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Reversed charge transfer induced by nickel in Fe-Ni/Mo_(2)C@nitrogen-doped carbon nanobox for promoted reversible oxygen electrocatalysis

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Journal of Energy Chemistry 2024年第1期88卷 202-212,I0005页

作者： Zhicheng Nie Lei Zhang Qiliang Zhu Zhifan Ke Yingtang Zhou Thomas Wågberg Guangzhi Hu School of Materials Science and Engineering Anhui University of Science and TechnologyHuainan 232001AnhuiChina Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504YunnanChina National Engineering Research Center for Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004ZhejiangChina Department of Physics UmeåUniversityUmeåS-90187Sweden

The interaction between metal and support is critical in oxygen catalysis as it governs the charge transfer between these two entities,influences the electronic structures of the supported metal,affects the adsorption energies of reaction intermediates,and ultimately impacts the catalytic *** this study,we discovered a unique charge transfer reversal phenomenon in a metal/carbon nanohybrid ***,electrons were transferred from the metal-based species to N-doped carbon,while the carbon support reciprocally donated electrons to the metal domain upon the introduction of *** led to the exceptional electrocatalytic performances of the resulting Ni-Fe/Mo_(2)C@nitrogen-doped carbon catalyst,with a half-wave potential of 0.91 V towards oxygen reduction reaction(ORR)and a low overpotential of 290 m V at 10 mA cm^(-2)towards oxygen evolution reaction(OER)under alkaline ***,the Fe-Ni/Mo_(2)C@carbon heterojunction catalyst demonstrated high specific capacity(794 mA h g_(Zn)~(-1))and excellent cycling stability(200 h)in a Zn-air *** calculations revealed that Mo_(2)C effectively inhibited charge transfer from Fe to the support,while secondary doping of Ni induced a charge transfer reversal,resulting in electron accumulation in the Fe-Ni alloy *** local electronic structure modulation significantly reduced energy barriers in the oxygen catalysis process,enhancing the catalytic efficiency of both ORR and ***,our findings underscore the potential of manipulating charge transfer reversal between the metal and support as a promising strategy for developing highly-active and durable bi-functional oxygen electrodes.

关键词： Metal-support interaction Charge transfer reversal Oxygen reduction reaction Oxygen evolution reaction Zinc-air battery

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Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange

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Chinese Chemical Letters 2024年第4期35卷 210-213页

作者： Linhui Liu Wuwan Xiong Mingli Fu Junliang Wu Zhenguo Li Daiqi Ye Peirong Chen National Engineering Laboratory for VOCs Pollution Control Technology and Equipment Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution ControlSchool of Environment and EnergySouth China University of TechnologyGuangzhou 510006China National Engineering Laboratory for Mobile Source Emission Control Technology China Automotive Technology&Research Center Co.Ltd.Tianjin 300300China

Palladium-exchanged chabazite(Pd-CHA) zeolites as passive NO_x adsorbers(PNAs) enable efficient purification of nitrogen oxides(NO_x) in cold-start diesel exhausts. Their commercial application, however,is limited by the lack of facile preparation method. Here, high-performance CHA-type Pd-SAPO-34 zeolite was synthesized by a modified solid-state ion exchange(SSIE) method using PdO as Pd precursor,and demonstrated superior PNA performance as compared to Pd-SAPO-34 prepared by conventional wetchemistry strategies. Structural characterization using Raman spectroscopy and X-ray diffraction revealed that the SSIE method avoided water-induced damage to the zeolite framework during Pd loading. Mechanistic investigations on the SSIE process by in situ infrared spectroscopy and X-ray photoelectron spectroscopy disclosed that, while PdO precursor was mainly converted to Pd^(2+) cations coordinated to the zeolite framework by consuming the-OH groups of the zeolite, a portion of PdO could also undergo thermal decomposition to form highly dispersed Pd~0 clusters in the pore channels. This simplified and scalable SSIE method paves a new way for the cost-effective synthesis of defect-free high-performance Pd-SAPO-34 zeolites as PNA catalysts.

