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Fabrication of La,Ce co-doped ZnO nanorods for improving photodegradation of methylene blue

Journal of Rare Earths 2024年第1期42卷 76-83,I0003页

作者： Erfan Hakim Azmal Zaid Jin-Chung Sin Sze-Mun Lam Abdul Rahman Mohamed School of Chemical Engineering Universiti Sains Malaysia(USM)14300Nibong TebalPenangMalaysia College of Environmental Science and Engineering Guilin University of TechnologyGuilin541004China Guangxi Key Laboratory of Theory and Technology for Environmental Pollution Control Guilin University of TechnologyGuilin541004China Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area Guilin University of TechnologyGuilin541004China Faculty of Engineering and Green Technology Universiti Tunku Abdul RahmanJalan UniversitiBandar Barat31900KamparPerakMalaysia

La,Ce co-doped ZnO nanorods(ZnLC)were synthesized through a one-step solvothermal *** photocatalysts were characterized by X-ray diffraction,Raman spectroscopy,field-emission scanning electron microscopy,energy dispersive X-ray,transmission electron microscopy,UV-vis diffuse reflectance spectroscopy and photo luminescence *** La and Ce doping enhanced the visible light absorption ability of ZnLC and a red shift was detected for *** simulated solar light irradiation,the ZnO doped with 3 at%La and 1 at%Ce(ZnLC1)degrades methylene blue(MB)more effectively than those of pure ZnO,La-doped ZnO(ZnL)and commercially available *** improved photocatalytic performance of ZnLC1 can be attributed to the high charge separation efficiency as demonstrated by the photoluminescence ***,the photocatalytic experiments reveal that several parameters have their own impact on the MB *** a variety of radical scavengers,it is discovered that superoxide anion radical plays a crucial role in the degradation of *** ZnLC1 is also reused several times without noticeable decrease of photoactivity,indicating that it has a substantial potential for environmental remediation applications.

关键词： ZnO Lanthanum Cerium Co-doping Photodegradation Rare earths

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Effectiveness of Precursor Emission Reductions for the control of Summertime Ozone and PM2.5 in the Beijing–Tianjin–Hebei Region under Different Meteorological Conditions

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Advances in Atmospheric Sciences 2025年第4期42卷 653-669页

作者： Jing QIAN Hong LIAO Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044JiangsuChina

We used observed concentrations of air pollutants,reanalyzed meteorological parameters,and results from the Goddard Earth Observing System Chemical Transport Model to examine the relationships between concentrations of maximum daily 8-h average ozone(MDA8 O_(3)),PM_(2.5)(particulate matter with diameter of 2.5μm or less),and PM_(2.5)components and 2-m temperature(T2)or relative humidity(RH),as well as the effectiveness of precursor emission reductions on the control of O_(3) and PM_(2.5) in Beijing–Tianjin–Hebei(BTH)under different summertime temperature and humidity *** observed(simulated)MDA8 O_(3) and PM_(2.5) concentrations increased as T2 went up,with linear trends of 4.8(3.2)ppb℃^(−1) and 1.9(1.5)μg m^(−3)℃^(−1),*** results showed that the decreases in MDA8 O_(3) from precursor emission reductions were more sensitive to T2 than to *** a larger proportion of volatile organic compound(VOC)emissions at higher T2 was more effective for the control of summertime O_(3) in *** the control of summertime PM_(2.5) in BTH,reducing nitrogen oxides(NOx)combined with a small proportion of VOCs was the best *** magnitude of reduction in PM_(2.5) from reducing precursor emissions was more sensitive to RH than to T2,with the best efficiency at high *** from this study are helpful for formulating effective policies to tackle O_(3) and PM_(2.5) pollution in BTH.

关键词： ozone PM_(2.5) emission reductions meteorological conditions

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Novel Ag-bridged dual Z-scheme g-C_(3)N_(4)/BiOI/AgI plasmonic heterojunction: Exceptional photocatalytic activity towards tetracycline and the mechanism insight

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Journal of environmental Sciences 2023年第9期131卷 123-140页

