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Wood-derived freestanding integrated electrode with robust interface-coupling effect boosted bifunctionality for rechargeable zinc-air batteries

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Green Energy & Environment 2024年第12期9卷 1835-1846页

作者： Benji Zhou Nengneng Xu Liangcai Wu Dongqing Cai Eileen HYu Jinli Qiao State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Environmental Science and EngineeringDonghua University2999 Ren'min North RoadShanghai201620China College of Science Donghua University2999 Ren'min North RoadShanghai201620China Shanghai Institute of Pollution Control and Ecological Security 1515 North Zhongshan RoadShanghai200092China Department of Chemical Engineering Loughborough UniversityLoughboroughLE113TUUK

Fabricating non-noble metal-based carbon air electrodes with highly efficient bifunctionality is big challenge owing to the sluggish kinetics of oxygen reduction/evolution reaction(ORR/OER).The efficient cathode catalyst is urgently needed to further improve the performance of rechargeable zinc-air ***,an activation-doping assisted interface modification strategy is demonstrated based on freestanding integrated carbon composite(CoNiLDH@NPC)composed of wood-based N and P doped active carbon(NPC)and CoNi layer double hydroxides(CoNiLDH).In the light of its large specific surface area and unique defective structure,CoNiLDH@NPC with strong interfacecoupling effect in 2D-3D micro-nanostructure exhibits outstanding *** carbon composites show half-wave potential of 0.85 V for ORR,overpotential of 320 mV with current density of 10 mA cm^(-2) for OER,and ultra-low gap of 0.70 ***,highly-ordered open channels of wood provide enormous space to form abundant triple-phase boundary for accelerating the catalytic ***,zinc-air batteries using CoNiLDH@NPC show high power density(aqueous:263 mW cm^(-2),quasi-solid-state:65.8 mW cm^(-2))and long-term stability(aqueous:500 h,quasi-solid-state:120 h).This integrated protocol opens a new avenue for the rational design of efficient freestanding air electrode from biomass resources.

关键词： Wood biomass Bifunctional air electrode Freestanding carbon composite Interface-coupling effect Zinc-air battery

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Tuning static drop friction

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Droplet 2023年第1期2卷 56-63页

作者： Alexandre Laroche Abhinav Naga Chirag Hinduja Azadeh Aghili Sharifi Alexander Saal Hyeonjin Kim Nan Gao Sanghyuk Wooh Hans‐Jürgen Butt Rüdiger Berger Doris Vollmer Physics at Interfaces Max Planck Institute for Polymer ResearchMainzGermany School of Chemical Engineering&Materials Science Chung‐Ang UniversitySeoulRepublic of Korea Department of Mechanical Engineering University of BirminghamBirminghamUK

The friction force opposing the onset of motion of a drop on a solid surface is typically considered to be a material property for a fixed drop volume on a given ***,here we show that even for a fixed drop volume,the static friction force can be tuned by over 30%by preshaping the *** static friction usually exceeds the kinetic friction that the drop experiences when moving in a steady *** forces converge when the drop is prestretched in the direction of motion or when the drop shows low contact angle *** contrast to static friction,kinetic friction is independent of preshaping the drop,that is,the drop *** friction forces reflect the material properties.

关键词： friction properties forces

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Autonomous self-healing 3D micro-suction adhesives for multi-layered amphibious soft skin electronics

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InfoMat 2024年第10期6卷 65-79页

作者： Dohyun Lim Min Woo Jeong Hyeongho Min Yeon Soo Lee Gui Won Hwang Seung Hwan Jeon Kyu Ho Jung Ngoc Thanh Phuong Vo Min-Seok Kim Da Wan Kim Jin Young Oh Changhyun Pang School of Chemical Engineering Sungkyunkwan University(SKKU)SuwonGyeonggi-doRepublic of Korea Department of Chemical Engineering(Integrated Engineering Program) Kyung Hee UniversityYonginGyeonggiRepublic of Korea Convergence Research Group for Meta-Touch Korea Research Institute of Standards and ScienceDaejeonRepublic of Korea Department of Electronic Engineering Korea National University of TransportationChungju-siChungbukRepublic of Korea Samsung Advanced Institute for Health Sciences and Technology(SAIHST) Sungkyunkwan UniversitySuwonGyunggi-doRepublic of Korea

