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Structural, Morphological, Optical, and Antibacterial Activities of Zinc Oxide Nanopowders: A Comparative Study of Green and Soft Chemical Synthesis

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Advances in materials science and Engineering 2022年第0期2022卷

作者： Siriya Pushpa, K. Catherine Sakthivel, P. Saravanakumar, K. Anuradha, N. Sankaranarayanan, R.K. Paulraj, Mosae Selvakumar Post-Graduate and Research Department of Physics Bon Secours College for Women Tamil Nadu Thanjavur613006 India Centre for Materials Science Department of Physics Science and Humanities Faculty of Engineering Karpagam Academy of Higher Education Coimbatore641021 India Mallasamudram Tamil Nadu Namakkal637503 India Centre for Nano Science and Technology Department of Chemistry Chennai Institute of Technology Tamil Nadu Kundrathur600069 India AUW Chemistry Hub Science and Math Program Asian University for Women Chattogram Bangladesh

Zinc oxide, a well-known inorganic metal oxide in nanoparticle form, has outstanding antibacterial properties. In this work, the authors focus on determining ZnO nanoparticles’ structural, optical, and antibacterial activity. A simple soft chemical route synthesizes C-ZnO nanoparticles chemically, while the green synthesis method is used to prepare G-ZnO nanoparticles. Ocimum tenuiflorum leaf extract was used to prepare G-ZnO nanopowders. These samples are investigated and compared in terms of their structural, morphological, optical, and antibacterial properties. According to XRD investigations, the synthesized ZnO nanopowders possess a hexagonal structure. The particle size of G-ZnO is smaller than that of C-ZnO nanoparticles. The XPS result revealed the binding and interactions between molecules. The FTIR study confirmed the presence of molecules and their vibrations. UV-vis-DRS spectroscopy was used to investigate optical properties such as reflectance and band gap. The grain size of the G-ZnO nanopowders was decreased, and oxygen vacancy was produced. The antibacterial efficiency of plant extracts against two different bacterial strains, S. aureus (Gram-positive) and *** (Gram-negative), has been studied and reported. Copyright © 2022 K. Catherine Siriya Pushpa et al.

关键词： ZnO nanoparticles

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Tumor-derived interleukin-1 receptor antagonist exhibits immunosuppressive functions and promotes pancreatic cancer

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Cell and Bioscience 2023年第1期13卷 1页

作者： Fan, Yu-Ching Fong, Yu-Cin Kuo, Chun-Tse Li, Chia-Wei Chen, Wei-Yu Lin, Jian-Da Bürtin, Florian Linnebacher, Michael Bui, Quoc Thang Lee, Kuan-Der Tsai, Yuan-Chin Ph.D. Program for Cancer Molecular Biology and Drug Discovery College of Medical Science and Technology Taipei Medical University and Academia Sinica Taipei Taiwan Graduate Institute of Cancer Biology and Drug Discovery College of Medical Science and Technology Taipei Medical University Taipei Taiwan Institute of Biomedical Sciences Academia Sinica Taipei Taiwan Department of Pathology Wan Fang Hospital Taipei Medical University Taipei Taiwan Department of Pathology School of Medicine College of Medicine Taipei Medical University Taipei Taiwan Department of Biochemical Science and Technology College of Life Science National Taiwan University Taipei City 10617 Taiwan Center for Computational and Systems Biology National Taiwan University Taipei City 10617 Taiwan Clinic of General Surgery University Medical Center Rostock Schillingallee 35 Rostock 18057 Germany Clinic of General Surgery Molecular Oncology and Immunotherapy University Medical Center Rostock Schillingallee 69 Rostock 18057 Germany International Ph.D. Program for Cell Therapy and Regeneration Medicine (IPCTRM) School of Medicine College of Medicine Taipei Medical University Taipei Taiwan Department of Post-Baccalaureate Medicine College of Medicine Natioanl Chung Hsing University Taichung Taiwan Cell Therapy and Regenerative Medicine Center and Comprehensive Cancer Center Taichung Veterans General Hospital Taichung Taiwan Ph.D. Program for Cancer Molecular Biology and Drug Discovery College of Medical Science and Technology Taipei Medical University Taipei Taiwan