作者： Wenxia Wang Zhen Li Kailin Wu Guodong Dai Qingping Chen Lihua Zhou Junxia Zheng Liang Ma Guiying Li Wanjun Wang Taicheng An School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Guangzhou Key lab of Clean Transport Energy and Chemistry Guangdong University of TechnologyGuangzhou 510006China Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control Guangdong Technology Research Center for Photocatalytic Technology Integration and Equipment EngineeringSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Rational design and synthesis of highly efficient and robust photocatalysts with positive exciton splitting and interfacial charge transfer for environmental applications is ***,aiming at overcoming the common shortcomings of traditional photocatalysts such as weak photoresponsivity,rapid combination of photo-generated carriers and unstable structure,a novel Ag-bridged dual Z-scheme g-C_(3)N_(4)/BiOI/AgI plasmonic heterojunction was successfully synthesized using a facile *** showed that Ag-AgI nanoparticles and three-dimensional(3D)BiOI microspheres were decorated highly uniformly on the 3D porous g-C_(3)N_(4) nanosheet,resulting in a higher specific surface area and abundant active *** optimized 3D porous dual Z-scheme g-C_(3)N_(4)/BiOI/Ag-AgI manifested exceptional photocatalytic degradation efficiency of tetracycline(TC)in water with approximately 91.8%degradation efficiency within 165 min,outperforming majority of the reported g-C_(3)N_(4)-based ***,g-C_(3)N_(4)/BiOI/Ag-AgI exhibited good stability in terms of activity and ***-depth radical scavenging and electron paramagnetic resonance(EPR)analyses confirmed the relative contributions of various *** analysis indicated that the improved photocatalytic performance and stability were ascribed to the highly ordered 3D porous framework,fast electron transfer of dual Z-scheme heterojunction,desirable photocatalytic performance of BiOI/AgI and synergistic effect of Ag ***,the 3D porous Z-scheme g-C_(3)N_(4)/BiOI/Ag-AgI heterojunction had a good prospect for applications in water *** current work provides new insight and useful guidance for designing novel structural photocatalysts for environment-related applications.

关键词： Three-dimensional Porous heterostructure Graphitic carbon nitride(g-C_(3)N_(4)) Dual Z-scheme heterojunction Tetracycline(TC)degradation Mechanism insight

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Efficient photocatalytic NADH regeneration with Rh-loaded Z-scheme mediator-free system

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Chinese Chemical Letters 2024年第2期35卷 496-500页

作者： Yi Zhou Yiling He Ming Gao Ningkai Ding Juying Lei Yanbo Zhou State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery East China University of Science and TechnologyShanghai 200237China Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Nicotinamide adenine dinucleotide(NADH)regeneration is necessary for the sustainable application of enzymatic *** Rh-based complex[Cp^(*)Rh(bpy)(H)]+has been widely used as an important mediator in NADH regeneration systems,but it is limited by complexity and high ***,a Z-scheme was constructed by loading Rh onto carbon nitride nanosheets/carbon nitride quantum dots(CN-CNQD).The resultant catalyst achieved a high yield of NADH in a mediator-free(M-free)system of 0.283 mmol L^(−1) g^(−1) min^(−1),which is 5.29 times that of pure *** enzyme introduction experiments confirmed that the enzyme active product 1,4-NADH could reach 34.21%selectivity in the M-free *** research revealed that the heterojunction between CNs and CNQDs improved the NADH regeneration activity in the traditional M-involved system,while Rh loading was proved to optimize the yield and selectivity of 1,4-NADH in M-free *** immobilized Rh shows more competitiveness than[Cp^(*)Rh(bpy)(H)]^(+).This study contributes to the construction of an M-free system for further application in greener,lower-cost enzymatic processes.

关键词： Photocatalysis NADH regeneration Mediator-free Carbon nitride Z-scheme

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Dual-selective silver recovery strategy by simultaneous adsorption-reduction boosted by in-situ magnetic field

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Green Energy & Environment 2025年第2期10卷 433-440页

作者： Jianran Ren Zhiliang Zhu Yanling Qiu Fei Yu Tao Zhou Jie Ma Jianfu Zhao Research Center for Environmental Functional Materials State Key Laboratory of Pollution Control and Resource ReuseCollege of Environmental Science and EngineeringTongji UniversityShanghai200092China School of Civil Engineering Kashi UniversityKashi844000China College of Marine Ecology and Environment Shanghai Ocean UniversityShanghai201306China

The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated ***,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation *** achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic *** recovered silver crystals could be directly physically exfoliated,without acid/base *** selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective *** in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional ***,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective ***-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery *** study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.

关键词： In-situ magnetic field Silver recovery Adsorption-reduction Selectivity Physical separation

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Simultaneous removal of Cd(Ⅱ)and As(Ⅴ)by ferrihydrite-biochar composite:Enhanced effects of As(Ⅴ)on Cd(Ⅱ)adsorption

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Journal of environmental Sciences 2024年第5期139卷 267-280页

作者： Wenjun Zeng Yang Lu Jingyan Zhou Jie Zhang Yuanxiao Duan Changxun Dong Wencheng Wu College of Sciences Nanjing Agricultural UniversityNanjing 210095China South China Institute of Environmental Sciences Ministry of Ecology and EnvironmentGuangzhou 510655China Guangdong Engineering&Technology Research Center for System Control of Livestock and Poultry breeding Pollution Guangzhou 510655China

