检索结果-内蒙古大学图书馆

Electrospun advanced nanomaterials for in situ transmission electron microscopy:Progress and perspectives

InfoMat 2023年第12期5卷 1-27页

作者： Jingyue Zhao Zulin Li Shiwen Lv Manxi Wang Chuanping Li Xuan Li Hongyang Chen Manxian Li Xiaochuan Chen Feifeng Wang Weiwei Fan Junxiong Wu Ziqiang Wang Xiaoyan Li Yuming Chen Engineering Research Center of Polymer Green Recycling of Ministry of Education Fujian Key Laboratory of Pollution Control&Resource ReuseCollege of Environmental and Resource Sciences and College of Carbon Neutral Modern IndustryFujian Normal UniversityFuzhouFujianthe People's Republic of China Department of Materials Science and Engineering and Department of Nuclear Science and Engineering Massachusetts Institute of TechnologyCambridgeMassachusettsUSA Institute of Materials Research Shenzhen International Graduate SchoolTsinghua UniversityShenzhenthe People's Republic of China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouFujianthe People's Republic of China

Electrospun nanofibers(NFs)have shown excellent properties including high porosity,abundant active sites,controllable diameter,uniform and designable structure,high mechanical strength,and superior resistance to external destruction,which are ideal nanoreactors for in situ *** various techniques,in situ transmission electron microscopy(TEM)has enabled operando observation at the atomic level due to its high temporal and spatial resolution combined with excellent sensitivity,which is of great importance for rational materials design and performance *** this review,the basic knowledge of in situ TEM techniques and the advantages of electrospun nanoreactors for in situ TEM characterization are first *** recent development in electrospun nanoreactors for studying the physical properties,structural evolution,phase transition,and formation mechanisms of materials using in situ TEM is then *** electrochemical behaviors of carbon nanofibers(CNFs),metal/metal oxide NFs,and solidelectrolyte interphase for different rechargeable batteries are ***,challenges faced by electrospun nanoreactors for in situ TEM characterization are discussed and potential solutions are proposed to advance this field.

关键词： batteries electrospun advanced nanofibers in situ transmission electron microscopy nanoreactors

来源：评论

学校读者我要写书评

暂无评论

Computational Insights into Deep Eutectic Solvent Design: Modeling Interactions and Thermodynamic Feasibility Using Choline Chloride & Glycerol

SSRN

引用

SSRN 2023年

作者： Uzochukwu, Maryann I. Oyegoke, Toyese Momoh, Raheem O. Shuwa, Suleiman M. Isa, Mohammed T. Jibril, Baba Y. Chemical Engineering Department Faculty of Engineering Ahmadu Bello University Zaria Kaduna State Nigeria Department of Polymer Technology Directorate of Polymer and Environmental Technology Nigerian Institute of Leather and Science Technology Kaduna State Zaria Nigeria

To address climate change and environmental concerns, the chemical process industries are increasingly adopting green technology and exploring eco-friendly waste management practices. Deep Eutectic Solvents (DES) have emerged as promising green solvents with diverse applications in the industries in separation processes, catalysis, drug design, and a lot more. However, the ideal way for modeling ionic interactions within the hydrogen-bond acceptor (HBA) during DES synthesis remains uncertain, and theoretical insight on the formation mechanism of energetically stable DESs from choline chloride (CHL) and urea (URE) is yet to be explored. In this study, we investigate different modeling approaches (no bond, generic bond, or single bond) for ionic interactions in hydrogen-bond acceptor (HBA) molecules during DES synthesis and the thermodynamic feasibility of forming an energetically stable DES using choline chloride (CHL) and urea (URE) through theoretical calculations (PM3, HF, and DFT). Our findings indicate that the choice of modeling approach does not significantly affect the outcomes across calculation levels. The H-X DES formation pathway emerges as the most viable route for CHL: GLC DES synthesis, offering strong binding energy and high exothermicity. This pathway provides a robust solution for synthesizing energetically stable DES with potential applications in various industries. Researchers can consider alternative calculation levels when DFT becomes cost-prohibitive to optimize computational costs. Our study contributes valuable insights into DES design and synthesis, promoting environmentally sustainable and cost-effective processes. © 2023, The Authors. All rights reserved.

