检索结果-内蒙古大学图书馆

Biobased Poly(ester amide)s as Sustainable Coating materials for Vegan Leather with Improved Haptic Sensation

ACS Sustainable Chemistry and engineering 2025年第20期13卷 7585-7597页

作者： Ryu, Jieun Hao, Lam Tan Kim, Hyeri Lee, Somyong Jeon, Hyeonyeol Hwang, Dong Soo Park, Jeyoung Park, Cheol Hun Oh, Dongyeop X. Koo, Jun Mo Park, Sung Bae Ulsan44429 Korea Republic of Pohang37673 Korea Republic of Ulsan44429 Korea Republic of Pohang37673 Korea Republic of Daejeon34113 Korea Republic of Department of Chemical and Biomolecular Engineering Sogang University Seoul04107 Korea Republic of Department of Polymer Science and Engineering and Program in Environmental and Polymer Engineering Inha University Incheon22212 Korea Republic of Department of Organic Materials Engineering Chungnam National University Daejeon34134 Korea Republic of Department of Materials Science and Engineering Chungnam National University Daejeon34134 Korea Republic of

Increased consumer awareness of animal welfare and environmental sustainability has driven the development of vegan leather alternatives to natural leather. Fossil-derived leather substitutes offer superior strength and thermal stability but often lack biodegradability, carbon neutrality and aesthetics. Biorenewable alternatives are more eco-friendly but typically suffer from insufficient thermal and mechanical properties and poor moisture resistance. This study presents the synthesis of mechanically reinforced, thermally enhanced and biodegradable poly(ester amide)s (PEAs) incorporating hydrogen bonds as vegan leather coating materials. Synthesized from biobased 1,4-butanediol, adipic acid and nylon 46 via a two-step transesterification/polycondensation process, the resulting PEAs exhibit over eight times higher tensile strength, 3-fold greater toughness, and enhanced thermal stability compared to their constituting homopolymers, poly(butylene adipate) and nylon 46. All PEAs disintegrate within 18 weeks and achieve over 60% biodegradation rate relative to cellulose under composting conditions within one month. When applied to mushroom fabrics, the PEA coating provides haptic sensations (slipperiness and softness) comparable to commercially available leather. Life-cycle assessment indicates that PEA-coated leather imposes considerably lower environmental impacts than both bovine and polyurethane-based leather. This novel material holds promise as a sustainable, high-performance vegan leather substitute. © 2025 American Chemical Society.

关键词： Biodegradability

来源：评论

学校读者我要写书评

暂无评论

Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix

引用

Chinese Chemical Letters 2025年第2期36卷 202-205页

作者： Tianyi Yang Fangxi Su Dehuan Shi Shenghong Zhong Yalin Guo Zhaohui Liu Jianfeng Huang State Key Laboratory of Coal Mine Disaster Dynamics and Control Institute of Advanced Interdisciplinary StudiesSchool of Chemistry and Chemical EngineeringChongqing UniversityChongqing 400044China Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesCollege of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

Propane dehydrogenation(PDH)is a vital industrial process for producing propene,utilizing primarily Cr-based or Pt-based *** catalysts often suffer from challenges such as the toxicity of Cr,the high costs of noble metals like Pt,and deactivation issues due to sintering or coke formation at elevated *** introduce an exceptional Ru-based catalyst,Ru nanoparticles anchored on a nitrogendoped carbon matrix(Ru@NC),which achieves a propane conversion rate of 32.2%and a propene selectivity of 93.1%at 550°C,with minimal coke deposition and a low deactivation rate of 0.0065 h^(-1).Characterizations using techniques like TEM and XPS,along with carefully-designed controlled experiments,reveal that the notable performance of Ru@NC stems from the modified electronic state of Ru by nitrogen dopant and the microporous nature of the matrix,positioning it as a top contender among state-of-the-art PDH catalysts.

