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Numerical simulation and printability analysis of fused deposition modeling with dual-temperature control

Bio-Design and Manufacturing 2023年第2期6卷 174-188页

作者： Xiaodan Huo Bin Zhang Qianglong Han Yong Huang Jun Yin The State Key Laboratory of Fluid Power and Mechatronic Systems School of Mechanical EngineeringZhejiang UniversityHangzhou 310028China Key Laboratory of 3D Printing Process and Equipment of Zhejiang Province School of Mechanical EngineeringZhejiang UniversityHangzhou 310028China Department of Mechanical and Aerospace Engineering University of FloridaGainesvilleFL 32611USA

Ideal tissue engineering scaffolds need interconnected pores and high porosity to enable cell survival,migration,proliferation,and ***,obtaining a high-resolution structure is difficult with traditional one-temperature control fused deposition modeling(FDM).In this study,we propose a dual-temperature control method to improve printability.A numerical model is developed in which the viscosity is a function of temperature and shear rate to study the influence of two different temperature control *** tests are used to assess filament formation and shape fidelity,including one-dimensional filament printing,deposition at corners,fusion,and *** using dual-temperature control,the width of the deposited poly(ε-caprolactone)filament is reduced to 50μ*** comparative results of both the experimental method and numerical simulation suggest that the dual-temperature control FDM can manufacture spatially arranged constructs and presents a promising application in tissue engineering。

关键词： Fused deposition modeling(FDM) Dual-temperature control Filament deposition Printing resolution Viscosity

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Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid

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Chinese Journal of Chemical engineering 2023年第1期53卷 133-141页

作者： Mi Feng Bin He Xinyan Chen Junli Xu Xingmei Lu Cai Jia Jian Sun Key Laboratory of Molecular Medicine and Biotherapy Ministry of Industry and Information TechnologySchool of Life SciencesBeijing Institute of TechnologyBeijing 100081China Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information TechnologyAdvanced Research Institute of Multidisciplinary ScienceBeijing Institute of TechnologyBeijing 100081China CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex SystemsState Key Laboratory of Biochemical EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical and Engineering University of Chinese Academy of SciencesBeijing 100049China Innovation Academy for Green Manufacture Chinese Academy of SciencesBeijing 100190China

Chitin is a widely used important industrial polymer mainly from shrimp shells, but its commercial preparation is under the great challenge of serious pollution due to the requirement of HCl and Na ***, we demonstrated that high purity chitin can be obtained from waste shrimp shells(WSSs) by cascade separation with transition metal salt aqueous solution and ionic liquid(IL). Firstly, calcium carbonate of WSSs was effectively removed in the metal salt aqueous solution driven by the ion exchange interaction. Subsequently, 1-butyl-3-methylimidazolium chloride([Bmim]Cl) had bifunctional abilities to remove residual protein and introduced metal salts simultaneously by hydrogen bonding and coordination interactions. The key experimental factors affecting the separation process were systematically studied, including the type of metal salts, temperature, and [Bmim]Cl loading. After sequential treatment with a 20%(mass) Ni SO4aqueous solution at 130 ℃ and [Bmim]Cl at 150 ℃, the purity of a-chitin can be up to 96.5%(mass) that meets commercial requirements. The use of metal salts with higher coordination ability makes the preparation of chitin no longer depend on the commonly acid-base reaction, which is conducive to the preservation of chitin structure.

关键词： Chitin Ionic liquids Transition metal salts Separation Sustainability

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Insight into the effect of gel drying temperature on the structure and desulfurization performance of ZnO/SiO_(2)adsorbents

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Chinese Journal of Chemical engineering 2023年第4期56卷 233-241页

作者： Chao Yang Zhelin Su Yeshuang Wang Huiling Fan Meisheng Liang Zhaohui Chen College of Environmental Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024China State Key Laboratory of Multi-phase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

