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Alkali-Aggregate Reaction and its Mineral Reactive Phases Contribution to the Microstructural Consolidation of Portland Cement and Geopolymeric Mortars with Metakaolin-Based Precursors

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SSRN 2023年

作者： Valenga, Matheus Villian de Lima, Rubia Catarina Przybysz Pereira, Elias Pereira, Eduardo Farias, Marcelo Miranda Pianaro, Sidnei Antonio State University of Ponta Grossa Postgraduate Program in Engineering and Materials Science Carlos Cavalcanti Avenue 4748 Uvaranas Paraná Ponta GrossaCEP: 84030-900 Brazil

HIGHLIGHTS Metakaolin-based geopolymeric mortars are not negatively affected by *** aggregates contribute to geopolymer matrix consolidation and *** cement partial replacement by metakaolin reduces AAR effects in *** ... 详细信息

关键词： Mortar

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Development and Application of a Genetic Algorithm for Selecting High Entropy Alloys with Good Combinations of Mechanical Properties

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SSRN 2024年

作者： Stoco, Caroline Binde Cassar, Daniel Roberto Kaufman, Michael Clarke, Amy Coury, Francisco Gil Federal University of São Carlos Graduate Program in Materials Science and Engineering SP São Carlos Brazil SP Campinas Brazil Center for Advanced Non-Ferrous Structural Alloys George S. Ansell Department of Metallurgical and Materials Engineering Colorado School of Mines GoldenCO United States

A genetic algorithm was developed to search for high entropy alloys (HEAs) with good combinations of mechanical properties. The algorithm was designed to solve a multi-objective problem of finding single-phase face-centered cubic HEAs with high Hall-Petch constants and high critical resolved shear stresses. The goal was to obtain an alloy with good ductility and strength. The most promising alloy suggested by the genetic algorithm was an unconventional composition (Co32.73Cu15.11Fe0.72Hf0.72Mn35.97Mo3.96Ni10.43Sn0.36);this alloy was experimentally produced and characterized. An advantage of the proposed method is the possibility of more systematically identifying and exploring new compositions in the complex composition space characteristic of these multicomponent alloys. However, the thermodynamic parameters used for this selection process exhibited limitations, which were further explored in the present study, as evidenced by the fact that the microstructure of the selected alloy was not single-phase. © 2024, The Authors. All rights reserved.

关键词： Phase equilibria

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Waste-to-Resource: Employing Lime Mud as a Foaming Agent in Glass Foam Manufacturing

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SSRN 2024年

作者： Boonphayak, Piyanan Khansumled, Sirikarn Thavornyutikarn, Boonlom Yatongchai, Chokchai Department of Industrial Engineering Faculty of Engineering Naresuan University Phitsanulok65000 Thailand National Metal and Materials Technology Center National Science and Technology Development Agency Pathumthani12120 Thailand Program of Materials Innovation Faculty of Science Maejo University Chiang Mai50290 Thailand Composite Materials and 3D Prototyping Research Unit The Office of Agricultural Research Extension Maejo University Maejo University Chiang Mai50290 Thailand

This study investigates the use of lime mud as an eco-friendly foaming additive in the production of glass foam. Glass foams were prepared through a simple sintering method, utilizing glass cullet collected from households and incorporating different lime mud contents (0.5-2.0wt%). The effects of lime mud concentration on the density, porosity, and pore size distribution of the glass foams were examined. Additionally, the thermal conductivity, compressive strength, and Weibull modulus were investigated in relation to the average porosity. The results revealed that the pore size distribution was dependent on the amount of lime mud, exhibiting three distinct distributions: positively skewed, non-symmetric bimodal, and symmetric bimodal. The compressive strength of the prepared glass foams ranged from 5.53 to 12.73 MPa, while the bulk density and porosity fell within the ranges of 0.41-0.70 and 72.12-85.38%, respectively. The thermal conductivity could be as low as 0.07 W/m⋅K, approaching the upper limit for commercial glass foams used in thermal energy storage systems and meeting the requirements for Type I cellular glass thermal insulation classified by ASTM C552-16. © 2024, The Authors. All rights reserved.

