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Enhanced removal of crystal violet using rawfava bean peels, its chemically activated carbon compared with commercial activated carbon

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Case Studies in Chemical and Environmental engineering 2024年 9卷

作者： Sh, Husien El-taweel, Reem M. Alrefaey, KhloodA. Labena, Ahmed Fahim, Irene Samy Said, Lobna A. Radwan, Ahmed G. School of Engineering and Applied Sciences Nile University Giza Egypt Industrial Engineering Program SESC Research Center Nile University Giza Egypt Egyptian Petroleum Research Institute (EPRI) Nasr City Cairo Egypt Nanoelectronics Integrated Systems Center (NISC) Nile University Giza Egypt Engineering Mathematics and Physics Dept. Faculty of Engineering Cairo University Giza 12613 Egypt

Crystal violet is a basic dye that is widely used by various industries, such as textiles and paints. These industries discharge their effluents, contaminated with crystal violet, into water streams, and these effluents have an adverse effect on aquatic organisms, the environment, and human health. Crystal violet is a basic dye that is widely used by various industries, such as textiles and paints. These industries discharge their effluents, contaminated with crystal violet, into water streams, and these effluents have an adverse effect on aquatic organisms, the environment, and human health. Hence, this paper is directed at studying the removal of crystal violet using environmentally friendly, cost-effective adsorbent materials such as raw fava bean (RFP-H₃F), and chemically activated carbon (H3F) in comparison to commercial activated carbon (CAC).Various characterization techniques are applied, such as XRD, FT-IR,and SEM analyses. Then, the process of optimizing is shown through some preliminary experiments and a Response Surface Methodology (RSM) experiment to find the best conditions for removing crystal violet efficiently. Results revealed that the raw fava bean peels and the commercial activated carbon have the maximum removal efficiency of 95 %, and 83 % respectively, after 180 min of contact time. It is hypothesized that raw fava bean peels (RFP) and chemically activated carbon using phosphoric acid RFP-H₃F will exhibit comparable efficiency in removing crystal violet when compared to commercial activated carbon (CAC). Various characterization techniques, including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR),and scanning electron microscopy (SEM), are applied to analyze the properties of the adsorbent materials. Afterwards, the optimization process is displayed through some preliminary experiments followed by a Response Surface Methodology (RSM) experiment to obtain the optimum conditions, which achieve high

关键词： Adsorption ANN Crystal violet Dyes Fava bean Peels RSM

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Design and Characterization of Octave Spanning, 1-THz Kerr Frequency Microcombs in Silicon Nitride

Design and Characterization of Octave Spanning, 1-THz Kerr F...

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Conference on Lasers and Electro-Optics (CLEO)

作者： Tristan Melton Alwaleed Aldhafeeri Hsiao Hsuan Chin Lala Rukh Gabriel M. Colación Tara E. Drake Chee Wei Wong Mesoscopic Optics and Quantum Electronics Laboratory University of California Los Angeles CA USA Optical Science & Engineering Program Center for High Technology Materials University of New Mexico Albuquerque NM USA Dept. of Physics & Astronomy University of New Mexico Albuquerque NM USA

We design microresonators for octave-spanning soliton frequency comb generation in silicon nitride. We lock the repetition rate via an electro-optic comb and achieve phase noise of -130-dBc/Hz, with the resultant modu... 详细信息

ISBN: (纸本)9798350369311

关键词： Phase noise Frequency modulation Laser noise Silicon nitride Solitons Electro-optic modulators Electro-optic effects Microcavities

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Measuring Minority Carrier Diffusion Length Using High-Injection Scanning Photocurrent Microscopy

arXiv

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arXiv 2024年

作者： Lian, Xiujun Gao, Hanwei Department of Physics Florida State University TallahasseeFL32306 United States Materials Science and Engineering Program Florida State University TallahasseeFL32306 United States Condensed Matter Science National High Magnetic Field Laboratory TallahasseeFL32310 United States

Scanning photocurrent microscopy (SPCM) has been widely used for characterizing charge transport properties, in particular, the minority carrier diffusion length of semiconductors. However, studying lightly doped or intrinsic semiconductors using SPCM remained challenging. Methods used in previous work required low levels of optical injection, which could not be fulfilled easily in semiconductors with lower carrier concentration. In this work, using finite-element simulation, we show that the minority diffusion length can also be quantified under high optical excitation. Not only being applicable both doped and intrinsic semiconductors, the method also lifted the restriction of implementing a Schottky contact in testing devices-a condition assumed to be necessary in previous studies. The results significantly expanded the versatility of SPCM in studying a broad spectrum of semiconducting materials with unprecedented flexibility in experimental conditions. Copyright © 2024, The Authors. All rights reserved.