A series of ZnO/SiO_(2) adsorbents were prepared by a sol-gel method using tetraethyl orthosilicate,ethylene glycol(EG)and nitrates as *** effect of gel drying temperature on the structure and desulfurization performance of the adsorbents were investigated in *** is found that the low drying temperature led to a weak interaction among EG,Si AOH/H_(2)O and the nitrates in the gel system,which caused the oxidation of EG by NO3-and formed zinc glyoxylate complex during the gel calcination process,whereas this oxidation process also occurred at a high drying temperature during the gel drying *** formed zinc glyoxylate complex promoted the generation of monodentate carbonate on the surface of Zn O,which resulted in the inferior desulfurization performance of adsorbents despite they have smaller Zn O *** gel dried at 120°C formed the hydrogen bonds between EG and Si AOH/H_(2)O and a strong interaction between zinc oxo-clusters and NO3-was also found in the gel system,which avoided the oxidation of EG by NO3-during the preparation process and the Zn O nanoparticles with sizes of 6 nm were formed by a combustion *** adsorbent affords a highest sulfur capacity of 104.9 mg·g^(-1) in this *** addition,the gel drying temperature has a significant influence on the textural properties of the adsorbents except their surface area.

关键词： Sol-gel method Drying temperature H_(2)S removal Zinc-silica composites Hydrogen bonds

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Actuator Fault Estimation Based on Sliding Mode Observer for Continuous-Time Switched systems 21

Actuator Fault Estimation Based on Sliding Mode Observer for...

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21st International Multi-Conference on systems, Signals and Devices, SSD 2024

作者： Elouni, Mohamed Hamdi, Habib Rabaoui, Bouali Rodrigues, Mickael Braiek, Naceur Benhadj Polytechnic School of Tunisia University of Carthage Advanced Systems Laboratory La Marsa2078 Tunisia University of Lyon Automation and Process Engineering Laboratory Villeurbanne LyonF-69622 France

ISBN: (纸本)9798350374131

In this paper, an actuator fault reconstruction scheme for a class of continuous-time switched systems with unknown external disturbances is investigated. The proposed fault estimation approach uses a switching Sliding Mode Ob-server (SMO) which allows achieving fast and exact fault information. Sufficient conditions are formulated in terms of Linear Matrix Inequalities (LMIs) optimization by using a multiple Lyapunov-Krasovskii functional while respecting the Mode-Dependent Average Dwell Time (MDADT) constraints in the objective to obtain less conservative results. Finally, a simulation study on a two-tank process is considered to illustrate the effectiveness of the proposed fault reconstruction approach. © 2024 IEEE.

关键词： Continuous time systems

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Effect of Operation Parameters on the Thermal Characteristics in a Planar Solid Oxide Fuel Cell

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Journal of Thermal Science 2024年第5期33卷 1974-1989页

作者： WANG Mingyuan WANG Ke WANG Yongqing CHEN Jiangshuai AN Bo TU Shantung School of Mechanics and Safety Engineering Zhengzhou UniversityZhengzhou 450001China Key Laboratory of Process Heat Transfer and Energy Saving of Henan Province Zhengzhou UniversityZhengzhou 450002China School of Mechanical and Power Engineering Zhengzhou UniversityZhengzhou 450001China Key Laboratory of Pressure Systems and Safety(MOE) East China University of Science&TechnologyShanghai 200237China

Effective operation strategies in the solid oxide fuel cell(SOFC)can adjust the spatial distribution of temperature gradient favoring the long-term *** investigate the effects of different operating conditions on the thermal behavior inside SOFC,a three-dimensional model is developed in this *** model is verified by comparing it with the experimental *** heat generation rate and its variation under different operating conditions are *** combined effects of operating voltage and gas temperature are considered to be the key factor influencing the temperature *** to the original case,the temperature of SOFC decreases by 21.4 K when the fuel velocity reaches 5 m/*** the maximum temperature gradient increases by21.2%.Meanwhile,higher fuel velocities can eliminate about 32%of the area with higher temperature *** when the oxidant velocity reaches 7.5 m/s,the peak temperature gradient effectively decreases by 16.59%.Simultaneous adjustment of the oxidant and fuel velocities can effectively reduce the peak temperature gradient and increase the safety *** effects of operation conditions on the temperature gradient of the cell are clarified in this study,which can be a reference for further research on the reliability of SOFCs.