关键词： Urea

来源：评论

学校读者我要写书评

暂无评论

Recent progress in perovskite solar cells:material science

引用

science China Chemistry 2023年第1期66卷 10-64页

作者： Jiang-Yang Shao Dongmei Li Jiangjian Shi Chuang Ma Yousheng Wang Xiaomin Liu Xianyuan Jiang Mengmeng Hao Luozheng Zhang Chang Liu Yiting Jiang Zhenhan Wang Yu-Wu Zhong Shengzhong(Frank)Liu Yaohua Mai Yongsheng Liu Yixin Zhao Zhijun Ning Lianzhou Wang Baomin Xu Lei Meng Zuqiang Bian Ziyi Ge Xiaowei Zhan Jingbi You Yongfang Li Qingbo Meng Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China Laboratory for Renewable Energy(CAS) Beijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of SciencesBeijing 100190China Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologyInstitute for Advanced Energy MaterialsSchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China Institute of New Energy Technology College of Information Science and TechnologyJinan UniversityGuangzhou 510632China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China School of Physical Science and Technology Shanghai Tech UniversityShanghai 201210China Australian Institute for Bioengineering and Nanotechnology and School of Chemical Engineering The University of QueenslandSt LuciaBrisbaneQLD 4072Australia Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology&EngineeringChinese Academy of SciencesNingbo 315201China Key Laboratory of Polymer Chemistry and Physics of Ministry of Education School of Materials Science and EngineeringPeking UniversityBeijing 100871China Key Laboratory of Semiconductor Materials Science Institute of SemiconductorsChinese Academy of SciencesBeijing 100083China School of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China Dalian National Laboratory for Clean Energy Collaborative Innovation Center of Chemistry for Energy Materials(iChEM)Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Key Laboratory of Funct

Perovskite solar cells represent a promising third-generation photovoltaic technology with low fabrication cost and high power conversion *** light of the rapid development of perovskite materials and devices,a systematic survey on the latest advancements covering a broad range of related work is urgently *** review summarizes the recent major advances in the research of perovskite solar cells from a material science *** discussed topics include the devices based on different type of perovskites(organic-inorganic hybrid,all-inorganic,and lead-free perovskite and perovskite quantum dots),the properties of perovskite defects,different type of charge transport materials(organic,polymeric,and inorganic hole transport materials and inorganic and organic electron transport materials),counter electrodes,and interfacial materials used to improve the efficiency and stability of *** discussions focus on the key progresses reported within the recent five ***,the major issues limiting the production of perovskite solar cells and the prospects for the future development of related materials are discussed.

关键词： perovskite solar cells power conversion efficiency perovskite materials hole transport materials electron transport materials counter electrode materials interfacial functional materials defects

来源：评论

学校读者我要写书评

暂无评论

Bioinspired Mineralization On Pdms Membranes for the Enhancement of Microbial Adhesion and Nitrogen Removal Performance in Mabr System

SSRN

引用

SSRN 2024年

作者： Wang, Minjie Tian, Yi Tong, Xiao Lou, Tingfei Zhou, Wei Lou, Jiahao Xu, Zhikang Huang, Xiaojun Department of Polymer Science and Engineering Zhejiang University Hangzhou310027 China China Electronics Innovation Environmental Technology Co. Ltd Wuxi214028 China

Nitrifying and denitrifying bacteria preferentially adhere to rough surfaces in nature, such as stones. Therefore, an innovative polydimethylsiloxane membrane with mineral coatings was fabricated, imitating natural stone surfaces that are suitable for bioadhesion. The mineralized membrane surfaces exhibited characteristics of improved hydrophilicity, roughness, and surface energy, which supported biomass accumulation on membrane surfaces and increased the secretion of extracellular polymeric substances in a membrane aerated bioreactor (MABR) for nitrogen removal from wastewater. Compared with pristine membranes, the mineralized membranes showed significantly increased nitrogen removal efficiencies, especially when treating wastewater with a high ammonia nitrogen concentration and low carbon to nitrogen ratio. Under optimized conditions (210 mg/L NH4+-N, C/N ratio of 2, pH 8.0), the NH4+-N removal and total nitrogen removal rates of the mineralized MABR system reached 4.00 g·d-1·m-2 and 4.97 g·d-1·m-2, respectively, corresponding to a 1.63- and 1.36-fold increase compared to the pristine system. The biofilms adhered onto mineralized membrane surfaces exhibited enrichment of both nitrifying and denitrifying bacteria, particularly the dominant denitrifying genus Moheibacter, promoting the simultaneous removal of ammonia nitrogen and total nitrogen. These findings show that the simulation of natural surfaces is beneficial for bioadhesion onto material surfaces, improving the nitrogen removal performance of MABR systems and providing an effective approach for the enhanced treatment of wastewater containing high concentration nitrogen compounds. © 2024, The Authors. All rights reserved.

