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Separation of microalgae from bacterial contaminants using spiral microchannel in the presence of a chemoattractant

Bioresources and Bioprocessing 2024年第1期11卷 511-525页

作者： Leticia F.Ngum Y.Matsushita Samir F.El-Mashtoly Ahmed M.R.Fath El-Bab Ahmed L Abdel-Mawgood Institute of Basic and Applied Sciences Biotechnology ProgramEgypt-Japan University of Science and TechnologyAlexandria 21934Egypt Institute of Basic and Applied Sciences Nanoscience ProgramEgypt-Japan University of Science and TechnologyAlexandria 21934Egypt Mechatronics and Robotics Engineering Department Egypt-Japan University of Science and TechnologyAlexandria 21934Egypt.

Cell separation using microfluidics has become an effective method to isolate biological contaminants from bodily fluids and cell cultures,such as isolating bacteria contaminants from microalgae cultures and isolating bacteria contaminants from white blood *** this study,bacterial cells were used as a model contaminant in microalgae culture in a passive microfluidics device,which relies on hydrodynamic forces to demonstrate the separation of microalgae from bacteria contaminants in U and W-shaped cross-section spiral microchannel fabricated by defocusing CO_(2) laser *** a flow rate of 0.7 ml/min in the presence of glycine as bacteria chemoattractant,the spiral microfluidics devices with U and W-shaped cross-sections were able to isolate microalgae(Desmodesmus sp.)from bacteria(***)with a high separation efficiency of 92%and 96%*** the same flow rate,in the absence of glycine,the separation efficiency of microalgae for U-and W-shaped cross-sections was 91%and 96%,*** was found that the spiral microchannel device with a W-shaped cross-section with a barrier in the center of the channel showed significantly higher separation *** microchannel chips with U-or W-shaped cross-sections were easy to fabricate and exhibited high *** these advantages,these devices could be widely applicable to other cell separation applications,such as separating circulating tumor cells from blood.

关键词： W-shaped cross-section CO_(2)laser ablation Glycine Separation efficiency Removal ratio

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Enhancing the Versatility and Performance of Soft Robotic Grippers, Hands, and Crawling Robots Through Three-Dimensional-Printed Multifunctional Buckling Joints

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Soft Robotics 2024年第5期11卷 741-754页

作者： Yang, Chih-Wen Ou Yu, Shao-Yi Chan, Che-Wei Tseng, Chien-Yao Cai, Jing-Fang Huang, Han-Pang Juang, Jia-Yang Department of Mechanical Engineering National Taiwan University Taipei Taiwan Department of Mechanical Engineering University of California at Berkeley BerkeleyCA United States Program in Nanoengineering and Nanoscience Graduate School of Advanced Technology National Taiwan University Taipei Taiwan

Soft robotic grippers and hands offer adaptability, lightweight construction, and enhanced safety in human–robot interactions. In this study, we introduce vacuum-actuated soft robotic finger joints to overcome their limitations in stiffness, response, and load-carrying capability. Our design—optimized through parametric design and three-dimensional (3D) printing—achieves high stiffness using vacuum pressure and a buckling mechanism for large bending angles (>90◦) and rapid response times (0.24 s). We develop a theoretical model and nonlinear finite-element simulations to validate the experimental results and provide valuable insights into the underlying mechanics and visualization of the deformation and stress field. We showcase versatile applications of the buckling joints: a three-finger gripper with a large lifting ratio (*96), a five-finger robotic hand capable of replicating human gestures and adeptly grasping objects of various characteristics in static and dynamic scenarios, and a planar-crawling robot carrying loads 30 times its weight at 0.89 body length per second (BL/s). In addition, a jellyfish-inspired robot crawls in circular pipes at 0.47 BL/s. By enhancing soft robotic grippers’ functionality and performance, our study expands their applications and paves the way for innovation through 3D-printed multifunctional buckling joints. © Mary Ann Liebert, Inc.