关键词： Thermal insulation

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Biomimetic natural biomaterials for tissue engineering and regenerative medicine:new biosynthesis methods,recent advances,and emerging applications

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Military Medical Research 2024年第1期11卷 50-79页

作者： Shuai Liu Jiang-Ming Yu Yan-Chang Gan Xiao-Zhong Qiu Zhe-Chen Gao Huan Wang Shi-Xuan Chen Yuan Xiong Guo-Hui Liu Si-En Lin Alec McCarthy Johnson V.John Dai-Xu Wei Hong-Hao Hou Guangdong Provincial Key Laboratory of Construction and Detection in Tissue Engineering the Fifth Affiliated HospitalSchool of Basic Medical ScienceSouthern Medical UniversityGuangzhou 510900China Department of Orthopedics Tongren HospitalShanghai Jiao Tong UniversityShanghai 200336China The Eighth Affiliated Hospital Sun Yat-Sen UniversityShenzhen 518033GuangdongChina Engineering Research Center of Clinical Functional Materials and Diagnosis&Treatment Devices of Zhejiang Province Wenzhou InstituteUniversity of Chinese Academy of SciencesWenzhou 325011ZhejiangChina Department of Orthopedics Union HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430022China Department of Orthopaedics and Traumatology Faculty of Medicinethe Chinese University of Hong KongHong Kong SAR 999077China Department of Functional Materials Terasaki Institute for Biomedical InnovationLos AngelesCA 90064USA Mary&Dick Holland Regenerative Medicine Program College of MedicineUniversity of Nebraska Medical CenterOmahaNE 68130USA Zigong Affiliated Hospital of Southwest Medical University Zigong Psychiatric Research CenterZigong Institute of Brain ScienceZigong 643002SichuanChina Key Laboratory of Resource Biology and Biotechnology in Western China Ministry of EducationSchool of MedicineDepartment of Life Sciences and MedicineNorthwest UniversityXi’an 710127China

Biomimetic materials have emerged as attractive and competitive alternatives for tissue engineering(TE)and regenerative *** contrast to conventional biomaterials or synthetic materials,biomimetic scaffolds based on natural biomaterial can offer cells a broad spectrum of biochemical and biophysical cues that mimic the in vivo extracellular matrix(ECM).Additionally,such materials have mechanical adaptability,micro-structure interconnectivity,and inherent bioactivity,making them ideal for the design of living implants for specific applications in TE and regenerative *** paper provides an overview for recent progress of biomimetic natural biomaterials(BNBMs),including advances in their preparation,functionality,potential applications and future *** highlight recent advances in the fabrication of BNBMs and outline general strategies for functionalizing and tailoring the BNBMs with various biological and physicochemical characteristics of native ***,we offer an overview of recent key advances in the functionalization and applications of versatile BNBMs for TE ***,we conclude by offering our perspective on open challenges and future developments in this rapidly-evolving field.

关键词： Biomimic Scaffold Biosynthesis Natural biomaterial Tissue engineering

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Gender Mainstreaming in Drought Disaster Risk Reduction 2

Gender Mainstreaming in Drought Disaster Risk Reduction

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2nd International Conference on sciences and Technology Applications, ICOSTA 2020

作者： Retno Susilorini, Rr M. I. Lika, Rusnianti Rambu Sriyana Angghita, Lintang Jata Sinaga, Julio Ignatius Department of Infrastructure and Environmental Engineering Faculty of Environmental Science and Technology Soegijapranata Catholic University Semarang Indonesia Master Program of Environmental and Urban Studies Faculty of Environmental Science and Technology Soegijapranata Catholic University Semarang Indonesia Department of Civil Engineering Faculty of Engineering Diponegoro University Semarang Indonesia

Climate change has affected the whole world and caused disasters, include drought. Since Tana Mbanas village in Central Sumba District is the driest remote area in eastern region of Indonesia, gender inequality has affected in daily life of people in the village instead of other social and environmental problems. This research aimed to evaluate how gender mainstreaming implemented in drought disaster risk reduction in Tana Mbanas village in Central Sumba Regency, East Nusa Tenggara Province. The result of the research is expected to become a mirror that reflects Sumba island gender and development issues. The research took place in Tana Mbanas village in Central Sumba Regency, East Nusa Tenggara Province, and conducted by qualitative method with purposive data sampling. The steps taken in the research were observation, data collecting by questionnaire and in-depth interview to respondents, and literature review. It was reported that Tana Mbanas village people has given water management assistance by village fund, conducting water management counselling, saving water, and harvesting rain systems in every household. This research meets conclusions that: (1) Several programs and planned actions in water supply system and infrastructure development have become initiatives of government agencies of village authorities, BPBD and Public Work Agency of Central Sumba Regency;(2) People demonstrated vulnerability to drought as well as lack of water supply and also water resources;(3) Strong efforts should be conducted to educate people and increase women capacity in coping issues of poverty, drought, and lack of water supply;and (4) Government agencies and other private institutions have to build women capacity as their participation in enhancing gender equality and mainstreaming gender. © Published under licence by IOP Publishing Ltd.

