检索结果-内蒙古大学图书馆

Enhanced bacterial and virus disinfection with copper nanoparticle optimized LIG composite electrodes and filters

Journal of Environmental sciences 2025年第6期152卷 623-636页

作者： Nandini Dixit Akhila M.Nair Swatantra P.Singh Environmental Science and Engineering Department Indian Institute of Technology BombayMumbai-400076India Center for Research in Nanotechnology and Science(CRNTS) Indian Institute of Technology BombayMumbai-400076India Interdiscliniplary Program in Climate Studies Indian Institute of Technology BombayMumbai-400076India Center of Excellence on Membrane Technologies for Desalination Brine Management and Water Recycling(DESALTM)Indian Institute of Technology BombayMumbai-400076India

Waterborne pathogens pose a lifelong threat, necessitating advanced disinfection systemswith state-of-the-art materials. Laser-Induced Graphene (LIG), a 3-dimensional form ofgraphene, is a widely known electrode material for its electrically-induced antimicrobialproperties. However, LIG surfaces exhibit antimicrobial properties exclusively in the presenceof electricity. In this work, copper-doped LIG (Cu-LIG) composite electrodes and filterswere developed with enhanced antimicrobial properties in single-step laser scribing. Thework emphasizes the optimization of copper doping with LIG for both electrical and nonelectrical-based disinfection. The copper doping was optimized to a minimal concentration(∼1%) just to enhance the electrochemical properties of LIG. Furthermore, the excess additionof copper was helpful towards non-electricity-based treatment without significantleaching. The prepared surfaces were tested in both electrodes and filter configuration andshowed excellent antibacterial and antiviral activity against mixed bacterial culture and amodel enteric virus, MS2 bacteriophage. On the application of 2.5 V with Cu-LIG electrodes,6-log removal of bacteria and virus was achieved. Furthermore, the membrane-based electroconductivefilters were tested in a flow-through configuration and demonstrated 6-logremoval at 2.5 V with a flux of ∼ 500 (L·m^(2))/h with both bacteria and viruses at minimumenergy expense. Additionally, reactive oxygen species scavenging and hydrogen peroxidegeneration experiments have confirmed the role of electrical effects and indirect oxidationon the inactivation mechanism. The prepared Cu-LIG composite surfaces showed potentialfor environmental remediation applications.

关键词： Electrochemical Disinfection Copper-doped LIG Electroconductive filtration Copper nanoparticle optimization Enhanced electrocatalytic activity

来源：评论

学校读者我要写书评

暂无评论

Low-density diamondlike amorphous carbon at nanostructured metal-diamond interfaces

引用

Physical Review materials 2024年第9期8卷 096001页

作者： Brendan McBennett Yuka Esashi Nicholas W. Jenkins Albert Beardo Yunzhe Shao Emma E. Nelson Theodore H. Culman Begoña Abad Michael Tanksalvala Travis D. Frazer Samuel Marks Weilun Chao Sadegh Yazdi Joshua L. Knobloch Henry C. Kapteyn Margaret M. Murnane Department of Physics Materials Science and Engineering Center for X-Ray Optics Renewable and Sustainable Energy Institute and the Materials Science & Engineering Program 4775 Walnut Street #102 Boulder Colorado 80309 USA

Next-generation nanoelectronic, energy, and quantum technologies require increasingly stringent thermal, optical, mechanical, and electrical properties of component materials, often surpassing the limits of widely used materials such as silicon. Diamond, an ultrawide bandgap semiconductor, is a promising material for these applications because of its very high stiffness, thermal conductivity, and electron mobility. However, incorporating diamond into devices that require high-quality metal-diamond interfaces is challenging. In this work, we use a suite of electron microscopy measurements to reveal an ultrathin amorphous carbon layer that emerges at metal-diamond interfaces after electron beam lithography. Using extreme ultraviolet scatterometry, we nondestructively determine lower bounds on the layer's Young's modulus and thermal conductivity, which at >230GPa and >1.1 W/(mK) are indicative of a diamondlike form of amorphous carbon with high sp3 bonding. However, extreme ultraviolet coherent diffractive imaging reflectometry and energy-dispersive x-ray spectroscopy measurements indicate a low and likely inhomogeneous density in the range of 1–2g/cm3. The low density of such a stiff and conductive layer could indicate that it contains nanometer-scale voids or atomic-scale vacancies. The appearance of this unusual layer illustrates the nanofabrication challenges for diamond and highlights the need for better techniques to characterize surfaces and interfaces in nanoscale devices.