关键词： Grippers

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The revolution of type I organic photosensitizers:current strategies and future directions

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Science Bulletin 2025年第8期70卷 1203-1206页

作者： Mengyao Yang Luyan Zhou Yuan-Yuan Zhao Kunemadihalli Mathada Kotraiah Swamy Aibing Chen Juyoung Yoon College of Chemical and Pharmaceutical Engineering Hebei University of Science and TechnologyShijiazhuang 050018China Department of Chemistry and Nanoscience Ewha Womans UniversitySeoul03760Republic of Korea Graduate Program in Innovative Biomaterials Convergence Ewha Womans UniversitySeoul03760Korea

In contrast to traditional treatment methods,such as surgery,chemotherapy,and radiotherapy,photodynamic therapy(PDT)is a unique non-invasive modality with accurate temporal and spatial control,minimal side effects,and... 详细信息

关键词： pdt photodynamic therapy traditional treatment contrast radiotherapyphotodynamic therapy pdt type I organic photosensitizers cancer treatment revolution

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Advancements in nanocarbon-based catalysts for enhanced fuel cell performance: a comprehensive review

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International Journal of Energy and Water Resources 2025年第2期9卷 1005-1027页

作者： Agrawal, P. Ebrahim, S. Ponnamma, D. Materials Science and Technology Program Department of Mathematics Statistics and Physics College of Arts and Sciences Qatar University Doha 2713 Qatar Department of Nanoscience and Technology University of Calicut Kerala Calicut India Center for Advanced Materials Qatar University Doha 2713 Qatar

Fuel cells hold great promise as a clean energy technology, yet challenges such as material compatibility, manufacturing costs, and durability issues, particularly with noble metal-based electrocatalysts like platinum (Pt), hinder their widespread adoption. This review explores strategies to enhance fuel cell performance while minimizing costs, focusing on developing efficient and cost-effective catalysts supported by nanocarbon materials, such as carbon nanotubes, graphene, carbon films, and their composites. The investigation delves into how these catalysts supports improve activity and stability, leading to superior fuel cell performance characterized by higher current density and enhanced durability compared to conventional Pt/C catalysts, with a specific focus on proton-exchange membrane fuel cells. Key topics covered include the role of nanocarbon in fuel cells, various nanocarbon-based catalyst supports, Pt-containing alloys, non-Pt catalysts, and nanocarbon composites for electrolyte membranes and corrosion protection. Notable findings include the importance of heteroatom doping in enhancing reactivity, the effectiveness of organic–inorganic composite proton exchange membranes in improving proton conductivity, and the potential of amorphous carbon film coatings and conductive polymer-nanocarbon composites in enhancing corrosion resistance. These advancements underscore the potential of nanocarbon-based catalysts and coatings in ensuring the reliability and longevity of fuel cell components, thus contributing to the widespread commercialization of fuel cell technology. © The Author(s) 2024.

关键词： Carbon corrosion: Nanocarbon materials Catalyst support Current density Durability Electrocatalysts

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Selective activation of MoS2 grain boundaries for enhanced electrochemical activity

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Nanoscale Horizons 2024年第6期9卷 946-955页

作者： Raman, Radha Muthu, Jeyavelan Yen, Zhi-Long Qorbani, Mohammad Chen, Yu-Xiang Chen, Ding-Rui Hofmann, Mario Hsieh, Ya-Ping Department of Physics National Central University Taoyuan32001 Taiwan Institute of Atomic and Molecular Sciences Academia Sinica Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei10617 Taiwan Department of Physics National Taiwan University Taipei10617 Taiwan Nanoscience and Technology Program Taiwan International Graduate Program Academia Sinica Taipei115 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Center for Condensed Matter Sciences National Taiwan University Taipei10617 Taiwan Center of Atomic Initiative for New Materials National Taiwan University Taipei10617 Taiwan