关键词： Water management

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Tailoring Chloride Solid Electrolytes for Reversible Redox

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Journal of the American Chemical Society 2025年第23期147卷 2025 May 28页

作者： Phillip Ridley George Duong Sarah L Ko Jin An Sam Oh Grayson Deysher Kent J Griffith Ying Shirley Meng Department of Nano Engineering University of California San Diego La Jolla California 92093 United States. Department of Chemistry and Biochemistry University of California San Diego California 92093 United States. Program of Materials Science and Engineering University of California San Diego La Jolla California 92093 United States. Pritzker School of Molecular Engineering The University of Chicago Chicago Illinois 60637 United States.

Solid-state electrolytes enable next-generation batteries that can theoretically deliver higher energy densities while improving device safety. However, when fabricating cathodes for all-solid-state batteries, solid-state electrolytes must be combined with the active materials in high weight fractions in order to achieve sufficient ionic percolation within the cathode composite. This requirement drastically hinders the practicality of solid-state batteries as the solid-state electrolyte is conventionally designed to be electrochemically inactive and is effectively electrochemical "dead weight", lowering both the gravimetric and volumetric energy density of the cell. In this work, a well-known solid-state electrolyte, NaZrCl, is modified by aliovalent substitution of inactive Zr cations with redox-active ( = Nb or Ta) cations to create a series of NaZrCl solid solutions that possess both high ionic conductivities and active sites for Na storage. The Na intercalation mechanisms of these solid-solution materials, in addition to those of the NaCl end-member materials, are elucidated in this work. It was discovered that both the niobium- and tantalum-containing chlorides exhibit rather high electrochemical potentials (2.2-2.8 V vs NaSn), making them ideal catholytes to pair with commonly used oxide cathode materials like NaCrO. This synergistic pairing leads to a cathode composite with an 83-102% increase in energy density and 39-81% improvement in areal discharge capacity compared to a redox-innocent solid electrolyte. This approach highlights the benefits of designing and employing redox-active solid-state electrolytes that can reversibly intercalate charge-carrying cations, opening up a broad new avenue for solid-state electrolyte discovery and solid-state battery design.

关键词： Redox reactions

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Low-Loss, Nonvolatile Tuning of Bragg Structures with Sb2Se3

Low-Loss, Nonvolatile Tuning of Bragg Structures with Sb2Se3

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Conference on Lasers and Electro-Optics (CLEO)

作者： Nicholas A. Nobile Chuanyu Lian Hongyi Sun Yi-Siou Huang Brian Mills Cosmin Constantin Popescu Dennis Callahan Juejun Hu Carlos A. Ríos Ocampo Nathan Youngblood Electrical & Computer Engineering Department University of Pittsburgh Pittsburgh PA USA Department of Materials Science & Engineering University of Maryland College Park MD USA Institute for Research in Electronics and Applied Physics University of Maryland College Park MD USA Department of Materials Science & Engineering Massachusetts Institute of Technology Cambridge MA USA Draper Scholar Program The Charles Stark Draper Laboratory Inc Cambridge MA USA The Charles Stark Draper Laboratory Inc Cambridge MA USA

Sb 2 Se 3 is used to switch between broadband transparency and enhanced index contrast in two device types leveraging Bragg gratings for tunable stop-and pass-band functionalities. Experimental results highlight fabr... 详细信息

ISBN: (纸本)9798350369311

关键词： Bragg gratings Waveguide transitions Phase change materials Optical filters Optical switches Refractive index Fabry-Perot Indexes Passband Optical waveguides

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High-value utilization of CO_(2) to synthesize sulfur-doped carbon nanofibers with excellent capacitive performance

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International Journal of Minerals,Metallurgy and materials 2020年第12期27卷 1666-1677页

作者： Meng-jun Hu Ming-zhu Yin Li-wen Hu Peng-jie Liu Shuo Wang Jian-bang Ge College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and Advanced Materials Chongqing UniversityChongqing 400044China Nuclear Engineering Program Department of Mechanical EngineeringVirginia Polytechnic Institute and State UniversityBlacksburgVirginia 24061USA