Background: Pancreatic ductal adenocarcinoma (PDA) is a pernicious disease characterized by an immunosuppressive milieu that is unresponsive to current immunotherapies. Interleukin-1 receptor antagonist (IL-1Ra) is a natural anti-inflammatory cytokine;however, its contribution to cancer pathogenesis and immunosuppression remains elusive. In this research, we investigated the role and mechanism of IL-1Ra in malignant progression of PDA. Results: Through analyzing clinical dataset and examining the pathological tumor tissues and serum samples, we have demonstrated that IL-1Ra expression is elevated in human PDA and positively associated with malignant progression of PDA. To study the biological function of IL-1Ra in tumors, we generated a set of mouse pancreatic cancer cell lines with a knockout (KO) of the Il1rn gene, encoding IL-1Ra, and compared the tumor growth rates in immune-competent and immune-deficient mice. We found that the Il1rn KO cells exhibited greater tumor inhibition in immune-competent mice, highlighting the crucial role of a functional immune system in Il1rn KO-mediated anti-tumor response. Consistently, we found an increase in CD8⁺ T cells and a decrease in CD11b⁺Ly6G⁻ immunosuppressive mononuclear population in the tumor microenvironment of Il1rn KO-derived tumors. To monitor the inhibitory effects of IL-1Ra on immune cells, we utilized a luciferase-based reporter CD4⁺ T cell line and splenocytes, which were derived from transgenic mice expressing ovalbumin-specific T cell receptors in CD8⁺ T cells, and mice immunized with ovalbumin. We showed that IL-1Ra suppressed T cell receptor signaling and inhibited antigen-specific interferon-γ (IFN-γ) secretion and cytolytic activity in splenocytes. Conclusions: Our findings illustrate the immunosuppressive properties of the natural anti-inflammatory cytokine IL-1Ra, and provide a rationale for considering IL-1Ra-targeted therapies in the treatment of

关键词： IFN-γ Immunosuppression interleukin-1 receptor antagonist Pancreatic adenocarcinoma Patient-derived xenograft Tumor microenvironment

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Stabilizing zinc anode via a chelation and desolvation electrolyte additive

Advanced Powder Materials

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Advanced Powder materials 2022年第1期1卷 97-105页

作者： Jin Cao Dongdong Zhang Rungroj Chanajaree Yilei Yue Zhiyuan Zeng Xinyu Zhang Jiaqian Qin International Graduate Program of Nanoscience&Technology Chulalongkorn UniversityBangkok10330Thailand Metallurgy and Materials Science Research Institute Chulalongkorn UniversityBangkok10330Thailand State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao066004China Department of Materials Science and Engineering City University of Hong Kong83 Tat Chee AvenueKowloonHong Kong999077China Research Unit of Advanced Materials for Energy Storage Chulalongkorn UniversityBangkok10330Thailand

The uncontrollable dendrites growth and intricately water-induced side reactions occurred on zinc anode leads to safety issues and poor electrochemical kinetics,which largely limit the widespread application of zinc-ion batteries(ZIBs).Herein,ethylenediaminetetraacetic acid disodium salt(EDTA-2Na)is utilized as an electrolyte additive to strengthen the reversibility and cycling stability of zinc *** results and theoretical calculation demonstrate that the EDTA-2Na presents a much stronger coordination with Zn^(2+)when comparing with H_(2)O molecular,implying the EDTA-2Na is capable to enter the solvation shell of[Zn(OH_(2))_(6)]^(2+)and coordinate with Zn^(2+)ions,thus achieving a flat and smooth zinc deposition with less by-products(Zn_(4)SO_(4)(OH)6·xH_(2)O and H_(2)).Consequently,the zinc symmetric battery with EDTA-2Na additive delivers an excellent cycling stability up to 1800 h under current density of 1 mA cm^(-2),and the hydrogen evolution reaction(HER),corrosion,by-product issues are significantly ***,the rate performance and stability of coin-type and pouch-type Zn||MnO2/graphite batteries are significantly boosted via EDTA-2Na additive(248 mAh g^(-1)at 0.1 A g^(-1),81.3%after 1000 cycles at a A g^(-1)).This kind of electrolyte additive with chelation and desolvation functions shed lights on strategies of improving zinc anode stability for further application of ZIBs.

关键词： Zinc-ion battery Zinc anode Dendrites EDTA-2Na Desolvation

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Fabrication of sandwich-structured capacitor containing core@shell polystyrene@graphene oxide microspheres for switchable removal of dyes from water by dielectrophoresis force

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Separation and Purification technology 2024年 331卷

作者： Chen, Wei-Liang Cheng, Chih-Chia Lu, Chien-Hsing Chen, Jem-Kun Department of Materials Science and Engineering National Taiwan University of Science and Technology 43 Sec. 4 Keelung Road Taipei 106 Taiwan Division of Gastroenterology and Hepatology Department of Internal Medicine Chung Shan Medical University Hospital Taichung City402 Taiwan Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology Taipei10607 Taiwan Department of Obstetrics and Gynecology Taichung Veterans General Hospital Taichung40705 Taiwan Institute of Biomedical Sciences Ph.D. Program in Translational Medicine and Rong-Hsing Research Center for Translational Medicine National Chung-Hsing University Taichung940227 Taiwan

