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Feasibility evaluation of near dissolved organic matter microfiltration (NDOM MF) for the efficient removal of microplastics in the water treatment process

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Chemosphere 2024年 356卷 141882页

作者： Lee, Uje Park, Kyeongyeon Chang, Seungwon Cho, Min Lee, Jaewoo Department of Bionanotechnology and Bioconvergence Engineering Jeonbuk National University 567 Baekje-daero Deokjin-gu Jeonju54896 Korea Republic of Division of Biotechnology SELS Center College of Environmental and Bioresource Sciences Jeonbuk National University Iksan54596 Korea Republic of Department of Polymer-Nano Science and Technology Department of JBNU-KIST Industry-Academia Convergence Research Polymer Materials Fusion Research Center Jeonbuk National University 567 Baekje-daero Deokjin-gu Jeonju54896 Korea Republic of

Microfiltration (MF) using membranes with a mean pore size smaller than 0.45 μm has generally been used for particle removal from water, given that materials larger and smaller than 0.45 μm are regarded as particulates and dissolved organic matter (DOM), respectively. It is also the case for removing small-size microplastics (MPs). However, given their sizes (ca. 1 μm), there is room for further improvement of the productivity (i.e., water flux) in the pore size range of 0.45–1 μm on the condition that the removal rate is maintained. With this in mind, MF's water flux and removal rate were tested using seven different MF membranes, and the right pore, with the size of 0.8 μm, was found for MP removal, which is called near DOM (NDOM) MF. In the filtration test using polystyrene surrogate beads with an average particle diameter of 1.20 μm, NDOM MF exhibited a 1.7 to 13 times higher permeate flux than the conventional MF using 0.1, 0.2, and 0.45 μm membranes while maintaining a higher removal rate than 2 log. The excellent removal rate of the NDOM MF was attributable to the following three factors: (1) smaller mean pore size than the average particle diameter, (2) particle screening effect enhanced by the secondary layer formed by surface deposition, and (3) 3D mesh sublayer structure favorable for capturing penetrated particles. Furthermore, the outstanding filtration performance also appeared in a low-temperature ( © 2024 Elsevier Ltd

关键词： Microfiltration

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Tailoring Ion Dynamics in Energy Storage Conductors for Ultra-Stable, High-Performance Solid-State Microsupercapacitor Array

SSRN

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SSRN 2022年

作者： Park, Gaeun Lee, Dawoon Kim, Youngoh Choi, Joonmyung Choi, U. Hyeok Kim, Jaekyun Department of Photonics and Nanoelectronics Hanyang University Ansan15588 Korea Republic of Department of Mechanical Design Engineering Hanyang University Seoul04763 Korea Republic of Department of Mechanical Engineering Hanyang University Ansan15588 Korea Republic of Department of Polymer Science and Engineering and Program in Environmental and Polymer Engineering Inha University Incheon22212 Korea Republic of BK21 FOUR ERICA-ACE Center Hanyang University Ansan15588 Korea Republic of

All-solid-state electrochemical energy storage (EES) devices with prolonged lifetime, operational stability, and mechanical flexibility can be a promising route to powering up wearable electronics. However, conventional EES devices have been often hindered by a gradual decrease in energy capacity due to low ionic conducting electrolytes, non-suitable electrode materials, or poor electrode/electrolyte interfaces. Herein, we propose a harmonization of the molecular-level tailoring of ionic gel polymer electrolyte (IGPE) and graphene-based electrodes, significantly improving and sustaining the electrochemical performance (11.9 μWh cm-2) of EES microsupercapacitor (MSC) devices. Our optimized MSC device based on ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EMIM-FSI) and interdigitated reduced-graphene oxide (rGO) electrode array maintains 99% of the initial electrochemical capacity even after 20,000 cycles, also demonstrating the excellent mechanical flexibility (bending radius up to 4 mm) and environmental stability (>30 days) of the MSC-based array. Molecular-level simulation and spectroscopic atomic analysis revealed noticeably lower residual ionic liquid (IL) molecules of EMIM-FSI, compared to EMIM-trifluoromethyl FSI, between the graphene-based layers of electrodes during the charge/discharge cycles. Therefore, our optimization strategy and finding will pave the way to accomplishing next-generation of all-solid-state EES devices with ultra-high operational stability, powering wearable electronics. © 2022, The Authors. All rights reserved.

