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Boosting Thermoelectric Performance in Nanocrystalline Ternary Skutterudite Thin Films through Metallic CoTe2 Integration

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ACS Applied materials and Interfaces 2024年第12期16卷 14770-14780页

作者： Jarwal, Bhawna Abbas, Suman Chou, Ta-Lei Vailyaveettil, Suneesh M. Kumar, Ashutosh Quadir, Shaham Ho, Thi-Thong Wong, Deniz P. Chen, Li-Chyong Chen, Kuei-Hsien Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei10617 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Institute of Atomic and Molecular Sciences Academia Sinica Taipei10617 Taiwan Center for Condensed Matter Sciences National Taiwan University Taipei10617 Taiwan Department of Physics National Central University Taoyuan32001 Taiwan Department of Materials Science and Metallurgical Engineering Indian Institute of Technology Bhilai Chhattisgarh Durg491001 India GoldenCO80401 United States Helmholtz-Zentrum Berlin für Materialien und Energie Hahn-Meitner-Platz 1 BerlinD-14109 Germany Department of Physics National Taiwan University Taipei10617 Taiwan Center of Atomic Initiative for New Materials National Taiwan University Taipei10617 Taiwan

Metal-semiconductor nanocomposites have emerged as a viable strategy for concurrently tailoring both thermal and electronic transport properties of established thermoelectric materials, ultimately achieving synergistic performance. In this investigation, a series of nanocomposite thin films were synthesized, embedding metallic cobalt telluride (CoTe2) nanophase within the nanocrystalline ternary skutterudite (Co(Ge1.22Sb0.22)Te1.58 or CGST) matrix. Our approach harnessed composition fluctuation-induced phase separation and in situ growth during thermal annealing to seamlessly integrate the metallic phase. The distinctive band structures of both materials have developed an ohmic-type contact characteristic at the interface, which raised carrier density considerably yet negligibly affected the mobility counterpart, leading to a substantial improvement in electrical conductivity. The intricate balance in transport properties is further influenced by the metallic CoTe2 phase’s role in diminishing lattice thermal conductivity. The presence of the metallic phase instigates enhanced phonon scattering at the interface boundaries. Consequently, a 2-fold enhancement in the thermoelectric figure of merit (zT ∼ 1.30) is attained with CGST-7 wt. % CoTe2 nanocomposite film at 655 K compared to that of pristine CGST. © 2024 The Authors. Published by American Chemical Society.

关键词： Nanocomposites

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Effective monitoring of environmental hazardous drug moxifloxacin hydrochloride using silver selenide on octadecyl amine modified reduced graphene oxide composite

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Journal of Environmental Chemical Engineering 2024年第1期12卷

作者： Hwa, Kuo-Yuan Ganguly, Anindita Graduate Institute of Organic and Polymeric Materials National Taipei University of Technology Taipei China Department of Molecular Science and Engineering National Taipei University of Technology Taipei China International Graduate Program in Energy and Optoelectronic Materials National Taipei University of Technology China

The precise detection of antibiotics is very critical. Here, silver selenide (Ag2Se) nanorods are hydrothermally synthesized and ultrasonically treated with rGO surface modified with octadecylamine (rGO-ODA). The optical, structural, morphological, and functional analysis were performed which revealed the orthorhombic pattern of the P2221 E space group, the crystalline purity of Ag2Se, and the substantial composite formation. The morphological studies revealed nanorod like structure of the Ag2Se material and wrinkled sheets of rGO-ODA. A sensor that detects moxifloxacin hydrochloride (MOXH) antibiotic using the cyclic voltammetry (CV), differential pulse voltammetry (DPV) and UV-Vis absorbance was developed. For DPV analysis, a quite low value for detection limit 12.46 nM was exhibited with 0.199 μM – 425.16 μM linear range, and a sensitivity of 5.0439 μA M−1cm−2. For UV-Vis, the sensor demonstrated a very low limit of detection 17.42 nM over 0.12 μM – 7.7 μM working range. The use of this sensor was validated in real-time analysis with industrial waste water, fish, human blood, and urine samples. The results suggested an excellent rate of analyte recovery and enhanced efficiency for MOXH detection with a potential for commercialization in the future. © 2023

