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Getting insights into gas-phase sulfation effect on catalytic performance of praseodymium oxides in NH_(3)-SCR of NO

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Journal of Rare Earths 2023年第6期41卷 952-958,I0005页

作者： Yandi Cai Peng Yang Qinglong Liu Kaili Ma Wenxin Ma Wang Song Qiuhui Qian Fei Gao Wei Tan Lin Dong State Key Laboratory of Pollution Control and Resource Reuse School of EnvironmentJiangsu Key Laboratory of Vehicle Emissions ControlCenter of Modern AnalysisKey Laboratory of Mesoscopic Chemistry of MOESchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Analysis and Testing Center Southeast UniversityNanjing 211189China National and Local Joint Engineering Laboratory of Municipal Sewage Resource Utilization Technology School of Environmental Science and EngineeringSuzhou University of Science and TechnologySuzhou 215009China

Sulfation treatment has been widely used to promote the catalytic performance of ceria(CeO_(2))based catalysts for the selective catalytic reduction of NO by NH_(3)(NH_(3)-SCR of NO).Praseodymium oxide(PrO_(x)),another commonly used rare earth material with similar structural properties as CeO_(2),also shows satistactory redox properties due to the facile redox cycle of Pr^(3+)■Pr^(4+).In this work,gas phase sulfation treatment with varied duration was performed on PrO_(x) at 200℃,and the NH_(3)-SCR activity of sulfated PrO_(x) was *** on the results of systematic characterizations(e.g.,N_(2)-physisorption,NH_(3) oxidation,NO oxidation,in situ diffuse Fourier transform infrared spectroscopy),it is revealed that the catalytic performance of sulfated PrO_(x)is highly dependent on the sulfation time(or the amount of sulfate species deposited on PrO_(x)),which has a significant impact on the competitive reaction between NH_(3) oxidation and NH_(3)-SCR of NO,thus determining the NH_(3)-SCR activity of PrO_(x).This work provides new insight into tuning the interaction between PrO_(x) surface and reactants(NO,NH_(3))via sulfation treatment,which cam guide the design and application of PrO_(x)based catalysts for NH_(3)-SCR of NO in the future.

关键词： NH_(3)-SCR Praseodymium oxides Sulfation treatment Surface acidity NH_(3)oxidation Rare earths

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Deciphering decadal urban ozone trends from historical records since 1980

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national science Review 2024年第11期11卷 117-129页

作者： Haolin Wang Xiao Lu Paul I.Palmer Lin Zhang Keding Lu Ke Li Tatsuya Nagashima Ja-Ho Koo Hiroshi Tanimoto Haichao Wang Meng Gao Cheng He Kai Wu Shaojia Fan Yuanhang Zhang School of Atmospheric Sciences Sun Yat-sen University and Key Laboratory of Tropical Atmosphere-Ocean System Ministry of Education Guangdong Provincial Observation and Research Station for Climate Environment and Air Quality Change in the Pearl River Estuary Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) School of Geo Sciences University of Edinburgh National Centre for Earth Observation University of Edinburgh Laboratory for Climate and Ocean-Atmosphere Studies Department of Atmospheric and Oceanic SciencesSchool of PhysicsPeking University State Key Joint Laboratory of Environmental Simulation and Pollution Control The State Environmental Protection Key Laboratory of Atmospheric Ozone Pollution ControlCollege of Environmental Sciences and Engineering Peking University Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment Technology School of Environmental Science and Engineering Nanjing University of Information Science &Technology National Institute for Environmental Studies Department of Atmospheric Sciences Yonsei University Department of Geography Hong Kong Baptist University Department of Civil and Environmental Engineering University of California

