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Fluorinated Functional Units for Li+ Flux Homogenization in Silica Framework-Based Zwitterionic Single Ion Conductors for Stable Lithium Metal Batteries

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Advanced Energy Materials 2025年第0期

作者： Handayani, Puji Lestari Yun, Susung Kim, Gihyeon Choi, U Hyeok Department of Polymer Science and Engineering and Program in Environmental and Polymer Engineering Inha University Incheon22212 Korea Republic of

Progress in commercializing solid polymer electrolytes (SPEs) for lithium metal batteries (LMBs) has been impeded by challenges, like concentration polarization, non-uniform Li+ flux, and an unstable solid electrolyte interface (SEI), which contribute to dendrite formation. To address these issues, silica framework (SF)-based single-ion conductors are proposed, featuring a unique solvation channel composed of a fluorinated segment, a high-dipole zwitterion, and a rotation-motion-driven ion-hopping medium. This design promotes low resistance at the cathode/electrode interface, suppresses dendrite growth at the anode/electrolyte interface, and maintains a uniform Li+ flux. This results show that continuous ion channels within a robust framework enhance Li-ion dissociation and transport, achieving high ionic conductivity (σDC = 8.8 × 10−4 S cm−1), a modulus of 0.9 GPa, a high lithium transference number (≈0.83), and an extended electrochemical stability window (up to 5.2 V) at 25 °C. This design fosters the formation of a hybrid organic/inorganic SEI layer composed of Li2CO3, LiF, and Li2O, enabling ultra-stable Li plating/stripping for over 4000 h at 0.1 mA cm−2. Furthermore, the full cells demonstrate excellent rate performance and long-term cycling stability and capacity retention (81% for Li||LFP and 86% for Li||NCM811 after 400 cycles at 1 C) and high coulombic efficiency, offering a promising strategy to stable LMBs. © 2025 Wiley-VCH GmbH.

关键词： Solid electrolytes

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Ion-Anchoring Dipole-Integrated Composite Elastomer Electrolyte and Cathode for High-Performance Lithium Metal Batteries via Multiple-Bridge engineering

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Advanced Energy Materials 2025年第0期

作者： Cho, A Hyeon Je, Ji Hyang Choi, U Hyeok Department of Polymer Science and Engineering and Program in Environmental and Polymer Engineering Inha University Incheon22212 Korea Republic of

Solid-state electrolytes (SSEs) hold significant potential for advancing lithium metal batteries (LMBs) by enhancing safety through the replacement of liquid electrolytes. However, challenges such as low ionic conductivity, limited electrochemical stability, and poor electrolyte/electrode interface compatibility hinder the development of high-energy-density LMBs. Herein, a strategy for designing SSEs is proposed using multiple-bridge engineered composite elastomer electrolytes (CEEs) that incorporate ion-rotating dipole interactions, ion-anchoring dipole interactions, and hydrogen bonding, along with a CEE-based composite elastomer cathode (CEC). This design combines a volume-adaptive elastomer matrix, a high-Li+ conducting deep eutectic electrolyte, and robust nanowires. The resultant CEE exhibits high ionic conductivity (1.7 × 10−3 S cm−1), a lithium transference number of 0.72, and a wide electrochemical stability window (up to 4.9 V) at 298 K. The engineered uniform Li+ flux also promotes stable Li plating/stripping for over 900 h at 0.1 mA cm−2. Furthermore, the LFP-based CEC|CEE|Li full cells deliver a reversible capacity of 133 mAh g−1 with 95% retention after 300 cycles in coin cells, and 129 mAh g−1 with 96% retention after 250 cycles in pouch cells at 1 C. This strategy presents a promising approach for designing solid-state polymer electrolytes to extend the lifespan of high-energy-density LMBs. © 2025 Wiley-VCH GmbH.