Molybdenum disulfide (MoS2) has emerged as a promising material for catalysis and sustainable energy conversion. However, the inertness of its basal plane to electrochemical reactions poses challenges to the utilization of wafer-scale MoS2 in electrocatalysis. To overcome this limitation, we present a technique that enhances the catalytic activity of continuous MoS2 by preferentially activating its buried grain boundaries (GBs). Through mild UV irradiation, a significant enhancement in GB activity was observed that approaches the values for MoS2 edges, as confirmed by a site-selective photo-deposition technique and micro-electrochemical hydrogen evolution reaction (HER) measurements. Combined spectroscopic characterization and ab-initio simulation demonstrates substitutional oxygen functionalization at the grain boundaries to be the origin of this selective catalytic enhancement by an order of magnitude. Our approach not only improves the density of active sites in MoS2 catalytic processes but yields a new photocatalytic conversion process. By exploiting the difference in electronic structure between activated GBs and the basal plane, homo-compositional junctions were realized that improve the photocatalytic synthesis of hydrogen by 47% and achieve performances beyond the capabilities of other catalytic sites. © 2024 The Royal Society of Chemistry

关键词： Electronic structure

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One-step flow synthesis of size-controlled polymer nanogels in a fluorocarbon microfluidic chip

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RSC Advances 2024年第16期14卷 11258-11265页

作者： Montalbo, Reynaldo Carlos K. Wu, Meng-Jie Tu, Hsiung-Lin Institute of Chemistry Academia Sinica Taipei11529 Taiwan Nanoscience and Technology Taiwan International Graduate Program Academia Sinica Taipei11529 Taiwan Department of Engineering and System Science National Tsing-Hua University Hsinchu300044 Taiwan Department of Chemistry National Cheng-Kung University Tainan70101 Taiwan Genome and Systems Biology Degree Program Academia Sinica and National Taiwan University Taiwan

Synthetic polymer nanoparticles (NPs) with biomimetic properties are ideally suited for different biomedical applications such as drug delivery and direct therapy. However, bulk synthetic approaches can suffer from poor reproducibility and scalability when precise size control or multi-step procedures are required. Herein, we report an integrated microfluidic chip for the synthesis of polymer NPs. The chip could sequentially perform homopolymer synthesis and subsequent crosslinking into NPs without intermediate purification. This was made possible by fabrication of the chip with a fluorinated elastomer and incorporation of two microfluidic mixers. The first was a long channel with passive mixing features for the aqueous RAFT synthesis of stimuli-responsive polymers in ambient conditions. The polymers were then directly fed into a hydrodynamic flow focusing (HFF) junction that rapidly mixed them with a crosslinker solution to produce NPs. Compared to microfluidic systems made of PDMS or glass, our chip had better compatibility and facile fabrication. The polymers were synthesized with high monomer conversion and the NP size was found to be influenced by the flow rate ratio between the crosslinker solution and polymer solution. This allowed for the size to be predictably controlled by careful adjustment of the fluid flow rates. The size of the NPs and their stimuli-responses were studied using DLS and SEM imaging. This microfluidic chip design can potentially streamline and provide some automation for the bottom-up synthesis of polymer NPs while offering on-demand size control. © 2024 The Royal Society of Chemistry.

关键词： Microfluidic chips

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Double-antibody-based nano-biosensing systemfor the onsite monitoring of SARS-CoV-2 variants

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Microsystems & Nanoengineering 2023年第4期9卷 247-262页

作者： Heba A.Hussein Ahmed Kandeil Mokhtar Gomaa Rabeay Y.A.Hassan Virology Department Animal Health Research Institute(AHRI)Agricultural Research Center(ARC)Giza 12619Egypt Biosensors Research Laboratory Zewail City of Science and Technology6th October CityGiza 12578Egypt Center of Scientific Excellence for Influenza Viruses Environmental Research DivisionNational Research CentreGiza 12622Egypt Nanoscience Program University of Science and Technology(UST)Zewail City of Science and TechnologyGiza 12578Egypt