关键词： Propane dehydrogenation Ru nanoparticles Porous carbon matrix Ru@NC Electronic interaction

来源：评论

学校读者我要写书评

暂无评论

Unraveling the impacts of intermolecular interaction on morphology evolution for highly efficient organic solar cells and modules

引用

science China Chemistry 2025年第1期68卷 264-272页

作者： Xueqing Ma Yingying Cheng Yuqiang Liu Xinming Zheng Guangliu Ran Hongxiang Li Xinyue Cui Andong Zhang Wenkai Zhang Pei Cheng Wenchao Huang Zhishan Bo Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing 100875China College of Textiles and Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao 266071China Key State Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Department of Physics and Applied Optics Beijing Area Major Laboratory Center for Advanced Quantum StudiesBeijing Normal UniversityBeijing 100875China State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu 610065China

Understanding the effect of intermolecular interaction on the growth dynamic of active layers is critical for advancing organic solar cells(OSCs).However,the diverse structure of donors and acceptors makes the research *** with customizable structures and properties could simplify this ***,we meticulously tailor two additives of 3,4-ethylenedioxythiophene(EDOT)and 2,5-dibromo-3,4-ethylenedioxythiophene(DBEDOT),possessing distinct intermolecular interaction features to elaborate the inherent *** is found that varied interaction strengths can alter film formation *** enhanced intermolecular interaction between the DBEDOT and non-fullerene acceptor BTP-e C9-4F results in pre-aggregation and longer crystallization duration of BTP-e C9-4F,facilitating the formation of films with compact molecular packing and decent phase ***,exciton dissociation and charge transport become more ***,devices processed with DBEDOT exhibit a remarkable power conversion efficiency of 19.35%in small-area OSCs and 14.11%in bladecoated 5 cm×5 cm organic solar ***,OSCs can maintain 80%of their initial efficiency after continuous annealing at 85℃for over 2,100 h.

关键词： organic solar cell non-fullerene acceptor film growth molecular packing intermolecular interaction

来源：评论

学校读者我要写书评

暂无评论

Flexible refractory castables based on the Al2O3-MgO-TiO2 system

引用

Ceramics International 2025年第15期51卷 20822-20829页

作者： Reitmann, B. Borges, O.H. Falsetti, L.O.Z. Pagliosa Neto, C. Pandolfelli, V.C. Federal University of São Carlos Graduate Program in Materials Science and Engineering São Carlos Brazil São Carlos Brazil RHI Magnesita Research and Development Center Contagem Brazil

Toughening by in-situ phase formation is highly desired for high-performance refractories, as it enhances their thermomechanical properties (e.g. thermal shock damage resistance). For this purpose, pseudobrookite and intermediary spinels are promising phases due to their thermal expansion mismatch, resulting in self-microcracking. Aiming to develop highly flexible refractory castables, compositions based on the Al2O3-MgO-TiO2 system were formulated with the aid of computational thermodynamics. Of the most promising compositions, five of them were experimentally produced and had their thermomechanical and physical properties assessed by X-ray diffraction, in-situ elastic modulus, thermal shock damage analysis (ΔT = 1000 °C) and scanning electron microscopy. Results pointed out that small titania contents led to a positive effect on microstructure densification, improving the mechanical performance of the refractories and generation of phases that induce microcracking upon cooling, enhancing the thermal shock damage resistance. Nevertheless, an excess of TiO2 led to extensive cracking and cohesion loss in the refractory matrix. © 2025

关键词： Microcracking

来源：评论

学校读者我要写书评

暂无评论

Recent advances in bio-integrated electrochemical sensors for neuroengineering

引用

Fundamental Research 2025年第1期5卷 29-47页

作者： Shulin Chen Tzu-Li Liu Yizhen Jia Jinghua Li Department of Materials Science and Engineering The Ohio State UniversityColumbusOH 43210USA Chronic Brain Injury Program The Ohio State UniversityColumbusOH 43210USA