关键词： Elastomers

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Sulfur-doped hard carbon hybrid anodes with dual lithium-ion/metal storage bifunctionality for high-energy-density lithium-ion batteries

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Carbon Energy 2023年第1期5卷 71-81页

作者： Sungmin Cho Jong Chan Hyun Son Ha Yeonhua Choi Honggyu Seong Jaewon Choi Hyoung-Joon Jin Young Soo Yun Program in Environmental and Polymer Engineering Inha UniversityIncheonSouth Korea KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoulSouth Korea Departmant of Chemistry and Research Institute of Natural Science Gyeongsang National UniversityJinjuSouth Korea Department of Polymer Science and Engineering Inha UniversityIncheonSouth Korea Division of Energy Engineering Kangwon National UniversityGangwon-doSouth Korea

Bifunctional hybrid anodes(BHAs),which are both a high-performance active host material for lithium-ion storage as well as a guiding agent for homogeneous lithium metal nucleation and growth,exhibit significant potential as anodes for next-generation high-energy-density lithium-ion batteries(LIBs).In this study,sulfur-doped hard carbon nanosphere assemblies(S-HCNAs)were prepared through a hydrothermal treatment of a liquid organic precursor,followed by high-temperature thermal annealing with elemental sulfur for application as BHAs for *** a carbonate-based electrolyte containing fluoroethylene carbonate additive,the S-HCNAs showed high lithium-ion storage capacities in sloping as well as plateau voltage sections,good rate capabilities,and stable *** addition,high average Coulombic efficiencies(CEs)of~96.9%were achieved for dual lithium-ion and lithium metal storage *** the LIB full-cell tests with typical NCM811 cathodes,the S-HCNA-based BHAs containing~400 mA h g^(−1) of excess lithium led to high energy and power densities of~500Wh kg^(−1) and~1695Wkg^(−1),respectively,and a stable cycling performance with~100%CEs was achieved.

关键词： hard carbon hybrid anode lithium-ion batteries lithium metal anode lithium metal batteries sulfur-doped carbon

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Core/shell magnetite/copolymer composite nanoparticles enabling highly stable magnetorheological response

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International Journal of Mechanical System Dynamics 2022年第2期2卷 155-164页

作者： Wenjiao Han Shun Wang Xiaoting Rui Yuzhen Dong Hyoungjin Choi School of Energy and Power Engineering Nanjing University of Science and TechnologyNanjingChina School of Materials Science and Engineering Harbin Institute of Technology at WeihaiWeihaiChina Department of Polymer Science and Engineering Inha UniversityIncheonRepublic of Korea Program of Environmental and Polymer Engineering College of EngineeringInha UniversityIncheonRepublic of Korea

Magnetorheological fluids(MRFs)have been successfully used in a variety of smart control systems,but are still limited due to their relatively poor settling ***,a core/shell‐structured Fe_(3)O_(4)/copolymer composite nanoparticle is synthesized as a new candidate material for stimulus‐responsive MRFs to tackle the limitation of the long‐term dispersion ***‐co‐diphenylamine copolymers(PANI‐co‐PDPA)are loaded onto the surface of Fe_(3)O_(4) nanoparticles,providing a lighter density and sufficient active interface for the dispersion of magnetic particles in the carrier *** features of the Fe_(3)O_(4)/copolymer composite nanoparticles,including morphology,compositional,and crystalline properties,are *** MRF is prepared by suspending Fe_(3)O_(4)/copolymer composite nanoparticles in a nonmagnetic medium oil,and its rheological properties are assessed using a controlled shear rate test and dynamic oscillation tests using a rotational *** models including the Bingham model and the Herschel–Bulkley model are fitted to the flow curves of the *** obtained Fe_(3)O_(4)/copolymer composite shows soft‐magnetic properties,as well as greater density adaptability and higher stability,compared to Fe_(3)O_(4).Moreover,the sedimentation testing provides information about the dispersion stability characteristics of MRF and shows a good correlation with high‐stability magnetorheological(MR)*** Fe_(3)O_(4)/copolymer‐based MRF with a tunable and instantaneous MR response is considered a promising material for smart control applications.

