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An interfacial robust and entire self-healing ionogel-elastomer hybrid for elastic electronics enables discretionary assembly and reconfiguration

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science China Chemistry 2024年第4期67卷 1316-1323页

作者： Lei Yang Lijie Sun Hongfei Huang Rasoul Esmaeely Neisiany Zhengwei You State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Institute of Functional MaterialsCollege of Materials Science and EngineeringDonghua UniversityResearch Base of Textile Materials for Flexible Electronics and Biomedical Applications(China Textile Engineering Society)Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineShanghai 201620China Department of Polymer Engineering Hakim Sabzevari UniversitySabzevar ***Iran Biotechnology Centre Silesian University of TechnologyGliwice 44-100Poland

Inspired by the multi-layer architecture of mammal skins,interfacial robust,stretchable,and entirely healable gel-elastomer hybrids hold great potential in diverse fields including biomedical devices,wearable electrical devices,and soft ***,existing gel-elastomer hybrids have numerous limitations including low interfacial bonding toughness,complex and time-consuming preparation process,unhealable,and ***,we propose a simple and general chemical strategy through the interfacial dynamic bonding between gel and elastomer to simultaneously address the abovementioned *** covalent bonds readily and repeatably covalent bonding ionogel and elastomer(interfacial toughness:390 J m^(-2)),endowed the hybrids with entire self-healing features like skin and enabled discretionary assembly and ***,this strategy resolved the troublesome contradiction between interfacial stability and *** advantage of the aforementioned features,we readily constructed a multi-module,self-healing,self-powered,and realtime monitoring of personal status integrated elastic electronics,which could simply reconfigure the output signal of elastic electronics into an input signal of the devices-braille keyboard.

关键词： ionogel elastomer interface bonding self-healing dynamic covalent bond

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Highly aligned reduced graphene oxide in alumina composites for strengthening,toughening,and electromagnetic interference shielding

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Journal of Materiomics 2023年第6期9卷 993-1003页

作者： Tufail Mustafa Yongping Liu Jie Gao Peng Yan Qi Ding Yuchi Fan Wan Jiang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Institute of Functional MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai200050China Department of Chemical Engineering Balochistan University of Information TechnologyEngineering&Management Sciences(BUITEMS)Quetta87300Pakistan

engineering ceramics with high strength,toughness and electromagnetic interference(EMI)shielding effectiveness(SE)are highly desirable as electromagnetic protecting material in harsh ***,we show that both excellent mechanical and EMI shielding performance can be realized in alumina composites embedded with highly aligned reduced graphene oxide(RGO),which are readily prepared via sintering of core-shell structured RGO@Al_(2)O_(3)nanoplates with *** to monolithic Al_(2)O_(3),the highly aligned RGO/Al_(2)O_(3)composites show simultaneously improved strength and toughness up to~26.1%and~60.2%,*** steeply rising R-curve behavior proves the better crack tolerance in the highly aligned structure with respect to randomly oriented ***,the RGO/Al_(2)O_(3)composites also exhibit a high specific EMI SE reaching~34 dB/mm in K band,due to the reflection and highly enhanced absorption after percolation in the out-of-plane *** findings provide a novel strategy of designing mechanically reliable engineering ceramic for EMI shielding.

关键词： Reduced graphene oxide Ceramic composites Strengthening Toughening Electromagnetic interference shielding

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Alternating Copolymerization of Epoxides and Isothiocyanates to Diverse Functional Polythioimidocarbonates and Related Block polymers

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Chinese Journal of Chemistry 2023年第23期41卷 3311-3318页

作者： Xiao-Feng Zhu Xin-Yu Lu Cheng-Kai Xu Yu-Bo Fang Guan-Wen Yang Wei Li Jingdai Wang Guang-Peng Wu MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhouZhejiang310027 China Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological EngineeringZhejiang UniversityHangzhouZhejiang310027 China