关键词： Molecular dynamics

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Crystallization of POSS in a PEG-Based Multiblock Polyurethane: Toward A Hybrid Hydrogel

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MRS Online Proceedings Library 2021年第1期847卷 59-64页

作者： Jian Wu Qing Ge Kelly A. Burke Patrick T. Mather Chemical Engineering Department and Polymer Program Institute of Materials Science University of Connecticut Storrs USA Department of Macromolecular Science and Engineering Case Western Reserve University Cleveland USA

Building upon earlier success in forming materials with crystalline ordering of POSS via the telechelic architecture with POSS end-capping polyethylene glycols, here we report similar ordering in PEG-POSS thermoplastic polyurethane applicable to a novel hybrid hydrogel. Thus, a unique series of hybrid thermoplastic polyurethanes (TPUs) were synthesized using poly(ethylene glycol) (PEG) as soft segment and incorporating an isobutyl-functionalized POSS diol (TMP POSS diol) in the hard segment. The molecular weight of PEG was systematically varied to include 10, 20, and 35 kDa while the mole ratio of PEG to POSS diol (as chain extender) was chosen as 8:1. The diisocyanate employed for TPU polymerization was 4, 4'-methylenebis(phenyl-isocyanate) (MDI). Wide-angle X-ray diffraction (WAXD) studies revealed that both the hydrophilic soft segments (PEG) and hydrophobic hard segments (POSS) can form crystalline structures driven by micro-phase separation, itself due to thermodynamic incompatibility. Differential scanning calorimetry (DSC) and rheological studies revealed that thermal history is important in controlling the crystallization of a POSS-rich nanophase. Increasing the cooling rate monotonically decreases the crystallinity of POSS-rich phase and results in a decrease in the ultimate dynamic storage modulus following POSS crystallization and an increase of the loss angle for temperatures above Tm of PEG and below Tm of POSS. We conclude that both composition and thermal history are key factors in determing the internal network built by the POSS nanophase, which will have a significant influence on the properties of the resulting hybrid hydrogels now being studied.

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Subtle side chain modification of triphenylamine‐based polymer hole‐transport layer materials produces efficient and stable inverted perovskite solar cells

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Interdisciplinary Materials 2022年第2期1卷 281-293页

作者： Yue-Min Xie Qin Yao Qifan Xue Zixin Zeng Tianqi Niu Yingzhi Zhou Ming-Peng Zhuo Sai-Wing Tsang Hin-Lap Yip Yong Cao Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhouP.R.China Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(South China University of Technology) GuangzhouP.R.China Department of Materials Science and Engineering City University of Hong KongKowloonHong KongChina School of Energy and Environmental Science City University of Hong KongKowloonHong KongChina

polymer hole-transport layers(HTLs)are critical components of inverted perovskite solar cells(IPVSCs).Triphenylamine derivatives PTAA(poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine])and Poly-TPD(poly[N,N′-bis(4-butylphenyl)-N,N′-bis(phenyl)benzidine])have been widely adopted as hole-transport materials due to their perovskite passivation effects and suitable energy ***,the passivation mechanism(i.e.,the functional group responsible for perovskite passivation)of triphenylamine derivative polymers remains unclear,hindering the development and application of this polymer ***,we develop a novel Poly-TPD derivative,S-Poly-TPD,by replacing the n-butyl functional group of Poly-TPD with an isobutyl group to explore the influence of alkyl groups on HTL performance and top-deposited perovskite *** with Poly-TPD,the increased CH_(3)-terminal unit density and the decreased spatial distance between the-CH-CH_(3) and-CH_(2)-CH_(3) units and the benzene ring in S-Poly-TPD not only enhanced the hole-transport ability but also improved the perovskite passivation effect,revealing for the first time the role of the alkyl groups in perovskite *** a result,the S-Poly-TPD-based IPVSCs demonstrated high power-conversion efficiencies of 15.1% and 21.3% in wide-bandgap[MAPbI_(2)Br(SCN)0.12]and normal-bandgap[(FAPbI_(3))0.92(MAPbBr_(3))0.08]devices,respectively.