关键词： magnetorheological fluids core/shell dispersion stability copolymer magnetite

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Nanoconfinement effect of nanoporous carbon electrodes for ionic liquid-based aluminum metal anode

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Journal of Energy Chemistry 2022年第11期31卷 121-127,I0005页

作者： Juhee Yoon Seongbak Moon Son Ha Hyung-Kyu Lim Hyoung-Joon Jin Young Soo Yun Program in Environmental and Polymer Engineering Inha UniversityIncheon 22212South Korea Department of Polymer Science and Engineering Inha UniversityIncheon 22212South Korea KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoul 02841South Korea Division of Chemical Engineering and Bioengineering Kangwon National UniversityGangwon-do 24341South Korea Department of Integrative Energy Engineering Korea UniversitySeoul 02841South Korea

Rechargeable aluminum batteries(RABs),which use earth-abundant and high-volumetric-capacity metal anodes(8040 m Ah cm-3),have great potential as next-generation power sources because they use cheaper resources to deliver higher energies,compared to current lithium ion ***,the mechanism of charge delivery in the newly developed,ionic liquid-based electrolytic system for RABs differs from that in conventional organic ***,targeted research efforts are required to address the large overpotentials and cycling decay encountered in the ionic liquid-based electrolytic *** this study,a nanoporous carbon(NPC)electrode with well-developed nanopores is used to develop a high-performance aluminum *** negatively charged nanopores can provide quenched dynamics of electrolyte molecules in the aluminum deposition process,resulting in an increased collision *** fast chemical equilibrium of anionic species induced by the facilitated anionic collisions leads to more favorable reduction reactions that form aluminum *** nanoconfinement effect causes separated nucleation and growth of aluminum nanoparticles in the multiple confined nanopores,leading to higher coulombic efficiencies and more stable cycling performance compared with macroporous carbon black and 2D stainless steel electrodes.

关键词： Nanoconfinement effect Nanoporous carbon Ionic liquid electrolyte Metal anode Aluminum batteries Multivalent batteries

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Green Fabrication of Underwater Superoleophobic Biopolymeric Nanofibrous Membranes for Effective Oil-Water Separation

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Advanced Fiber Materials 2023年第2期5卷 603-616页

作者： Subin Oh Junsik Bang Hyoung‑Joon Jin Hyo Won Kwak Program in Environmental and Polymer Engineering Inha University100 Inha‑RoMichuhol‑GuIncheon 22212South Korea Department of Agriculture Forestry and BioresourcesCollege of Agriculture and Life SciencesSeoul National University1 Gwanak‑RoGwanak‑GuSeoul 08826South Korea Department of Polymer Science and Engineering Inha University100 Inha‑RoMichuhol‑GuIncheon 22212South Korea Research Institute of Agriculture and Life Sciences Seoul National University1 Gwanak‑RoGwanak‑GuSeoul 08826South Korea

Currently,most of the materials for oil-water separation membranes are limited to fluorine-based polymers with low surface ***,it is not biodegradable and requires large amounts of organic and toxic solvents in the membrane manufacturing ***,interest in the development of a new eco-friendly oil-water separation membrane that does not cause secondary pollution and exhibits selective wettability characteristics in water or oil is *** biopolymeric nanofibrous membranes inspired by fish skin can provide specific underwater oleophobicity,which is effective for excellent oil-water separation efficiency and prevention of secondary *** gelatin,which is highly soluble in water and has a low gelation temperature,can be electrospun in an aqueous solution and has the same polar functional groups as the hydrophilic mucilage of fish *** addition,the micro/nanostructure of fish skin,which induces superoleophobicity in water,introduces a bead-on-string structure using the Rayleigh instability of *** solubility of fish gelatin in water was removed using an eco-friendly crosslinking method using reducing *** skin-mimicking materials successfully separated suspended oil and emulsified oil,with a maximum flux of 2086 Lm^(−2) h^(−1) and a separation efficiency of more than 99%.The proposed biopolymeric nanofibrous membranes use fish gelatin,which can be extracted from fish waste and has excellent biodegradability with excellent oil-water separation *** addition,polymer material processing,including membrane manufacturing and crosslinking,can be realized through eco-friendly ***,fish skin-inspired biopolymeric membrane is expected to be a promising candidate for a sustainable and effective oil-water separation membrane in the future.