关键词： Nanorods

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Effect of Sn addition on electrochemical activity of ribbons of Mg-Al-Ca anode material for rechargeable magnesium batteries fabricated by rapid solidification

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Keikinzoku/Journal of Japan Institute of Light Metals 2025年第1期75卷 9-13页

作者： Fukuta, Yoshitaka Kikura, Kensei Tsukeda, Tadayoshi Aida, Tetsuo Tabata, Hironobu Kurihara, Hideki Suzuki, Mayumi Program of Materials Science and Engineering Studies in Science and Engineering Graduate School of Science and Engineering University of Toyama 3190 Gofuku Toyama-shi Toyama930-8555 Japan Graduate School of Science and Engineering University of Toyama Toyama-shi Toyama Japan Faculty of Sustainable Design Academic Assembly University of Toyama Toyama-shi Toyama Japan CHUETSU METAL WORKS CO. LTD. Nakaniikawagun Toyama Japan Saitama Industrial technology Center Kawaguchi-shi Saitama Japan Department of Mechanical Systems Engineering Faculty of Engineering Toyama Prefectural University Imizu-shi Toyama Japan

Magnesium-based batteries are potential candidates for next-generation rechargeable batteries due to the divalent nature of magnesium cations and the natural abundance of magnesium resources. In this study, the electrochemical activity of Mg-6mass%Al-3mass%Ca anodes combined with Sn was investigated. Thin ribbons of the anode specimens were prepared by a single-roll rapid solidification method. The results showed that the electrochemical activity increased upon adding 1 mass% Sn, while it decreased for 3 mass% Sn. Based on the results of an X-ray diffraction analysis, the addition of Sn led to the formation of Mg2Sn and Ca2Sn phases, which increased the lattice distortion. Scanning electron microscopy observations indicated that these secondary phases were homogeneously distributed for 1 mass% Sn addition, while they were coarsely distributed for 3 mass% Sn. © 2025 The Japan Institute of Light Metals.

关键词： X ray diffraction analysis

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Preparation of LFP-based cathode materials for lithium-ion battery applications

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materials Today: Proceedings 2022年 65卷 2347-2350页

作者： Suttison, Suchanat Pengpat, Kamonpan Intatha, Uraiwan Fan, Jinchen Zhang, Wei Eitssayeam, Sukum Master's Degree Program in Materials Science Faculty of Science Chiang Mai University Chiang Mai 50200 Thailand Graduate School Chiang Mai University Chiang Mai Thailand Department of Physics and Materials Science Faculty of Science Chiang Mai University Thailand Center of Innovative Materials for Sustainability School of Science Mae Fah Luang University Chiang Rai 57100 Thailand School of Materials and Chemistry University of Shanghai for Science and Technology Shanghai 200093 China Department of Engineering Mechanics Dalian University of Technology Dalian 116024 China

Lithium-ion batteries (LIB) have developed into the mainstream power source of energy storage devices due to their advantages: high power density, high power, long service life, and less pollution. This materials development for LFP batteries was considered successful in synthesizing powder. Here we show that three synthesis conditions were performed. LFP doped NiO, NMC, and (NH4)2HPO4 were synthesized by the nitrogen gas flow method. LFP-doped NiO was burned at 600 °C and 700 °C for five h. NMC doped with LFP burned at 550 °C for five h, and NMC-doped LFP and (NH4)2HPO4 were burned at 550 °C and 600 °C for five h. The structure and morphology of the material were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). © 2022

关键词： Lithium-ion batteries

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The effects of growth environments on WS2 in electrocatalytic hydrogen evolution reaction

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Journal of Physics and Chemistry of Solids 2024年 185卷

作者： Chang, Yung-Huang Huang, Chien-Sheng Chen, Yuan-Tsung Chiang, Chia-Yu Bachelor Program in Industrial Technology National Yunlin University of Science and Technology Yunlin Taiwan Department of Electronic Engineering National Yunlin University of Science and Technology Yunlin Taiwan Graduate School of Materials Science National Yunlin University of Science and Technology Yunlin Taiwan