Absorption rates for traditional adsorbents were predominately determined by the concentration gradient from bulk to absorbents and surface area. A novel sandwich-structured capacitor (SSC) containing adsorbents is designed to reduce the time consuming of absorption of pollutants by dielectrophoresis force (FDEP). Graphene oxide (GO) are coated on polystyrene microspheres (PSs) as the core/shell PS@GO adsorbents that were encapsulated within the SSC to treat the solution of dye-emulsified micells (DEM). The FDEP results the assembling of PS@GOs and DEMs under polarization and enhance the adsorption rate ca. 1 ∼ 2 times with polarization at 3 V and 200 kHz. Additionally, most adsorbents are recycled with secondary pollution. Only two-fifth pure water volume of the wastewater through the SSC could achieve the recycling of the adsorbents at 900 kHz. The high complex permittivity of GO coating at high frequency allows ultrafast alternative spinning of the induced dipoles in the PS@GOs facilitates desorption and hinders the re-adsorption of the DEM during the recycling of PS@GOs. The PS@GOs was reused ca. 10 times at 20 mL min−1 of flow rate through the SSC without damages between 200 and 900 kHz. The designed SSC containing PS@GOs accomplishes either reusing of adsorbents or concentrating of dyes with low secondary pollution in practice through frequency manipulation. © 2023 Elsevier B.V.

关键词： Graphene

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Chiral metal-organic framework based spin-polarized flexible photodetector with ultrahigh sensitivity

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materials Today Nano 2023年 21卷

作者： Mustaqeem, M. Kamal, S. Ahmad, N. Chou, P.-T. Lin, K.-H. Huang, Y.-C. Guo, G.-Y. Paul Inbaraj, C.R. Li, W.-K. Yao, H.-C. Lu, K.-L. Chen, Y.-F. Department of Chemistry National Taiwan University No. 1 Section 4 Roosevelt Rd Taipei10617 Department of Physics National Taiwan University No. 1 Section 4 Roosevelt Rd Taipei10617 Nano-Science and Technology Program Taiwan International Graduate Program Institute of Physics Academia Sinica Taipei106 Taiwan Institute of Chemistry Academia Sinica Taipei115 Taiwan Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei10607 Taiwan Institute of Physics Academia Sinica Taipei11529 Taiwan Department of Materials Engineering Ming Chi University of Technology

Spin-optoelectronics plays a key role in developing next-generation technologies with potential applications covering from pharmaceutical synthesis and quantum computing to optical communication. One of the most feasible ways to achieve high-performance spin optoelectronic devices is based on chiral materials. Chiral metal-organic frameworks (CMOFs), an emerging class of chiral hybrid materials, have sparked interest due to their structural variety and flexibility, order nanopores, cost-effectiveness, and unique chirality features. Herein, we have developed CMOF [Sr (9,10-adc) (DMAc)2]n based on achiral building blocks [(9,10-adc)] to detect circularly polarized light (CPL) with ultrahigh sensitivity. Their application in spin-polarized flexible detectors gives a detectivity (D∗) as high as 1.83 × 1012 jones, superior to all reported heterochiral MOF-based detectors. Meanwhile, the anisotropy factor (gIph) is up to 0.38 for CPL detection. The maximum photoresponsivity (Rph) and photogain (η) values of CMOFs reach up to 6.0 × 105 (A/W) and 1.8 × 106, respectively, which are also the record values among reported chiral MOFs. Additionally, the photodetector is mechanically flexible and durable, manifesting an important feature for wearable devices. Therefore, our study shown here is significant and timely to open a route for advancing spin-optoelectronics based on CMOF. © 2023 Elsevier Ltd

关键词： Photodetectors

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Development and Validation of a Portable Optical Instrument for Estimating Leaf Nitrogen in Maize (Zea Mays L.)