关键词： Pd-SAPO-34 Passive NO_x adsorber Pd loading Solid-state ion exchange Pd transformation

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Lattice expansion boosting photocatalytic degradation performance of CuCo_(2)S_(4) with an inherent dipole moment

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Chinese Chemical Letters 2023年第2期34卷 355-361页

作者： Yicheng Guo Biguo Yan Fang Deng Penghui Shao Jianping Zou Xubiao Luo Shuqu Zhang Xibao Li National-Local Joint Engineering Research Center of Heavy Metal Pollutants Control and Resource Utilization Nanchang Hangkong UniversityNanchang 330063China

Realizing efficient charge separation and directional transfer is a challenge for single-component *** spatial electric field generated by dipole moment could promote charge ***,three-dimensional hierarchical Cu Co_(2)S_(4)microspheres with lattice distortion were prepared,and lattice distortion was modulated by changing feed Co/Cu molar ratios in *** Co_(2)S_(4)showed asymmetric crystal structure,leading to generation of dipole *** charge separation efficiency of Cu Co_(2)S_(4)was related to lattice distortion,and lattice expansion was in favor for charge *** Cu Co_(2)S_(4)with feed Cu/Co molar ratio of 1:4 (CCS-4) showed the maximum lattice expansion and exhibited the highest photocatalytic activity,which was attributable to the highest charge separation efficiency and the largest specific surface ***-4 can remove 95.4%of tetracycline hydrochloride within 40 min photocatalysis,and effectively improve the biodegradability of pharmaceutical ***,this study provides a new vision for constructing single-component photocatalysts with high photocatalytic performance.

关键词： CuCo_(2)S_(4) Lattice distortion Visible-light photocatalysis Structure-activity relationship Biodegradability improvement

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Deep-Learning-Based Uncertainty-Estimation Approach for Unknown Traffic Identification

IEEE Transactions on Artificial Intelligence

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IEEE Transactions on Artificial Intelligence 2025年第3期6卷 533-548页

作者： Le, Siqi Lai, Yingxu Wang, Yipeng He, Huijie Beijing University of Technology Faculty of Information Technology Beijing100124 China Ministry of Education Engineering Research Center of Intelligent Perception and Autonomous Control Beijing100124 China

Real open network environments include the traffic generated by known applications or protocols, which have been previously identified and labeled, and unknown network traffic that cannot be identified based on existing knowledge. Accurately identifying unknown traffic is critical to network management and security, not only to help managers allocate bandwidth appropriately for all types of applications and ensure quality of service but also to prevent security breaches that may result from unknown applications or protocols. Notably, the unknown network traffic has been increasing with the emergence of new applications or protocols, which further increases the difficulty in identifying them. Existing unknown traffic classification methods based on Softmax output confidence values cause bias in the prediction probability due to overconfidence of the model during the training process, thus decreasing the identification accuracy. Thus, for unknown traffic identification, this study proposes a deep-learning-based uncertainty-estimation (EUE) approach. EUE introduces the theory of evidence to the task of identifying unknown traffic by inferring traffic uncertainty directly from traffic evidence without the need for a Softmax layer, thus avoiding overconfidence in the model. Thus, the EUE can accurately identify unknown traffic while classifying known traffic at the application level. We construct two experimental scenarios simulating the real network environments with different proportions of unknown traffic to evaluate EUE. The experimental results show that the proposed approach EUE exhibits excellent classification accuracy. © 2024 IEEE. All rights reserved.

关键词： Internet protocols

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Distributed Nash equilibrium seeking with order-reduced dynamics based on consensus exact penalty

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control Theory and Technology 2023年第3期21卷 363-373页

作者： Shu Liang Shuyu Liu Yiguang Hong Jie Chen The Department of Control Science and Engineering Tongji UniversityShanghai 201804China Shanghai Research Institute for Intelligent Autonomous Systems Shanghai 201210China

In this paper,we consider a networked game with coupled constraints and focus on variational Nash equilibrium *** distributed algorithm design,we eliminate the coupled constraints by employing local Lagrangian functions and construct exact penalty terms to attain multipliers'optimal consensus,which yields a set of equilibrium conditions without any coupled constraint and consensus ***,these conditions are only based on strategy and multiplier variables,without auxiliary ***,we present a distributed order-reduced dynamics that updates the strategy and multiplier variables with guaranteed *** with many other distributed algorithms,our algorithm contains no auxiliary variable,and therefore,it can save computation and communication.