关键词： Amorphous materials Diamond Interfaces Thin films Electron energy loss spectroscopy Energy-dispersive x-ray spectroscopy High-harmonic generation Ultrafast femtosecond pump probe X-ray reflectivity

来源：评论

学校读者我要写书评

暂无评论

Evaluation of temperature dependent vortex pinning properties in strongly pinned YBa_(2)Cu_(3)O_(7-δ)thin films with Y_(2)BaCuO_(5)nanoinclusions

引用

Superconductivity 2024年第1期9卷 95-105页

作者： Alok K.Jha Kaname Matsumoto Tomoya Horide Shrikant Saini Ataru Ichinose Paolo Mele Yutaka Yoshida Satoshi Awaji Department of Materials Science and Engineering Kyushu Institute of TechnologyTobata-kuKitakyushu 804-8550Japan Department of Mechanical and Control Engineering Kyushu Institute of TechnologyTobata-kuKitakyushu 804-8550Japan Central Research Institute of Electrical Power Industry YokosukaKanagawa 240-0196Japan College of Engineering-Innovative Global Program Shibaura Institute of TechnologyMinuma-kuSaitama 337-8570Japan Department of Energy Engineering and Science Nagoya UniversityChikusa-kuNagoya 464-8603Japan Institute for Materials Research Tohoku UniversityAoba-kuSendai 980-8577Japan

The pinning of quantized magnetic vortices in superconducting YBa_(2)Cu_(3)O_(7-δ)(YBCO or Y123)thin films with Y_(2)BaCuO_(5)(Y211)nanoinclusions have been investigated over wide temperature range(4.2-77 K).The concentration of Y211 nanoinclusions has been systematically varied inside YBCO thin films prepared by laser ablation technique using surface modified target *** pinning force density values(Fp∼0.5 TNm^(−3)at 4.2 K,9 T)have been observed for the YBCO film with moderate concentration of Y211 nanoinclusions(3.6 area%on ablation target).In addition,uniform enhancement in critical current density(J_(c))was observed in the angular dependent J_(c)measurement of YBCO+Y211 nanocomposite films.Y211 nanoinclusions have been found to be very efficient in pinning the quantized vortices thereby enhancing the in‐field J_(c)values over a wide range of *** the concentration of Y211 secondary phase into Y123 film matrix results into agglomeration of Y211 phase and observed as increased Y211 nanoparticle *** larger secondary phase nanoparticles are not as efficient pinning centers at lower temperatures as they are at higher temperatures due to substantial reduction of the coherence length at lower *** of the temperature dependence of J_(c)for YBCO+Y211 nanocomposite films has been conducted and possible vortex pinning mechanism in these nanocomposite films has been discussed.

关键词： YBCO thin film Critical current Vortex pinning Nanoscale APCs

来源：评论

学校读者我要写书评

暂无评论

Utilizing a blend of expandable graphite and calcium/zinc stearate as a heat stabilizer environmentally friendly for polyvinyl chloride

SPE Polymers

引用

SPE Polymers 2024年第1期5卷 45-57页

作者： Morsy, Ashraf Anwar, Abbas Anwar, Hossam Abdel-Hamid, H. Soliman, Aya Materials Science Department Institute of Graduate Studies and Research Alexandria University Alexandria Egypt Petrochemicals Department Faculty of Engineering Pharos University Alexandria Ezbet El-Nozha Egypt Department of Chemistry Faculty of Science Alexandria University Alexandria Egypt