Autonomously self-healing, reversible, and soft adhesive microarchitecturesand structured electric elements could be important features in stable and versatilebioelectronic devices adhere to complex surfaces of the human body(rough, dry, wet, and vulnerable). In this study, we propose an autonomousself-healing multi-layered adhesive patch inspired by the octopus, which possessself-healing and robust adhesion properties in dry/underwater *** implement autonomously self-healing octopus-inspired architectures, adynamic polymer reflow model based on structural and material design suggestscriteria for three-dimensional patterning self-healing elastomers. In addition,self-healing multi-layered microstructures with different moduli endowsefficient self-healing ability, human-friendly reversible bio-adhesion, and stablemechanical deformability. Through programmed molecular behavior ofmicrolevel hybrid multiscale architectures, the bioinspired adhesive patchexhibited robust adhesion against rough skin surface under both dry andunderwater conditions while enabling autonomous adhesion restoring performanceafter damaged (over 95% healing efficiency under both conditions for24 h at 30℃). Finally, we developed a self-healing skin-mountable adhesiveelectronics with repeated attachment and minimal skin irritation by laminatingthin gold electrodes on octopus-like structures. Based on the robust adhesionand intimate contact with skin, we successfully obtained reliable measurements during dynamic motion under dry, wet, and damagedconditions.

关键词： biomimetics dry adhesive self-healing polymer stretchable electronics

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Cement-inspired readily fabricated water-strengthened polymeric materials

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science China Chemistry 2024年第10期67卷 3458-3467页

作者： Han Zuo Luzhi Zhang Huixia Xuan Shijia Gu Xinxin Xu Rasoul Esmaeely Neisiany Qilin Wu Zhengwei You State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Institute of Functional MaterialsCollege of Materials Science and EngineeringDonghua UniversityResearch Base of Textile Materials for Flexible Electronics and Biomedical Applications(China Textile Engineering Society)Shanghai Key Laboratory of Lightweight CompositeShanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineShanghai 201620China Zhejiang Hexin Science and Technology Co. Ltd.Jiaxing 314033China Biotechnology Centre Silesian University of TechnologyKrzywoustego 844-100 GliwicePoland Department of Polymer Engineering Hakim Sabzevari UniversitySabzevar ***Iran

polymeric materials have penetrated all aspects of society and play an irreplaceable ***,there is an inherent contradiction between their mechanical properties and processing ***,inspired by cement,a crucial construction material renowned for its excellent fabricating behavior and self-strengthening properties,we have developed dynamic crosslinked poly(oxime-urethane)(CPOU).The synthesized CPOU showed good self-healing ability and 3D printability owing to the dynamic dissociation and re-association of oxime-carbamate *** objects printed through the fused deposition modeling technique were able to be readily assembled into complex architectures through intrinsic ***,the self-strengthening of CPOU was successfully realized through multiple-step tandem *** dissociation of dynamic oxime-carbamate bonds produced–NCO groups,which reacted with the surrounding water to form polar urea bonds in the polymer network,leading to an increase in the tensile strength of CPOU from 11.95 to 19.37 *** work not only develops the polymers with combined self-healing,facile fabricating,and self-strengthening properties but also provides a new molecular strategy to modulate the properties of polymers,which could be potentially applied in diverse areas.