关键词： alkyl group inverted perovskite solar cells(IPVSCs) perovskite passivation polymer hole transport layers(HTLs) Poly-TPD,PTAA

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Biopolymer passivation for high-performance perovskite solar cells by blade coating

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Journal of Energy Chemistry 2021年第3期30卷 45-52页

作者： Shudi Qiu Xin Xu Linxiang Zeng Zhen Wang Yijun Chen Culling Zhang Chaohui Li Jinlong Hu Tingting Shi Yaohua Mai Fei Guo Institute of New Energy Technology College of Information Science and TechnologyJinan UniversityGuangzhou 510632GuangdongChina Siyuan Laboratory Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy Materials Department of Physics Jinan UniversityGuangzhou 510632GuangdongChina College of Chemistry Environmental Engineering Datong University.Datong 037009ShanxiChina National Engineering Research Center for Advanced Polymer Processing Technology Zhengzhou UniversityZhengzhou 450002HenanChina

Thin films of perovskite deposited from solution inevitably introduce large number of defects,which serve as recombination centers and are detrimental for solar cell *** many small molecules and polymers have been delicately designed to migrate defects of perovskite films,exploiting credible passivation agents based on natural materials would offer an alternative ***,an ecofriendly and cost-effective biomaterial,ploy-L-lysine(PLL),is identified to effectively passivate the defects of perovskite films prepared by *** is found that incorporation of a small amount(2.5 mg mL^(-1))of PLL significantly boosts the performance of printed devices,yielding a high efficiency of 19.45% with an increase in open-circuit voltage by up to 100 *** functional theory calculations combined with X-ray photoelectron spectroscopy reveal that the functional groups(-NH2,-COOH)of PLL effectively migrate the Pb-I antisite defects via Pb-N coordination and suppress the formation of metallic Pb in the blade-coated perovskite *** work suggests a viable avenue to exploit passivation agents from natural materials for preparation of high-quality perovskite layers for optoelectronic applications.

关键词： Perovskite solar cells Blade coating Biopolymer passivation Density functional theory

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Enhanced Photocatalytic Reduction of Cr (Vi) Using Porous Hierarchical Bi2o3/Bi2s3 High-Low Heterojunctions: Novel Strategies and Charge Transfer Mechanisms

SSRN

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SSRN 2024年

作者： Sang, Yan Xue, Jingwei Hu, Junjie Zhang, Peng Zhao, Fu-Gang He, Yanping College of Chemistry and Materials Science Center for Nano Science and Technology Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Normal University Wuhu241002 China Department of Environmental Science and Engineering University of Science and Technology of China Hefei230026 China School of Chemistry and Chemical Engineering Key Laboratory of Surface and Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University Zhejiang Hangzhou310018 China