关键词： Carrier concentration

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IoT-based Wireless Sensor Networks for Monitoring Drinking Water Treatment Plants

IoT-based Wireless Sensor Networks for Monitoring Drinking W...

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International Workshop on Secure Internet of Things (SIoT)

作者： Luiz Octávio Martini Lima Lucas Carvalho Goncalves Gustavo Campos Menezes Lucas Silva de Oliveira Gleb Wataghin Institute of Physics UNICAMP Campinas SP Brazil Master Degree Program in Automation and Systems CEFET-MG Leopoldina MG Brazil Department of Electronics and Computing CEFET-MG Contagem MG Brazil Department of Mechatronics Engineering CEFET-MG Divinópolis MG Brazil

ISBN: (数字)9798331507466

ISBN: (纸本)9798331507473

The increasing need for efficient monitoring of parameters in challenging industrial environments, such as basic sanitation, has led to the search for integrated and user-friendly solutions that can address specific challenges of this setting. This project aims to develop a solution to meet monitoring requirements in water treatment plants. The proposed solution involves the development of both hardware and software for collecting data from the water treatment process using sensors and transmitting this information to a server structure, database, and communication interface with the cloud-based user. The effectiveness of the proposed device is being evaluated in six water treatment units located in the states of Alagoas, Mato Grosso, Paraná, Rio de Janeiro, and São Paulo. Preliminary results indicate that the proposed solution is capable of monitoring the variables involved in the water flocculation stage and generating a comprehensive set of information about the process over time.

关键词： Cloud computing Chemical sensors Wireless sensor networks User interfaces Hardware Software Sensors Social Internet of Things Servers Monitoring

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Ground state phases of the two-dimension electron gas with a unified variational approach

arXiv

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arXiv 2024年

作者： Smith, Conor Chen, Yixiao Levy, Ryan Yang, Yubo Morales, Miguel A. Zhang, Shiwei Center for Computational Quantum Physics Flatiron Institute New YorkNY10010 United States Department of Electrical and Computer Engineering University of New Mexico AlbuquerqueNM87131 United States Program in Applied and Computational Mathematics Princeton University PrincetonNJ08544 United States

The two-dimensional electron gas (2DEG) is a fundamental model, which is drawing increasing interest because of recent advances in experimental and theoretical studies of 2D materials. Current understanding of the ground state of the 2DEG relies on quantum Monte Carlo calculations, based on variational comparisons of different ansatze for different phases. We use a single variational ansatz, a general backflow-type wave function using a message-passing neural quantum state architecture, for a unified description across the entire density range. The variational optimization consistently leads to lower ground-state energies than previous best results. Transition into a Wigner crystal (WC) phase occurs automatically at rs = 37±1, a density lower than currently believed. Between the liquid and WC phases, the same ansatz and variational search strongly suggest the existence of intermediate states in a broad range of densities, with enhanced short-range nematic spin correlations. Copyright © 2024, The Authors. All rights reserved.

关键词： Message passing

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Towards seamless environmental prediction-development of Pan-Eurasian EXperiment(PEEX)modelling platform

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Big Earth Data 2024年第2期8卷 189-230页