关键词： dynamic bonds 3D printing self-strengthening self-healing

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Crystalline porous ionic salts assembled from polyoxometalates and cationic capsule for the selective photocatalytic aerobic oxidation of aromatic alcohols to aldehydes

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Chinese chemical Letters 2023年第4期34卷 555-558页

作者： Qianxia Gu Xiao-Li Zhao Min Meng Zhiyu Shao Qi Zheng Weimin Xuan College of Chemistry Chemical Engineering and Biotechnology&State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsDonghua UniversityShanghai 201620China Shanghai Key Laboratory of Green Chemistry and Chemical Processes Department of ChemistryEast China Normal UniversityShanghai 200062China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials&College of Materials Science and Engineering Donghua UniversityShanghai 201620China

Crystalline porous ionic salts(CPISs) represent a new type of porous materials constructed by electrostatic interaction, however, synthesis of CPISs bearing pre-designed functionality while exhibiting permanent porosity is still challenging. Herein we report the facile synthesis of a series of CPISs 1-3 built from photocatalytic-active polyoxometalate(POM) clusters and cationic Zr-based capsules, which showed open porous frameworks with BET surface area up to 33 m^(2)/g and high activity and selectivity for photodriven aerobic oxidation of alcohols to aldehydes. Compared with the pristine POM cluster {W10}, 1 can promote the reaction in much higher efficiency due to the concerted catalysis of preinstalled {W10} and Zr-based capsule together with open channels. This work highlights the advantage of CPISs as porous heterogeneous catalysts in organic transformation, and may shed light on the rational design of more delicate CPISs-derived functional materials.

关键词： Crystalline porous ionic salts Polyoxometalates Cationic capsule Photocatalysis Oxidation

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Bending the Rule: Naphthobisthiadiazole-Based Terpolymers with Both High Solubility and Crystallinity for Organic Photovoltaics

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ACS Applied polymer Materials 2024年第5期6卷 2586-2593页

作者： Chou, Li-Hui Chen, Fengkun Nakano, Kyohei Yamanaka, Kodai Mikie, Tsubasa Saito, Masahiko Liu, Cheng-Liang Tajima, Keisuke Osaka, Itaru Department of Applied Chemistry Graduate School of Engineering Hiroshima University Hiroshima Higashi-Hiroshima739-8527 Japan Department of Chemical and Materials Engineering National Central University Taoyuan32001 Taiwan Saitama Wako351-0198 Japan Applied Chemistry Program Graduate School of Advanced Science and Engineering Hiroshima University Hiroshima Higashi-Hiroshima739-8527 Japan Department of Materials Science and Engineering National Taiwan University Taipei10617 Taiwan

Achieving a good balance between the crystallinity and solubility is of great importance in the design of π-conjugated polymers. Here, we synthesized a series of terpolymers in which small fractions of a planar V-shaped fused ring, triphenyleno[1,2-c:7,8-c′]bis([1,2,5]thiadiazole) (TPTz), are incorporated into the linear-shaped backbone of a highly crystalline polymer based on naphtho[1,2-c:5,6-c′]bis([1,2,5]thiadiazole) (NTz), PNTz4T. Due to the "bending" structure induced by the TPTz unit, the terpolymers had greatly improved solubility by about 5-9 times compared to the linear-shaped PNTz4T. In particular, the terpolymers preserved the crystallinity of PNTz4T to a considerable extent with a higher fraction of face-on oriented domains in films. As a result, the highly solution-processable terpolymers exhibited high photovoltaic performances and slightly outperformed PNTz4T. Our results indicate that the incorporation of a V-shaped unit into a linearly shaped polymer is a good strategy to develop π-conjugated polymers with high solubility and crystallinity. © 2024 American chemical Society.

关键词： Solubility

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Unassisted photoelectrochemical CO_(2)reduction by employingⅢ-Ⅴphotoelectrode with 15%solar-to-fuel efficiency

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Carbon Energy 2025年第3期7卷 1-10页

作者： Karthik Peramaiah Purushothaman Varadhan Vinoth Ramalingam Bilawal Khan Pradip Kumar Das Hao Huang Hui-Chun Fu Xiulin Yang Vincent Tung Kuo-Wei Huang Jr-Hau He Chemistry Program Center for Renewable Energy and Storage Technologies(CREST)and Division of Physical Science and EngineeringKing Abdullah University of Science and Technology(KAUST)ThuwalSaudi Arabia Institute of Sustainability for Chemicals Energyand Environment(ISCE2)Agency for ScienceTechnologyand Research(A*STAR)Singapore School of Computing Engineering and TechnologyRobert Gordon UniversityAberdeenUK Department of Materials Science and Engineering City University of Hong KongKowloonSARHong KongChina Guangxi Key Laboratory of Low Carbon Energy Materials School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilinChina Department of Chemical System and Engineering University of TokyoTokyoJapan