Transition metal dichalcogenides (TMDs) recently have attracted much attention because of their outstanding catalytic activity, low cost, and earth abundance in the hydrogen evolution reaction (HER). Among these TMDs, MoS2 and WS2 are recognized as promising HER electrocatalysts and have been explored to be one of the candidates for replacing precious metals. In this work, the electrocatalytic activity of WS2 grown in Ar-only, Ar + H2, and ambient environments were studied, where the WS2 was synthesized by thermolysis from (NH4)2WS4 precursor. Different surface morphologies are shown under the different growth atmospheres. The structures of pure WS2, WS2 and WO3 mixed, and almost WO3 were prepared in different growth atmospheres of Ar-only, Ar + H2, and ambient environment, respectively. All the materials prepared in these different environments exhibit high crystalline characteristic. Especially, the pure WS2 grown in an Ar-only environment presents the preferred (103) lattice plane. The pure WS2 performs the best H2 evolution efficiency, indicating that high crystallinity and preferred (103) lattice plane could be relative to the electrocatalytic activity. The studies provide fundamental insight for further design and preparation of electrocatalysts, useful in the development of clean energy. © 2023 Elsevier Ltd

关键词： Electrocatalysts

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Total Antioxidant Capacity of Meals Suggested in the Dietary Guidelines for the Brazilian Population

SSRN

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SSRN 2025年

作者： Ranzi, Maria Eduarda Noronha, Luana Alberti Arruda, Giovana Eduarda Koehnlein, Eloá Angélica Federal University of Fronteira Sul Realeza Brazil Post-Graduate Program in Food Science and Technology Federal University of Fronteira Sul Laranjeiras do Sul Brazil

Chronic non-communicable diseases have modifiable risk factors, with dietary habits being a key component. A diet abundant in antioxidant-rich foods is inversely correlated with the onset and progression of these diseases. This study aimed to estimate the total antioxidant capacity (TAC) of meals suggested in the Dietary Guidelines for the Brazilian population (DGBP) (2014), as well as identify the main contributing foods. The research was quantitative and descriptive, based on the analysis of secondary data from photographic records of the suggested meals (breakfast, lunch, and dinner) in the DGBP. The foods, their preparation methods, and portion sizes were identified. The TAC of the foods was primarily estimated according to Carlsen et al. (2010), through the Ferric-Reducing Ability of Plasma (FRAP) assay. Subsequently, the TAC of the meals, the percentage contribution of each food item, and the TAC adjusted to 250 kcal were estimated. The average TAC found was 3.01 ± 1.35 mmol in breakfast suggestions, 1.93 ± 0.84 mmol in lunch suggestions, and 2.49 ± 3.34 mmol in dinner suggestions, with no significant differences when comparing the TAC results among the three meals (p=0.608). However, coffee was identified as the main contributor in breakfast suggestions, while beans stood out as the main contributor in lunch and dinner suggestions. Therefore, the foods that most prominently contributed to the TAC of the meals suggested by DGBP were those that, in addition to being part of the national food culture, are classified as in natura or minimally processed, highlighting their importance in providing bioactive compounds with health benefits. © 2025, The Authors. All rights reserved.

关键词： Food ingredients

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Microencapsulated phenolic-rich extract from juice processing grape pomace(Vitis *** Var):Effects on oxidative stability of raw and pre-cooked bovine burger

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Food Bioscience 2022年第6期50卷 2120-2129页

作者： Marcelo Edvan dos Santos Silva Rodrigo Lira de Oliveira Thamyres Cesar de Albuquerque Sousa Cristiani Viegas Brandão Grisi Valquíria Cardoso da Silva Ferreira Tatiana Souza Porto Marta Suely Madruga Suzana Pedroza da Silva Fábio Anderson Pereira da Silva Post-Graduate Program in Food Science and Technology Department of Food EngineeringTechnology CentreFederal University of ParaibaJoão PessoaParaiba58051-900Brazil Northeast Biotechnology Network/RENORBIO Federal Rural University of Pernambuco (UFRPE)Dom Manoel de MedeirosDois Irmãos52171-900RecifePEBrazil Federal University of Pernambuco's Agreste (UFAPE) GaranhunsAv.Bom PastorBoa Vista55296-901 GaranhunsPEBrazil Post-Graduate Program in Agrifood Technology Federal University of ParaibaCampus Universitario IIIBananeirasPBBrazil