Ozone pollution is a major environmental threat to human health. Timely assessment of ozone trends is crucial for informing environmental policy. Here we show that for the most recent decade（2013–2022） in the northern hemisphere, warm-season（April–September） mean daily 8-h average maximum ozone increases much faster in urban regions with top ozone levels(mainly in the North China Plain, 1.2 ± 1.3 ppbv year-1) than in other, low-ozone regions(0.2 ± 0.9 ppbv year-1). These trends widen the ozone differences across urban regions, and increase extreme pollution levels and health threats from a global perspective. Comparison of historical trends in different urban regions reveals that ozone increases in China during 2013–2022 differ in magnitude and mechanisms to historical periods in other regions since *** reflects a unique chemical environment characterized by exceptionally high nitrogen oxides and aerosol concentrations, where reducing ozone precursor emissions leads to substantial ozone *** increase in China has slowed down in 2018–2022 compared to 2013–2017, driven by ongoing emission reductions, but with ozone-favorable weather conditions. Historical ozone evolution in Japan and South Korea indicates that ozone increases should be suppressed with continuous emission *** temperature and associated wildfires have also reversed ozone decreases in the USA and Europe,with anthropogenic ozone control slowing down in recent decades.

关键词： air quality surface ozone trends

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Comparative analysis of DNA-SIP and magnetic-nanoparticle mediated isolation (MMI) on unraveling dimethoate degraders

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Frontiers of environmental science & engineering 2024年第1期18卷 59-69页

作者： Luning Lian Yi Xing Dayi Zhang Longfei Jiang Mengke Song Bo Jiang School of Energy and Environmental Engineering University of Science&Technology BeijingBeijing 100083China Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants University of Science&Technology BeijingBeijing 100083China National Environmental and Energy Science and Technology International Cooperation Base University of Science&Technology BeijingBeijing 100083China College of New Energy and Environment Jilin UniversityChangchun 130021China Guangzhou Institute of Geochemistry Chinese Academy of SciencesGuangzhou 510640China College of Natural Resources and Environment South China Agricultural UniversityGuangzhou 510642China National Engineering Laboratory for Site Remediation Technologies Beijing 100015China

Microorganisms are crucial in the bioremediation of organophosphorus pesticides. However, most functional microorganisms (> 99%) are yet to be cultivated. This study applied two cultivation-independent approaches, DNA-SIP and magnetic-nanoparticle mediated isolation (MMI), to identify the functional microorganisms in degrading dimethoate in agricultural soils. MMI identified five dimethoate degraders: Pseudomonas, Bacillus, Ramlibacter, Arthrobacter, and Rhodococcus, whereas DNA-SIP identified three dimethoate degraders: Ramlibacter, Arthrobacter, and Rhodococcus. Also, MMI showed higher resolution than DNA-SIP in identifying functional microorganisms. Two organic phosphohydrolase (OPH) genes: ophC2 and ophB, were involved in dimethoate metabolism, as revealed by DNA-SIP and MMI. The degradation products of dimethoate include omethoate, O,O,S-trimethyl thiophosphorothioate, N-methyl-2-sulfanylacetamide, O,O-diethyl S-hydrogen phosphorodithioate, O,O,O-trimethyl thiophosphate, O,O,S-trimethyl thiophosphorodithioate, and O,O,O-trimethyl phosphoric. This study emphasizes the feasibility of using SIP and MMI to explore the functional dimethoate degraders, expanding our knowledge of microbial resources with cultivation-independent approaches.

关键词： Stable isotope probing(SIP) Magnetic-nanoparticle mediated isolation(MMI) Dimethoate Biodegradation Cultivation-independent approach

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Optimization control method for dedicated outdoor air system in multi-zone office buildings based on deep reinforcement learning

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建筑模拟（英文版） 2025年第4期18卷 881-896页

作者： Xudong Tang Ling Zhang Yongqiang Luo College of Civil Engineering Hunan UniversityChangsha 410082China National Center for International Research Collaboration in Building Safety and Environment Hunan UniversityChangsha 410082China Key Laboratory of Building Safety and Energy Efficiency of the Ministry of Education Hunan UniversityChangsha 410082China School of Environmental Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China

