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Conversion of biochar into sulfonate-bearing solid acids used for the hydrolysis of tylosin:the effect of aromaticity and degree of condensation

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Biochar 2023年第1期5卷 1514-1526页

作者： Qianqian Xie Xiao Yang Binoy Sarkar Xiaomin Dou Piumi Amasha Withana Yong Sik Ok College of Environmental Science and Engineering Beijing Forestry UniversityBeijing 100083People’s Republic of China Key Laboratory of Land Surface Pattern and Simulation Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101People’s Republic of China Future Industries Institute University of South AustraliaMawson LakesSA 5095Australia Korea Biochar Research Center APRU Sustainable Waste Management Program&Division of Environmental Science and Ecological EngineeringKorea UniversitySeoul 02841Republic of Korea International ESG Association(IESGA) Seoul 06621Republic of Korea

In the last few decades,sulfonated carbon materials have garnered significant attention as Brøsted solid acid *** sulfonation process and catalytic activity of sulfonated biochar can be influenced by the aromaticity and degree of condensation exhibited by ***,the relationships between the aromaticity,sulfonating ability,and resultant catalytic activity are not fully *** this study,biochar samples pyrolyzed at 300-650℃ exhibiting different aromaticity and degrees of condensation were sulfonated and employed as sulfonate-bearing solid catalysts for hydrolytically removing *** exhibited excellent hydrolytic performance and their kinetic constants were positively correlated with the total acidity and negatively correlated with their *** study has uncovered the relationship between the structure,properties,sulfonating ability,and subsequent hydrolytic performance of biochar *** was observed that the aromaticity of biochar decreased as the pyrolysis temperature *** pyrolysis temperatures resulted in a reduced degree of condensation,smaller ring size,and an increased number of ring edge sites available for sulfonation,ultimately leading to enhanced catalytic *** findings provide valuable insights into the fundamental chemistry behind sulfonation upgrading of biochar,with the aim of developing functional catalysts for mitigating antibiotics in contaminated water.

关键词： Biochar upgrading Sulfonation Hydrolytic mitigation Tylosin removal Biochar-based solid acids

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Optimal Strategy to Reduce Energy Waste in an Electricity Distribution Network Through Direct/Indirect Bulk Load Control

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SSRN 2023年

作者： Cerna, Fernando Vladimir Dantas, Jamile T. Naderi, Ehsan Contreras, Javier Department of Electrical Engineering Federal University of Roraima Boa Vista69310-000 Brazil Postgraduate Program in Natural Resources Research Area in Management and Dynamics of Natural Resources – Renewable Energies Federal University of Roraima Av. Nova Iorque – Aeroporto Boa Vista69310-000 Brazil School of Electrical Computer and Biomedical Engineering Southern Illinois University CarbondaleIL62901 United States School of Industrial Engineering University of Castilla-La Mancha Ciudad Real13071 Spain

In recent decades, the ever-increasing demand for electricity in large cities is leading the electricity distribution network (EDN) to an operational state of fatigue, especially at peak load times. Thus, the lifetime of feeders, transformers, circuit breakers, among others, can be compromised. In this context, load congestion, technical losses, and voltage deviations across the EDN can contribute to the high waste of electricity as well as to the worsening of the supply service. To face this problem, this paper proposes a mixed integer linear programming (MILP) model that aims to reshape the demand profile (i.e., load reduction in peak periods without load rebound in the remaining periods of the day) of total consumers while the voltage deviations and technical losses are minimized. In the proposed model, the demand profile reshaping is carried out through direct (DC) and indirect (IC) bulk control of residential, commercial, and industrial loads, while the load factor (LF), i.e., indicator related to the efficient use of electricity, is improved. Due to the scheduling of these loads at certain times of the day, the occurrence of voltage deviations and technical losses can be mitigated by the efficient control of capacitor banks (CBs). © 2023, The Authors. All rights reserved.

关键词： Electric circuit breakers

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Characterization of Nanocomposite Membrane Based Bacterial Cellulose Made of Pineapple Waste Reinforced by Graphite Nanoplatelets

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Journal of Renewable Materials 2022年第9期10卷 2465-2475页

作者： Heru Suryanto Bili Darnanto Susilo Jibril Maulana Aminnudin Uun Yanuhar Surjani Wonorahardjo Husni Wahyu Wijaya Abu Saad Ansari Center of Excellence for Cellulose Composite(CECCom) Department of Mechanical EngineeringUniversitas Negeri MalangMalang65145Indonesia Centre of Advanced Material for Renewable Energy(CAMRY) Universitas Negeri MalangMalang65145Indonesia Master Program of Mechanical Engineering Faculty of EngineeringUniversitas Negeri MalangMalang65145Indonesia Department of Aquatic Resources Management Faculty of Fisheries and Marine SciencesBrawijaya UniversityMalang65145Indonesia Department of Chemistry Faculty of Mathematics and Natural SciencesUniversitas Negeri MalangMalang65145Indonesia Department of Materials Science&Engineering Incheon National UniversityIncheon464-742South Korea