The coexistence of cadmium(Cd(Ⅱ))and arsenate(As(Ⅴ))pollution has long been an environmental ***,a porous carbonaceous material with tunable functionality,has been used for the remediation of contaminated ***,it is still challenging for the dynamic quantification and mechanistic understanding of the simultaneous sequestration of multi-metals in biochar-engineered environment,especially in the presence of *** this study,ferrihydrite was coprecipitated with biochar to investigate how ferrihydritebiochar composite affects the fate of heavy metals,especially in the coexistence of Cd(Ⅱ)and As(Ⅴ).In the solution system containing both Cd(Ⅱ)and As(Ⅴ),the maximum adsorption capacities of ferrihydrite-biochar composite for Cd(Ⅱ)and As(Ⅴ)reached 82.03μmol/g and 531.53μmol/g,respectively,much higher than those of the pure biochar(26.90μmol/g for Cd(Ⅱ),and 40.24μmol/g for As(Ⅴ))and ferrihydrite(42.26μmol/g for Cd(Ⅱ),and 248.25μmol/g for As(Ⅴ)).Cd(Ⅱ)adsorption increased in the presence of As(Ⅴ),possibly due to the changes in composite surface charge in the presence of As(Ⅴ),and the increased dispersion of ferrihydrite by *** microscopic and mechanistic results showed that Cd(Ⅱ)complexed with both biochar and ferrihydrite,while As(Ⅴ)was mainly complexed by ferrihydrite in the Cd(Ⅱ)and As(Ⅴ)coexistence *** posed vital importance for the co-adsorption of Cd(Ⅱ)and As(Ⅴ).The different distribution patterns revealed by this study help to a deeper understanding of the behaviors of cations and anions in the natural environment.

关键词： Ferrihydrite Biochar Cadmium Arsenate Simultaneous sequestration Binding mechanisms

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Experimental observation of fine secular frequency resonance oscillation with a rectilinear ion trap mass spectrometer

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Chinese Journal of Chemical Physics 2024年第6期37卷 792-796,I0042页

作者： Lixin Shan Zuojian Zhang Zhiyang Wei Yongze Gao Zhiyuan Luo Shiyu Cheng Jinian Shu Research Center for Environmental Material and Pollution Control Technology University of Chinese Academy of SciencesBeijing 101408China National Engineering Laboratory for VOCs Pollution Control Material&Technology Beijing 101408China

The mass resolution of the ordinary ion trap mass spectrometer derived from the quadrupole mass spectrometer usually ranges from hundreds to *** this study,the fine secular frequency resonance oscillation was observed with a rectilinear ion trap mass *** FWHM of the responding resonance secular frequency of benzene was 0.012 *** corresponding mass resolution was 8600 m/Δm for benzene(m/z=78).The mass spectrometer with secular frequency scanning has a linear response to benzene in the concentration range from 200 ppbv to 10000 *** study shows a new feature of the secular frequency scanning for ion trap mass spectrometers.

关键词： Fine secular frequency Resonance oscillation Mass resolution Rectilinear ion trap mass spectrometer

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Advanced modeling of the absorption enhancement of black carbon particles in chamber experiments by considering the morphology and coating thickness

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Frontiers of environmental Science & engineering 2024年第9期18卷 129-142页

作者： Xiaodong Wei Jianlin Hu Chao Liu Xiaodong Xie Junjie Yin Song Guo Min Hu Jianfei Peng Huijun Wang Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters Key Laboratory of Meteorological Disaster(Ministry of Education)Nanjing University of Information Science and TechnologyNanjing 210044China Nansen−Zhu International Research Centre Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China East China Air Traffic Management Bureau CAAC Shanghai 200335China State Key Joint Laboratory of Environmental Simulation and Pollution Control International Joint Laboratory for Regional Pollution Control(IJRC)(Ministry of Education)College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Tianjin Key Laboratory of Urban Transport Emission Research&State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control College of Environmental Science and EngineeringNankai UniversityTianjin 300071China

Measurements studies have shown that the absorption of radiation by black carbon(BC)increases as the particles ***,there are significant discrepancies between the measured and modeled absorption enhancement(E_(abs)),largely due to the simplifications used in modeling the mixing states and shape *** took advantage of chamber experiments on BC aging and developed an efficient method to resolve the particle shape based on the relationship between the coating fraction(ΔD_(ve)/D_(ve),0)and fractal dimension(D_(f)),which can also reflect the variations of D_(f)during the whole BC aging *** with externally and partly mixed states(0≤ΔD_(ve)/D_(ve),0≤0.5)can be considered to be uniformly distributed with the D_(f)values of 1.8–2.1,whereas the Df values are constrained in the range 2.2–2.8 for fully mixed states(ΔD_(ve)/D_(ve),0>0.5).The morphological parameters(i.e.,the effective density and the dynamic shape factor)were compared with the measured values to verify the simulated *** simulated mean deviations of morphological parameters were smaller than 8%for the method resolving the particle *** applying a realistic shape and refractive index,the mass absorption cross for fully mixed states can be improved by 11%compared with a simplified core–shell *** on our understanding of the influence of D_(f)andΔD_(ve)/D_(ve),0 on E_(abs),we propose a two-stage calibration equation to correct the E_(abs)values estimated by the core–shell model,which reduces the simulation error in the Mie calculation by 6%–14%.

