitioning

来源：评论

学校读者我要写书评

暂无评论

The Law of Secondary Electron Multiplication of Aluminum under Different Frequency Microwaves 9

The Law of Secondary Electron Multiplication of Aluminum und...

引用

9th IEEE International Symposium on Microwave, Antenna, Propagation and EMC Technologies for Wireless Communications, MAPE 2022

作者： Shang, Shengfei Yang, Xiaoning Yang, Yong Bi, Yanqiang Wu, Nankai Li, Xiyuan Beijing Institute of Spacecraft Environment Engineering National Key Laboratory of Science and Technology on Reliability and Environmental Engineering Beijing China

ISBN: (数字)9781665427753

ISBN: (纸本)9781665427753

In this paper, the discharge phenomena of aluminum materials under the action of strong electromagnetic waves are investigated. The electron multiplication phenomenon of aluminum surface under different amplitude of microwave at 1GHz-300GHz was calculated using 1D3V simulation framework. It shows that the easiest discharge interval of aluminum is about 0.05MV/m-8.5MV/m at 1GHz and about 20MV/m-1700MV/m at 300GHz, and the easiest discharge interval increases with the frequency and follows nearly a linear power law. © 2022 IEEE.

关键词： Aluminum

来源：评论

学校读者我要写书评

暂无评论

Modeling and Experimental Study of an Open Two-Phase Loop Driven by Osmotic Pressure and Capillary Force

引用

Frontiers in Heat and Mass Transfer 2025年第1期23卷 55-70页

作者： Hanli Bi Zheng Peng Chenpeng Liu Zhichao Jia Guoguang Li Yuandong Guo Hongxing Zhang Jianyin Miao National Key Laboratory of SpacecraftThermal Control Beijing Institute of Spacecraft System EngineeringChina Academy of Space TechnologyBeijing100094China School of Aeronautical Science and Engineering Beihang UniversityBeijing100083China School of Energy and Environment Engineering University of Science and Technology BeijingBeijing100083China

As space technology advances,thermal control systems must effectively collect and dissipate heat from distributed,multi-source *** heat pipe is a highly reliable two-phase heat transfer component,but it has several limitations when addressing multi-source heat *** by the transport and heat dissipation system of plants,large trees achieve stable and efficient liquid supply under the influence of two driving forces:capillary force during transpiration in the leaves(pull)and root pressure generated by osmotic pressure in the roots(push).The root pressure provides an effective liquid supply with a driving force exceeding 2 MPa,far greater than the driving force in conventional capillary-pumped two-phase *** has shown that osmotic heat pipes offer a powerful driving force,and combining osmotic pressure with capillary force has significant ***,this paper designs a multi-evaporator,dual-drive two-phase loop,using both osmotic pressure and capillary force to solve the multi-source heat dissipation ***,a transmembrane water flux model for the osmotic pressure-driven device was established to predict the maximum heat transfer capacity of the dual-drive two-phase ***,an experimental setup for a multi-evaporator“osmotic pressure+capillary force”dual-drive two-phase loop was constructed,capable of transferring at least 235 W of power under a reverse gravity condition of 20 *** study also analyzed the effects of reverse gravity height,heat load distribution among the three evaporators,startup sequence,and varying branch resistances on the performance of the dual-drive two-phase loop.

关键词： Multi-heat sources osmotic pressure two-phase loop dual-drive loop heat pipe

来源：评论

学校读者我要写书评

暂无评论

A novel order-reduced thermal-coupling electrochemical model for lithium-ion batteries

引用

Chinese Physics B 2024年第5期33卷 637-654页

作者：谢奕展王舒慧王震坡程夕明 School of Mechanical Engineering Beijing Institute of TechnologyBeijing 100081China National Engineering Research Center for Electric Vehicles Beijing Institute of TechnologyBeijing 100081China The Hong Kong University of Science and Technology (Guangzhou) Sustainable Energy and Environment Thrust and Guangzhou MunicipalKey Laboratory of Materials InformaticsGuangzhou 511400China