Polyvinyl chloride (PVC) is one of the most important commercial plastics but it is thermally unstable at processing temperatures. Therefore, heat stabilizers are widely used to safeguard by improving resistance of PVC products at high temperature. But most of them are a highly toxic that can cause severe health issues in humans and harmful to the environment. In the present study mixed of calcium/zinc stearate heat stabilizer and green Expandable graphite (EG) is prepared via hydrothermal treatment using additives of nontoxic, environmental protection. The characteristics of the thermal stability of poly vinyl chloride can be investigated by Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) will be used to examine structure of the heat stabilizers, A universal testing equipment will be used to determine the mechanical properties and thermal gravimetric analysis (TGA). From TGA results the weight loss was 43.49% at 342°C for sample with Ca/Zn- stearate, while wt loss is 55.87% at 260°C for sample with EG which increase thermal stability. Differential scanning calorimetry affirmed the enhancement of PVC's thermal stability, showing a shift in the glass transition temperature an increase of 67°C. Mechanical tests indicated that samples with EG exhibited higher tensile strength and elongation at break, emphasizing the positive impact on PVC's mechanical properties. The burning test highlighted thermal stability of EG-containing samples, retaining color and structure even after exposure to 180°C heat. This innovative approach not only enhances thermal stability but also aligns with eco-friendly principles, making it a promising solution for improving PVC properties. Highlights: Ca/Zn- stearate, expandable graphite developed by a safe hydrothermal process. Comprehensive analysis indicates improved thermal stability. Safe stabilization of eco-friendly calcium/zinc, expandable graphite. Effective solution: Eco-friendly, improved PVC prop

关键词： environmentally friendly expandable graphite green chemistry heat stabilizer polyvinyl chloride

来源：评论

学校读者我要写书评

暂无评论

Effect of electrolyte anions on the cycle life of a polymer electrode in aqueous batteries

引用

escience 2022年第1期2卷 110-115页

作者： Ye Zhang Lihong Zhao Yanliang Liang Xiaojun Wang Yan Yao Department of Electrical and Computer Engineering Materials Science and Engineering ProgramUniversity of HoustonHoustonTX77204USA Texas Center for Superconductivity at the University of Houston HoustonTX77204USA

Redox polymers are a class of high-capacity, low-cost electrode materials for electrochemical energy storage, butthe mechanisms governing their cycling stability are not well understood. Here we investigate the effect of anionson the longevity of a p-dopable polymer through comparing two aqueous zinc-based electrolytes. Galvanostaticcycling studies reveal the polymer has better capacity retention in the presence of triflate anions than that withsulfate anions. Based on electrode microstructural analysis and evolution profiles of the cell stacking pressure, theorigin of capacity decay is ascribed to mechanical fractures induced by volume change of the polymer activematerials during repeated cycling. The volume change of the polymer with the triflate anion is 61% less than thatwith the sulfate anion, resulting in fewer cracks in the electrodes. The difference is related to the different anionsolvation structures—the triflate anion has fewer solvated water molecules compared with the sulfate anion,leading to smaller volume expansion. This work highlights that anions with low solvation degree are preferablefor long-term cycling.

关键词： Aqueous batteries Polymer electrode Anions Volume chang

来源：评论

学校读者我要写书评

暂无评论

Ambiently fostering solid electrolyte interphase for low-temperature lithium metal batteries

引用

Journal of Energy Chemistry 2023年第12期87卷 473-478,I0012页

作者： Jia-Yue Duan Jin-Xiu Chen Fang-Fang Wang Jin-Hao Zhang Xiao-Zhong Fan Liping Wang Yingze Song Wei Xia Yusheng Zhao Long Kong Frontiers Science Center for Flexible Electronics and Xi’an Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710129ShaanxiChina Department of Physics Academy for Advanced Interdisciplinary StudiesSouthern University of Science and TechnologyShenzhen 518055GuangdongChina State Key Laboratory of Environment-Friendly Energy Materials School of Materials Science and EngineeringGraphene Joint Innovation CentreSouthwest University of Science and TechnologyMianyang 621010SichuanChina Eastern Institute for Advanced Study Eastern Institute of TechnologyNingbo 315201ZhejiangChina