SSRN

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SSRN 2024年

作者： Nogueira, Felipe Hermínio Meireles Ribeiro, Sharon Gomes Lima, Guilherme Santos Moreira, Luís Clênio Jario da Rocha Neto, Odílio Coimbra Nogueira, Ricardo Emílio Ferreira Quevedo dos Santos Teixeira, Adunias Department of Agricultural Engineering Federal University of Ceara Fortaleza60455-760 Brazil Soil Science Graduate Program Federal University of Ceara Fortaleza60455-760 Brazil Department of Agronomy Federal Institute of Education Science and Technology of Ceara Limoeiro do Norte62930-000 Brazil Department of Metallurgical and Materials Engineering Federal University of Ceara Fortaleza60455-760 Brazil

This study proposes the development and evaluation of a new portable multispectral instrument to estimate the leaf nitrogen concentration in maize crops in the field. The MSPAT (Multispectral Soil Plant Analysis Tools) includes the AS7265x sensor, which has 18 bands and covers the spectrum from 410 to 940 nm. The device was designed to be portable, using the ESP32 microcontroller and incorporating such functionality as data storage on a MicroSD card, communication with a smartphone via WiFi and geolocation of the acquired data. The MSPAT was evaluated in an experiment conducted at the Federal University of Ceará (UFC), where the maize was subjected to different doses of nitrogen fertiliser (0, 60, 90, 120, 150 and 180 ***−1 N). Spectral readings were taken at three phenological stages (V5, V10, R2) using the MSPAT, the SPAD-502 chlorophyll meter and the FieldSpec PRO FR3 spectroradiometer. After taking the optical measurements, the nitrogen content of the leaves was determined in the laboratory using the method proposed by Kjeldahl. The data analysis included the calculation of normalised ratio indices (NRIs) for the estimation using linear regression, and the application of multivariate statistical methods (PLSR and PCR) for predicting the leaf nitrogen concentration (LNC). The results showed that the MSPAT index with the best performance used the 900 nm band in a normalised ratio with the 560 nm band (R2 = 0.64) at stage V10. In the validation, the MSPAT presented an R2 of 0.79, demonstrating superior performance to the SPAD-502, which achieved an R2 of 0.70. This confirms the potential of the MSPAT compared to commercial equipment, and made it possible to obtain similar results to the reference spectroradiometer. The PLSR model with data from the FieldSpec 3 provided important validation metrics when using reflectance data with first-derivative transformation (R2 = 0.88, RMSE = 1.94 and MAE = 1.28). When using the MSPAT, PLSR (R2 = 0.75, RMSE = 2.77 and MAE = 2

关键词： Network security

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Pulmonary Disease Pattern Recognition on X-Ray Radiography Image Using Artificial Neural Network (ANN) Method 3

Pulmonary Disease Pattern Recognition on X-Ray Radiography I...

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3rd Annual Scientific Meeting on Medical Physics and Biophysics, PIT-FMB in conjunction with the 17th South-East Asia Congress of Medical Physics, SEACOMP 2019

作者： Fitriyah, N. Kurniawati, L.D. Purwanti, E. Astuti, S.D. Department of Physics Faculty of Science and Technology Universitas Airlangga Surabaya60115 Indonesia Biomedical Engineering Study Program Faculty of Science and Technology Universitas Airlangga Surabaya60115 Indonesia Department of Biomedical Engineering Post-Graduate Program Faculty of Science and Technology Universitas Airlangga Surabaya60115 Indonesia

This research aims to recognize the pattern of pulmonary disease on x-ray radiography image using artificial neural network (ANN) method. The images, which were used such as images of healthy pulmonary, pulmonary tuberculosis, and pulmonary tumour. Pattern recognition was using an extraction feature of GLCM (Gray Level Co-occurrence Matrix) and back propagation method. Before being identified, the images were processed by median filter and adaptive histogram equalization. The GLCM features that used were homogeneity, energy, contrast, variance and correlation. The parameters were learning rate and hidden layer. Learning rate was 0.3 and hidden layer was 25. Back propagation training showed 100% accuracy, which all of 44 images were used had been successfully identified. From the result, the healthy pulmonary showed 60% accuracy, 83.3% for pulmonary tuberculosis and 100% for pulmonary tumor. Hence, the overall result showed 81.25% accuracy, which 13 of 16 images had been successfully identified. From these result, extraction feature of GLCM using back propagation method was capable to recognize the pattern of pulmonary disease. However, due to narrow range of the feature, this application may not be used optimally for comparing features in every category of images. Therefore, the further research is needed to determine the best features and parameters of training back propagation. © Published under licence by IOP Publishing Ltd.