关键词： Membranes

来源：评论

学校读者我要写书评

暂无评论

Biomass-Based Discrete Furan Oligomers as Materials for Electrochromic Devices

引用

ACS Sustainable Chemistry and engineering 2024年第1期12卷 459-469页

作者： Atayde, Eduardo C. Fong, Guan-Lun Yeh, Jyun-Yi Matsagar, Babasaheb M. Wang, Yu-Cheng Chen, De-Chian Peng, Chi-How Li, Yi-Pei Yamauchi, Yusuke Ho, Kuo-Chuan Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program (TIGP-MST) Academia Sinica No. 128 Sec. 2 Academia Road Taipei 11529 Taiwan Department of Chemistry National Tsing Hua University No. 101 Sec. 2 Kuang-Fu Road Hsinchu 30013 Taiwan Department of Chemical Engineering National Taiwan University No. 1 Sec. 4 Roosevelt Road Taipei 10617 Taiwan Sustainable Chemical Science and Technology Program Taiwan International Graduate Program (TIGP-SCST) Academia Sinica No. 128 Sec. 2 Academia Road Taipei 11529 Taiwan School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensl Brisbane 4072 QLD Australia Department of Materials Process Engineering Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan Institute of Polymer Science and Engineering National Taiwan University No.1 Sec. 4 Roosevelt Rd. Taipei 10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University No. 135 Yuandong Rd. Taoyuan 320 Taiwan

Electrochromic devices (ECDs) are materials that can undergo reversible changes in transmittance when exposed to different applied potentials. While many conjugated heterocyclic oligomers, such as oligothiophenes, have been developed for this purpose, there is no reported study on the use of discrete oligomeric furans as ECD materials. In this work, we introduce a furan trimer that can be utilized as a discrete electrochromic material, which transitions from light yellow to red and has a very high coloration efficiency of 1940 cm²/C at 507 nm. We propose that the reversible π-stack formation of the oligomer radical cations is behind this phenomenon, as evidenced by both experimental and computational results. The derivability of this oligomer from biomass and its facile synthesis make it an interesting alternative for other existing organic electrochromic materials. © 2023 American Chemical Society

关键词： electrochromism furan oligomer hydroxyalkylation−alkylation reaction solvatochromism π-stacks

来源：评论

学校读者我要写书评

暂无评论

Investigation of urban atmospheric visibility using Haar wavelet transform

引用

Aerosol and Air Quality Research 2024年第1期5卷 39-47页

作者： Luo, Chin-Hsiang Yuan, Chung-Shin Wen, Che-Yen Liaw, Jiun-Jian Chiu, Shih-Hsuan Department of Environmental Engineering Hung-Kuang University Taichung Taiwan Republic of China Institute of Environmental Engineering National Sun Yat-Sen University Kaohsiung Taiwan Republic of China Department of Forensic Science National Central Police University Da-Gang Guei-Shan Tao-Yuan Taiwan Republic of China Department of Polymer Engineering National Taiwan University of Science and Technology Taipei Taiwan Republic of China

A method of image processing, Haar wavelet transform, was first applied to establish a new index and provide accurate digital data to present urban atmospheric visibility, instead of the conventional observing method. Digital images of urban areas in Kaohsiung, a city at the south of Taiwan, are analyzed according to brightness (gray level). An index value for a scene image is calculated with a processor of Haar wavelet transform. As a result, a good correlation between the wavelet index values and the visual range values estimated by three trained observers is affirmed by the correlation coefficient (R2) of 0.81. Convenient transmission and the exchangeability of digital images of the real-time landscape facilitate the demonstration of the results on the web site.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Multifaceted regulation of chiroptical properties and self-assembly behaviors of chiral fluorescent polymers