High-low heterojunctions derived from metal-organic frameworks (MOFs) have promising applications in photocatalytic wastewater treatment because of their high photo-redox ability and boosted charge separation efficiency. Herein, Bi-MOF derived porous hierarchical Bi2O3/Bi2S3 nanoflower-like heterojunctions were prepared by the calcination-hydrothermal method. The optimized Bi2O3/Bi2S3-2 composite showed a higher degradation rate of Cr (VI) (99.79% in 30 min) than the pure substance. Moreover, comprehensive studies were conducted on the kinetics, stability and recycling of Bi2O3/Bi2S3, as well as optical characteristics. The active species trapping experiments confirmed that e- plays a dominant role in the elimination of Cr (VI). These findings provided novel strategies for construction of porous hierarchical heterojunctions with advanced visible-light-induced degradation performance. The enhanced photo-degradation efficiency of the optimal nanocomposite was assigned to the higher visible-light absorbance, separation of photogenerated carriers, reduced recombination of photo-induced carriers, and enhanced redox capability owing to the construction of porous hierarchical heterojunctions amongst the components. © 2024, The Authors. All rights reserved.

关键词： Bismuth compounds

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Enhanced Photocatalytic Reduction of Cr (Vi) Using Porous Hierarchical Bi2o3/Bi2s3 High-Low Heterojunctions: Novel Strategies And Charge Transfer Mechanisms

SSRN

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SSRN 2024年

作者： Sang, Yan Xue, Jingwei Hu, Junjie Zhang, Peng Zhao, Fugang He, Yanping College of Chemistry and Materials Science Center for Nano Science and Technology Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Normal University Wuhu241002 China Department of Environmental Science and Engineering University of Science and Technology of China Hefei230026 China School of Chemistry and Chemical Engineering Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University Zhejiang Hangzhou310018 China

关键词： Bismuth compounds

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Surface engineering Towards Boosted Dielectric Properties for High-Temperature polymers Under Electrical Extremes

Surface Engineering Towards Boosted Dielectric Properties fo...

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Conference on Electrical Insulation and Dielectric Phenomena, (CEIDP)

作者： Jierui Zhou Marina Dabaghian Anna Marie LaChance Jing Hao Wesley Zhong Luyi Sun Yang Cao Department of Electrical and Computer Engineering University of Connecticut Storrs CT USA Electrical Insulation Research Center Institute of Materials Science University of Connecticut Storrs CT USA Department of Chemical and Biomolecular Engineering University of Connecticut Storrs CT USA Polymer Program Institute of Materials Science University of Connecticut Storrs CT USA

polymer-thin films are critical dielectric materials for capacitive energy storage in power and electronic systems. The rapid development of wide bandgap semiconductors urgently calls for polymers that can attain high energy density and high charge-discharge efficiency at elevated temperatures. However, high-temperature polymers usually suffer from compromised dielectric breakdown strength and soaring conduction loss due to the intrinsic constraint between their bandgaps and thermal stability. In this work, we propose a facile and high throughput interface engineering technique utilizing nanocoatings formed by montmorillonite (MMT) nanoclays, which can serve as an out-of-the-box solution to bypass this constraint. The highly ordered MMT-based nanocoatings with layered structure can significantly block the excessive charge injection at high electric fields and dissipate the charge carriers along the in-plane direction. The MMT-coated PI films exhibit improved breakdown strength, suppressed conduction loss, and boosted charging-discharging efficiency. This work holds the promise of improving the dielectric properties of polymers through surface engineering, enabling their application at concurrent electrical and thermal extremes.

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Effect of Different Manufacturing Methods on Polyamide Reverse-Osmosis Membranes for Desalination: Insights from Molecular Dynamics Simulations

SSRN

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SSRN 2022年

作者： He, Jinlong McCutcheon, Jeffrey R. Li, Ying Department of Mechanical Engineering University of Connecticut StorrsCT06269 United States Department of Chemical & Biomolecular Engineering Center for Environmental Sciences and Engineering University of Connecticut StorrsCT06269 United States Polymer Program Institute of Materials Science University of Connecticut StorrsCT06269 United States