Synthesis of diverse polythioimidocarbonates via ring-opening copolymerization of epoxides and isothiocyanates catalyzed by organoboron catalyst was reported *** aromatic and aliphatic isothiocyanates underwent successful copolymerization with terminal and internal epoxides,allowing for the precise tuning of the performance of the resultant copolymers over a broad *** wide scope of available isothiocyanates and epoxides enables the direct construction of sulfur-containing functional polymers featuring both high glass transition temperature and refractive ***,it was observed that aromatic isothiocyanates polymerize much faster than aliphatic ones,and the reactivity difference facilitated the one-step synthesis of block polymers from mixed aromatic isothiocyanates,aliphatic isothiocyanates and epoxides due to the preferential incorporation of aromatic isothiocyanates over the aliphatic analogues during their alternating copolymerization with *** produced polythioimidocarbonates can be used as positive resists for electron beam lithography(sensitivity of 130μC/cm^(2) and contrast of 1.53 for poly(CHO-alt-EITC)).Coupling with their high refractive index(1.58—1.68),polythioimidocarbonates might find functional applications in *** results render ring-opening copolymerization of epoxides and isothiocyanates a facile route to enrich functional polymer library.

关键词： Ring-opening copolymerization Metal-free catalysis Sulfur-containing polymers Block polymers Electron beam lithography High refractive index

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Effect of Mixed Dispersants on Suppression of the Gel Effect during Aqueous Adiabatic Terpolymerization of AM,NaAA,and DMC

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China Petroleum Processing & Petrochemical Technology 2023年第3期25卷 83-91页

作者： Yang Junfeng Zhou Manli Wang Meng Qingyuan Yakoo Chemical Co. LtdQingyuan 510640China Department of Polymer Science and Engineering South China University of TechnologyGuangzhou 510640China

Gelation adversely affects the aqueous adiabatic terpolymerization of acrylamide (AM), sodium acrylate (NaAA),and 2-methacryloyloxyethyl trimethylammonium chloride (DMC). Here, the mixed dispersants sorbitan monooleate (Span80) and polyoxyethylene sorbitan monooleate (Tween 80) were introduced to the terpolymerization system in an attemptto mitigate the gel effect. This enabled the preparation of high-performance amphoteric polyacrylamides, which werecharacterized by Fourier-transform infrared spectroscopy and thermogravimetric analysis. The influences of the dispersanttype and content as well as the hydrophilic-lipophilic balance (HLB) on the gel effect were examined, and the mechanismunderlying the suppression of the gel effect was considered. The obtained results indicated that the gel effect can beeffectively mitigated using an aqueous adiabatic terpolymerization system containing mixed Span 80/Tween 80 dispersantsat various contents. In particular, mixed dispersant contents of 0.6%–0.8% with HLB values of 5.0–6.0 afforded the optimalperformance (e.g., high viscosity, fast aqueous dissolution time, and the like).

关键词： gel effect dispersants amphoteric polyacrylamide terpolymerization

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A dual-responsive hyaluronic acid nanocomposite hydrogel drug delivery system for overcoming multiple drug resistance

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Chinese chemical Letters 2023年第1期34卷 255-261页

作者： Yi Liu Man Zhu Minsi Meng Qiao Wang Yun Wang Yu Lei Yanmin Zhang Lin Weng Xin Chen Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities College of Chemical EngineeringSichuan University of Science and EngineeringZigong 643000China Institute of Precision Medicine Zigong Fourth People’s HospitalZigong 643000China Department of Chemical Engineering Shaanxi Key Laboratory of Energy Chemical Process IntensificationInstitution of Polymer Science in Chemical EngineeringSchool of Chemical Engineering and TechnologyXi’an Jiao Tong UniversityXi’an 710049China School of Pharmacy Health Science CenterXi’an Jiaotong UniversityXi’an 710061China

Chemotherapy is restricted by efficient drug outflow due to the multiple drug resistance(MDR)in heterogenous nature of ***,we present a dual-responsive hyaluronic acid(HA)nanocomposite hydrogel that can not only response to the tumor microenvironment but also enhance *** HA hydrogel consists of a core-shell SiO_(2)(GOD@SiO_(2)-Arg)and mesoporous silica nanoparticles(MSNs)with doxorubicin(DOX)as the cargo(DOX@MSN).It could rapidly release the GOD@SiO_(2)-Arg nanoparticles at the low p H tumor-specific environment due to the cleavage of imine ***@SiO_(2)-Arg activated by over-expressed glutathione(GSH)in tumor cells releases GOD due to the cleavage of disulfide bonds,which could oxidize glucose to produce hydrogen peroxide(H2O2)for in situ NO generation via reaction between Arg and *** validity of this study might provide a method to modulate the tumor microenvironment for enhancing chemotherapy.