Waste is the main problem for the *** waste for various useful applications has a benefit for the *** work has been studied for handling pineapple peel waste to make composite film bacterial cellulose nanocomposite membrane(BCNM)with addition graphite nanoplatelet(GNP).The concentration of GNP in the membrane influence the membrane *** bacterial cellulose(BC)pellicle was synthesized by using media from pineapple peel waste *** pellicle is cleaned with water and NaOH solution to be free from *** is synthesized through the mechanical disintegration *** results of disintegration using high pressure homogenizer at 150 bar and five ***/GNP is synthesized with varying addition of GNP of 2.5,5.0,10 and 100 wt%of dry bacterial nanocellulose(BNC).The BC and GNP solution were dried in an oven for 14 h at 80℃.BCNM morphology was observed using *** is dispersed and distributed in the BC matrix as *** analysis shows many peaks of BNC less pronounced with increasing of *** higher concentration of GNP,the rougher of *** optimum tensile strength of BCNM was achieved after addition GNP of 2.5 wt%.

关键词： Bacterial nanocellulose graphite nanoplatelet membrane nanocomposite pineapple waste

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Current status of sustainability of Belawan Port toward SDG program 2

Current status of sustainability of Belawan Port toward SDG ...

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2nd International Conference on natural resources and Technology, ICONART 2020

作者： Sulaiman, I.A. Nasution, Z. Rauf, A. Kusuma, M.S.B. Doctoral Program Natural Resources and Environmental Management Universitas Sumatera Utara Medan Indonesia Faculty of Agriculture Universitas Sumatera Utara Medan Indonesia Faculty of Civil and Environmental Engineering Bandung Institute of Technology Bandung Indonesia

Belawan Port is one of the main ports in Indonesia whose role and function are important in the national logistics system. Belawan Port is a gateway for the Province of North Sumatra. The port must have sustainability in carrying out its role and function as transportation and economic infrastructure. In this research, Belawan Port sustainability will be evaluated from several aspects or dimensions, namely ecology, economy, social culture, technology, and institutions and law. Belawan port sustainability analysis using the Multidimensional Scaling method, using the modified Rapfish program. The analysis is carried out on five dimensions and 49 attributes/factors, which are used as a reference in the SDGs program. Not every SDG will be relevant for every business, however, every SDG should be considered. SDGs no.4 and no.5 are not directly related to port management activities, while SDGs no.8,9,11,14,17 are directly related. From the analysis obtained Ecology sustainability index = 48.38 (less-sustainable), Economic sustainability index = 42.89 (Less-Sustainable), Socio-Cultural sustainability index = 52.47 (Fair-Sustainable), Technological sustainability index = 54.11 (Fair-Sustainable), Institutional and Legal sustainability index = 50.74 (Fair-Sustainable). With policy and program interventions, the sustainability of the existing Belawan Port in the short term can be improved to be fair-sustainable for all dimensions (ecology, economy, social & culture, Technology, Institution & Law) evaluated. © Published under licence by IOP Publishing Ltd.

关键词： Sustainable development

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Combination of cellulose nanocrystal and graphene oxide as modifying agent for improving the performance of PVDF membranes

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Case Studies in Chemical and Environmental engineering 2024年 10卷

作者： Sofyana Muslim, Abrar Supardan, Muhammad Dani Ambarita, Aulia Chintia Arahman, Nasrul Doctoral Program School of Engineering Science Syiah Kuala University Department of Chemical Engineering Syiah Kuala University Graduate School of Environmental Management Universitas Syiah Kuala Research Center for Environmental and Natural Resources Universitas Syiah Kuala Oil Palm and Coconut Research Center Universitas Syiah Kuala

The effectiveness of polyvinylidene fluoride (PVDF) membranes in various applications is often hampered by fouling, necessitating the exploration of modification strategies to enhance their antifouling properties. This study investigates the effect of combining cellulose nanocrystal (CNC) and graphene oxide (GO) on PVDF membranes to address this issue. Six flat sheet membranes with different compositions were fabricated using a non-solvent-induced phase separation method. The resulting membrane (M5: CNC 1 % w/w and GO 0.25 % w/w) exhibited increased surface pores, a finger-like cross-sectional structure, and higher water content. The pure water flux (PWF) in the M5 membrane increased to 37 L/m²∙h, with a humic acid (HA) rejection rate of 60 % and excellent antifouling properties (98.32 %). In conclusion, this study successfully modified PVDF membranes by combining CNC and GO, resulting in membranes with improved properties and performance. The present study provides valuable insights into composite membrane design and offers potential solutions to fouling challenges. © 2024 The Authors

关键词： Antifouling Cellulose nanocrystals Composite membrane Graphene oxide Polyvinylidene fluoride

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Effectiveness of Situ for Ciliwung Flood Mitigation in Bogor Regency

Effectiveness of Situ for Ciliwung Flood Mitigation in Bogor...