Although the single-particle model enhanced with electrolyte dynamics(SPMe)is simplified from the pseudo-twodimensional(P2D)electrochemical model for lithium-ion batteries,it is difficult to solve the partial differential equations of solid–liquid phases in real-time ***,working temperatures have a heavy impact on the battery ***,a thermal-coupling SPMe is ***,a lumped thermal model is established to estimate battery *** order of the SPMe model is reduced by using both transfer functions and truncation techniques and merged with Arrhenius equations for thermal *** polarization voltage drop is then modified through the use of test data because its original model is unreliable ***,the coupling-model parameters are extracted using genetic *** results demonstrate that the proposed model produces average errors of about 42 mV under 15 constant current conditions and 15 mV under nine dynamic conditions,*** new electrochemicalthermal coupling model is reliable and expected to be used for onboard applications.

关键词： lithium-ion batteries order-reduced electrochemical models SPMe thermal-coupling model transient polarization voltage drop

来源：评论

学校读者我要写书评

暂无评论

Microstructure Characterization of Bubbles in Gassy Soil Based on the Fractal Theory

引用

Journal of Ocean University of China 2024年第1期23卷 129-137页

作者： WU Chen LIN Guoqing LIU Lele LIU Tao LI Chengfeng GUO Zhenqi Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering Ocean University of ChinaQingdao 266100China Key Laboratory of Gas Hydrate Ministry of Natural ResourcesQingdao Institute of Marine GeologyQingdao 266237China College of Environmental Science and Engineering Ocean University of ChinaQingdao 266100China Key Laboratory of Marine Environment and Ecology Ministry of EducationOcean University of ChinaQingdao 266100China Qingdao National Laboratory for Marine Science and Technology Qingdao 266237China

The microscopic characterization of isolated bubbles in gassy soil plays an important role in the macroscopic physical properties of sediments and is a key factor in the study of geological hazards in gas-bearing *** on the box-counting method and the pore fractal features in porous media,a fractal model of bubble microstructure parameters in gassy soil under different gas con-tents and vertical load conditions is established by using an industrial X-ray CT scanning *** results show that the fractal di-mension of bubbles in the sample is correlated with the volume fraction of bubbles,and it is also restricted by the vertical *** three-dimensional fractal dimension of the sample is about 1 larger than the average two-dimensional fractal dimension of all the slices from the same *** uniform porous media fractal model is used to test the equivalent diameter,and the results show that the variation of the measured pore diameter ratio is jointly restricted by the volume fraction and the vertical *** addition,the measured self-similarity interval of the bubble area distribution is tested by the porous media fractal capillary bundle model,and the fitting curve of measured pore area ratio in a small loading range is obtained in this paper.

关键词： gassy soil bubble microstructure parameters fractal dimension vertical load

来源：评论

学校读者我要写书评

暂无评论

The preparation, microstructure, and performance of MoAlB-Si ceramic sintered from combustion-synthesized powder

引用

Ceramics International 2025年第16期51卷 21800-21809页

作者： Yu, Wanjun Ding, Qizhang Li, Xiangming Zhang, Enliang Han, Wenbo Zheng, Yongting Qi, Yushi School of Environment and Materials Engineering Yantai University Yantai264005 China School of Materials Science and Engineering Harbin Institute of Technology Weihai264209 China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and Structures Harbin Institute of Technology Harbin150080 China

To streamline the preparation process and improve the performance of the MoAlB phase, the technical potential of an ultra-fast combustion synthesis followed by hot pressing to prepare the MoAlB–Si ceramic was investigated. During the combustion process, the Si atoms occupied the Al positions, which forms a Mo(Al,Si)B solid solution phase. Si doping resulted in the effective grain refinement of the hot-pressed MoAlB-Si ceramic. The grain-refined and solid-solution-strengthened MoAlB-Si ceramic exhibits excellent mechanical properties with a compressive strength of 2.63 GPa, flexural strength of 650 MPa, fracture toughness of 7.26 MPa m1/2, and Vickers hardness of 13.32 GPa. At elevated temperatures, a newly formed oxidation-derived dense and continuous layer on the surface prevents the inward diffusion of oxygen and the volatilisation of oxidation products, indicating good oxidation resistance of the MoAlB-Si ceramic. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Compressive strength