关键词： SOFC heat generation temperature gradient distribution heat source thermal behavior

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Tuning the atomic configuration environment of MnN_(4) sites by Co cooperation for efficient oxygen reduction

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Journal of Energy Chemistry 2023年第7期82卷 547-559,I0012页

作者： Jing Wang Haihong Zhong Jun Yang Huiyu Li Pinggui Tang Yongjun Feng Dianqing Li State Key Laboratory of Chemical Resource Engineering Beijing Engineering Center for Hierarchical CatalystsCollege of ChemistryBeijing University of Chemical TechnologyBeijing 100029China College of Science Hainan UniversityHaikou 570228HainanChina State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Carbon-based N-coordinated Mn(Mn-N_(x)/C)single-atom electrocatalysts are considered as one of the most desirable non-precious oxygen reduction reaction(ORR)candidates due to their insignificant Fenton reactivity,high abundance,and intriguing electrocatalytic ***,current MnN_(x)/C single-atom electrocatalysts suffer from high overpotentials because of their low intrinsic activity and unsatisfactory chemical ***,through an in-situ polymerization-assisted pyrolysis,the Co as a second metal is introduced into the Mn-N_(x)/C system to construct Co,Mn-N_(x)dual-metallic sites,which atomically disperse in N-doped 1D carbon nanorods,denoted as Co,Mn-N/CNR and *** electron microscopy and X-ray absorption spectroscopy(XAS)techniques,we verify the uniform dispersion of CoN4and MnN4atomic sites and confirm the effect of Co doping on the MnN_(4) electronic *** functional theory(DFT)calculations further elucidate that the energy barrier of ratedetermining step(^(*)OH desorption)decreases over the 2 N-bridged MnCoN_(6) moieties related to the pure MnN_(4).This work provides an effective strategy to modulate the local coordination environment and electronic structure of MnN_(4) active sites for improving their ORR activity and stability.

关键词： Dual-atom sites Oxygen reduction reaction M-Nx/C catalysts Coordination environment Electronic structure Synergistic effect

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Biomass as an alternative solution to energy production and reduction of the greenhouse gas emissions: a review

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International Journal of Power and Energy Conversion 2025年第1期16卷 78-99页

作者： Abouallal, Hafida El Idrissi, Ayoub Najah Dkhireche, Nadia Touhami, Mohammed Ebn Laboratory of Advanced Material Engineering Process Department of Chemistry Faculty of Sciences Ibn Tofail University University Campus P.O. Box 242 Kenitra Morocco Advanced Systems – Engineering Laboratory National School of Applied Science Ibn Tofail University University Campus P.O. Box 242 Kenitra Morocco

The increase in population and the expansion of transportation, agriculture, and industry drive the need for energy, leading to a reliance on fossil fuels as the primary energy source. This reliance results in heightened greenhouse gas emissions and environmental damage. To address this, efforts have been made to harness the diverse range of available biomass for energy production, including gas, heat, and electricity through various conversion methods. This article explores the global availability of biomass for energy production, current energy consumption and production trends, biomass classifications and sources, conversion techniques, challenges hindering biomass implementation, and the potential of biomass as an alternative energy source alongside wind, geothermal, and hydroelectric power to eventually replace fossil fuels. The analysis indicates that biomass holds promise for energy generation and can complement other renewable resources in transitioning away from fossil fuels. Copyright © 2025 Inderscience Enterprises Ltd.

关键词： Greenhouse gas emissions

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Effect of oxygen enrichment on sintering behavior of high proportion vanadium-titanium magnesite concentrates

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Journal of Iron and Steel Research International 2023年第11期30卷 2122-2132页

作者： Shi-hong Peng Hao Liu Ze-zheng Sun Chang-wei Li Yue-lin Qin Wei-qiang Liu Guang Wang School of Metallurgy and Materials Engineering Chongqing University of Science and TechnologyChongqing401331China Value-Added Process and Clean Extraction of Complex Metal Mineral Resources Chongqing Municipal Key Laboratory of Institutions of Higher EducationChongqing401331China Chongqing Chuanyi Automation Co. Ltd.Chongqing401120China Process and Systems Engineering Åbo Akademi UniversityÅbo20500Finland Department of Materials Science and Engineering McMaster UniversityOntarioL8S 4L7Canada

To achieve high-efficiency utilization of complex and unmanageable iron-containing minerals,the effects of oxygen enrichment on productivity,yield,flame front speed,exhaust gas peak temperature,and desulphurization reaction of the vanadium-titanium magnetite sintering process as well as sinter tumble index and mineralogy were clarified,with oxygen enrichment concentrations ranging from 21 to 29 vol.%.Results indicated that with increasing the oxygen enrichment concentration from 21 to 27 vol.%,the flame front speed increased from 30.3 to 40.0 mm min^(-1),the yield enhanced from 72%to 77%,and the productivity augmented from 1.83 to 2.67t m^(-2)h^(-1);in the meantime,the tumble index was improved from 73.7%to 77.9%,and the exhaust gas peak temperature rose from 376.4 to 484.8℃.The main reason for the improvement in sintering properties was the increased combustibility of fuels and the generation of proper liquid phase that improved the permeability of the packed *** improved sinter strength is mainly due to the increase in the phase fraction of silico-ferrites of calcium and *** addition,oxygen enrichment sintering could significantly increase the desulphurization level of vanadium-titanium magnetite sinter and the rate of desulphurization reaction during sintering process.