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Sustainable Urban Water International Seminar 2019, SUWIS 2019

作者： Nugraheni, Claudia Tyas Pawitan, Hidayat Purwanto, Yanuar Jarwadi Ridwansyah, Iwan Postgraduate Program in Natural Resources and Environmental Management IPB Bogor Indonesia Department of Geophysics and Meteorology IPB Bogor Indonesia Department of Civil and Environmental Engineering IPB Bogor Indonesia Limnology Research Center LIPI Bogor Indonesia

Bogor Regency is one of Regencies in Jabodetabek area that is experiencing rapid urban growth. This condition impacted the decreasing conditions of 39's from 95's urban small lakes or locally known as 'situ'. This research aims to analyze the effectiveness of situ Kebantenan and situ Cikaret as Ciliwung flood mitigation measure in the Bogor Regency. The SWAT model was employed for quantification the water balance of situ and watershed management. The simulation results of the water balance analysis indicated that the monthly average of volume of Situ Kabantenan and Situ Cikaret (2008-2015) were 136,955 m3 and 508,907 m3, the annual inflow Situ Cikaret were 24,693,822 m3/year and outflow were 25,177,593 m3/year, precipitation were 648,520 m3/year, evaporation were 166,543 m3/year, delta storage (1,794) m3/year, respectively. The result of hydrological responses analysis on application of situ and watershed management scenarios that combined the structural and non-structural measures was the best scenario for decreasing maximum discharge at situ outlet which is decreased 41% discharge. So that, in order to enhance the effectiveness of situs for Ciliwung flood mitigation, the combination of the structural and non structural management of 13 situ's in Ciliwung river basin within the Bogor Regency is recommended that can increase the storage capacity from 1.8 million m3 to 4.7 million m3. © 2020 Published under licence by IOP Publishing Ltd.

关键词： Urban growth

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Research on the matching relationship of municipal solid waste management and alternative fuel in Indonesia's cement industry

Case Studies in Chemical and Environmental Engineering

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Case Studies in Chemical and Environmental engineering 2025年 11卷

作者： Wiharja Suherman Syafrudin Kholiq, Muhammad Abdul Pratama, Reba Anindyajati Robbani, Muhammad Haqqiyuddin Suryanto, Feddy Doctoral Program of Environmental Science School of Postgraduate Studies Diponegoro University Central Java Semarang 50275 Indonesia Research Center for Environmental and Clean Technology National Research and Innovation Agency Banten South Tangerang 15314 Indonesia Department of Chemical Engineering Faculty of Engineering Diponegoro University Central Java Semarang 50275 Indonesia Department of Environmental Engineering Faculty of Engineering Diponegoro University Central Java Semarang 50275 Indonesia Directorate of Environment Maritime Natural Resources and Nuclear Policy National Research and Innovation Agency Jakarta 10340 Indonesia

The cement industry in Indonesia, heavily relies on coal, contributing significantly to greenhouse gas (GHG) emissions. Simultaneously, Java Island generates over 23 million tons of municipal solid waste (MSW) annually, with limited utilization for energy recovery. This study evaluates the feasibility of substituting coal with refuse-derived fuel (RDF) from MSW in Java's cement industry, focusing on environmental, economic, and technical aspects. Scenario analyses indicate that substituting 10%, 20%, and 30% of thermal energy with RDF could divert up to 8.7 million tons of MSW from landfills annually, reducing GHG emissions by up to 2.77 million Gg CO₂-eq. These reductions align with Indonesia's environmental policies and global climate commitments under the Paris Agreement. The economic assessment demonstrates the viability of RDF, with potential annual cost savings of up to $421 million. Beyond addressing coal dependency, RDF adoption supports circular economy practices, reduces landfill reliance, and mitigates environmental pollution. However, challenges such as infrastructure gaps and regulatory barriers require attention. This study provides actionable insights to guide policy formulation, foster industry investment, and facilitate the implementation of RDF-based energy solutions. By bridging waste management and sustainable energy practices, the findings contribute to Indonesia's renewable energy goals, emphasizing the practical applications of RDF for a more sustainable future in industrial operations. © 2025 The Authors

关键词： Alternative fuel Cement industry Municipal solid waste Refused-derived fuel Sustainable energy

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Health risk assessment of soil contamination with heavy metals in a child care center co-located in vicinity to small scale industrial area: Case study of Thailand

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Case Studies in Chemical and Environmental engineering 2024年 9卷