关键词： Fish gelatin Nanofibrous membrane Superoleophobicity Superhydrophilicity Oil/water separation

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High-performance solid-solution potassium-ion intercalation mechanism of multilayered turbostratic graphene nanosheets

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Journal of Energy Chemistry 2022年第4期31卷 814-823页

作者： Jiae Um Seung Uk Yoon Hoseong Kim Beom Sik Youn Hyoung-Joon Jin Hyung-Kyu Lim Young Soo Yun Program in Environmental and Polymer Engineering Inha Universityncheon 22212 South Korea Department of Polymer Science and Engineering Inha UniversityIncheon 22212South Korea Division of Chemical Engineering and Bioengineering Kangwon National University Chuncheon Gangwon-do 24341 South Korea KU-KIST Graduate School of Converging Science and Technologyea University 145 Anam-roSeongbuk-guSoul02841 South Korea Department of Integrative Energy Engineering 145 Anam-roSongbuk-guKorea UniversitySeoul 02841 South Korea

The solid-solution reaction between an alkali cation and an active host material is known as a singlephase redox mechanism,and it is typically accompanied by a continuous voltage *** is distinct from the typical alkali cation intercalation reaction at an equivalent site of the active host material,which exhibits a voltage ***,we report an unusual solid-solution potassium-ion intercalation mechanism with a low-voltage plateau capacity on multilayered turbostratic graphene nanosheets(T-GNSs).Despite the disordered graphitic structure with a broad range of d-spacings(3.65–4.18À),the T-GNSs showed a reversible plateau capacity of~200 m A h g^(-1),which is higher than that of a well-ordered graphite nanoplate(~120 m A h g^(-1)).In addition,a sloping capacity of~220 m A h g^(-1)was delivered with the plateau capacity,and higher rate capabilities,better reversibility,and a more stable cycling performance were confirmed on the turbostratic ***-principles calculations suggest that the multitudinous lattice domains of the T-GNSs contain diverse intercalation sites with strong binding energies,which could be the origin of the high-performance solid-solution potassium-ion intercalation behavior when the turbostratic graphene stacks have a d-spacing smaller than that of equilibrium potassium–graphite intercalation compounds(5.35À).

关键词： Turbostratic graphite Graphene nanosheet Defective carbon Anode Potassium-ion batteries

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Optimization of photocatalytic ceramic membrane filtration by response surface methodology: Effects of hydrodynamic conditions on organic fouling and removal efficiency

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Chemosphere 2024年 356卷 141885页

作者： Jang, Hoseok Lee, Chang Soo Kim, Jong Hak Kim, Jeonghwan Department of Environmental Engineering Program of Environmental and Polymer Engineering Inha University Michuholgu Incheon22212 Korea Republic of Department of Chemical Engineering Pukyong National University Busan48513 Korea Republic of Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Korea Republic of

The effects of the operating conditions, including the applied pressure, feed organic concentration, and recirculation flowrate along the TiO2-coated ceramic membrane, on the normalized membrane permeability and organic removal efficiency were systematically investigated by operating a photocatalytic membrane reactor (PMR). Response surface methodology (RSM) was conducted to better understand the interactive effect of operational conditions as well as their individual and combined effects to control membrane performance. Our results showed that the applied pressure and feed organic concentration, as single parameter, affected the normalized membrane permeability and organic removal efficiency more dominantly than the recirculation flowrate. The polynomial performance equations generated by RSM successfully predicted the membrane performance of the PMR. The responses to the normalized membrane permeability and organic removal efficiency with respect to the operational conditions were less sensitive to any combination of operational conditions than to their individual impacts. The combined effects of the operating conditions were less pronounced in promoting the catalytic performance of organic contaminants on the TiO2 surface. Our RSM analysis based on experimental observations designed by Box–Behnken Design (BBD) suggested that 1.3 bar of applied pressure, 44 mg/L of feed organic dye concentration and 0.8 L/min as recirculation flowrate as optimum conditions achieved more than 98% of organic removal efficiency and less than 5% of decline in normalized membrane permeability. This research shows that the RSM provides effective tool to optimize operational conditions to determine fouling rate and organic removal in PMR. © 2024 Elsevier Ltd

关键词： Titanium dioxide

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Molecular simulation-guided and physics-informed mechanistic modeling of multifunctional polymers

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Acta Mechanica Sinica 2021年第5期37卷 725-745,I0002页