关键词： Sinter Oxygen enrichment Vanadium-titanium magnetite Sintering behavior

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Balancing electron transfer and intermediate adsorption ability of metallic Ni-Fe-RE-P bifunctional catalysts via 4f-2p-3d electron interaction for enhanced water splitting

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Journal of Energy Chemistry 2024年第7期94卷 458-465页

作者： Hong-Rui Zhao Cheng-Zong Yuan Chenliang Zhou Wenkai Zhao Lunliang Zhang Cong-Hui Li Lei Xin Fuling Wu Shufeng Ye Xiaomeng Zhang Yunfa Chen School of Rare Earths University of Science and Technology of ChinaHefei 230026AnhuiChina Jiangxi Province Research Institute of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou 341119JiangxiChina State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Balancing electron transfer and intermediate adsorption ability of bifunctional catalysts via tailoring electronic structures is crucial for green hydrogen production,while it still remains challenging due to lacking efficient ***,one efficient and universal strategy is developed to greatly regulate electronic structures of the metallic Ni-Fe-P catalysts via in-situ introducing the rare earth(RE)atoms(Ni-Fe-RE-P,RE=La,Ce,Pr,and Nd).Accordingly,the as-prepared optimal Ni-Fe-Ce-P/CC self-supported bifunctional electrodes exhibited superior electrocatalytic activity and excellent stability with the low overpotentials of 247 and 331 mV at 100 mA cm^(-2) for HER and OER,*** the assembled electrolyzer,the Ni-Fe-Ce-P/CC as bifunctional electrodes displayed low operation potential of 1.49 V to achieve a current density of 10 mA cm^(-2),and the catalytic performance can be maintained for 100 *** results combined with density functional theory(DFT)calculation reveal that Ce doping leads to electron decentralization and crystal structure distortion,which can tailor the band structures and d-band center of Ni-Fe-P,further increasing conductivity and optimizing intermediate adsorption *** work not only proposes a valuable strategy to regulate the electron transfer and intermediate adsorption of electrocatalysts via RE atoms doping,but also provides a deep under-standing of regulation mechanism of metallic electrocatalysts for enhanced water splitting.

关键词： RE atoms Electron transfer Adsorption energy Oxygen evolution Hydrogen evolution

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Recent progress of green sorbents-based technologies for low concentration CO_(2) capture

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Chinese Journal of Chemical engineering 2021年第3期34卷 113-125页

作者： Yuanyue Zhao Yihui Dong Yandong Guo Feng Huo Fang Yan Hongyan He College of Mathematics Science Bohai UniversityJinzhou 121013China Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and EngineeringState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

The increased concentration of CO_(2) due to continuous breathing and no discharge of human beings in the manned closed space,like spacecraft and submarines,can be a threat to health and *** removal of low concentration CO_(2) from the manned closed space is essential to meet the requirements of long-term space or deep-sea exploration,which is an international frontier and *** liquids(ILs),as a widespread and green solvent,already showed its excellent performance on CO_(2) capture and absorption,indicating its potential application in low concentration CO_(2) *** this review,we first summarized the current methods and strategies for direct capture from low concentration CO_(2) in both the atmosphere and manned closed ***,the multi-scale simulation methods of CO_(2) capture by ionic liquids are described in detail,including screening ionic liquids by COSMO-RS methods,capture mechanism by density functional theory and molecular dynamics simulation,and absorption process by computational fluid dynamics ***,some typical IL-based green technologies for low concentration CO_(2) capture,such as functionalized ILs,co-solvent systems with ILs,and supported materials based on ILs,are introduced,and analyzed the subtle possibility in manned closed ***,we look forward to the technology and development of low concentration CO_(2) capture,which can meet the needs of human survival in closed space and proposed that supported materials with ionic liquids have great advantages and infinite possibilities in the vital area.

关键词： Low concentration CO_(2)capture Ionic liquids Manned closed spaces

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