Grape processing generates residues rich in bioactive compounds with potential application in the meat ***,these substances are unstable and needs to be treated to allow their action during the processing and storage of meat *** this sense,a phenolic-rich extract from grape pomace was microencapsulated and evaluated for its potential to inhibit the oxidative process in raw and precooked beef burgers during cold *** hamburger formulations containing lyophilized extract(LEB),microencapsulated extract(MEB)and synthetic antioxidant sodium erythorbate(SEB)were prepared,pre-cooked,and evaluated for lipid and protein *** microencapsulation,with 95.0%efficiency,provided a material with a crystalline structure,rich in phenolics and with high antioxidant potential,showing 377.4±0.01,1768.1±0.07 and 1185.0±0.20μmol TEAC.100 g^(−1) for DPPH,ABTS and FRAP,*** values of malonaldehyde were found in LEB and MEB(2.9±0.3 and 1.4±0.5 mg ***^(−1),respectively)at the end of storage,with emphasis on for the hamburgers that received the microencapsulated *** behavior was observed for the analysis of carbonyl compounds,with values of 11.1±1.1,8.7±1.4 and 6.8±1.0 nM ***^(−1) in SEB,LEB and MEB,***,the freeze-dried and microencapsulated grape extracts showed superior results when compared to the synthetic antioxidant,increasing the oxidative stability of hamburgers,and avoiding significant color changes during the cold *** results indicate the high potential of the microencapsulated material to be used as a natural antioxidant in the meat industry.

关键词： Lipid oxidation Protein oxidation Meat products Natural antioxidant Encapsulation

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What are the Levels of Polyphenols in Brazilian Meals? An Estimate Based on the Degree of Food Processing (Nova Classification)

SSRN

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SSRN 2024年

作者： Grigol, Eduarda Camila Bau Noronha, Luana Alberti Arruda, Giovana Eduarda Ranzi, Maria Eduarda Koehnlein, Eloá Angélica Federal University of Fronteira Sul Realeza Brazil Post-Graduate Program in Food Science and Technology Federal University of Fronteira Sul Laranjeiras do Sul Brazil

Considering the importance of polyphenol intake in reducing the risk of non-communicable chronic diseases, it is essential to encourage populations around the world, especially in Brazil, to consume foods that increase the presence of these compounds in their diet. This study aimed to identify the foods with the highest total polyphenol content and classes consumed by the Brazilian population, as well as their degree of processing. The study was conducted using secondary data collected from the 2017-2018 Household Budget Survey, which included the actual per capita food consumption of the Brazilian population and the usual portion size of foods. The investigation focused on 41 food items with the highest consumption frequency. Estimates of the total polyphenol (TP) content and classes in the foods were obtained from the Phenol-Explorer database, and the degree of food processing was classified according to the NOVA classification. Based on the ranking of the main foods consumed by Brazilians with the highest total polyphenol (TP) content, coffee (169.527 mg) and beans (38.422 mg) stood out for the average per capita consumption, while corn and its preparations (187.250 mg) and oranges (72.683 mg) stood out when analyzing the portion consumed in a single occasion. Regarding the polyphenol classes, the foods with the highest amounts consumed by Brazilians predominantly contained phenolic acids. Concerning the degree of processing, based on the NOVA classification, 76% of the foods with the highest polyphenol levels belonged to the fresh and minimally processed food category, while 15% corresponded to ultra-processed foods. It is essential to encourage the consumption of traditional foods in the Brazilian diet, as these are important sources of polyphenols. It is worth emphasizing the relevance of in natura and minimally processed foods as the basis of the Brazilian diet, mainly concerning the total polyphenol contents. © 2024, The Authors. All rights reserved.