关键词： Dual-responsive HA hydrogel P-gp inhibition MDR Enhance chemotherapy

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Dual modifications of sensitizers and lanthanide ions on a two-dimensional zirconium-based metal-organic framework for photoluminescent detection

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CrystEngComm 2024年第22期26卷 2852-2861页

作者： Chang, Jhe-Wei Lin, Tzu-Chi Chen, You-Liang Han, Po-Chun Yang, Shang-Cheng Tsai, Meng-Dian Wu, Kevin C.-W. Kung, Chung-Wei Department of Chemical Engineering National Cheng Kung University Tainan City70101 Taiwan Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Ph. D. Program of Green Materials and Precision Devices College of Engineering National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Chung-Li Taoyuan320 Taiwan

A two-dimensional (2D) zirconium-based metal-organic framework (Zr-MOF) with abundant terminal -OH/-OH2 groups on its nodes, ZrBTB (BTB = 1,3,5-tris(4-carboxyphenyl)benzene), is utilized as a platform for dual post-synthetic modifications (PSM) to immobilize both the benzophenone-based photosensitizer (benzophenone-4,4′-dicarboxylate, bzpdc) and terbium ions onto the 2D Zr-MOF molecular sheets. Terbium ions are installed on the 2D Zr-MOF at various temperatures to adjust the loading of terbium ions on the 2D Zr-MOF while preserving the loading of the photosensitizer. The crystallinity, morphology, porosity, and loadings of both bzpdc ligands and terbium ions are characterized for each material, and the coordinating locations of terbium ions in the Zr-MOF structure are investigated. The photoluminescence (PL) properties of these materials are then examined. Since the installed bzpdc ligand can induce a highly efficient energy transfer to the neighbouring terbium ion upon excitation, the obtained material after dual PSM (ZrBTB-bzpdc-Tb-120) can show strong PL emissions of terbium ions upon the excitation of the bzpdc ligand at 355 nm, with a PL quantum yield of 5.04%. It is more advantageous than the 2D Zr-MOF solely functionalized with terbium ions, which can only exhibit similar emissions upon the excitation of the BTB linker at a less friendly wavelength of 310 nm, with a lower PL quantum yield of 2.94%. Owing to the high chemical stability as well as good dispersity of the luminescent ZrBTB-bzpdc-Tb-120 in water, its performances in selective PL sensing of Fe(iii) ions present in aqueous solutions are investigated. © 2024 The Royal Society of Chemistry.

关键词： Carboxylation

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Will the fibers of the future be considered fibers?

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National science Review 2024年第10期11卷 15-17页

作者： Dewen Xu Ya Liu Hailiang Wang Wei Yan Changjun Jiang Meifang Zhu State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Key Laboratory of Embedded System and Service Computing Ministry of Education Tongji University Department of Computer Science and Technology Tongji University

Fiber materials are key materials that have changed human history and promoted the progress of human civilization. In ancient times, humans used feathers and animal skins for clothing, and later they widely employed natural fibers such as cotton, hemp, silk and wool to make fabrics(Fig. 1a). Chinese ancestors had mastered the art of natural fiber weaving as early as the Neolithic *** thousand years ago, people were already familiar with and adept at techniques for spinning natural fibers [1].

关键词： future will considered fibers

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MXene:From synthesis to environment remediation

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Chinese Journal of chemical engineering 2023年第9期61卷 260-280页

作者： Ali Nikkhah Hasan Nikkhah Hadis langari Alireza Nouri Abdul Wahab Mohammad Ang Wei Lun Ng law Yong Rosiah Rohani Ebrahim Mahmoudi Department of Chemical and Process Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan MalaysiaBangi 43600Malaysia Department of Mechanical and Aerospace Engineering University at BuffaloBuffaloUSA Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsUSA Department of Chemistry and Medicinal Chemistry University at BuffaloBuffaloUSA Chemical and Water Desalination Engineering Program College of EngineeringUniversity of SharjahSharjah 27272United Arab Emirates Lee Kong Chian Faculty of Engineering and Science Universiti Tunku Abdul RahmanJalan Sungai LongBandar Sungai LongKajangSelangorMalaysia

A new burgeoning family of two-dimensional(2D)transition metal carbides/nitrides,better known as MXenes,have received extensive attention because of their distinct properties,such as metallic conductivity,good hydrophilicity,large surface area,good mechanical stability,and *** 40 different MXenes have been synthesized,and dozens more structures and properties have been theoretically ***,the recent progress in MXenes development is not well covered in chronological order based on different *** review article focuses on emerging synthesis methods,the properties of MXenes,and mainly the applications of MXenes and MXene-based material family in environmental remediation,a comprehensive review of gaseous and aqueous pollutants treatment.