关键词： Pattern recognition

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Developments in the utilization of heterogeneous catalysts for biodiesel generation: An update on recent advancements

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Journal of the Taiwan Institute of Chemical Engineers 2024年

作者： Parameshwar, Sai Agnihotri, Mayank Bhan, Uday Nangan, Senthilkumar Verma, Deepak Rajendran, Saravanan Jain, Siddharth Department of Petroleum Engineering and Earth Sciences UPES Dehradun248007 India Metallurgy and Materials Science Research Institute Chulalongkorn University Bangkok10330 Thailand International Graduate Program of Nanoscience and Technology Chulalongkorn University Bangkok10330 Thailand Instituto de Alta Investigacion Universidad de Tarapacá Arica1000000 Chile Department of Mechanical Engineering UPES Dehradun248007 India

Background: Biodiesel is one of the ecofriendly energy sources that can be generated from edible, non-edible, waste, and algae feedstocks. Over time, the utilization of different kinds of heterogeneous catalysts has been proven critical in the manufacture of biodiesel from diverse feedstocks. They exhibit better reusability and easier separation compared to the homogenous catalysts. Methods: In this work, the advances in the use of heterogeneous catalysts for biodiesel production from 2018 to 2024 have been evaluated. The process parameters like alcohol to oil molar ratio (M/O), catalyst concentration (%), reaction time and reaction temperature (RT), reusability of the catalyst, etc. are evaluated. The catalysts derived from waste materials through the calcination process are an efficient and cost-effective substitute for conventional catalysts. Nanomaterials, due to their small size and higher aspect ratio, provide very high efficiency and reusability in catalytic reactions. Significant findings: The heterogeneous catalysts are also found to be highly reusable for multiple cycles and the leaching of active sites, clogging of pore spaces of catalyst, etc. are the major causes of catalyst deactivation. Magnetic heterogeneous catalysts have shown good biodiesel yields and high reusability. Also, naturally occurring calcium oxide and potassium compounds present in waste derived catalysts helped to give high biodiesel yields. The future direction in the path of development of heterogeneous catalysts from cheap, abundant, and environmentally benign materials. The synthesis of heterogeneous catalysts from waste materials addresses the issue of waste disposal and converting solid waste to value-added catalysts. The life cycle assessment studies, encompassing heterogeneous catalyst synthesis, feedstock oil extraction, biodiesel production, and fuel combustion may give valuable input on the environmental impact of the entire process. © 2024

关键词： Potassium compounds

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High-Speed Optical Convolutional Neural Network Accelerator with 100 Gbaud EO-polymer/Si Hybrid Optical Modulator

High-Speed Optical Convolutional Neural Network Accelerator ...

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OptoElectronics and Communications Conference, OECC

作者： Akito Shinya Koji Kida Hiromu Sato Guo-Wei Lu Shiyoshi Yokoyama Junichi Fujikata Graduate School of Science and Technology for innovation Tokushima University Tokushima Japan Fuculty of Engineering and Design Kagawa University Takamatsu Japan Institute for Materials Chemistry and Engineering Kyushu University Kasuga Japan Division of Computer Engineering The University of Aizu Aizu Japan Institute of Post-LED Photonics Tokushima University Tokushima Japan

Convolutional neural networks are a powerful category of artificial neural networks that can extract hierarchical features of biological data to significantly reduce parametric complexity and increase prediction accuracy. In this paper, we propose high-speed optical convolutional neural network accelerator with 100Gbaud EO-polymer/Si hybrid optical modulator and demonstrated proof of concept both in simulation and experiment.

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MOF-catalyzed hydroxyalkylation-alkylation reaction for the controlled synthesis of furan oligomers

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Applied Catalysis A: General 2024年 669卷

作者： Atayde, Eduardo C. Matsagar, Babasaheb M. Wang, Yu-Cheng Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica No. 128 Sec. 2 Academia Road Taipei11529 Taiwan Department of Chemistry National Tsing Hua University No. 101 Sec. 2 Kuang-Fu Road Hsinchu30013 Taiwan Department of Chemical Engineering National Taiwan University No. 1 Sec. 2 Roosevelt Road Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan Chung-Li Taiwan

Hydroxyalkylation-alkylation (HAA) reaction is a type of C-C coupling technique utilized in the production of furan oligomers, which are potential biofuel precursors. In this study, we present the first application of an acidic MOF, Sulfated MOF-808, in catalyzing the HAA reactions of a series of furan oligomers with high yield and selectivity. Specifically, we focused on the optimization of the HAA between 5-methylfurfural (5-MFUR) and 2-methylfuran (2-MF) by varying different reaction conditions, which afforded a quantitative yield reaching 97% while preventing the self-condensation of 2-MF. The catalyst was also found to be recyclable and can be reused without significant loss in its activity. Lastly, we extended the substrate scope to include benzene-based electrophiles, thereby further proving the versatility of the Sulfated MOF-808 catalyst in the HAA reactions of a variety of starting materials. © 2023 Elsevier B.V.

关键词： Catalysis

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