关键词： Food chemistry

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Ultrahigh zT from strong electron-phonon interactions and a low-dimensional Fermi surface

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Energy and Environmental science 2024年第5期17卷 1904-1915页

作者： Ranganayakulu, V.K. Wang, Te-Hsien Chen, Cheng-Lung Huang, Angus Ma, Ma-Hsuan Wu, Chun-Min Tsai, Wei-Han Hung, Tsu-Lien Ou, Min-Nan Jeng, Horng-Tay Lee, Chih-Hao Chen, Kuei-Hsien Li, Wen-Hsien Brod, Madison K. Snyder, G. Jeffrey Chen, Yang-Yuan Institute of Physics Academia Sinica Taipei11529 Taiwan Department of Engineering and System Science National Tsing Hua University Hsinchu30013 Taiwan Taiwan International Graduate Program Taipei11529 Taiwan Department of Physics National Chung Hsing University Taichung City40227 Taiwan Graduate School of Materials Science National Yunlin University of Science and Technology Yunlin64002 Taiwan Bachelor Program in Semiconductor Materials and Fabrication Ming Chi University of Technology New Taipei City243303 Taiwan Department of Physics National Tsing Hua University Hsinchu30013 Taiwan Center for Theory and Computation National Tsing Hua University Hsinchu30013 Taiwan Physics Division National Center for Theoretical Sciences Taipei10617 Taiwan Department of Physics National Central University Jhongli32001 Taiwan National Synchrotron Radiation Research Center Hsinchu Science Park Hsinchu30076 Taiwan Institute of Atomic and Molecular Sciences Academia Sinica Taipei10617 Taiwan Department of Materials Science and Engineering Northwestern University EvanstonIL60208 United States Graduate Institute of Applied Physics National Chengchi University Taipei11605 Taiwan

The outstanding thermoelectric performance of GeTe has attracted significant attention in the research community in recent years. However, many of the underlying physical mechanisms that contribute to GeTe's exceptionally high figure of merit (zT) remain not fully understood. In this study, an Sb-Bi codoped GeTe single crystal (Ge0.86Sb0.08Bi0.06)Te with an ultrahigh zT of 2.7 at 700 K and a record high device zT of 1.41 in the temperature range of 300-773 K was synthesized and investigated. The ultrahigh zT is attributed to the extremely low lattice thermal conductivity induced by strong electron-phonon (EP) interactions as revealed by the experimentally observed Kohn anomaly, through inelastic neutron scattering (INS) measurements. First-principles calculations further demonstrate that the remarkable EP interaction arises from the Fermi surface nesting featured in a one-dimensional (double-walled) topology. Our finding unravels the ultrahigh-zT mechanism in GeTe-based materials, serving as an inspiring guide toward high thermoelectric performance. © 2024 The Royal Society of Chemistry.

关键词： Neutron scattering

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Laser ablation synthesis of BiOCl/Ag/WO₃nanocomposite to evaluate its photocatalysis performance

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Modern Physics Letters B 2025年第4期39卷

作者： Lin, Kai-Siang Furube, Akihiro Katayama, Testuro Koinkar, Pankaj Wu, Chang Mou Institute of Post-LED Photonics And Graduate School of Science and Technology for Innovation Tokushima University Tokushima 770 8506 Japan Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei Taiwan

Bismuth oxychloride (BiOCl)/silver (Ag)/tungsten oxide (WO3) nanocomposite was produced by laser ablation to enhance photocatalytic performance. The ternary nanocomposite showed a superior photocatalytic activity for methylene blue (MB) degradation under visible light compared to pure BiOCl and BiOCl/Ag with degradation up to 74%, 62%, and 52 %, respectively. The addition of Ag improved the dispersibility of BiOCl and WO3, which reduced the recombination of electron-hole pairs and can be responsible for higher photocatalytic activity. © 2025 World Scientific Publishing Company.

关键词： Bismuth oxychloride laser ablation nanocomposite photocatalysis

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