关键词： Game theory Nash equilibrium seeking Distributed algorithm Coupled constraints Order-reduced dynamics

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Subspace Identification for Closed-Loop Systems With Unknown Deterministic Disturbances

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IEEE/CAA Journal of Automatica Sinica 2023年第12期10卷 2248-2257页

作者： Kuan Li Hao Luo Yuchen Jiang Dejia Tang Hongyan Yang IEEE Shanghai Aerospace Control Technology Institute Shanghai 201109China the Control and Simulation Center School of AstronauticsHarbin Institute of TechnologyHarbin 150006China the Faculty of Information Technology Engineering Research Center of Digital CommunityMinistry of EducationBeijing University of TechnologyBeijing 100124China

This paper presents a subspace identification method for closed-loop systems with unknown deterministic *** deal with the unknown deterministic disturbances,two strategies are implemented to construct the row space that can be used to approximately represent the unknown deterministic disturbances using the trigonometric functions or Bernstein polynomials depending on whether the disturbance frequencies are *** closed-loop identification,CCF-N4SID is extended to the case with unknown deterministic disturbances using the oblique *** addition,a proper Bernstein polynomial order can be determined using the Akaike information criterion(AIC)or the Bayesian information criterion(BIC).Numerical simulation results demonstrate the effectiveness of the proposed identification method for both periodic and aperiodic deterministic disturbances.

关键词： Bernstein polynomial closed-loop system subspace identification unknown deterministic disturbances

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Dynamic recrystallization behavior and strengthening mechanism of a novel Mo-Ti_(3)AlC_(2) alloy at ultrahigh temperature

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Rare Metals 2024年第8期43卷 3946-3960页

作者： Lu Yang Xin-Yuan Zheng Yang Zhao Xi-Ran Wang Fang-Nao Xiao Shi-Zhong Wei School of Materials Science and Engineering Henan University of Science and TechnologyLuoyang 471023China National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and TechnologyLuoyang 471003China Department of Applied Mechanics Univ.Bourgogne FrancheComteFEMTO-ST InstituteCNRS/UF/ENSMM/UTBM25000BesangonFrance

Increasing the recrystallization temperature to achieve better high-temperature performance is critical in the development of molybdenum alloys for ultrahightemperature applications,such as the newest generation of multitype high-temperature nuclear *** this study,an innovative strategy was proposed to improve the performance of molybdenum alloys at high temperature by using the two-dimensional MAX(where M is an early transition metal,A is an A-group element and X is C or N)ceramic material Ti_(3)AlC_(2).The relationships between flow stress,strain rate and temperature were *** microstructure,distribution of misorientation and evolution of dislocations in the Mo-Ti_(3)AlC_(2) alloy were *** microscopic mechanism of the Ti_(3)AlC_(2) phase in the molybdenum alloy at high temperatures was *** experimental results showed that the peak flow stress of Mo-Ti_(3)AlC_(2) at 1600℃ reached 155 MPa,which was161.8% greater than that of pure *** activation energy of thermal deformation of Mo-Ti_(3)AlC_(2) was as large as537 kJ·mol~(-1),which was 17.6% more than that of pure *** recrystallization temperature reached 1600℃ or even *** topological reaction of the Ti_(3)AlC_(2) phase consumed a large amount of energy at high temperatures,resulting in increases in the deformation activation *** structures of AlTi_3 and Ti-O Magneli-phase oxides(Ti_nO_(2n-1)) were formed in-situ,which relied on kink bands and interlayer slip,resulting in many dislocations during ***,the special two-dimensional of the structure Ti_(3)AlC_(2) ceramic inhibited the recrystallization behavior of the Mo *** results of this study can provide theoretical guidance for the development of a new generation of molybdenum alloys for use in ultrahigh-temperature environments.

关键词： Mo alloy Two-dimensional reinforcement Dynamic recrystallization behavior Hot deformation Mechanical properties

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On the Efficiency of Economic Activity of Small Enterprises Operating in the Field of Ground Passenger Transportation (Code 34 in All-Russian Classifier of Economic Activities OKVED2) 17

On the Efficiency of Economic Activity of Small Enterprises ...