Detecting and diagnosing neurological diseases in modern healthcare presents substantial challenges that directly impact patient *** complex nature of these conditions demands precise and quantitative monitoring of disease-associated biomarkers in a continuous,real-time *** chemical sensing strategies exhibit restricted clinical effectiveness due to labor-intensive laboratory analysis prerequisites,dependence on clinician expertise,and prolonged and recurrent ***-integrated electronics for chemical sensing is an emerging,multidisciplinary field enabled by rapid advances in electrical engineering,biosensing,materials science,analytical chemistry,and biomedical *** review presents an overview of recent progress in bio-integrated electrochemical sensors,with an emphasis on their relevance to neuroengineering and *** traverses vital neurological biomarkers and explores bio-recognition elements,sensing strategies,transducer designs,and wireless signal transmission *** integration of in vivo biochemical sensors is showcased through *** review concludes by outlining future trends and advancements in in vivo electrochemical sensing,and highlighting ongoing research and technological innovation,which aims to provide inspiring and practical instructions for future research.

关键词： Biochemical sensing Neuroengineering Bioimplants Analytical chemistry Bio-integrated electronics

来源：评论

学校读者我要写书评

暂无评论

Femtosecond laser-induced KOH etching for in-volume microfluidic channels in corning EagleXG glass

引用

Journal of the Korean Ceramic Society 2025年 1-11页

作者： Choi, Kyeonggon Kim, Sung-Il Kim, Seung-Wook Park, Cheol-Woo Lee, Jae-Hyoung Chu, Baojin Kim, Hojong Jeong, Dae-Yong Program in Semiconductor Convergence Department of Materials Science and Engineering Inha University Incheon South Korea Corning Technology Center Korea Corning Precision Materials Asan South Korea Regional Leading Research Center for Smart Energy System Kyungpook National University Sangju South Korea School of Chemistry and Materials Science University of Science and Technology of China Hefei China Materials Science and Engineering The Pennsylvania State University University Park PA United States

Conventional planar or two-dimensional (2D) microfluidic channels have traditionally been fabricated using polymer materials. Although these materials are widely applied across various fields, they exhibit significant limitations, including low throughput, restricted fluid flow rates, and limited particle-handling efficiency. In addition, polymer-based channels have issues such as low thermal and pressure tolerance, inadequate chemical resistance, and challenges with leakage and bonding integrity. In contrast, glass presents a promising alternative due to its superior optical properties, long-term stability, high temperature and chemical resistance, and minimal sample adsorption. However, the complexity of the microelectromechanical systems (MEMS) fabrication processes has historically hindered the use of glass in microfluidics. In this study, we introduce a novel method for fabricating in-volume 3D microfluidic channels within glass substrates via selective laser-induced etching. Using a femtosecond laser with potassium hydroxide (KOH) solution, we etched the CORNING EagleXG glass substrate under various laser parameters to optimize etching conditions. Etching process was conducted at 100 °C with durations ranging from 6 to 42 h, producing channel lengths from 147.33 μm (6 h) to 556.66 μm (42 h) and channel diameters ranging from 11.15 μm to 49.72 μm, respectively. This study demonstrates the process parameters necessary for reliable 3D microfluidic channel fabrication in glass. The findings demonstrate an effective fabrication approach that significantly expands the potential applications of glass microfluidic channels, especially using EagleXG glass, marking a promising advancement in the field. © The Korean Ceramic Society 2025.

关键词： EagleXG glass Femtosecond laser KOH Microfluidic channel Selective laser-induced etching Wet etching

来源：评论

学校读者我要写书评

暂无评论

In-situ growth of cross-link NiAl-LDH nanosheets on the inner/outer surfaces of carbon microtubes for anti-corrosive electromagnetic wave absorption