Heating,ventilation,and air conditioning(HVAC)systems consume a significant amount of energy to maintain thermal comfort and indoor air quality in buildings,which results in high operational *** learning is an effective method for controlling HVAC ***,in large and complex HVAC systems,traditional reinforcement learning algorithms often face the challenges of slow training speed and poor convergence *** paper proposes a multi-objective optimization control method based on the multi-agent deep deterministic policy gradient(MADDPG)algorithm,which aims to minimize HVAC energy consumption while ensuring optimal thermal comfort and indoor air quality in each *** a multi-zone office building with fan coil units and a dedicated outdoor air system as a case study,we developed an EnergyPlus-Python co-simulation *** proposed control method was employed during both the heating and cooling seasons to independently control the temperature setpoints and fresh airflow in different zones of the office *** simulation results from both the heating and cooling seasons demonstrate that the MADDPG control method exhibits faster convergence during training and excellent learning capabilities,allowing it to adapt effectively to changes in environmental conditions and implement appropriate control *** similar indoor thermal comfort and air quality conditions,the MADDPG control method consumes less energy than the traditional reinforcement learning method,it saves 24.1%of energy during the heating season and 8.9%during the cooling season compared to the rule-based control ***,by adjusting the reward function in the MADDPG algorithm,it is possible to flexibly balance energy consumption,thermal comfort,and air quality preferences,demonstrating the algorithm's strong applicability.

关键词： multi-zone HVAC systems energy consumption thermal comfort indoor air quality multi-agent deep reinforcement learning

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KCl acts as a flux to assist the growth of sub-millimeter-scale metallic 2D non-layered molybdenum dioxide

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Rare Metals 2025年第1期44卷 404-416页

作者： Li-Ying Deng Qing Zhang Wang-Yang Li Xiao-Yuan Ye Yi-Fan Zhao Shen-Zhong Chen Yu-Lan Wang Xing-Hui Wang Hui-Peng Chen Zhi-Yang Yu Qun Yan Shu-Ying Cheng Tai-Liang Guo Wen-Ping Hu Feng Ding Jie Sun National and Local United Engineering Laboratory of Flat Panel Display Technology College of Physics and Information EngineeringFuzhou UniversityFuzhou350100China Fujian Key Laboratory of Agricultural Information Sensing Technology College of Mechanical and Electrical EngineeringFujian Agriculture and Forestry UniversityFuzhou350002China Key Laboratory of Organic Integrated Circuit Department of ChemistrySchool of ScienceMinistry of Education and Tianjin Key Laboratory of Molecular Optoelectronic SciencesTianjin UniversityTianjin300072China Collaborative Innovation Center of Chemical Science and Engineering(Tianjin) Tianjin300072China College of Physics and Information Engineering Institute of Micro-Nano Devices and Solar CellsFuzhou UniversityFuzhou350108China State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFuzhou350116China Faculty of Materials Science and Engineering/Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen518000China

Two-dimensional(2D)metal oxides(2DMOs),such as MoO_(2),have made impressive strides in recent years,and their applicability in a number of fields such as electronic devices,optoelectronic devices and lasers has been ***,2DMOs present challenges in their synthesis using conventional methods due to their non-van der Waals *** report that KCl acts as a flux to prepare large-area 2DMOs with sub-millimeter *** systematically investigate the effects of temperature,homogeneous time and cooling rate on the products in the flux method,demonstrating that in this reaction a saturated homogenous solution is obtained upon the melting of the salt and ***,the cooling rate was adjusted to regulate the thickness of the target crystals,leading to the precipitation of 2D non-layered material from the supersaturated solution;by applying this method,the highly crystalline non-layered 2D MoO_(2)flakes with so far the largest lateral size of up to sub-millimeter scale(~464μm)were *** studies have revealed that the 2D MoO_(2)features metallic properties,with an excellent sheet resistance as low as 99Ω·square^(-1 )at room temperature,and exhibits a property of charge density wave in the measurement of resistivity as a function of temperature.

关键词： 2D non-layered materials Metallic Metal oxide Thickness modulation Flux method

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Shear Strength and Dilatancy of Calcareous Sand in the South China Sea

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China Ocean engineering 2022年第5期36卷 781-790页

作者： PEI Hui-min WANG Dong Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering Ocean University of ChinaQingdao 266100China Qingdao National Laboratory for Marine Science and Technology Qingdao 266100China

The shear strength and dilatancy of typical uncemented calcareous sand from the South China Sea are investigated by soil lab *** to drained triaxial tests at various relative densities and confining stresses,it is found that the constant volume friction angle is approximated as 39°and the traditional Bolton’s equations can be modified to estimate the peak friction angle and dilation *** reliability of the equation proposed for the peak friction angle is verified in terms of calcareous sands from more onshore and offshore sites worldwide,while the errors of the predicted dilation angles scatter in a relatively large ***,the dilation angles of sands in the South China Sea are estimated by the equation presented with an error of±30%.The peak friction angle measured by the undrained is similar to that by the drained tests as the relative density smaller than 60%,while the former is slightly lower for denser samples.