作者： Alexander Mahura Alexander Baklanov Risto Makkonen Michael Boy Tuukka Petäjä Hanna KLappalainen Roman Nuterman Veli-Matti Kerminen Stephen R.Arnold Markus Jochum Anatoly Shvidenko Igor Esau Mikhail Sofiev Andreas Stohl Tuula Aalto Jianhui Bai Chuchu Chen Yafang Cheng Oxana Drofa Mei Huang Leena Järvi Harri Kokkola Rostislav Kouznetsov Tingting Li Piero Malguzzi Sarah Monks Mads Bruun Poulsen Steffen M.Noe Yuliia Palamarchuk Benjamin Foreback Petri Clusiu Till Andreas Soya Rasmussen Jun She Jens Havskov Sørensen Dominick Spracklen Hang Su Juha Tonttila Siwen Wang Jiandong Wang Tobias Wolf-Grosse Yongqiang Yu Qing Zhang Wei Zhang Wen Zhang Xunhua Zheng Siqi Li Yong Li Putian Zhou Markku Kulmala Faculty of Science Institute for Atmospheric and Earth System Research(INAR)/PhysicsUniversity of Helsinki(UHEL)HelsinkiFinland Science and Innovation Department World Meteorological Organization(WMO)GenevaSwitzerland Niels Bohr Institute University of CopenhagenCopenhagenDenmark Climate System Research Finnish Meteorological Institute(CSR-FMI)HelsinkiFinland School of Engineering Sciences Lappeenranta University of TechnologyLappeenrantaFinland Institute for Climate and Atmospheric Science School of Earth and EnvironmentUniversity of LeedsLeedsUK Biodiversity and Natural Resources Program International Institute for Applied Systems Analysis(IIASA)LaxenburgAustria Department of Physics and Technology UiT-The Arctic University of NorwayTromsoNorway Nansen Environmental and Remote Sensing Center(NERSC) BergenNorway Atmospheric Composition Finnish Meteorological Institute(AC-FMI)HelsinkiFinland Norwegian Institute for Air Research(NILU) KjellerNorway LAGEO Institute of Atmospheric PhysicsChinese Academy of Sciences(IAP-CAS)BeijingChina Max Planck Institute for Chemistry(MPI-Chem) MainzGermany Institute of Atmospheric Sciences and Climate National Research Council of Italy(CNR-15SAC)BolognaItaly Institute of Geographic Sciences and Natural Resources Research(IGSNRR) Chinese Academy of Sciences(CAS)BeijingChina Faculty of Science Helsinki Institute of Sustainability Science(HELSUS)University of Helsinki(UHEL)HelsinkiFinland Atmospheric Research Centre of Eastern Finland Finnish Meteorological Institute(ARCEF-FMI)KuopioFinland Institute of Atmospheric Physics Chinese Academy of Sciences(IAP-CAS)BeijingChina Department of Plant Physiology Estonian University of Life Sciences(EULS)Institute of Agricultural and Environmental Sciences(IAES)TartuEstonia Danish Meteorological Institute(DMI) CopenhagenDenmark State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry(LAPC) Institute of Atmospheric Physics(IAP)Chinese Academy of Sciences(CAS)BeijingChina Uni

The Pan-Eurasian Experiment Modelling Platform(PEEX-MP)is one of the key blocks of the PEEX Research *** PEEX MP has more than 30 models and is directed towards seamless envir-onmental *** main focus area is the Arctic-boreal regions and *** models used in PEEX-MP cover several main components of the Earth’s system,such as the atmosphere,hydrosphere,pedosphere and biosphere,and resolve the physicalchemicalbiological processes at different spatial and temporal scales and *** paper introduces and discusses PEEX MP multi-scale modelling concept for the Earth system,online integrated,forward/inverse,and socioeconomical modelling,and other approaches with a particular focus on applications in the PEEX geographical *** employed high-performance com-puting facilities,capabilities,and PEEX dataflow for modelling results are *** virtual research platforms(PEEXView,Virtual Research Environment,Web-based Atlas)for handling PEEX modelling and observational results are *** over-all approach allows us to understand better physical-chemicalbiological processes,Earth’s system interactions and feedbacks and to provide valuable information for assessment studies on evaluating risks,impact,consequences,*** population,envir-onment and climate in the PEEX *** work was also one of the last projects of *** Zilitinkevich,who passed away on 15 February *** the finalization took time,the paper was actually submitted in 2023 and we could not argue that the final paper text was agreed with him.