关键词： Black carbon Mixing states Fractal dimension Dynamic shape factor Absorption enhancement

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Synergistically enhancing nitrate reduction into N_(2)in water by N-doped Pd-Cu biochar bimetallic single-atom electrocatalysis

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Biochar 2024年第1期6卷 114-131页

作者： Lihao Zhang Yuqing Wu Zongqiang Zhu Yinian Zhu Yi Dong Meina Liang Huan Deng College of Environmental Science and Engineering Guilin University of TechnologyGuilin 541006People’s Republic of China. Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology Guilin 541006People’s Republic of China. Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area Guilin University of TechnologyGuilin 541006People’s Republic of China Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100035People’s Republic of China.

Noble metal materials have been identified as high efficiency catalysts for electrocatalytic reduction of nitrate,and the synthesis and manufacture of high catalytic activity and environmentally friendly catalysts of activating hydrogen for water purification applications is extremely *** this work,the Pd-Cu single-atom catalysts(Pd-Cu-N-BC)were first prepared by direct growth of Pd-Cu single-atom on bamboo biochar by regulating the concentration of precursors and doping method,and then enhanced electrocatalytic reduction nitrate performance and N2 *** results showed that Pd-Cu-N-BC displayed excellent catalytic activity and reusability in electrocatalytic reduction nitrate with a low potential of 0.47 V ***(@10 mA cm−2).The maximum nitrate removal efficiency and N2 generation could reach about 100%and 72.32%within 180 min,*** density functional theory(DFT)calculations confirmed that Cu atoms could catalyze the electrochemical reduction of nitrate to nitrite,and Pd atoms anchored in the nitrogen-doped biochar(N-BC)lattice could catalyze electrochemical reduction of nitrite to N2 involving the formation of hydrogen radical(H*).The characterization results of XANES showed that electronic synergistic effect between Pd and Cu single atoms significantly promotes the N2 production through hydrogenation while inhibiting the generation of byproducts,leading to significantly enhanced electrocatalytic reduction of nitrate to ***,Pd-Cu-N-BC was designed as a 3D particle electrode for enhanced electrocatalytic reduction of nitrate,exhibiting excellent stability and reusability,which could be considered as a suitable candidate for applications in the remediation of nitrate contamination.

关键词： Bamboo biochar Single atom catalyst Electrocatalytic denitration Hydrogen evolution reaction Density functional theory

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A hybrid fuel cell for water purification and simultaneously electricity generation

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Frontiers of environmental Science & engineering 2023年第1期17卷 121-132页

作者： Yujun Zhou Qinghua Ji Chengzhi Hu Huijuan Liu Jiuhui Qu Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China

The development of highly efficient energy conversion technologies to extract energy from wastewater is urgently needed,especially in facing of increasing energy and environment ***,we successfully fabricated a novel hybrid fuel cell with BiOCl-NH_(4)PTA as *** polyoxometalate(NH_(4)PTA)act as the acceptor of photoelectrons and could retard the recombination of photogenerated electrons and holes,which lead to superior photocatalytic *** utilizing BiOCl-NH_(4)PTA as photocatalysts and Pt/C air-cathode,we successfully constructed an electron and mass transfer enhanced photocatalytic hybrid fuel cell with flow-through field(F-HFC).In this novel fuel cell,dyes and biomass could be directly degraded and stable power output could be *** 87%of dyes could be degraded in 30 min irradiation and nearly 100%removed within 90 *** current density could reach up to~267.1μA/cm^(2);with maximum power density(Pmax)of~16.2μW/cm^(2) with Rhodamine B as organic pollutant in *** power densities were 9.0μW/cm^(2),12.2μW/cm^(2),and 13.9μW/cm^(2) when using methyl orange(MO),glucose and starch as substrates,*** hybrid fuel cell with BiOCl-NH_(4)PTA composite fulfills the purpose of decontamination of aqueous organic pollutants and synchronous electricity ***,the novel design cell with separated photodegradation unit and the electricity generation unit could bring potential practical application in water purification and energy recovery from wastewater.

关键词： Flow-through field Hybrid fuel cell Polyoxometalates Water purification Electricity generation

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