关键词： calcareous sand triaxial tests friction angle dilatancy drained South China Sea

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An SPH model reconstruction framework with fragment mapping method for multiplate structure hypervelocity impact simulation

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Advances in Space Research 2025年第11期75卷 8140-8157页

作者： Cao, Xu Zhou, Jianqiu Xu, Huadong Song, Di Miao, Changqing National Key Laboratory of Science and Technology on Advanced Composites in Special Environment Harbin Institute of Technology Harbin150001 China School of Basic Medical Sciences Harbin Medical University Harbin150001 China School of Mechanical and Electrical Engineering University of Electronic Science and Technology of China Sichuan Chengdu611731 China

Smoothed Particle Hydrodynamics (SPH) method is widely used in hypervelocity impact analysis, but it is computationally inefficient for common multiplate structures, such as multi-shock, mesh double-bumper, and stuffed shields. To improve the efficiency and accuracy of the SPH method, a reconstruction framework is proposed, including a fragment identification method, a fragment mapping method, and a sequential modeling and simulation approach. In the reconstruction framework, the total impact simulation of a multiplate structure consisting of n plates is decomposed into n individual impacts on each plate. To reduce the computation for each impact, a fragment identification method and a fragment mapping method are developed. Fragments generated from the impact with the i-th plate (i © 2025 COSPAR

关键词： 3D reconstruction

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Enhancing corn stalk-based anaerobic digestion with different types of zero-valent iron added during the acidification stage:Performance and mechanism

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Journal of environmental sciences 2024年第11期145卷 64-74页

作者： Xiang Liu Yue Liu Min Wang Qianzhen Deng Hao Yang College of Agricultural Science and Engineering Hohai UniversityNanjing 210098China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China National and Local Joint Engineering Research Center of Ecological Treatment Technology for Urban Water Pollution Wenzhou UniversityWenzhou 325035China Anhui Provincial Key Laboratory of Environmental Pollution Control and Resource Reuse Anhui Jianzhu UniversityHefei 230009China

Anaerobic digestion has been defined as a competitive approach to facilitate the recycling of corn ***,few studies have focused on the role of direct interspecies electron transfer(DIET)pathway in the acidification stage under the addition of different particle sizes of zero-valent iron(ZVI).In this study,three types of ZVI,namely iron filings,iron powder and nanoscale iron,were investigated,respectively,to enhance its high-value *** in volatile fatty acids(VFAs)and methane(CH4)production associated with the underlyingmechanisms were emphatically *** indicated that the addition of ZVI could increase the concentration of VFAs,with the most outstanding performance observed with the use of nanoscale ***,the conversion of propionic acid to acetic acid was driven by adding ZVI with no between-group differences in acidizing ***,the substrate was more fully utilized when supplied with iron powder compared with other groups in methanogenic phase,thereby displaying the maximumCH4 yield with a value of 263.1 mL/(g total solids(TS)).However,adding nanoscale iron could signally shorten the digestion time(T80),saving 7 days in comparison to the group of iron powder.

关键词： Zero-valent iron Corn stalk Anaerobic digestion Volatile fatty acids Methane

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Spatial and Temporal Distribution of Metal Elements in the Rivers of Northern Jiangsu Province

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Journal of Ocean University of China 2025年第1期24卷 157-168页

作者： YUAN Liping LIU Qian JIAN Huimin MI Tiezhu YANG Fuxia YAO Qingzhen Frontiers Science Center for Deep Ocean Multispheres and Earth System and Key Laboratory of Marine Chemistry Theory and TechnologyMinistry of EducationOcean University of ChinaQingdao 266100China Laboratory of Marine Ecology and Environmental Science Qingdao National Laboratory for Marine Science and TechnologyQingdao 266071China College of Environmental Science and Engineering Ocean University of ChinaQingdao 266100China Key Laboratory of Land and Sea Ecological Governance and Systematic Regulation of the Ministry of Ecology and Environment Shandong Academy for Environmental PlanningJinan 250101China