作者： Simatupang, Cathleen Ariella Santhaweesuk, Kanitthika Strezov, Vladimir Pongkiatkul, Prapat Boontanon, Narin Jindal, Ranjna Boontanon, Suwanna Kitpati Graduate Program in Environmental and Water Resources Engineering Department of Civil and Environmental Engineering Faculty of Engineering Mahidol University Nakhon Pathom 73170 Thailand School of Natural Sciences Faculty of Science and Engineering Macquarie University 2109 NSW Australia Department of Environmental Engineering King Mongkut's University of Technology Thonburi Bangkok 10800 Thailand Faculty of Environment and Resource Studies Mahidol University Nakhon Pathom 73170 Thailand Environmental Engineering and Management Program Department of Energy Environment and Climate Change School of Environment and Resources Development Asian Institute of Technology Pathumthani 12120 Thailand Graduate School of Global Environmental Studies Kyoto University Yoshida Sakyo-Ku Kyoto 606-8501 Japan

Environmental impacts of small scale industries are still not well investigated, especially for estates where multiple small scale industries are clustered causing cumulative effects potentially impacting most vulnerable groups. This study aimed to investigate the concentrations of heavy metals (Mn, Fe, Ni, Cu, Pb, Al, Zn, and Cr) and the metalloid (As) in surface soils near the intensely active small-scale industrial area in Thailand, assess the contamination levels in the co-located child care center, and estimate potential human health risks from exposure to the heavy metals. Surface soil heavy metal(loid) elements were evaluated across a background area, area near main roads, a small-scale industrial area, and a child care centre. The concentrations of Al were found be the highest at all investigation sites, with the most elevated concentrations observed in the small-scale industrial area. The concentration of Pb in the industrial area reached 1176 mg/kg, exceeding the national standard and acceptable limit. Moreover, the contamination level for Cu, Pb, and Zn in the industrial area imply a considerable risk with enrichment factor EF > 40, and geo-accumulation index Igeo ≥5. Heavy metal levels (Ni, Cu, Pb) in the soil near the road and the child care center were similar, suggesting shared contamination sources. Conversely, Al, Zn, As, and Cr in the child care center had slightly higher concentrations than near the road but lower than the small-scale industrial area, indicating potential industrial influence on metal levels within the child care center. The principal component analysis showed Mn and Fe distributed in the background, while As, Pb, Ni, Cu, Al, Zn, and Cr accumulated in the small-scale industrial area. The findings indicate that small-scale industrial activities contribute to elevated levels of heavy metals in the soil, particularly within the child care center, posing significant ingestion risks, especially for children (HI > 1). Implementing conta

关键词： Children Contamination sources Environmental impact PCA Surface soil

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Load Factor Improvement of the Electricity Grid Considering Distributed resources Operation and Regulation of Peak Load

SSRN

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SSRN 2022年

作者： Cerna, Fernando Vladimir Naderi, Ehsan Marzband, Mousa Contreras, Javier Coêlho, John K. Fantesia, Maurício P. Department of Electrical Engineering Federal University of Roraima Boa Vista69310-000 Brazil Postgraduate Program in Natural Resources Research Area in Management and Dynamics of Natural Resources – Renewable Energies Federal University of Roraima Av. Nova Iorque – Aeroporto Boa Vista69310-000 Brazil School of Electrical Computer and Biomedical Engineering Southern Illinois University CarbondaleIL62901 United States Department of Mathematics Physics and Electrical Engineering Faculty of Engineering and Environment Northumbria University Newcastle upon TyneNE1 8ST United Kingdom School of Industrial Engineering University of Castilla-La Mancha Ciudad Real13071 Spain

The load factor (LF) of an electricity network (EN) is an indicator related to the efficient electricity usage within a time horizon (e.g., day, month, year, etc.). LF improvement can be achieved through an efficient operational scheme that combines several strategies. Among them, peak load regulation in the demand profile of all the consumers together with the operation of distributed resources (DREs), such as renewable sources (RSs) and capacitor banks (CBs) represents a promising alternative. To address this efficient scheme, this work proposes a mixed-integer linear programming (MILP) model that aims to increase the LF through the bulk scheduling of residential, commercial, and industrial electrical appliances during the day, considering a baseline demand and an hourly rate. At the same time, voltage fluctuations and technical losses are mitigated by the presence of DREs in the EN. Operational constraints related to the performance of EN, RSs, and CBs are considered. Uncertainties in the habitual demand profiles and solar radiation incidence during the day are represent through simulation algorithms. In order to evaluate our proposal, a modified 14-node IEEE EN was used. The results corroborate the applicability of this proposed MILP model, reducing electricity waste and ensuring the efficient EN operation. © 2022, The Authors. All rights reserved.

关键词： Integer programming

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Load Factor Improvement of the Electricity Grid Considering Distributed resources Operation and Regulation of Peak Load

SSRN

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SSRN 2022年

关键词： Integer programming

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