关键词： MXene 2D materials Wastewater treatment CO_(2)capture Adsorption Photodegradation

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A review on reactive oxygen species-induced mechanism pathways of pharmaceutical waste degradation:Acetaminophen as a drug waste model

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Journal of Environmental sciences 2025年第1期147卷 688-713页

作者： Saba Humayun Maan Hayyan Yatimah Alias Department of Chemistry Faculty of ScienceUniversity of MalayaKuala Lumpur 50603Malaysia University of Malaya Centre for Ionic Liquids University of MalayaKuala Lumpur 50603Malaysia Chemical Engineering Program Faculty of Engineering and TechnologyMuscat UniversityMuscat P.C.130Oman

Innately designed to induce physiological changes,pharmaceuticals are foreknowingly hazardous to the *** oxidation processes(AOPs)are recognized as a set of contemporary and highly efficient methods being used as a contrivance for the removal of pharmaceutical *** reactive oxygen species(ROS)are formed in these processes to interact and contribute directly toward the oxidation of target contaminant(s),a profound insight regarding the mechanisms of ROS leading to the degradation of pharmaceuticals is fundamentally *** conceptualization of some specific reaction mechanisms allows the design of an effective and safe degradation process that can empirically reduce the environmental impact of *** review mainly deliberates themechanistic reaction pathways for ROS-mediated degradation of pharmaceuticals often leading to complete mineralization,with a focus on acetaminophen as a drug waste model.

关键词： Wastewater treatment Ionic liquid Hydroxyl radical Superoxide Pharmaceutical contaminant Advanced oxidation process Deep eutectic solvent Hydrogen peroxide

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X-CoOTe (X = S, Se, and P) with Oxygen/Tellurium Dual Vacancies and Banana Stem Fiber-Derived Carbon Fiber as Battery-Type Cathode and Anode Materials for Asymmetric Supercapacitor

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ACS Applied Materials and Interfaces 2024年第15期16卷 18754-18767页

作者： Sakthivel, Mani Ho, Kuo-Chuan Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Advanced Research Center for Green Materials Science and Technology National Taiwan University Taipei10617 Taiwan Institute of Polymer Science and Engineering National Taiwan University Taipei10617 Taiwan

In this work, we demonstrated the synthesis of anions (X = selenium (Se), sulfur (S), and phosphorus (P)) doped cobalt oxytelluride (X-CoOTe) with oxygen and tellurium dual vacancies using hydrothermal methods, followed by selenization, sulfurization, and phosphorization reactions. Especially, the Se-CoOTe-modified nickel foam (Se-CoOTe/NF) electrode delivered a higher specific capacity (752.95 C/g) and an extremely lower charge transfer resistance (0.87 Ω) than S-CoOTe/NF and P-CoOTe/NF due to the higher metallic conductivity of Se. Both oxygen and tellurium vacancies facilitate higher charge transfer conductivity, specific capacity, and stability. On the other hand, banana stem core fiber-derived activated carbon fiber (AC) with exfoliated carbon sheet, cracked surface, and corresponding high surface area boosts the excellent cycle stability up to 4000 cycles with capacitance retention of 100.29%. Thus, the asymmetric device (Se-CoOTe/NF//AC/NF) exhibited an extendable cell voltage (1.55 V), higher energy density (155.6 W h kg-1) at a power density (1356.2 W kg-1), and generous long-term stability (100% retention up to 10 000 cycles) in a liquid alkaline electrolyte. In the practicability test, the proposed asymmetric device mutually showed an increased operating voltage from 1.55 to 4.65 V for a three-series connection. In a three-series connection, a single white LED and an LED string glowed efficiently. This new finding will be very useful to develop tellurium-based chalcogenides and biowaste-derived carbon for energy storage applications. © 2024 The Authors. Published by American chemical Society.

关键词： Supercapacitor

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