Aggregate

引用

Aggregate 2024年第6期5卷 435-446页

作者： Youling He Junqian Zhang Chaoyang Ma Junkai Liu Jingjing Guo Ting Han Rongrong Hu Bing Shi Li Ben Zhong Tang Center for AIE Research Shenzhen Key Laboratory of Polymer Science and TechnologyGuangdong Research Center for Interfacial Engineering of Functional MaterialsGuangdong Provincial Key Laboratory of New Energy Materials Service SafetyCollege of Materials Science and EngineeringShenzhen UniversityShenzhenGuangdongChina College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhenGuangdongChina State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhouGuangdongChina Key Laboratory of New Lithium-Ion Battery and Mesoporous Material College of Chemistry and Environmental EngineeringShenzhen UniversityShenzhenGuangdongChina Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and ReconstructionThe Hong Kong University of Science and TechnologyClear Water BayKowloonHong KongChina School of Chemistry Chemical Engineering and BiotechnologyNanyang Technological University21 Nanyang LinkNanyangSingapore School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen(CUHK-Shenzhen)ShenzhenGuangdongChina

The multifaceted regulation of the chiroptical properties and self-assembly behaviors of chiral fluorescent polymers is of great significance yet remains challenging to ***,a series of novel salen-based chiral fluorescent polymers with aggregation-induced emission and varied substitution manners were facilely and efficiently *** factors were systematically investigated on the chiroptical properties and self-assembly performance of these polymers,which include molecular structures,solvent environments,metal coordination,and liquid crystal(LC)*** change in the solvent composition can lead to diverse assembly morphologies of all these chiral polymers,from single-handed helical fibers,helical toroids or loops,to spherical structures,consequently leading to an aggregation-reduced circular dichroism(CD)*** polymers bearing salen units show highly selective and reversible coordination with Zn^(2+)and can also induce multiple responses in the absorption,luminescence,CD,and circularly polarized luminescence(CPL)of these chiral fluorescent polymers via a coordination-and dissociation-initiated self-assembly ***,a small amount of the chiral fluorescent polymer in can induce achiral nematic 4-cyano-4′-n-pentylbiphenyl(5CB)to form ordered chiral nematic LC phase with significant improvement in their CD and CPL *** absolute absorption and luminescent dissymmetry factors of the resulting supramolecular assemblies can reach the order of 10^(−1).

关键词： aggregation-induced emission chirality circularly polarized luminescence fluorescent polymers selfassembly

来源：评论

学校读者我要写书评

暂无评论

A Review on Digital Simulation Strategies and Its Applications for Advanced Compression Garments 16

A Review on Digital Simulation Strategies and Its Applicatio...

引用

16th Textile Bioengineering and Informatics Symposium, TBIS 2023

作者： Youn, Seonyoung Darden, Ryan Mathur, Kavita Fiber and Polymer Science Ph.D. Program North Carolina State University RaleighNC27606 United States Department of Textile Engineering Chemistry and Sciences M.S. Textile Engineering Program North Carolina State University RaleighNC27606 United States Department of Textile and Apparel Technology and Management North Carolina State University RaleighNC27606 United States

ISBN: (纸本)9781713879473

This paper presents a comprehensive review on the current state of digital simulation technology and its strategic application usages with a key focus on advanced compression garments. Although three-dimensional (3D) digital garment simulators have significantly impacted the apparel and textile industry, their use has been limited to visual prototyping, quality checking, or marketing. The physical properties of garment simulators have been overlooked in advanced functional manufacturing. This literature review investigates the possibility of strategically utilizing virtual physical properties to enhance garment functions, specifically in wearables and medical-grade compression fields. The first phase of this paper gives an overview of the current state of 3D garment simulation tools and their measurement features. This is followed by a gap analysis between simulated and physical property evaluations, focusing on minimizing the gaps. The literature is thoroughly examined to identify appropriate studies that uses digital tools for compressional garments and add value to wearables and healthcare applications. This paper provides valuable insights for apparel and textile engineers, enabling them to better understand the limitations and capabilities of garment simulators in improving advanced features for specific end users. © TBIS 2023. All rights reserved.

关键词： Physical properties

来源：评论

学校读者我要写书评

暂无评论

What Can Topology Bring to Chemistry?