Solar-driven carbon dioxide reduction reaction(CO_(2)RR)provides an oppor tunity to produce value-added chemical feedstocks and ***,achieving efficient and stable photoelectrochemical(PEC)CO_(2)RR into selec tive products is challenging owing to the difficulties associated with the optical and the electrical configuration of PEC devices and electrocatalyst ***,we construct an efficient,concentrated sunlight-driven CO_(2)RR setup consisting of InGaP/GaAs/Ge triple-junction cell as a photoanode and oxide-derived Au(Ox-Au)as a cathode to perform the unassisted PEC CO_(2)*** one-sun illumination,a maximum operating current density of 11.5 mA cm^(-2) with an impressive Faradaic efficiency(FE)of~98%is achieved for carbon monoxide(CO)production,leading to a solar-to-fuel conversion efficiency of~15%.Under concentrated intensity of 10 sun,the photoanode records a maximum current density of~124 mAcm^(-2) and maintains~60%of FE for CO *** results demonstrate crucial advancements in usingⅢ-Ⅴbased photoanodes for concentrated PEC CO_(2)RR.

关键词： 3J photoanode CO_(2)reduction high STF unassisted PEC

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The Potential Game-Changer:A Concept-to-Proof Study on D:A Heterojunction-Free Organic Photovoltaics

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Chinese Journal of Chemistry 2024年第3期42卷 252-258页

作者： Lijian Zuo Sae Byeok Jo Xueliang Shi Francis Lin Alex Jen State Key Laboratory of Silicon and Advanced Semiconductor Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhouZhejiang310058 China Department of Materials Science and Engineering University of WashingtonSeattleWAUSA School of Chemical Engineering Sungkyunkwan University (SKKU)Suwon16419 Republic of Korea School of Chemistry and Molecular Engineering East China Normal UniversityShanghai200062 China Department of Materials Science and Engineering City University of Hong KongKowloonHong KongChina Department of Chemistry City University of Hong KongKowloonHong KongChina Hong Kong Institute for Clean Energy Hong KongChina

Since 1986,the donor-acceptor (D:A) heterojunction has been regarded a necessity for high-efficiency organic photovoltaics (OPVs),due to its unique advantage in compensating the intrinsic limitations of organic semiconductors,such as high exciton binding energy and poor ambipolar charge mobility. While this adversely causes tremendous non-radiative charge recombination and instability issues,which currently become the most critical limits for commercialization of OPVs. Here,we present a concept-to-proof study on the potential of D:A heterojunction free OPV by taking advantage of recent progress of non-fullerene acceptors. First,we demonstrate that the “free carriers” can be spontaneously generated upon illumination in an NFA,i.e.,the 6TIC-4F single layer. Second,the 6TIC-4F layer also exhibits good ambipolar charge transporting property. These exceptional characteristics distinguish it from the traditional organic semiconductors,and relieve it from the reliance of D:A heterojunction to independently work as active layer. As a result,the subsequent OPV by simply sandwiching the 6TIC-4F layer between the cathode and anode yields a considerably high power conversion efficiency ~1%. Moreover,we find the D:A heterojunction free device exhibits two order of magnitude higher electroluminescence quantum efficiency and significantly reduced VOC loss by 0.16 eV compared to those of the D:A BHJ structure,validating its promise for higher efficiency in the future. Therefore,our work demonstrates the possibility of using D:A heterojunction-free device structure for high performance,that can potentially become the next game changer of OPV.