Carbon nanofiber(CNF)is considered a promising material due to its excellent physical and chemical *** paper proposes a novel way to transform CO_(2) into heteroatom-doped CNFs,with the introduction of Fe,Co,and Ni as *** the electrolyte containing Ni O,Co2O3,and Fe_(2)O_(3) was employed,sulfur-doped CNFs in various diameters were *** the introduction of Fe catalyst,the obtained sulfur-doped CNFs showed the smallest and tightest diameter *** obtained sulfur-doped CNFs had high gravimetric capacitance(achieved by SDG-Fe)that could reach 348.5 F/g at 0.5 A/g,excellent cycling stability,and good rate *** comparison purposes,both Fe and nickel cathodes were tested,where the active metal atom at their surface could act as *** these two situations,sulfur-doped graphite sheet and sulfur-doped graphite quasi-sphere were the main products.

关键词： carbon dioxide capture electrochemical conversion carbon fiber molten salt

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Recent Advancements in Nanophotonics for Optofluidics

arXiv

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arXiv 2024年

作者： Yang, Sen Hong, Chuchuan Zhu, Guodong Anyika, Theodore Hong, Ikjun Ndukaife, Justus C. Institute of Physics Chinese Academy of Sciences Beijing National Laboratory for Condensed Matter Physics Beijing100190 China Department of Chemistry Department of Materials Science and Engineering Northwestern University EvanstonIL60208 United States Department of Electrical and Computer Engineering Vanderbilt University NashvilleTN37235 United States Department of Mechanical Engineering Vanderbilt University NashvilleTN37235 United States Interdisciplinary Materials Science Program Vanderbilt University NashvilleTN37240 United States

Optofluidics is dedicated to achieving integrated control of particle and fluid motion, particularly on the micrometer scale, by utilizing light to direct fluid flow and particle motion. The field has seen significant growth recently, driven by the concerted efforts of researchers across various scientific disciplines, notably for its successful applications in biomedical science. In this review, we explore a range of optofluidic architectures developed over the past decade, with a primary focus on mechanisms for precise control of micro and nanoscale biological objects and their applications in sensing. Regarding nanoparticle manipulation, we delve into mechanisms based on optical nanotweezers using nanolocalized light fields and light-based hybrid effects with dramatically improved performance and capabilities. In the context of sensing, we emphasize those works that used optofluidics to aggregate molecules or particles to promote sensing and detection. Additionally, we highlight emerging research directions, encompassing both fundamental principles and practical applications in the field. Copyright © 2024, The Authors. All rights reserved.

关键词： Flow of fluids

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DEVELOPMENT OF GREENER AND MORE EFFECTIVE HIGH-TEMPERATURE THERMAL INSULATORS 17

DEVELOPMENT OF GREENER AND MORE EFFECTIVE HIGH-TEMPERATURE T...

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17th Unified International Technical Conference on Refractories, UNITECR 2022

作者： Borges, O.H. dos Santos, T. Salvini, V.R. Pandolfelli, V.C. Federal University of Sao Carlos Graduate Program in Materials Science and Engineering SP Sao Carlos Brazil FIRE Associate Laboratory SP Sao Carlos Brazil Jordão Borghetti Street 480 SP Sertãozinho14160-050 Brazil

Aiming at reducing the remarkable shrinkage observed when porous ceramics are fired, the in-situ formation of hibonite (also known as CaO·6Al2O3 or CA6) was evaluated in a direct-foamed alumina-based macroporous thermal insulator with the addition of distinct calcium sources and contents. Among the tested compositions, that containing 12.9 wt% of CaCO3 showed promising results as high porosity (~ 80 %), no shrinkage after firing at 1600 ºC for 5 h, suitable mechanical strength, and a 200 ºC-lower strengthening temperature. However, the in-situ formation of CA6 took place just at high temperatures (~ 1600 ºC), implying a high energy consumption. To address this issue, SiO2, ZnO, and TiO2 were evaluated as mineralizing agents. The addition of 2.8 mol% of TiO2 induced CA6 formation at 1300ºC and low thermal conductivity (0.54 Wm-1K-1 at 1200 ºC), without significant changes in the refractoriness. © 2022 Unified International Technical Conference on Refractories, UNITECR 2022 - Proceedings. All rights reserved.

关键词： Titanium dioxide

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