引用

17th International Conference on Management of Large-Scale System Development, MLSD 2024

作者： Promakhina, Irina Federal Research Center 'Computer Science and Control' of the Ras Department of Information Systems Moscow Russia

ISBN: (纸本)9798350375718

The aim of the work was to identify factors affecting the total revenue of regional small enterprises operating in the field of ground passenger transportation, and to evaluate the efficiency of these enterprises. This was done using production function and stochastic frontier models. The statistics were taken from the Complete statistical survey of small and medium-sized businesses in 2020. © 2024 IEEE.

关键词： Economic efficiency

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Faithful geometric measures for genuine tripartite entanglement

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Physical Review A 2024年第1期110卷 L010402-L010402页

作者： Xiaozhen Ge Lijun Liu Yong Wang Yu Xiang Guofeng Zhang Li Li Shuming Cheng Department of Control Science and Engineering Department of Applied Mathematics The Department of Mathematics and Computer Science State Key Laboratory for Mesoscopic Physics School of Physics Frontiers Science Center for Nano-optoelectronics and Collaborative Innovation Center of Quantum Matter Shanghai Institute of Intelligent Science and Technology Institute for Advanced Study

We present a faithful geometric picture for genuine tripartite entanglement of discrete, continuous, and hybrid quantum systems. We first find that the triangle relation Ei|jkα≤Ej|ikα+Ek|ijα holds for all subadditive bipartite entanglement measure E, all permutations under parties i,j,k, all α∈[0,1], and all pure tripartite states. Then, we rigorously prove that the nonobtuse triangle area, enclosed by side Eα with 0<α≤1/2, is a measure for genuine tripartite entanglement. Finally, it is significantly strengthened for qubits that given a set of subadditive and nonsubadditive measures, some state is always found to violate the triangle relation for any α>1, and the triangle area is not a measure for any α>1/2. Our results pave the way to study discrete and continuous multipartite entanglement within a unified framework.

关键词： Entanglement measures Quantum correlations in quantum information Quantum correlations, foundations & formalism Resource theories

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Drosophila Larvae-Inspired Soft Crawling Robot with Multimodal Locomotion and Versatile Applications

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research 2025年第1期7卷 35-46页

作者： Qin Fang Jingyu Zhang Yinhui He Nenggan Zheng Yue Wang Rong Xiong Zhefeng Gong Haojian Lu State Key Laboratory of Industrial Control and Technology Zhejiang UniversityHangzhou 310027China Institute of Cyber-Systems and Control Zhejiang UniversityHangzhou 310027China Medical School of Zhejiang University Hangzhou 310027China College of Computer Science and Technology Zhejiang UniversityHangzhou 310027China Stomatology Hospital School of StomatologyZhejiang University School of MedicineZhejiang Provincial Clinical Research Center for Oral DiseasesKey Laboratory of Oral Biomedical Research of Zhejiang ProvinceCancer Center of Zhejiang UniversityEngineering Research Center of Oral Biomaterials and Devices of Zhejiang ProvinceHangzhou 310000China

Soft crawling robots have been widely studied and applied because of their excellent environmental adaptability and flexible ***,most existing soft crawling robots typically exhibit a single-motion mode and lack diverse *** by Drosophila larvae,this paper proposes a compact soft crawling robot(weight,13 g;length,165 mm;diameter,35 mm)with multimodal locomotion(forward,turning,rolling,and twisting).Each robot module uses 4 sets of high-power-density shape memory alloy actuators,endowing it with 4 degrees of motion *** analyze the mechanical characteristics of the robot modules through experiments and simulation *** plug-and-play modules can be quickly assembled to meet different motion and task *** soft crawling robot can be remotely operated with an external controller,showcasing multimodal motion on various material *** a narrow maze,the robot demonstrates agile movement and effective maneuvering around *** addition,leveraging the inherent bistable characteristics of the robot modules,we used the robot modules as anchoring units and installed a microcamera on the robot's head for pipeline *** robot completed the inspection in horizontal,vertical,curved,and branched pipelines,adjusted the camera view,and twisted a valve in the pipeline for the first *** research highlights the robot's superior locomotion and application capabilities,providing an innovative strategy for the development of lightweight,compact,and multifunctional soft crawling robots.

关键词： multimodal locomotion versatile applications Drosophila larvae soft crawling robot weight soft crawling robots shape memory alloy actuators

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