关键词： Organic solar cells Spontaneous charge generation Ambipolar charge transport Charge recombination Perovskite-like organic semiconductor Schottky-junction structure Single component

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A low-cost and environmentally-friendly chitosan/spent coffee grounds composite with high photothermal properties for interfacial water evaporation

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Journal of Industrial and engineering Chemistry 2023年 126卷 283-291页

作者： Hsieh, Po-Cheng Chen, Yi-Chun Zheng, Nai-Ci Mangindaan, Dave Chien, Hsiu-Wen Department of Chemical and Materials Engineering National Kaohsiung University of Science and Technology Kaohsiung80778 Taiwan Department of Forestry National Chung-Hsing University Taichung40227 Taiwan Professional Engineering Program Department Faculty of Engineering Bina Nusantara University Jakarta11480 Indonesia National Kaohsiung University of Science and Technology Kaohsiung80778 Taiwan

The present study explores the remarkable photothermal properties and potential applications exhibited by melanoidin-enriched spent coffee grounds (SCGs). However, the inherent challenge lies in the substantial particle size of SCGs, leading to rapid sedimentation within the medium and resulting in uneven heat distribution during photothermal analysis. To overcome this obstacle, acid hydrolysis was employed to liquefy the SCGs, allowing their dispersion in water and significantly enhancing their light absorption capacity. The photothermal properties of liquefied SCGs (LSCGs) were analyzed under 808-nm near-infrared (NIR) irradiation and compared with those of SCGs. Remarkably, the photothermal conversion efficiency of the LSCGs was as high as 52%, twice that of SCGs. To further explore their potential, the LSCGs were incorporated into chitosan (CS) to create homogenous and porous CS/LSCGs composites. These low-cost and environmentally friendly CS/LSCGs composites, made entirely from waste materials, demonstrated photothermal properties under NIR irradiation. Notably, they exhibited excellent performance in multiple cycles of water evaporation experiments, achieving an impressive water evaporation efficiency of nearly 90%. © 2023 The Korean Society of Industrial and engineering Chemistry

关键词： Lignocellulose

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engineering tiramisu-like phase change nanocomposite for superior thermal energy management and electromagnetic interference shielding

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材料科学技术（英文版） 2025年第3期206卷 113-124页

作者： Boyang Hu Hong Guo Ting Li Xiwei Cao Min Cao Weiyan Qi Ying Cui Baoan Li Carbon Neutrality Interdisciplinary Science Centre Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China Carbon Neutrality Interdisciplinary Science Centre Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionCollege of Environmental Science and EngineeringNankai UniversityTianjin 300350China Department of Energy and Chemical Engineering Tianjin Ren'ai CollegeTianjin 301636China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China Laboratoire des Solides Irradiés CEA/DRF/lRAMISEcole Poly techniqueCNRSInstitut Poly technique de ParisPalaiseau F-91128France

Exploiting advanced nanocomposites isochronally integrating outstanding thermal conductivity(TC)and electromagnetic interference shielding effectiveness(EMI SE)can boost the cutting-edge application of phase change ***,we report a tiramisu-like composite(GMP),where the typical"crust-and-cheese"hierarchical structure is replicated by an innovative two-step bidirectional freezing assem-bly(BFA)and compressive ***-aligned graphene array(G-GA)with ultralow ther-mal resistance is fabricated through 1st BFA and *** the 2nd BFA,the MXene-CNF crosslinking network with hydrogen-bond actions is used for encapsulating polyethylene glycol(PEG)onto the microlayers of the G-GA ***,the microlaminated GMP4 achieves a recorded TC of 34.05 W m-1 K-1,unprecedented EMI SE of 87.4 dB,and preferable enthalpy density of 179.4 J cm-3,along with leakage-free function,and eminent thermal ***,the GMP-loaded equipment is demonstrated for efficient microelectronics cooling and sustainable solar energy *** work opens new avenues for multiscale designing multifunctional macro-composites,broadening the application prospects in advanced electronics and solar energy utilization systems.

关键词： Phase change composite Multiscale structure construction Bidirectional freezing assembly Thermal management EMI shielding

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