Despite being a leading candidate to meet stringent energy targets,lithium(Li) metal batteries(LMBs)face severe challenges at low temperatures such as dramatic increase in impedance,capacity loss and dendrite *** fingerprinting rate-limited factors of low-temperature LMBs would encourage targeted approaches to promote ***,the charge transfer impedance across solid electrolyte interphase(SEI) is identified to restrict battery operation under low temperature,and we propose a facile approach on the basis of ambiently fostering SEI(af-SEI) to facilitate charge *** concept of af-SEI stems from kinetic benefits and structural merits to construct SEI at ambient temperature over low temperature developed SEI that is temporally consuming to achieve steady state and that is structurally defective to incur dendrite *** af-SEI allows ionically conductive and morphologically uniform layer on the anode surface,which exhibits a lower resistance and induces an even deposition of Li in the subsequent low temperature battery *** with af-SEI,the LMBs deliver the improved rate performance and prolonged cycle life when subjected to low temperature *** work unveils the underlying causes that limit low temperature LMB performances,and enlightens the facile test protocols to build up favorable SEI,beyond scope of material and morphology design.

关键词： Li matel batteries Ambiently fostering SEI Charge transfer impedance Low temperature kinetics

来源：评论

学校读者我要写书评

暂无评论

Freestanding carbon fiber-confined yolk-shelled silicon-based anode for promoted lithium storage applications

引用

Rare Metals 2023年第11期42卷 3718-3728页

作者： Dong-Chen Jia Yuan-Yong Feng Chuan-Long Zhang Jian-Jiang Li Bin-Wei Zhang Yu-Hai Dou Jagadish Chandra Roy Xiao-Yi Zhu Lei Zhang School of Environmental Science and Engineering Qingdao UniversityQingdao266071China Department of Oral and Maxillofacial Surgery The Affiliated Hospital of Qingdao UniversityQingdao266071China Centre for Catalysis and Clean Energy Gold Coast CampusGriffith UniversitySouthportQLD4222Australia Center of Advanced Energy Technology and Electrochemistry Institute of Advanced Interdisciplinary StudiesSchool of Chemistry and Chemical EngineeringChongqing UniversityChongqing400044China Institute of Energy Materials Science University of Shanghai for Science and TechnologyShanghai200093China

A flexible carbon fiber-confined yolk-shelled silicon-based composite is reported as an anode material for lithium storage *** nanoparticles(Si NPs)are confined by the N-doped hollow carbon cages(SiNHC)and these uniform dispersed yolk-shell-structured Si-NHC units were encapsulated by the carbon fibers within an interconnected three-dimensional(3D)framework(Si-NHC@CNFs).For the encapsulated yolkshelled Si-NHC,the void space between the inner Si NPs and outer NHC can accommodate the structural changes of Si NPs during charging/discharging processes,leading to effectively improved structural stability and cycling *** importantly,all the Si-NHC units were bridged together through a conductive CNFs"highway"to enhance the overall conductivity and tap density *** observed,Si-NHC@CNFs exhibited an initial discharge capacity of 1364.1 mAh·g^(-1)at 1000 mA·g^(-1)and678.9 mAh·g^(-1)at 2000 mA·g^(-1).Furthermore,the reversible capacity was well maintained at 752.2 mAh·g^(-1)at500 mA·g^(-1)after 6000 ultra-long cycles.

关键词： Silicon ZIF-8 Carbon fibers Anode Lithium-ion battery(LIB)

来源：评论

学校读者我要写书评

暂无评论

Smart Soft materials with Multiscale Architecture and Dynamic Surface Topographies

引用

Accounts of materials Research 2022年第11期3卷 1115-1126页

作者： Songshan Zeng Andrew T.Smith Kuangyu Shen Luyi Sun Polymer Program Institute of Materials Science and Department of Chemical&Biomolecular EngineeringUniversity of ConnecticutStorrsConnecticut 06269United StatesPresent Address:Macao Institute of Materials Science and Engineering(MIMSE)Zhuhai MUST Science and Technology Research InstituteFaculty of Innovation EngineeringMacao University of Science and TechnologyTaipa999078MacaoChina Polymer Program Institute of Materials Science and Department of Chemical&Biomolecular EngineeringUniversity of ConnecticutStorrsConnecticut 06269United States

CONSPECTUS:Smart soft materials have one or more characteristics that can be significantly altered in convertible fashions by external stimuli,such as light,moisture,mechanical force,temperature,electric/magnetic fields,pH,and so *** materials can lead to widespread application in multifunctional smart ***,various smart soft materials have been developed under the inspiration of the intriguing multiscale structures,adaptive mechanisms,and dynamic responses of natural life,with an aim to further design advanced material systems with novel,intriguing,and unprecedented properties.