引用

CCS Chemistry 2024年第9期6卷 2084-2109页

作者： Wei Wang Songtao Zhou Xiujun Yu Qing-Hui Guo Yanhang Ma Jie Song Liang Zhang Xuzhou Yan Lu Han Qing Liao Xiaopeng Li Wen-Bin Zhang Yiyong Mai Shaodong Zhang Shunai Che Hai-Bo Yang Xuefeng Fu Mei-Xiang Wang School of Chemistry and Molecular Engineering East China Normal UniversityShanghai 200062 Hangzhou Institute of Medicine Chinese Academy of SciencesHangzhou 310022Zhejiang College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060Guangdong MOE Key Laboratory of Bioorganic Phosphorous and Chemical Biology Department of ChemistryTsinghua UniversityBeijing 100084 School of Physical Science and Technology and Shanghai Key Laboratory of High-Resolution Electron Microscopy ShanghaiTech UniversityShanghai 201210 School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesState Key Laboratory of Composite MaterialsShanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai 200240 School of Chemical Science and Engineering Tongji UniversityShanghai 200092 Beijing Key Laboratory for Optical Materials and Photonic Devices Department of ChemistryCapital Normal UniversityBeijing 100048 Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenter for Soft Matter Science and EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 Department of Chemical Sciences National Natural Science Foundation of ChinaBeijing 10085

The unique mathematical perspectives and principal concepts of topology have not only promoted the development of other branches of mathematics but have also deeply influenced other subjects,particularly physics and *** minireview aims to elucidate the substantial influence of topology on chemistry by critically examining both the contributions of topology to current chemical science and its potential future *** will discuss the topology of molecular structures and assemblies across various scales—from small molecules and mechanically interlocked molecules to polymers,biomacromolecules,and supramolecular *** discussion will include an exploration of cutting-edge techniques for characterizing topological features,underscoring the role of topology as a novel paradigm for the design and synthesis of new molecular ***,a critical analysis of topology’s role in the development of functional materials—such as photonic materials,polymers,biomacromolecules,and chiral materials—will demonstrate its emerging significance as a crucial parameter in unveiling novel properties and *** topology’s formidable potential,it is anticipated to be used increasingly to address pivotal challenges within chemistry and adjacent disciplines.

关键词： chemical topology topological invariants molecular graphs links and knots structureproperty relationship

来源：评论

学校读者我要写书评

暂无评论

Anion-regulation engineering toward Cu/In/MOF bimetallic electrocatalysts for selective electrochemical reduction of CO_(2) to CO/formate

引用

Materials Reports(Energy) 2022年第3期2卷 65-70页

作者： Bingqing Xu Israr Masood Ul Hasan Luwei Peng Junyu Liu Nengneng Xu Mengyang Fan Nabeel Khan Niazi Jinli Qiao State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Environmental Science and EngineeringDonghua UniversityShanghai201620China Shanghai Institute of Pollution Control and Ecological Security Shanghai200092China Institute of Soil and Environmental Sciences University of Agriculture FaisalabadFaisalabad38040Pakistan Department of Mechanical and Industrial Engineering University of TorontoTorontoOntarioM5S 3G8Canada

The conversion of carbon dioxide(CO_(2))into high-value added energy fuels and chemicals(CO,formate,C_(2)H_(4),etc.)through electrochemical reduction(eCO_(2)R)is a promising avenue to sustainable ***,low selectivity,barren activity and poor stability of the electrodes hinder the large-scale application of eCO_(2)***,we reported a copper-indium-organic-framework(CuIn-MOF)based high-performance catalyst for eCO_(2)***-trochemical measurement results reveal that CuIn-MOF exhibits high Faradaic efficiency(FE)of CO and formate(300 mV,FE_(CO)=78.6%at-0.86 V ***,FE_(HCOO^(-))=48.4%at-1.16 V ***,respectively)in a broad range of current density(20.1–88.4 mA cm^(-2))with long-term stability(6 h)for eCO_(2)R in 0.5 M KHCO_(3)electrolyte ***,through anion-regulation engineering,SO_(4)^(2-)anion precursor is more beneficial for the formic acid generation than NO_(3)^(-)anion precursor;while for SO_(4)^(2-)anion precursor,Cu plays a positive regulating role in eCO_(2)R to CO compared to ***,the high performance in a home-made eCO_(2)R reactor derives benefit from enhanced intrinsic activity and charge re-distribution can be attributed to the formation of In-doped Cu layer.

关键词： CuIn-MOF based Catalyst Anion-regulation engineering CO_(2)electroreduction CO/Formate production CO_(2)electrolyzer

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：