The fast and reliable diagnosis of COVID-19 is the foremost priority for promoting public health ***, double-antibody-based immunobiosensor chips were designed, constructed, and exploited for clinicaldiagnosis. Gold nanoparticles/tungsten oxide/carbon nanotubes (AuNPs/WO3/CNTs) were used as the active workingsensor surface to support the chemical immobilization of a mixture of SARS-CoV-2 antibodies (anti-RBD-S and anti-RBD-S-anti-Llama monoclonal antibodies). The morphology and chemical functionalization of the fabricateddisposable immunochips was characterized using scanning electron microscopy (SEM), Fourier transform infrared(FTIR) spectroscopy, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). After full assayoptimization, the immunobiosensor showed a high sensitivity to detect SARS-CoV-2-S protein with limits of detectionand quantification of 1.8 and 5.6 pg/mL, respectively. On the other hand, for the SARS-CoV-2 whole virus particleanalysis, the detection and quantification limits were determined to be 5.7 and 17 pg/mL, respectively. The biosensorshowed a highly selective response toward SARS-CoV-2, even in the presence of influenza, nontargeting humancoronaviruses, and Middle East respiratory syndrome coronavirus (MERS-CoV). The immunochips exhibited distinctresponses toward the variants of concern: B.1>C.36.3>Omicron> Delta> Alpha coronavirus variants. For biosensorvalidation, twenty-nine clinical specimens were analyzed, and the impedimetric responses were positively detected fortwo Delta samples, eighteen Omicron samples, and six B.1-type samples in addition to three negative ***, the immunobiosensor was fabricated in the form of ready-to-use chips capable of sensitive detection ofvirus variants, especially variants of concern (VOC) and interest, in a specimen within 15 min. The chips providedinstantaneous detection with the direct application of clinical samples and are considered a point-of-care

关键词： system limits optimization

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Folding angle and wing flexibility influence the flight performance of origami winged fruits

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Nonlinear Dynamics 2024年第13期112卷 10995-11011页

作者： Cai, Jing-Fang Hsu, Ya-Chun Yen, Yu-Chen Lee, Yun-Chung Peyton, Bernie Huang, Mei-Jiau Yu, Hon-Tsen Juang, Jia-Yang Department of Mechanical Engineering National Taiwan University Taipei106319 Taiwan Department of Life Science National Taiwan University Taipei106319 Taiwan Berkeley CA United States Program in Nanoengineering and Nanoscience Graduate School of Advanced Technology National Taiwan University Taipei106319 Taiwan Degree Program of Genome and Systems Biology National Taiwan University Taipei106319 Taiwan

Winged fruits possess a unique flight mechanism relying on simple geometric structures rather than neuromuscular control. This study proposes an innovative approach using origami techniques to create three-winged model fruits, serving as a proxy for understanding the flight dynamics of natural winged fruits. Paper is employed to simulate inherent wing flexibility, with the option to add plastic frames for rigidity. We comprehensively investigate the free fall motion of both rigid and flexible winged fruits through experimental and numerical analyses. Velocity–time curves reveal a three-stage descent pattern—acceleration, deceleration, and steady states. The overshoot phenomenon is attributed to rapid lift increase due to leading-edge vortices attaching stably to the wings. This insight sheds light on aerodynamics governing fruit flight. Compared with rigid wings, flexible wings exhibit two key properties—slower descent and higher self-orienting capability—that facilitate a more stable and longer-distance dispersal of seeds under crosswind conditions. Our study demonstrates the potential benefits of flexible wings in natural seed distribution. This study advances our understanding of winged fruit flight dynamics, utilizing origami as a powerful tool for biomimetic investigations. The findings have broad implications, from improving aerodynamic designs to developing efficient micro air vehicles and electronic microfliers, and understanding seed dispersal evolution. Graphical abstract: (Figure presented.). © The Author(s), under exclusive licence to Springer Nature B.V. 2024.