关键词： Smart properties. Dynamic

来源：评论

学校读者我要写书评

暂无评论

Understanding the stability of advanced inorganic-organic hybrid thin films for advanced resist applications 41

Understanding the stability of advanced inorganic-organic hy...

引用

Advances in Patterning materials and Processes XLI 2024

作者： Le, Dan N. Chu, Thi Thu Huong Kim, Jin-Hyun Veyan, Jean-Francois Lee, Won-Il Tiwale, Nikhil Lee, Minjong Choi, Seungsoo Woo, Jihoon Nam, Chang-Yong Choi, Rino Kim, Jiyoung Department of Materials Science and Engineering University of Texas at Dallas RichardsonTX75080 United States Department of Materials Science and Chemical Engineering Stony Brook University Stony BrookNY11794 United States Center for Functional Nanomaterials Brookhaven National Laboratory UptonNY11973 United States Department of Electrical and Computer Engineering University of Texas at Dallas RichardsonTX75080 United States Program in Enviromental and Polymer Engineering Inha University Incheon22212 Korea Republic of Department of Materials Science and Engineering Inha University Incheon22212 Korea Republic of

ISBN: (纸本)9781510672208

In this study, we focus on examining the stability of Al-based inorganic-organic hybrid thin films deposited through the molecular atomic layer deposition (MALD) process in ambient environment. Our observations reveal an initial reduction in material thickness within the first 3 days, followed by a period of stability. XPS analysis is employed to further investigate the chemical alternations in the aged Al-based hybrid thin films, revealing an increase in C=O species as well as overall oxygen content in the material. We also evaluate the effects of atmospheric exposure on the sensitivity of the Al-based hybrid thin films using electron flood exposure. This study aims to enhance the understanding of the stability of a vapor-phase synthesized hybrid thin film system for advanced resist applications. © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

关键词： Atomic layer deposition

来源：评论

学校读者我要写书评

暂无评论

Highly efficient and stable binary and ternary organic solar cells using polymerized nonfused ring electron acceptors

引用

National science Review 2024年第9期11卷 235-242页

作者： Xiaodong Wang Nan Wei Ya-nan Chen Guangliu Ran Andong Zhang Hao Lu Zhengdong Wei Yahui Liu Wenkai Zhang Zhishan Bo College of Textiles &Clothing State Key Laboratory of Bio-fibers and Eco-textiles Qingdao University Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal University School of Physics and Astronomy Applied Optics Beijing Area Major Laboratory Center for Advanced Quantum Studies Beijing Normal University College of Materials Science and Engineering Qingdao University

This study reports the successful design and synthesis of two novel polymerized nonfused ring electron acceptors, P-2BTh and P-2BTh-F, derived from the high-performance nonfused ring electron acceptor,2BTh-2F. Prepared via Stille polymerization, these polymers feature thiophene and fluorinated thiophene asπ-bridge units. Notably, P-2BTh-F, with difluorothiophene as the π-bridge, exhibits a more planar backbone and red-shifted absorption spectrum compared with P-2BTh. When employed in organic solar cells(OSCs) with PBDB-T as the donor material, P-2BTh-F-based devices demonstrate an outstanding power conversion efficiency(PCE) of over 11%, exceeding the 8.7% achieved by P-2BTh-based ***, all-polymer solar cells utilizing PBDB-T:P-2BTh-F exhibit superior storage ***, P-2BTh-F was explored as a functional additive in a high-performance binary system,enhancing stability while maintaining comparable PCE(19.45%). This strategy offers a cost-effective approach for fabricating highly efficient and stable binary and ternary organic solar cells, opening new horizons for cost-effective and durable solar cell development.

关键词： organic solar cells all-polymer organic solar cells ternary blend strategy nonfused ring electron acceptors

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：