The industry-leading polyamide (PA) reverse osmosis (RO) membranes can be manufactured via molecular layer-by-layer (mLBL) deposition, interfacial polymerization (IP), and 3D-printing technique. However, the influence of different manufacturing methods on PA membrane’s properties is far from understood. In this study, we present the high-pressure transport behavior of water and salt ions for PA membranes formed with IP, mLBL, and 3D-printing through non-equilibrium molecular dynamics simulations. Studies show that membranes fabricated with 3D-printing have similar performances to those manufactured using mLBL, quantified by water permeability, rejection of salt ions, structural integrity, and porosity features. However, the membranes formed with IP exhibit faster water transport, lower rejection, worse structural integrity, and more inhomogeneous network pores than those constructed using mLBL and 3D-printing. The unconnected water-accessible space governs water transport for PA membranes formed with mLBL and 3D-printing, which offers the impermanent open-closed pores that enable water to jump through PA membranes. In contrast, the permeated water-enterable space plays a prominent role in water movement across the PA membrane formed with IP, providing a continuous transport channel at high pressure. Importantly, we observe the more significant compaction features at high pressure for PA membranes formed with IP than mLBL and 3D-printing. © 2022, The Authors. All rights reserved.

关键词： polymerization

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Carbon dioxide, global boiling, and climate carnage, from generation to assimilation, photocatalytic conversion to renewable fuels, and mechanism

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science of the Total Environment 2025年 965卷 178629页

作者： Khan, Muhammad Sun, Xiaohui Zada, Amir Azizi, Shohreh Shah, Muhammad Ishaq Ali Khan, Javed Ali Ragab, Ahmed H. Taher, Mostafa A. Abbas, Qumber Han, Changseok College of Civil and Transportation Engineering Shenzhen University 3688 Nanhai Avenue Guangdong Province Shenzhen518060 China Department of Chemistry Abdul Wali Khan University Mardan Mardan23200 Pakistan UNESCO-UNISA Africa Chair in Nanosciences and Nanotechnology College of Graduate Studies University of South Africa Muckleneuk Ridge PO Box 392 Pretoria0002 South Africa Chemistry Department Faculty of Science King Khalid University P.O. Box 9004 Abha61413 Saudi Arabia Biology Department Faculty of Science and Arts King Khalid University Mohail Assir 61321 Saudi Arabia Department of Technologies and Installations for Waste Management Faculty of Energy and Environmental Engineering Silesian University of Technology Gliwice44-100 Poland Program in Environmental and Polymer Engineering of INHA University 100 Inha-ro Michuhol-gu Incheon22212 Korea Republic of Department of Environmental Engineering INHA University 100 Inha-ro Michuhol-gu Incheon22212 Korea Republic of

The increasing CO2 concentration in the atmosphere has substantial impacts on the global temperature. For energy sustainability and minimization of the effects of global warming, an approach to understand CO2 capturing and a carbon neutral culture is extremely essential in the present circumstances. The CO2 emission from vehicles and industries can be minimized using energy cost-effective techniques and can be converted more selectively into reusable fuels via thermochemical, electrochemical, photochemical, photocatalytic, electrocatalytic, biological and inorganic carbonate-based approaches. In this review article, we have discussed the effects of increased global temperature on human beings, economy and climate change. Further, we have discussed the photocatalytic conversion of CO2 (PC-CO2) into gaseous and liquid fuels under solar light driven photocatalysis. The adsorption and activation of CO2, its conversion into various intermediates, their stability and selectivity of the final products have been elaborated comprehensively. The conversion mechanisms of CO2 into CO, CH4, alcohol, aldehyde and carboxylic acid have been discussed in detail. The role of defects and exposed facets of photocatalysts, effect of metal and non-metal dopants, and the additive role of co-catalyst on the mechanisms and selectivity of the conversion products have been discussed comprehensively. Finally, future perspective is discussed to highlight the research gap in the PC-CO2. We hope that this article will help to understand the mechanisms of PC-CO2 and will direct researchers to add their role in the reduction of CO2 to control global warming and make life easier on earth in the coming years. © 2025 Elsevier B.V.

关键词： Kyoto Protocol

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