引用

Journal of materials science and Technology 2025年 238卷 109-118页

作者： Liu, Rui Liu, Xiao Wu, Lihong Du, Changlong Lv, Haiming Wan, Gengping Xiong, Hualin Yuan, Xiang Wang, Jieping Wang, Guizhen Institute of Electromagnetic Protection Materials and Spectral Innovation Technology State Key Laboratory of Tropic Ocean Engineering Materials and Materials Evaluation School of Materials Science and Engineering Hainan University Haikou570228 China Center for New Pharmaceutical Development and Testing of Haikou Center for Advanced Studies in Precision Instruments Haikou570228 China Key Laboratory of Pico Electron Microscopy of Hainan Province Center for Advanced Studies in Precision Instruments Haikou570228 China

Electromagnetic wave (EMW) absorbers with anti-corrosion property are highly desired to enhance the durability of military targets in harsh condition. Herein, cross-link NiAl-layered double hydroxide (NiAl-LDH) nanosheets on the inner/outer surfaces of carbon microtubes (CMTs) are ingeniously constructed through the combination of atomic layer deposition technique and a hydrothermal method. The obtained NiAl-LDH/CMT composite exhibits excellent EMW absorption and corrosion resistance performance. The large internal cavity of CMT significantly enhances impedance matching. The uniform distribution of NiAl-LDH nanosheets on both the inner and outer surfaces of CMT generates numerous heterogeneous interfaces that induce substantial polarization loss. Consequently, at a filler rate of only 5 wt.%, the NiAl-LDH/CMT composite exhibits a minimum reflection loss of −60.2 dB and a maximum effective absorption bandwidth of 5.9 GHz. In addition, the combined high impermeability of CMT and the effective Cl−-trapping ability of NiAl-LDH endows NiAl-LDH/CMT composite with outstanding corrosion protection property in simulated seawater environment. Furthermore, the PO43− anions are effectively incorporated into the NiAl-LDH interlayer via anion exchange, which can further enhance corrosion protection capacity through surface inactivation from slow-release PO43− anions without reducing their EMW absorption performance. In summary, this work can give guidance for the development of efficient anti-corrosion EMW absorption materials. © 2025

关键词： Anodic protection

来源：评论

学校读者我要写书评

暂无评论

Energy Transfer Mechanisms in Large Low-Bandgap Polymers from Time-Resolved Experiments and Nonadiabatic Molecular Dynamics Calculations

引用

Chemistry of materials 2025年第10期37卷 3769-3775页

作者： Phun, Gabriel S. Kern, Dana B. Sfeir, Matthew Y. Azoulay, Jason D. Wong, Bryan M. Department of Chemistry Department of Physics & Astronomy Materials Science & Engineering Program University of California-Riverside Riverside 92521 CA United States School of Chemistry and Biochemistry School of Materials Science and Engineering Center for Organic Photonics and Electronics Georgia Institute of Technology Atlanta 30332 GA United States Materials Science Center National Renewable Energy Laboratory Golden 80401 CO United States

Conjugated polymers offer unprecedented chemical tunability for modulating energy transfer in a multitude of infrared light applications. In this work, we use a combination of time-resolved spectroscopic experiments and nonadiabatic molecular dynamics calculations to probe the photochemistry and nonradiative transitions in a recently synthesized narrow bandgap donor-acceptor conjugated polymer based on alternating cyclopentadithiophene and electronegative benzothiadiazole heterocycles. Using large-scale semi-empirical nonadiabatic molecular dynamics, which can treat a large 260-atom hexamer, we calculate an S₅ → S₁ lifetime of 34.75 fs, which is consistent with our time-resolved spectroscopic data. Our simulations suggest that vibronic motions of the central carbons in the cyclopentadithiophene functional groups are predominantly involved in the nonradiative transitions, and the excitation becomes more localized on a monomer fragment over time. The combined use of time-resolved experiments and nonadiabatic molecular dynamics calculations in this work provides mechanistic insight into chemical functionalities that can be tuned to enhance energy transfer in other prospective low-bandgap polymer materials. © 2025 The Authors. Published by American Chemical Society.