来源：评论

学校读者我要写书评

暂无评论

Effect of surface species on the alcohol-acid adsorption from FTS wastewater on graphene:A structure-capacity study

引用

Journal of environmental sciences 2025年第3期149卷 651-662页

作者： Xiao Liu Xiaolong Zhang Chunyu Geng Qinglan Hao Jie Chang Xin Hu Yongwang Li Botao Teng Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization College of Chemical Engineering and Materials ScienceTianjin University of Science and TechnologyTianjin 300457China State Key Laboratory of Medicinal Chemical Biology Key Laboratory of Functional Polymer MaterialsCollege of ChemistryNankai UniversityTianjin 300071China National Energy Center for Coal to Liquids Synfuels China Co.Ltd.Beijing 101407China Institute of Sustainability of Chemical Energy and EnvironmentAgency for ScienceTechnology and Research627833Singapore Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Normal UniversityJinhua 321004China

Fischer-Tropsch synthesis(FTS)wastewater retaining low-carbon alcohols and acids are organic pollutants as a limiting factor for FTS *** this work,the structurecapacity relationships between alcohol-acid adsorption and surface species on graphene were reported,shedding light into their intricate *** graphene oxide(GO)and reduced graphene oxide(rGO)were synthesized via improved Hummers method with flake graphite(G).The physicochemical properties of samples were characterized via SEM,XRD,XPS,FT-IR,and *** alcohol-acid adsorption behaviors and adsorption quantities on G,GO,and rGO weremeasured via theoretical and *** was revealed that the presence of COOH,C=O and C–O species on graphene occupy the adsorption sites and increase the interactions of water with graphene,which are unfavorable for alcoholacid *** equilibrium adsorption quantities of alcohols and acids grow in pace with carbon *** monolayer adsorption occurs on graphene was verified viamodel *** has the highest FTS modeling wastewater adsorption quantity(110 mg/g)due to the reduction of oxygen *** novel findings provide a foundation for the alcoholacid wastewater treatment,as well as the design and development of high-performance carbon-based adsorbent materials.

关键词： Alcohol-acid adsorption Fischer-Tropsch synthesis wastewater Graphene Surface species Density functional theory

来源：评论

学校读者我要写书评

暂无评论

Characteristics of Antarctic aerosol composition during the Australian fires of 2019-2020

引用

Advances in Polar science 2024年第4期35卷 421-437页

作者： CHEN Afeng WANG Longquan LIU Hongwei YUE Fange XIE Zhouqing Institute of Polar Environment&Anhui Key Laboratory of Polar Environment and Global Change Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Engineering and Technological Research Centre of National Disaster Relief Equipment Army Logistics AcademyChongqing 401331China State Key Laboratory of Fire Science University of Science and Technology of ChinaHefei 230026China

During the 36th Chinese national Antarctic Research Expedition,aerosol samples were gathered from the Ross Sea in Antarctic to assess the climatic impact of the Australian fires that occurred in *** chemical compositions,including levoglucosan(Lev)and its isomers,galactosan(Gan)and mannosan(Man),were *** component analysis helped identify the potential sources of these chemical *** combining backward trajectories with the ratios of CLev/CMan and CMan/CGan,it was further inferred that Australia might be the potential source region for biomass *** radiative forcing resulting from biomass burning was evaluated using the Santa Barbara DISORT Atmospheric Radiative Transfer(SBDART)model,which revealed that black carbon emitted from biomass burning could slightly warm the atmosphere(+0.52 W·m^(-2))while causing slightly cooling at the surface(-0.73 W·m^(-2))and the top of the atmosphere(-0.22 W·m^(-2))over the Ross Sea.

关键词： Australian fires biomass burning aerosol composition climate effect Ross Sea

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：