作者： Guang Chen Weikang Xian Qiming Wang Ying Li Department of Mechanical Engineering University of ConnecticutStorrsCT 06269USA Sonny Astani Department of Civil and Environmental Engineering University of Southern CaliforniaLos AngelesCA 90089USA Department of Mechanical Engineering and Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsCT 06269USA

polymeric materials have a broad range of mechanical and physical *** have been widely used in material science,biomedical engineering,chemical engineering,and mechanical *** introduction of active elements into the soft matrix of polymers has enabled much more diversified functionalities of polymeric materials,such as self-healing,electroactive,magnetosensitive,pH-responsive,and many *** further enable applications of these multifunctional polymers,a mechanistic modeling method is required and of great significance,as it can provide links between materials’micro/nano-structures and their macroscopic mechanical *** this goal,molecular simulation plays an important role in understanding the deformation and evolution of polymer networks under external loads and *** molecular insights provide physical guidance in the formulation of mechanistic-based continuum models for multifunctional *** this perspective,we present a molecular simulation-guided and physics-informed modeling framework for polymeric ***,the physical theory for polymer chains and their networks is briefly *** serves as the foundation for mechanistic-models of polymers,linking their chemistry,physics,and mechanics ***,the deformation of the polymer network is used to derive the strain energy density ***,the corresponding continuum models can capture the intrinsic deformation mechanisms of polymer *** then highlight several representative examples across multiphysics coupling problems to describe in detail for this proposed *** but not least,we discuss potential challenges and opportunities in the modeling of multifunctional polymers for future research directions.

关键词： Molecular simulation Multiphysics modeling Multiscale modeling Multifunctional polymers Soft Matter

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Assessing the Potential of Biodegradable Plastics in a Circular Economy: A Methodological Outlook

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Circular Economy and Sustainability 2025年第2期5卷 1291-1305页

作者： Scheers, Quinten Nimmegeers, Philippe Galant, Or Spatari, Sabrina Van den Brande, Niko Brancart, Joost Billen, Pieter Faculty of Applied Engineering Intelligence in Processes Advanced Catalysts and Solvents (iPRACS) University of Antwerp Groenenborgerlaan 171 Antwerp 2020 Belgium Faculty of Business and Economics Department of Engineering Management Environmental Economics (EnvEcon) University of Antwerp Prinsstraat 13 Antwerp 2000 Belgium Flanders Make@UAntwerp Antwerp 2000 Belgium Faculty of Civil and Environmental Engineering Technion– Israel Institute of Technology Haifa 3200003 Israel Grand Technion Energy Program Technion– Israel Institute of Technology Haifa 3200003 Israel Physical Chemistry and Polymer Science (FYSC) Vrije Universiteit Brussel Pleinlaan 2 Brussels 1050 Belgium IVL Swedish Environmental Research Institute Valhallavägen 81 Stockholm 11428 Sweden

Increased biodegradability, in other words reduced environmental recalcitrance, has the potential to be an important asset in the battle against plastics pollution. It can partially mitigate global plastic leakages into the environment, which is next to their impact on climate change the biggest concern regarding plastics use. Biodegradation should be regarded as an optimal safety net in many applications and should often not be the targeted waste management option for biodegradable plastics. Biodegradability should not preclude reuse or proper recyclability, which are impactful means to reduce the carbon intensity of plastics lifecycles. Despite the added advantages, the market penetration of biodegradable plastics is only very slowly growing. Moreover, policy recommends its use only in limited applications, driven by sometimes-higher cost and limited recyclability. In this article, we posit that arguments against widespread application of biodegradable plastics are largely driven by misperceptions arising from intrinsic limitations of contemporary sustainability assessments and offer an alternative viewpoint that could compensate for this. In general, sustainability assessments fail to properly assess learning curves, often do not take littering potential into account, and are rather conservative with respect to background systems. Hence, recyclability– or better: circularity– judgements often do not resolve the paradoxical situation in which increased market shares lead to easier and more profitable recycling schemes and vice versa. Judging disruptive innovations by incorporating thermodynamics-inspired, less data-intensive, state-based methods, based on, e.g., statistical entropy analysis, into the decision support framework could allow to forecast packaging markets with performant materials that are intrinsically circular, having reduced environmental recalcitrance. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024.

关键词： Biodegradable Plastics Decision Making Statistical Entropy Sustainability Assessments

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