关键词： Spectroscopic analysis

来源：评论

学校读者我要写书评

暂无评论

Quantum Interference in a Molecular Analog of the Crystalline Silicon Unit Cell

引用

Journal of the American Chemical Society 2025年第19期147卷 16602-16610页

作者： Hight, Matthew O. Pimentel, Ashley E. Siu, Timothy C. Wong, Joshua Y. Nguyen, Jennifer Carta, Veronica Su, Timothy A. Department of Chemistry University of California RiversideCA92506 United States Materials Science & Engineering Program University of California RiversideCA92506 United States

This manuscript describes the emergence of destructive σ-quantum interference (σ-DQI) in sila-adamantane, a molecule whose cluster core is isostructural with the crystalline silicon unit cell. To reveal these σ-DQI effects, we take a bridge-cutting approach where we conceptually pare sila-adamantane down to its bicyclic Si[3.3.1] and linear oligosilane forms. Scanning tunneling microscopy break-junction (STM-BJ) measurements reveal that conductance in single-molecule junctions of the tricyclic sila-adamantane is 2.7-times lower than their bicyclic Si[3.3.1] analog. The only structural difference between their cluster cores is a remote dimethylsilylene bridge that is present in sila-adamantane yet absent in Si[3.3.1]. Density functional theory calculations reveal that this dimethylsilylene enforces C3 symmetry at the sila-diamondoid bridgeheads, allowing each electrode to couple into the three cluster bridge dimensions equally. Though each bridge alignment is sterically equivalent, they have profound electronic differences: when electrodes align with the long branches of sila-adamantane, strong σ-DQI interactions occur between frontier molecular orbitals that suppress electronic transmission across the molecular junction. We exploit these alignment-dependent σ-DQI effects to create new forms of stereoelectronic conductance switches, where a reversible mechanical stimulus controls which pathway through the diamondoid framework the electrodes align through. This represents the first example of dynamic modulation of σ-DQI and enables us to achieve switching ratios (average on/off ∼5.6) higher than previously reported σ-stereoelectronic switches. These studies reveal how the innate dimensionality and symmetry of crystalline silicon influence charge transport at its most fundamental level, and how these principles can be harnessed to control quantum interference in single-molecule electronics. © 2025 The Authors. Published by American Chemical Society.

关键词： Molecular orbitals

来源：评论

学校读者我要写书评

暂无评论

Heterogeneous β-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl bifunctional electrocatalyst for superior concurrent conversion of glycerol and nitrite

引用

Journal of Energy Chemistry 2025年第5期104卷 185-193页

作者： Mingdan Wang Pengzuo Chen Huigang Wang Yanying Zhao School of Chemistry and Chemical Engineering Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018ZhejiangChina Hangzhou Institute of Advanced Studies Zhejiang Normal UniversityHangzhou 311231ZhejiangChina

The electrochemical biomass valorization of industrial by-products or pollutants using renewable electricity offers significant promise for carbon ***,the huge challenges still exist in the development of efficient bifunctional ***,we put forward a high-efficiency coelectrolysis system by coupling the nitrite reduction reaction(NO_(2)RR)and the glycerol oxidation reaction(GOR)over a novel heterogeneous β-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl ***β-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl shows excellent bifunctional performance with high Faradaic efficiencies of formate(90.1%)and NH_(3)(91.9%)at cell voltage of 1.5 V,high yield rate of formate(89.6 mg h^(-1)cm^(-2))and NH_(3)(36.07 mg h^(-1)cm^(-2))at cell voltage of 1.9 V,and superior stability in an anion exchange membrane *** in-situ Raman result confirms the unique Co/Cu-based bimetallic synergistic sites of β-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl towards superior GOR performance,while the operando Fourier transform infrared spectroscopy demonstrates the improved protonation kinetics of key intermediates and optimized water dissociation ability ofβ-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl for high NO_(2)RR *** work illuminates alternative avenues to exploit the innovative and energy-saving technology for the co-production of high-added chemicals.

关键词： Heterogeneous catalyst β-Co(OH)_(2)/Cu_(2)(OH)_(3)Cl Bifunctional performance Nitrite reduction reaction Glycerol oxidation reaction

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：