关键词： Fruits

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A double transition metal Ti_(2)NbC_(2)T_(x) MXene for enhanced lithium-ion storage

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Rare Metals 2023年第1期42卷 100-110页

作者： Wei Liu Jin Cao Feng Song Dong-Dong Zhang Manunya Okhawilai Jin Yi Jia-Qian Qin Xin-Yu Zhang State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao066004China International Graduate Program of Nanoscience&Technology Chulalongkorn UniversityBangkok10330Thailand Metallurgy and Materials Science Research Institute Chulalongkorn UniversityBangkok10330Thailand Center of Excellence in Responsive Wearable Materials Chulalongkorn UniversityBangkok10330Thailand Institute for Sustainable Energy College of SciencesShanghai UniversityShanghai200444China

MXene,an emerging two-dimensional(2D)layered material,has received worldwide attention in various energy storage systems because of its excellent ***,the low capacity of pristine MXene restricts its application in energy storage devices especially for the lithium-ion batteries(LIBs).To address the above issue,herein,a stable and highly conductive double transition metal MXene(Ti_(2)NbC_(2)T_(x)) is successfully fabricated,which provides enlarged interlayer spacing and excellent conductivity for fast ion diffusion and charge *** the Ti_(2)NbC_(2)T_(x)s anode for LIBs,a superior specific capacity of 196.2 mAh·g-1and an excellent long-term cycling stability of~100%after 400cycles under 0.1 A·g^(-1) are achieved for *** particular,Ti_(2)NbC_(2)T_(x) delivers an impressive capacity retention of 81%over 4000 cycle under 1 A·g^(-1),outperforming the Ti_(3)C_(2)T_(x) and various previously reported MXene-based *** results offer an attractive strategy for the future application of MXene-based materials.

关键词： Double transition metal MXene Ti_(2)NbC_(2)T_(x) Ti_(3)C_(2)T_(x) Lithium-ion batteries(LIBs) Anode

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Impact of High-k Materials and Tube Numbers on CNFET Gate's Performances 5

Impact of High-k Materials and Tube Numbers on CNFET Gate's ...

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5th International Conference on Smart Systems and Inventive technology, ICSSIT 2023

作者： Yalung, Christofer Tantraviwat, Doldet Uatrongjit, Sermsak Yamwong, Wittawat Doctor of Philosophy Program in Nanoscience and Nanotechnology International Program/Interdisciplinary Center of Excellence in Materials Science and Technology Faculty of Science Chiang Mai University Chiang Mai Thailand Chiang Mai University Faculty of Engineering Department of Electrical Engineering Chiang Mai Thailand Chachoengsao Thailand

ISBN: (纸本)9781665474672

Carbon nanotube field effect transistor (CNFET) performance is primarily influenced by a variety of characteristics, such as nanotube diameter, operating voltage, pitch, the number of tubes, dielectric constant, and contact materials. In this study, the dielectric constant and the number of carbon nanotubes (CNTs) were emphasized to analyze the propagation delay and average power dissipation of basic logic gates. Zirconium dioxide (ZrO2), hafnium oxide (HfO2), and silicon dioxide (SiO2) were used as dielectric materials. In this experiment, the Stanford CNFET model was utilized, and variable factors such as the number of CNTs and the dielectric constant (Kox) accumulated on the nanotube gate's surface were diversified. The correlation coefficients of the delay, the average power, and the CNT numbers were also presented. Furthermore, the multi-objective genetic algorithm and the Rmethod were utilized to find the optimal Kox and the number of CNTs for minimizing the average dissipation power and the propagation delay of some logic gates designed with CNFET. For all the gates considered, the optimal number of CNTs is 4 while the dielectric constant is within the ranges of 19 to 24. © 2023 IEEE.

关键词： Carbon nanotubes

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