The concentrations of V,Cr,Mn,Fe,Co,Ni,Cu,Zn,As,Mo,Cd,and Pb were determined in Doulonggang River,Xinyanggang River,Huangshagang River,Sheyanghe River,Guangaizongqu River,and Linhonghe River at the North of Jiangsu Province in *** annual average concentrations of V,Cr,Mn,Fe,Co,Ni,Cu,Zn,As,Mo,Cd and Pb in the six rivers were 2.20,1.22,4.53,21.9,0.13,2.79,1.77,4.00,2.97,3.87,0.01,0.19μg L^(-1)*** highest concentration of most trace metals were found in Guangaizongqu River and Linhonghe River,and the lowest concentration were found in Xinyanggang River and Huangshagang *** principal component analysis(PCA)resulted of two factors together explained 91.2%of the variance with>1initial eigenvalue,indicating that both natural and anthropogenic activities were contributing factors as the source of metal abundance in rivers of northern Jiangsu *** first major component represented the influence of anthropogenic activities,including industry and agriculture,with a contribution rate of 54.1%,affected Cr,Fe,Cu,Zn,Mo,Cd and *** second(such as V,Mn,Co,Ni,As)was a mixed source,including the natural processes such as precipitation,erosion and weathering and anthropogenic action like industry and agriculture,with a contribution rate of 37.1%.Seasonal variations in trace metal concentrations were influenced by temperature,salinity,water discharge,and input of external *** highest concentrations were found in wet season and were strongly influenced by rainfall and seasonal industrial and agricultural activities.

关键词： trace metal distribution rivers northern Jiangsu Province

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Single-atomic tungsten-doped Co_(3)O_(4) nanosheets for enhanced electrochemical kinetics in lithium–sulfur batteries

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Carbon Energy 2023年第8期5卷 31-41页

作者： Sangni Wang Riming Hu Ding Yuan Lei Zhang Chao Wu Tianyi Ma Wei Yan Rui Wang Liang Liu Xuchuan Jiang Hua Kun Liu Shi Xue Dou Yuhai Dou Jiantie Xu National Engineering Laboratory for VOCs Pollution Control Technology and Equipment Guangdong Provincial Key Laboratory of Atmospheric EnvironmentPollution Control School of Environment and EnergySouth China University of TechnologyGuangzhouChina Shandong Institute of Advanced Technology JinanChina School of Materials Science and Engineering Institute for Smart Materials&EngineeringUniversity of JinanJinanChina Institute of Energy Materials Science University of Shanghai for Science and TechnologyShanghaiChina Institute for Superconducting and Electronic Materials University of WollongongWollongongAustralia School of Science RMIT UniversityMelbourneVictoriaAustralia State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghaiChina

The practical application of lithium–sulfur batteries(LSBs)is severely hindered by the undesirable shuttling of lithium polysulfides(LiPSs)and sluggish redox kinetics of sulfur ***,a series of ultrathin singleatomic tungsten-doped Co_(3)O_(4)(Wx-Co_(3)O_(4))nanosheets as catalytic additives in the sulfur cathode for LSBs are rationally designed and *** from the enhanced catalytic activity and optimized electronic structure by W doping,the Wx-Co_(3)O_(4) not only reduces the shuttling of LiPSs but also decreases the energy barrier of sulfur redox reactions of sulfur species,leading to accelerated electrode *** a result,LSB cathodes with the use of 5.0 wt%W0.02-Co_(3)O_(4) as the electrocatalyst show the high reversible capacities of 1217.0 and 558.6 mAh g^(-1) at 0.2 and 5.0 C,respectively,and maintain a high reversible capacity of 644.6 mAh g^(-1) at 1.0 C(1.0 C=1675 mA g^(-1))after 500 *** a high sulfur loading of 5.5 mg cm^(-2) and electrolyte–electrode ratio of 8μL_(electrolyte) mg_(sulfur)^(-1),the 5.0 wt%W_(0.02)-Co_(3)O_(4)-based sulfur cathode also retains a high reversible areal capacity of 3.86 mAh cm^(-2) at 0.1 C after 50 cycles with an initial capacity retention of 84.7%.

关键词： catalytic additives lithium-sulfur batteries single-atomic dopant sluggish redox kinetics

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