关键词： Multi-scale and-processes modelling concept seamless coupling high-performance computing data infrastructure virtual research platforms

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Terahertz spin dynamics in rare-earth orthoferrites

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Photonics Insights 2022年第2期1卷 1-56页

作者： Xinwei Li Dasom Kim Yincheng Liu Junichiro Kono Department of Physics California Institute of TechnologyPasadenaUSA Department of Electrical and Computer Engineering Rice UniversityHoustonUSA Applied Physics Graduate Program Smalley-Curl InstituteRice UniversityHoustonUSA Department of Physics and Astronomy Rice UniversityHoustonUSA Department of Materials Science and NanoEngineering Rice UniversityHoustonUSA

Recent interest in developing fast spintronic devices and laser-controllable magnetic solids has sparked tremendous experimental and theoretical efforts to understand and manipulate ultrafast dynamics in *** of spin dynamics in the terahertz(THz)frequency range are particularly important for elucidating microscopic pathways toward novel device ***,we review THz phenomena related to spin dynamics in rare-earth orthoferrites,a class of materials promising for antiferromagnetic *** expand this topic into a description of four key elements.(1)We start by describing THz spectroscopy of spin excitations for probing magnetic phase transitions in thermal *** acoustic magnons are useful indicators of spin reorientation transitions,electromagnons that arise from dynamic magnetoelectric couplings serve as a signature of inversion-symmetry-breaking phases at low temperatures.(2)We then review the strong laser driving scenario,where the system is excited far from equilibrium and thereby subject to modifications to the free-energy *** pathways for ultrafast laser manipulation of magnetic order are discussed.(3)Furthermore,we review a variety of protocols to manipulate coherent THz magnons in time and space,which are useful capabilities for antiferromagnetic spintronic applications.(4)Finally,new insights into the connection between dynamic magnetic coupling in condensed matter and the Dicke superradiant phase transition in quantum optics are *** presenting a review on an array of THz spin phenomena occurring in a single class of materials,we hope to trigger interdisciplinary efforts that actively seek connections between subfields of spintronics,which will facilitate the invention of new protocols of active spin control and quantum phase engineering.

关键词： terahertz spin dynamics magnetism orthoferrite ultrafast spectroscopy magneto-optics

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Modifying BiVO4 as a photocatalyst for water oxidation using constant-duration alkaline-etched post treatments

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New Journal of Chemistry 2023年第2期48卷 569-577页

作者： Hsu, Chuan-Chih Chuang, Kai-Jie Huang, Hsiao-Wen Pan, Bo-Jin Chen, Hung-Ming Husain, Sadang Yougbaré, Sibidou Hsiao, Yu-Cheng Wu, Yung-Fu Lin, Lu-Yin Division of Cardiovascular Surgery Department of Surgery School of Medicine College of Medicine Taipei Medical University Taiwan Division of Cardiovascular Surgery Department of Surgery Taipei Medical University Hospital Taiwan Department of Chemical Engineering and Biotechnology National Taipei University of Technology Taipei Taiwan Department of Chemical Engineering Ming Chi University of Technology New Taipei City24301 Taiwan Gingen Technology Co. Ltd. Rm. 7 10F. No. 189 Sec. 2 Keelung Rd. Xinyi Dist. Taipei11054 Taiwan Department of Physics Faculty of Mathematics and Natural Science Lambung Mangkurat University Banjarmasin70124 Indonesia /Nanoro Ouagadougou03 Burkina Faso International PhD Program in Biomedical Engineering College of Biomedical Engineering Taipei Medical University Taipei11031 Taiwan Stanford Byers Center for Biodesign Stanford University CA94305-5428 United States Graduate Institute of Biomedical Optomechatronics College of Biomedical Engineering Taipei Medical University Taipei11031 Taiwan Cell Physiology and Molecular Image Research Center Wan Fang Hospital Taipei Medical University Taipei11696 Taiwan

BiVO4 with suitable band edges and a small band gap is considered an efficient photocatalyst for the oxygen evolution reaction (OER), but short charge-transfer lengths limit its photocatalytic ability. Increasing active sites can essentially enhance oxidation reactions and photocatalytic ability. The alkaline etching technique can refine the surface properties of BiVO4 by introducing oxygen vacancies and possibly establishing a heterojunction, but suitable alkaline etching methods are rarely discussed. In this study, three alkaline etching methods, including hydrothermal, soaking, and electrodeposition processes, are first applied for a constant duration to tailor the surface properties of BiVO4 as a photocatalyst for the OER. Alkaline-etched BiVO4 prepared using hydrothermal and soaking processes shows better photocatalytic abilities due to the generation of additional oxygen vacancies, while poor photocatalytic ability is found for that fabricated using electrodeposition due to the formation of less photocatalytic VO2. The highest photocurrent density of 2.38 mA cm−2 is obtained at 1.23 V versus a reversible hydrogen electrode in an electrolyte without a hole scavenger for the BiVO4 etched in the hydrothermal process, while the untreated BiVO4 presents a photocurrent density of 0.58 mA cm−2. A photocurrent retention of 92.3% is achieved after 5000 seconds of continuous illumination. The study supplies blueprints for establishing effective alkaline etching methods for enhancing the photocatalytic ability of BiVO4, with the exception of time costs. © 2024 The Royal Society of Chemistry.

关键词： Charge transfer

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Chiral, Topological, and Knotted Colloids in Liquid Crystals

arXiv

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arXiv 2024年

作者： Yuan, Ye Smalyukh, Ivan I. Hiroshima University Hiroshima Higashi-Hiroshima739-8526 Japan Department of Physics Department of Electrical Computer and Energy Engineering Materials Science and Engineering Program Soft Materials Research Center University of Colorado BoulderCO80309 United States Renewable and Sustainable Energy Institute National Renewable Energy Laboratory University of Colorado BoulderCO80309 United States

The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low symmetry and nontrivial topology of surface confinement are of particular interest, including surfaces shaped as handlebodies, spirals, knots, multi-component links, and so on. These types of colloidal surfaces induce topologically nontrivial three-dimensional director field configurations and topological defects. Director switching by electric fields, laser tweezing of defects, and local photo-thermal melting of the liquid crystal host medium promote transformations among many stable and metastable particle-induced director configurations that can be revealed by means of direct label-free three-dimensional nonlinear optical imaging. The interplay between topologies of colloidal surfaces, director fields, and defects is found to show a number of unexpected features, such as knotting and linking of line defects, often uniquely arising from the nonpolar nature of the nematic director field. This review article highlights fascinating examples of new physical behavior arising from the interplay of nematic molecular order and both chiral symmetry and topology of colloidal inclusions within the nematic host. Furthermore, the article concludes with a brief discussion of how these findings may lay the groundwork for new types of topology-dictated self-assembly in soft condensed matter leading to novel mesostructured composite materials, as well as for experimental insights into the pure-math aspects of low-dimensional topology. © 2024, CC BY.

关键词： Crystal symmetry

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Quantum aspects of hydrodynamic transport from weak electron-impurity scattering

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Physical Review B 2020年第12期101卷 121107(R)-121107(R)页

作者： Aaron Hui Samuel Lederer Vadim Oganesyan Eun-Ah Kim School of Applied & Engineering Physics Cornell University Ithaca New York 14853 USA Department of Physics Cornell University Ithaca New York 14853 USA Department of Physics and Astronomy College of Staten Island CUNY Staten Island New York 10314 USA Physics Program and Initiative for the Theoretical Sciences The Graduate Center CUNY New York New York 10016 USA

Recent experimental observations of apparently hydrodynamic electronic transport have generated much excitement. However, the understanding of the observed nonlocal transport (whirlpool) effects and parabolic (Poiseuille-like) current profiles has largely been motivated by a phenomenological analogy to classical fluids. This is due to difficulty in incorporating strong correlations in quantum mechanical calculation of transport, which has been the primary angle for interpreting the apparently hydrodynamic transport. Here we demonstrate that even free-fermion systems, in the presence of (inevitable) disorder, exhibit nonlocal conductivity effects such as those observed in experiments because of the fermionic system's long-range entangled nature. On the basis of explicit calculations of the conductivity at finite wave vector, σ(q), for selected weakly disordered free-fermion systems, we propose experimental strategies for demonstrating distinctive quantum effects in nonlocal transport at odds with the expectations of classical kinetic theory. Our results imply that the observation of whirlpools or other “hydrodynamic” effects does not guarantee the dominance of electron-electron scattering over electron-impurity scattering.

关键词： Electrical conductivity Quantum field theory Disordered systems Hydrodynamics

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